Search

Your search keyword '"Price JT"' showing total 2 results
Start Over Author "Price JT" Database OpenAIRE
2 results on '"Price JT"'

1. An Azide-Functionalized Nitronyl Nitroxide Radical: Synthesis, Characterization and Staudinger-Bertozzi Ligation Reactivity

Author

Joe B. Gilroy, Pierangelo Gobbo, Wilson Luo, Mark C. Biesinger, Mark S. Workentin, Stephanie M. Barbon, Jacquelyn T. Price, Barbon, Sm, Gobbo, P, Luo, W, Price, Jt, Biesinger, Mc, Workentin, M, and Gilroy, Jb

Subjects
Nitroxide mediated radical polymerization, Chemistry, Organic Chemistry, Nanoparticle, Photochemistry, law.invention, chemistry.chemical_compound, law, Colloidal gold, Covalent bond, Polymer chemistry, Reactivity (chemistry), Azide, Bioorthogonal chemistry, Electron paramagnetic resonance
Abstract

An azide-functionalized nitronyl nitroxide was successfully synthesized and its reactivity towards the Staudinger-Bertozzi ligation was explored. While a model reaction in solution showed the conversion of the nitronyl nitroxide to an imino nitroxide radical, the same reaction at the interface of gold nanoparticles allowed for successful covalent incorporation of the nitronyl nitroxide radical onto the nanoparticles.

Published
2016

2. Expanding the scope of strained-alkyne chemistry: a protection-deprotection strategy via the formation of a dicobalt-hexacarbonyl complex

Author

Stephanie M. Barbon, Tommaso Romagnoli, Jacquelyn T. Price, Jennifer L.A. Keir, Pierangelo Gobbo, Joe B. Gilroy, Mark S. Workentin, Gobbo, P, Romagnoli, T, Barbon, Sm, Price, Jt, Keir, J, Gilroy, Jb, and Workentin, Ms

Subjects
chemistry.chemical_classification, Reaction conditions, Scope (project management), Metals and Alloys, Chemical biology, food and beverages, Alkyne, General Chemistry, Catalysis, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, chemistry, Materials Chemistry, Ceramics and Composites, Organic chemistry, Reactivity (chemistry), Bioorthogonal chemistry
Abstract

A protection-deprotection strategy for strained alkynes used for bioorthogonal chemistry is reported. A strained alkyne can be protected with dicobalt-octacarbonyl and we demonstrate for the first time that a strained alkyne can be re-formed and isolated under mild reaction conditions for further bioorthogonal reactivity. The protection-deprotection strategy herein reported will expand the versatility of strained alkynes for the preparation of substrates in chemical biology and materials applications.

Published
2015

Catalog

Books, media, physical & digital resources
See catalog results