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In this study, we synthesized and characterized a 3D network of silver nanowires (AgNWs), employing the polyol approach in ethylene glycol (EG) as the reductant and polyvinylpyrrolidone (PVP) as the structure-directing agent for the growth of AgNWs to design inexpensive, timely responsive AgNWs-based heaters with different substrates. Data obtained from a field emission scanning electron microscope (FESEM) revealed that the average diameter of the synthesized AgNWs was 22 nm, and the average length was 28 µm. UV-visible absorption spectroscopy showed that AgNWs developed in a very pure phase. We investigated the impact of substrate type on the heating dissipation performance by depositing AgNW thin film over three chosen substrates made from readily available materials. The findings indicated that the AgNW-based heater with the wood substrate had the lowest response time of 21 s, the highest thermal resistance of 352.59 °C·cm2/W, and a steady temperature of 135 °C at a low bias voltage of 5 V compared to cement (95 s, 297.77 °C·cm2/W, and 120 °C) and glass (120 s, 270.25 °C·cm2/W, and 110 °C).

In this article, an in-depth optical investigation of Zn(Al)O-mixed metal oxide (MMO) film using Zn/Al-layered double hydroxide (LDH) was elucidated through co-precipitation and spin coating techniques. The field emission scanning electron microscopy (FE-SEM) analysis revealed the occurrence of a vertically aligned sheet-like structure with a thickness of 60 nm for pristine LDH, which further reduced to 45 nm after calcination at 300 °C. Additionally, pristine LDH showed multiple optical bandgaps of 5.18, 3.6, and 3.2 eV. Moreover, a good agreement of the obtained optical bandgaps was attained between both utilized methods, ultraviolet-visible light (UV-Vis), and photoluminescence (PL) spectroscopies. The optical bandgap decreased at higher calcination temperatures, which indicates the active role of the applied post-fabrication process on the optical profile of the deposited MMO film/s. The demonstrated transmittance spectra of the deposited MMO films exhibited a transparency between 85% and 95%; this indicates the usefulness and consistency of the proposed film for transparent conductive oxide (TCO) based optoelectronic applications.

This study reports a simple new technique for the preparation of novel hexagonal-shaped mixed metal oxides (MMO) nanorods using Zn/Al-layered double hydroxide (LDH) as a precursor for dye-sensitized solar cell (DSSC) application. The effect of the Zn to Al molar ratio demonstrated a sound correlation between the obtained nanorods’ diameter and the fabricated DSSCs efficiency. Additionally, the optical behavior of the fabricated MMO film as well as the absorption enhancement due to the utilized dye are also demonstrated; a cut-off phenomenon at around 376 nm corresponds to the attained hexagonal nanorods. The open-circuit voltage augmented noticeably from 0.6 to 0.64 V alongside an increase in the diameter of nanorods from 64 to 80 nm. The results indicated that an increment in the diameter of the nanorods is desirable due to the enhanced surface area through which a higher amount of dye N719 was loaded (0.35 mM/cm2). This, in turn, expedited the transport of electrons within the MMO matrix resulting in an advanced short-circuit current. Of the devices fabricated, ZA-8 exhibited the highest fill factor and efficiency of 0.37% and 0.69%, respectively, because of its boosted short-circuit current and open-circuit voltage.