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A second K/Pg boundary interval in the northern sector of the Antarctic Peninsula on Vega Island has been proposed, yet current temporal resolution of these strata prohibits direct testing of this hypothesis. To not only test for the existence of a K/Pg boundary on Vega Island but also provide increased age resolution for the associated vertebrate fauna (e.g., marine reptiles, non-avian dinosaurs, and avian dinosaurs), the Vega Island succession was intensively re-sampled. Stratigraphic investigation of the Cape Lamb Member of the Snow Hill Island Formation, and in particular, the overlying Sandwich Bluff Member of the López de Bertodano Formation, was conducted using biostratigraphy, strontium isotope stratigraphy, magnetostratigraphy, and detrital zircon geochronology. These data indicate a Late Campanian–early Maastrichtian age for the Cape Lamb Member and present three possible correlations to the global polarity time scale (GPTS) for the overlying Sandwich Bluff Member. The most plausible correlation, which is consistent with biostratigraphy, detrital zircon geochronology, sequence stratigraphy, and all but one of the Sr-isotope ages, correlates the base of the section to C31N and the top of the section with C29N, which indicates that the K/Pg boundary passes through the top of the unit. A second, less plausible option conflicts with the biostratigraphy and depends on a series of poorly defined magnetic reversals in the upper part of the stratigraphy that also correlates the section between C31N and C29R and again indicates an inclusive K/Pg boundary interval. The least likely correlation, which depends on favoring only a single Srisotope age at the top of the section over biostratigraphy, correlates the section between C31N and C30N and is inconsistent with an included K/Pg boundary interval. Although our preferred correlation is well supported, we failed to identify an Ir-anomaly, spherules/impact ejecta, or other direct evidence typically used to define the precise position of a K/Pg boundary on Vega Island. This study does, however, confirm that Vegavis, from the base of the Sandwich Bluff Member, is the oldest (69.2–68.4 Ma) phylogenetically placed representative of the avian crown clade, and that marine vertebrates and non-avian dinosaurs persisted in Antarctica up to the terminal Cretaceous.

Carbon dioxide release during Deccan Traps volcanism and the Chicxulub impact likely contributed to the Cretaceous-Paleogene (K-Pg) mass extinction; however, the intensity and duration of CO2 input differed between the two events. Large and rapid addition of CO2 to seawater causes transient decreases in pH, [CO32–], and carbonate mineral saturation states. Compensating mechanisms, such as dissolution of seafloor sediment, reduced biomineralization, and silicate weathering, mitigate these effects by increasing the same parameters. The calcium isotope ratios (δ44/40Ca) of seawater and marine carbonates are hypothesized to respond to these perturbations through weathering/carbonate deposition flux imbalances and/or changes in fractionation between carbonate minerals and seawater. We used a high-precision thermal ionization mass spectrometry method to measure δ44/40Ca values of aragonitic bivalve and gastropod mollusk shells from the K-Pg interval of the López de Bertodano Formation on Seymour Island, Antarctica. Well-preserved shells spanning the late Maastrichtian (ca. 67 Ma) to early Danian (ca. 65.5 Ma) have δ44/40Ca values ranging from −1.89‰ to −1.57‰ (seawater [sw]). Shifts in δ44/40Ca inversely correlate with sedimentological indicators of saturation state. A negative excursion begins before and continues across the K-Pg boundary. According to a simple mass-balance model, neither input/output flux imbalances nor change in the globally integrated bulk carbonate fractionation factor can produce variations in seawater δ44/40Ca sufficient to explain the measured trends. The data are consistent with a dynamic molluscan Ca isotope fractionation factor sensitive to the carbonate geochemistry of seawater. The K-Pg extinction appears to have occurred during a period of carbonate saturation state variability caused by Deccan volcanism.

Recent magnetostratigraphic works from different areas of the James Ross Basin have expanded on chronostratigraphic studies previously based on ammonite, palynomorph and nanoplankton biostratigraphy, and strontium isotope stratigraphy. Here we present a new magnetostratigraphy of Coniacian through Campanian marine sedimentary rocks from Hidden Lake, Santa Marta and Snow Hill Island Formations, on northwest James Ross Island. A total of 189 paleomagnetic directions were obtained along more than 1500 m of stratigraphic thickness from Brandy Bay to Santa Marta Cove areas, identifying three polarity chrons of the global polarity time scale. The local magnetostratigraphic column starts in the upper part of the Cretaceous Normal Superchron C34N (Coniacian) and ends in Chron C33N (middle Campanian). The correlation between the magnetostratigraphy and the age framework given by ammonite biostratigraphy allowed the assignment of precise ages to particular horizons of the Santa Marta Formation. The newly identified geomagnetic polarity reversals are the earliest identified in the James Ross Basin and include: a) C34N/C33R (84.2 Ma, late Santonian – early Campanian) in the Alpha Member of the Santa Marta Formation and b) C33R/C33N (79.9 Ma, middle Campanian) in the upper Beta Member (Santa Marta Formation). By integrating this new data with previous work, we present a complete Upper Cretaceous – lowermost Paleogene chronostratigraphical framework for the basin, spanning both proximal to distal sedimentary facies of the Marambio Group.

Day Nunatak exposes an actively emergent stratigraphic section located on Snow Hill Island to the east of the Antarctic Peninsula. Strata exposed on Snow Hill Island were deposited in the James Ross Basin, which includes marine units of Cretaceous–Paleogene (K–Pg) age. Here we provide the first report of the sedimentology and paleontology of Day Nunatak, and place it into the broader stratigraphic context of the basin. Day Nunatak was previously unexplored due to difficulties accessing the site, and the historically poor exposure which has recently improved due to warming of the Antarctic Peninsula. Deposits exposed at Day Nunatak are assigned to the Karlsen Cliffs Member (KCM) of the Snow Hill Island Formation, and are better preserved than deposits at the type section of the KCM at Karlsen Cliffs, which has been altered by cross-cutting basaltic dikes. Correlation of lithostratigraphic and biostratigraphic data from Day Nunatak with other outcrops in the basin allows the section to be placed within a previously developed stratigraphic framework, and assigned an early Maastrichtian age. Our observations, and previous descriptions of the KCM, are consistent with a middle- to inner-shelf depositional environment below storm-wave base. Ammonites of the genus Gunnarites are very common, with other ammonite genera and benthic mollusks an order of magnitude less common. Stable carbon and oxygen isotope values obtained from bivalve shells are similar to values previously reported from Seymour Island, and suggest seawater temperatures of ∼7 °C. Measured bedding orientations suggest the presence of a structural offset between Day Nunatak and other sections exposed further north on Snow Hill Island. Day Nunatak preserves a similar depositional environment to deposits reported from the uppermost Maastrichtian on Seymour Island, and is the deeper-water equivalent of contemporaneous proximal sections reported from Vega Island.

The Cretaceous-Paleogene boundary (KPB) in the Hell Creek area of Montana is recognized in several places by an iridium anomaly, which is typically identified at or very near the lithological contact between the Hell Creek Formation and the Tullock Member of the Fort Union Formation. Previous work in the area has argued that organic carbon isotope (δ13Corg) excursions can be used for chemostratigraphic correlation within these continental depositional environments, most importantly for the identification of the KPB where impact evidence is unavailable. However, it is unclear how modern surficial weathering affects δ13Corg values, particularly in terrestrial depositional settings, and whether standard sampling methods are sufficient to obtain unaltered rock material. We tested the fidelity of the terrestrial δ13Corg record with respect to surficial alteration and contamination through investigation of different field sampling techniques, including hand trenches, a backhoe-excavated trench, and sediment coring. We find that δ13Corg values in hand and backhoe trenched sections are more positive than δ13Corg values in cored sections, implying that modern surficial alteration affects δ13Corg values but not overall trends. A negative δ13Corg excursion associated with the KPB is present in most sections we analyzed, but it does not appear to be unique within our sections. The KPB excursion occurs within a coal layer, and we observe similar excursions within other carbon-rich lithologies. Given that we cannot disentangle local lithological effects from global atmospheric changes, we conclude that a negative δ13Corg excursion is not an unequivocal indicator of the KPB in the Hell Creek area.

Warming events observed in paleotemperature proxy records within 500 kyr of the Cretaceous–Paleogene (K–Pg) boundary have often been attributed to atmospheric CO 2 increases due to Deccan Traps flood volcanism. Currently, there is uncertainty in the size, nature, and timing of the Deccan eruptions, all of which lead to uncertainty in the likely climatic effects. Modeling the impact of Deccan Traps eruption on climate is complicated by the discrepancy between the lifetimes of emitted gasses and the length of the total eruptive sequence. Though SO 2 emissions can have important climatic effects, the short atmospheric lifetimes of SO 2 and resulting aerosols mean these effects are unlikely to be recognized in the proxy record. Here we focus on the CO 2 emissions, and attempt to match paleotemperature proxy records with plausible emissions scenarios. We also test the relevance for climate of the number, length, and arrangement (e.g., increasing or decreasing size) of individual eruptions as well as the total duration and size of the overall eruptive sequence. We find that the number and length of individual eruptions are largely unimportant to CO 2 -based based climate effects, but that the pattern and duration of eruption have measureable effects. Unsurprisingly, the total emitted CO 2 from the Deccan Traps exerts a strong control on climatic effects, and better constraints on the volume of emitted gas are necessary. At the high end of the uncertainty range, the Deccan Traps eruptions are capable of generating warming events recorded in the proxy record, but rates of silicate weathering above modern rates are necessary to draw down CO 2 in accordance with those records.

Two paleomagnetic poles of 80 and 75 Ma have been computed from 191 to 123 paleomagnetic samples, respectively, of the marine sedimentary units of the Upper Cretaceous Marambio Group exposed in the James Ross Island, Antarctic Peninsula. Paleomagnetic behaviors during stepwise thermal demagnetization and rock magnetic analyses indicate that magnetization is likely primary and carried by SD-PSD detrital titanomagnetite. Application of an inclination shallowing correction by the elongation-inclination method yielded a significant inclination shallowing affecting the older (ca. 80 Ma) succession exposed in the northwest area of the island. However, the paleomagnetic directions computed from the younger (ca. 75 Ma) succession outcropping in the southeast corner of the island yielded an indeterminate result using the same analysis. The inclination shallowing-corrected 80 Ma paleopole position plus previous ones of ca.110, 90 and 55 Ma were used to construct the Apparent Polar Wander Path (APWP) for the Antarctic Peninsula during the Late Cretaceous-Paleocene. This path confirms that oroclinal bending of the Antarctic Peninsula as well as relative displacement with respect to East Antarctica are negligible since 110 Ma. Comparison with the apparent polar wander path for South America for the 130-45 Ma period suggests that this continent and the Antarctic Peninsula kept a very similar relative paleogeographic position since 110 Ma until 55 Ma, which likely meant a physical link between both continental masses. During that period, both continents underwent a relatively fast southward displacement of around 7° and a clockwise rotation relative to the Earth spin axis that can be bracketed between around 100 and 90 Ma. Oroclinal bending of the Fuegian Andes was likely due to tectonic interactions between the Patagonian-Fuegian Andes and the Antarctic Peninsula promoted, at least partially, by such displacements. By 55 Ma the Antarctic Peninsula probably was starting or about to start its final separation from South America. Fil: Milanese, Florencia Nidia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Geociencias Básicas, Aplicadas y Ambientales de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Geociencias Básicas, Aplicadas y Ambientales de Buenos Aires; Argentina Fil: Rapalini, Augusto Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Geociencias Básicas, Aplicadas y Ambientales de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Geociencias Básicas, Aplicadas y Ambientales de Buenos Aires; Argentina Fil: Slotznick, Sarah P.. University of California at Berkeley; Estados Unidos Fil: Tobin, Thomas S.. University of Alabama at Birmingahm; Estados Unidos Fil: Kirschvink, Joseph. Tokyo Institute Of Technology; Japón Fil: Olivero, Eduardo Bernardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Austral de Investigaciones Científicas; Argentina

Cape Marsh, located on the eastern end of Robertson Island to the east of the Antarctic Peninsula, exposes an isolated outcrop of Upper Cretaceous sedimentary strata. The outcrop is approximately 120 km southwest of the much better-studied exposures of similar age on and around James Ross Island (JRI); as such, its remoteness has complicated logistical access to the site and hindered geologic correlations on a regional scale. Here we present the results of fieldwork conducted in 2016 that yielded a more diverse invertebrate fossil assemblage than had been previously recognized, in addition to new U–Pb detrital zircon and magnetostratigraphic data. The invertebrate fauna, particularly the ammonites and inoceramids, support a biostratigraphic correlation of the upper Cape Marsh strata to Ammonite Assemblage 7 previously established on JRI. Detrital zircon U–Pb analysis conducted on a sandstone sample from the same strata indicates a maximum depositional age of 74.2 ± 1.1 Ma, and magnetostratigraphic interpretation of the lower strata suggest a normal magnetochron. These results are all consistent with a Campanian age for the deposition of the upper strata at Cape Marsh, and deposition during magnetochron C33N for the lower layers. However, a slight age inconsistency between the biostratigraphic correlation and the detrital zircon-derived maximum depositional age may imply that the fossils are reworked. Regardless, these new data allow us to correlate the strata at Cape Marsh to the Santa Marta and Rabot formations (or possibly the lower part of the Snow Hill Island Formation) in the northern part of the James Ross Basin.

Ammonites are one of the most common fossils of the Mesozoic, but there is little consensus on their mode of life. Isotopic studies have been used to reconstruct their preferred water temperature from δ 18 O measurements, but δ 13 C values have more ambiguous interpretations. Previous studies have recorded population differences in δ 13 C values between ammonite and benthic organisms without explaining the cause in detail. Here we examine a molluscan community from Seymour Island, Antarctica and find a 4‰ carbon isotope offset between ammonites and other benthic mollusks. The most likely cause of this anomaly is an increased metabolic carbon contribution to ammonite shell material when compared with other mollusks, but we cannot rule out the possibility of a methane seep contribution. Increased respired CO 2 production could be generated by a more active lifestyle and increased energy demands, which may have increased the susceptibility of ammonites to the end Cretaceous mass extinction.

The Cretaceous-Paleogene (K-Pg) mass extinction has been attributed to the impact of a large bolide at the end of the Cretaceous Period, although other potential causes have also been proposed, most notably climate change caused by Deccan Traps (India) flood volcanism. Reconstructing paleoclimate, particularly in terrestrial settings, has been hindered by a lack of reliable proxies. The recent development of carbonate clumped isotope paleothermometry has contributed to temperature reconstructions using geochemical proxies in terrestrial settings. We employ this method, along with new stratigraphic constraints, in the Hell Creek (Cretaceous) and overlying Fort Union (Paleogene) Formations (Montana, USA) to examine changes in temperature leading to and across the K-Pg boundary. We demonstrate that well-preserved ca. 66 Ma aragonitic bivalves serve as suitable paleoclimate archives. Although there are limitations in the stratigraphic availability of fossil bivalves for clumped isotope analysis, we record an apparent 8 °C decrease in summer temperatures over the last 300 k.y. of the Cretaceous that corresponds broadly with patterns observed in other paleotemperature proxies. This observed decrease plausibly could be explained by an absolute temperature decrease or by other environmental stresses on the organisms, but in either case suggests changing living conditions over the interval. Previously documented declines in vertebrate and invertebrate biodiversity occur over the same stratigraphic interval at this study location. These results are consistent with published models of the end-Cretaceous mass extinction in which destabilized ecosystems become more susceptible to an abrupt event like a bolide impact.

Deccan Traps continental flood basalt eruptions spanned the Cretaceous-Paleogene mass extinction, erupting over a million cubic kilometers of basalt over a total duration of approximately a million years. The environmental consequences of flood basalt eruptions depend on the timing and amount of volatile release; eruption rates are thus needed to evaluate their potential to cause climate change. Radioisotopic dates are not currently sufficient to resolve sub-ten thousand year eruptive tempos, necessary for constraining the effects of short-lifetime volatiles including sulfur dioxide. Recent studies have demonstrated that increases in mercury concentration in sedimentary records correlate with flood basalt eruptions under some circumstances. However, mercury concentrations have primarily been used to show the presence or absence of flood basalt eruptions. We show that this proxy can be used to quantitatively estimate eruptive rates using a mercury geochemical cycle framework. We illustrate this using new mercury chemostratigraphic records from terrestrial Cretaceous-Paleogene boundary sections in eastern Montana, USA, with multiple high-resolution chronologic constraints. We estimate that Deccan eruptions lasted on the order of centuries and released 500–3000 megagrams (Mg) of mercury per year, corresponding to ∼50–250 km3/a of lava. The box model framework highlights the importance of carefully accounting for differences in sedimentation rate and sampling resolution when comparing mercury records from different locations and depositional environments. While there are uncertainties in the box model estimates due to possible variation in flood basalt mercury emissions and sedimentation rates, they provide a useful framework to quantitatively evaluate the global mercury budget change indicated by changing concentration in sedimentary records. Eruptions of the estimated size would have released enough SO2, if it reached the stratosphere, to cause significant cooling for the duration of the eruption. However, given our constraints on the duration of individual eruptions, these colder periods are likely too brief to be clearly visible in most existing paleoclimate records.

New biostratigraphic data obtained from measured stratigraphic sections of Santonian through Maastrichtian age located along the west coast of North America necessitate changes to the currently accepted chronostratigraphic framework for this region of the North Pacific biotic province. We recognize and/or define 12 molluscan zones over this interval of the Upper Cretaceous and propose revisions to the currently accepted integration of ammonite zones with global Upper Cretaceous magnetochrons. Our findings demonstrate that there was significantly more faunal interchange between the North American Pacific Coast and both the Western Interior and Gulf Coast regions of North America during the Late Cretaceous than has previously been recognized, and because of this, novel and direct biostratigraphic correlations can be made. These new faunal correlations are augmented with the magnetostratigraphic record from Pacific Coast localities to arrive at better interregional correlation for the Upper Cretaceous globally. The new integration of the global polarity time scale with the local, west coast ammonite zonation now allows better correlation between sections both within the North Pacific province (but geographically far from our study areas) as well as to sections outside of the province itself. However, we note here that previous correlations between biostratigraphy and the top and bottom of magnetochron 33r in west coast North American sections appear to have been in error due to unrecognized, modern-day normal-field overprint of originally reversed polarity in Upper Cretaceous sections. We reinterpret the position of this chron based on this new information.

Isotopic analysis of carbonate material has been greatly facilitated by the development of autosampling devices such as the Kiel III Carbonate Device, allowing rapid automated analysis of small sample sizes. This analysis is facilitated by holding samples and acid at temperatures around 70 °C prior to reaction. In most situations this has no measurable effect on sample powders on practical timeframes, but, when analyzing exceptionally fine-grained material produced by micromilling, the δ18O of both aragonite and calcite is altered by −0.1‰/day. Laboratories that use this technique should thoroughly test and correct for this phenomenon and avoid storing pre-weighed materials within the Kiel Device or similar drying oven prior to analysis. Copyright © 2011 John Wiley & Sons, Ltd.

Although abundant evidence now exists for a massive bolide impact coincident with the Cretaceous–Paleogene (K–Pg) mass extinction event (~ 65.5 Ma), the relative importance of this impact as an extinction mechanism is still the subject of debate. On Seymour Island, Antarctic Peninsula, the Lopez de Bertodano Formation yields one of the most expanded K–Pg boundary sections known. Using a new chronology from magnetostratigraphy, and isotopic data from carbonate-secreting macrofauna, we present a high-resolution, high-latitude paleotemperature record spanning this time interval. We find two prominent warming events synchronous with the three main phases of Deccan Traps flood volcanism, and the onset of the second is contemporaneous with a local extinction that pre-dates the bolide impact. What has been termed the K–Pg extinction is potentially the sum of multiple, independent events, at least at high latitudes.

Isotopic analysis of carbonate material has been greatly facilitated by the development of autosampling devices such as the Kiel III Carbonate Device, allowing rapid automated analysis of small sample sizes. This analysis is facilitated by holding samples and acid at temperatures around 70 °C prior to reaction. In most situations this has no measurable effect on sample powders on practical timeframes, but, when analyzing exceptionally fine-grained material produced by micromilling, the δ(18)O of both aragonite and calcite is altered by -0.1 ‰/day. Laboratories that use this technique should thoroughly test and correct for this phenomenon and avoid storing pre-weighed materials within the Kiel Device or similar drying oven prior to analysis.