1. Damage reduction and sealing of low-k films by combined He and NH3 plasma treatment
- Author
-
Urbanowicz, Adam, Baklanov, MR, Heijlen, J, Travaly, Y, and Cockburn, A
- Subjects
ellipsometric porosimetry ,radiation ,low dielectric-constant ,sio2 ,reflectivity - Abstract
Modification of chemical vapor deposition low-k films upon sequential exposure to helium plasma and then ammonia plasma is characterized using various methods. The He plasma emits extreme ultraviolet (EUV) photons creating O-2 vacancies, which impacts surface reactive sites and induces localized chemical modifications in the first surface monolayers. The subsequent NH3 plasma treatment provides complete sealing of the low-k surface. The depth of the modification, which is a factor of merit of the sealing process, is limited because of the high absorption coefficient of silica-based low-k materials in the range of EUV emission. (C) 2007 The Electrochemical Society. ispartof: Electrochemical and Solid-State Letters vol:10 issue:10 status: published
- Published
- 2007