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The cosmogenic radionuclides 7Be and 10Be are useful aerosol tracers for atmospheric transport studies. Combining 7Be and 10Be measurements with an atmospheric transport model can not only improve our understanding of the radionuclide transport and deposition processes but also provide an evaluation of the transport process in the model. To simulate these aerosol tracers, it is critical to evaluate the influence of radionuclides production uncertainties on simulations. Here we use the GEOS-Chem chemical transport model driven by the MERRA-2 reanalysis to simulate 7Be and 10Be with different production scenarios: the default production rate in GEOS-Chem based on an empirical approach (denoted as LP67), and two production rates from the CRAC:Be (Cosmic Ray Atmospheric Cascade: Beryllium) model considering only geomagnetic cut-off rigidities for a geocentric axial dipole (denoted as P16) or realistic spatial geomagnetic cut-off rigidity variations due to non-dipole moments of the geomagnetic field (denoted as P16spa). The model results are comprehensively evaluated with a large number of measurements including surface air concentrations and deposition fluxes. The model with the P16spa production can reproduce the absolute values and temporal variability of 7Be and 10Be surface concentrations and deposition fluxes on annual and sub-annual scales, as well as the vertical profiles of air concentrations. Simulations with the LP67 production tend to overestimate the absolute values of 7Be and 10Be concentrations. The P16 simulations suggest less than 10 % differences compared to P16spa but tend to produce a significant positive bias (>20 %) in the 7Be deposition fluxes over East Asia. We find that the deposition fluxes are more sensitive to the production in the troposphere and downward transport from the stratosphere. Independent of the production models, surface air concentrations and deposition fluxes from all simulations show similar seasonal variations, suggesting a dominant meteorological influence. The model can also reasonably simulate the stratosphere-troposphere exchange process of 7Be and 10Be by producing stratospheric contribution and 10Be / 7Be ratio values that agree with measurements. Finally, we illustrate the importance of including the time-varying solar modulation in the production calculation, which can significantly improve the agreement between model results and measurements, especially at mid- and high- latitudes. Reduced uncertainties in the production rates, as demonstrated in this study, improve the utility of 7Be and 10Be as aerosol tracers for evaluating and testing transport and scavenging processes in global models.

Between 15 and 27 kyr b2k (thousands of years before 2000 CE) during the last glacial, Greenland experienced a prolonged cold stadial phase, interrupted by two short-lived warm interstadials. Greenland ice-core calcium data show two periods, preceding the interstadials, of anomalously high atmospheric dust loading, the origin of which is not well understood. At approximately the same time as the Greenland dust peaks, the Chinese Hulu Cave speleothems exhibit a climatic signal suggested to be a response to Heinrich Event 2, a period of enhanced ice-rafted debris deposition in the North Atlantic. In the climatic signal of Antarctic ice cores, moreover, a relative warming occurs between 23 and 24.5 kyr b2k that is generally interpreted as a counterpart to a cool climate phase in the Northern Hemisphere. Proposed centennial-scale offsets between the polar ice-core timescales and the speleothem timescale hamper the precise reconstruction of the global sequence of these climatic events. Here, we examine two new 10Be datasets from Greenland and Antarctic ice cores to test the agreement between different timescales, by taking advantage of the globally synchronous cosmogenic radionuclide production rates. Evidence of an event similar to the Maunder Solar Minimum is found in the new 10Be datasets, supported by lower-resolution radionuclide data from Greenland and 14C in the Hulu Cave speleothem, representing a good synchronization candidate at around 22 kyr b2k. By matching the respective 10Be data, we determine the offset between the Greenland ice-core chronology, GICC05, and the Antarctic chronology for the West Antarctic Ice Sheet Divide ice core (WDC), WD2014, to be 125 ± 40 years. Furthermore, via radionuclide wiggle-matching, we determine the offset between the Hulu speleothem and ice-core timescales to be 375 years for GICC05 (75–625 years at 68 % confidence) and 225 years for WD2014 (−25–425 years at 68 % confidence). The rather wide uncertainties are intrinsic to the wiggle-matching algorithm and the limitations set by data resolution. The undercounting of annual layers in GICC05 inferred from the offset is hypothesized to have been caused by a combination of underdetected annual layers, especially during periods with low winter precipitation, and misinterpreted unusual patterns in the annual signal during the extremely cold period often referred to as Heinrich Stadial 1.

Here we present the high-resolution CFA data from the top 479 m of the East Greenland Ice coring Project (EGRIP) ice core covering the past 3.8 thousand years. The data consists of 1 mm-depth-resolution profiles of calcium, sodium, am- monium, nitrate and electrolytic conductivity as well as decadal averages of these profiles. Alongside the data we provide a description of the measurement setup, procedures, the relevant references for the specific methods as well as an assessment of the precision of the measurements, the sample to depth assignment and the depth and temporal resolution of the data set. The nominally 1-mm data represents an oversampling of the record as the true resolution is limited by the analytical setup to approximately 1 cm. The error of absolute depth assignment of the data may be on the order of 1 cm, however relative depth offsets be- tween the records of the individual species is only on the order of 1 mm. The presented data has sub-annual resolution over the entire depth range and has already formed part of the data for an annually layer-counted time scale for the EGRIP ice core used to improve and revise the multi-core Greenland ice-core chronology (GICC05) to a new version,GICC21 (Sinnl et al., 2021). The data is available in full 1-mm resolution and decadal averages on PANGAEA (https://doi.org/10.1594/PANGAEA.945293 (Erhardt et al., 2022b))

Das radioaktive Kohlenstoffisotop 14C, auch Radiokarbon genannt, ist ein wichtiger Informationsträger für die Geowissenschaften. Es hilft, unser Verständnis von Klimaprozessen, der Sonne, des Geodynamos und des Kohlenstoffkreislaufs der vergangenen 55 000 Jahre zu verbessern. Moderne Messmethoden erlauben auch 14C-Messungen an Kleinstproben. Das verringert die Unsicherheiten in den aktuellen IntCal20-Alterskalibrationskurven. Dadurch zeigen sich klarere Strukturen in den Veränderungen im 14C-Gehalt der Atmosphäre und des oberflächennahen Meerwassers während der vergangenen 55 000 Jahre. Dieser Fortschritt ermöglicht eine verbesserte Datierung und Untersuchungen von Sonnenaktivität, Erdmagnetfeld und Kohlenstoffkreislauf. In allen diesen Gebieten der Erdsystemforschung kommen Radiokarbon-Messungen erfolgreich zum Einsatz.

Additional file 1. Supplementary document.

The annual C-14 data in tree rings is an outstanding proxy for uncovering extreme solar energetic particle (SEP) events in the past. Signatures of extreme SEP events have been reported in 774/775 CE, 992/993 CE, and similar to 660 BCE. Here, we report another rapid increase of C-14 concentration in tree rings from California, Switzerland, and Finland around 5410 BCE. These C-14 data series show a significant increase of similar to 6 parts per thousand in 5411-5410 BCE. The signature of C-14 variation is very similar to the confirmed three SEP events and points to an extreme short-term flux of cosmic ray radiation into the atmosphere. The rapid C-14 increase in 5411/5410 BCE rings occurred during a period of high solar activity and 60 years after a grand C-14 excursion during 5481-5471 BCE. The similarity of our C-14 data to previous events suggests that the origin of the 5410 BCE event is an extreme SEP event.

The annual 14C data in tree rings is an outstanding proxy for uncovering extreme solar energetic particle (SEP) events in the past. Signatures of extreme SEP events have been reported in 774/775 CE, 992/993 CE, and ∼660 BCE. Here, we report another rapid increase of 14C concentration in tree rings from California, Switzerland, and Finland around 5410 BCE. These 14C data series show a significant increase of ∼6‰ in 5411–5410 BCE. The signature of 14C variation is very similar to the confirmed three SEP events and points to an extreme short-term flux of cosmic ray radiation into the atmosphere. The rapid 14C increase in 5411/5410 BCE rings occurred during a period of high solar activity and 60 years after a grand 14C excursion during 5481–5471 BCE. The similarity of our 14C data to previous events suggests that the origin of the 5410 BCE event is an extreme SEP event., Geophysical Research Letters, 48 (11), ISSN:0094-8276, ISSN:1944-8007

The research area of climate field reconstructions has developed strongly during the past 20 years, motivated by the need to understand the complex dynamics of the earth system in a changing climate. Climate field reconstructions aim to build a consistent gridded climate reconstruction of different variables, often from a range of climate proxies, using either statistical tools or a climate model to fill the gaps between the locations of the proxy data. Commonly, large-scale climate field reconstructions covering more than 500 years are of annual resolution. In this method study, we investigate the potential of seasonally resolved climate field reconstructions based on oxygen isotope records from Greenland ice cores and an isotope-enabled climate model. Our analogue-type method matches modeled isotope patterns in Greenland precipitation to the patterns of ice core data from up to 14 ice core sites. In a second step, the climate variables of the best-matching model years are extracted, with the mean of the best-matching years comprising the reconstruction. We test a range of climate reconstructions, varying the definition of the seasons and the number of ice cores used. Our findings show that the optimal definition of the seasons depends on the variability in the target season. For winter, the vigorous variability is best captured when defining the season as December–February due to the dominance of large-scale patterns. For summer, which has weaker variability, albeit more persistent in time, the variability is better captured using a longer season of May–October. Motivated by the scarcity of seasonal data, we also test the use of annual data where the year is divided during summer, that is, not following the calendar year. This means that the winter variability is not split and that the annual data then can be used to reconstruct the winter variability. In particularly when reconstructing the sea level pressure and the corresponding main modes of variability, it is important to take seasonality into account, because of changes in the spatial patterns of the modes throughout the year. Targeting the annual mean sea level pressure for the reconstruction lowers the skill simply due to the seasonal geographical shift of the circulation modes. Our reconstructions based on ice core data also show skill for the North Atlantic sea surface temperatures, in particularly during winter for latitudes higher than 50∘ N. In addition, the main modes of the sea surface temperature variability are qualitatively captured by the reconstructions. When testing the skill of the reconstructions using 19 ice cores compared to the ones using eight ice cores, we do not find a clear advantage of using a larger data set. This could be due to a more even spatial distribution of the eight ice cores. However, including European tree-ring data to further constrain the summer temperature reconstruction clearly improves the skill for this season, which otherwise is more difficult to capture than the winter season.

Radiocarbon (14C) ages cannot provide absolutely dated chronologies for archaeological or paleoenvironmental studies directly but must be converted to calendar age equivalents using a calibration curve compensating for fluctuations in atmospheric 14C concentration. Although calibration curves are constructed from independently dated archives, they invariably require revision as new data become available and our understanding of the Earth system improves. In this volume the international 14C calibration curves for both the Northern and Southern Hemispheres, as well as for the ocean surface layer, have been updated to include a wealth of new data and extended to 55,000 cal BP. Based on tree rings, IntCal20 now extends as a fully atmospheric record to ca. 13,900 cal BP. For the older part of the timescale, IntCal20 comprises statistically integrated evidence from floating tree-ring chronologies, lacustrine and marine sediments, speleothems, and corals. We utilized improved evaluation of the timescales and location variable 14C offsets from the atmosphere (reservoir age, dead carbon fraction) for each dataset. New statistical methods have refined the structure of the calibration curves while maintaining a robust treatment of uncertainties in the 14C ages, the calendar ages and other corrections. The inclusion of modeled marine reservoir ages derived from a three-dimensional ocean circulation model has allowed us to apply more appropriate reservoir corrections to the marine 14C data rather than the previous use of constant regional offsets from the atmosphere. Here we provide an overview of the new and revised datasets and the associated methods used for the construction of the IntCal20 curve and explore potential regional offsets for tree-ring data. We discuss the main differences with respect to the previous calibration curve, IntCal13, and some of the implications for archaeology and geosciences ranging from the recent past to the time of the extinction of the Neanderthals.

Modes of climate variability affect global and regional climates on different spatio-temporal scales, and they have important impacts on human activities and ecosystems. As these modes are a useful tool for simplifying the understanding of the climate system, it is crucial that we gain improved knowledge of their long-term past evolution and interactions over time to contextualise their present and future behaviour. We review the literature focused on proxy-based reconstructions of modes of climate variability during the Holocene (i.e., the last 11.7 thousand years) with a special emphasis on i) proxy-based reconstruction methods; ii) available proxy-based reconstructions of the main modes of variability, i.e., El Nino Southern Oscillation, Pacific Decadal Variability, Atlantic Multidecadal Variability, the North Atlantic Oscillation, the Southern Annular Mode and the Indian Ocean Dipole; iii) major interactions between these modes; and iv) external forcing mechanisms related to the evolution of these modes. This review shows that modes of variability can be reconstructed using proxy-based records from a wide range of natural archives, but these reconstructions are scarce beyond the last millennium, partly due to the lack of robust chronologies with reduced dating uncertainties, technical issues related to proxy calibration, and difficulty elucidating their stationary impact (or not) on regional climates over time. While for each mode the available reconstructions tend to agree at mutidecadal timescales, they show notable disagreement on shorter timescales beyond the instrumental period. The reviewed evidence suggests that the intrinsic variability of modes can be modulated by external forcing, such as orbital, solar, volcanic, and anthropogenic forcing. The review also highlights some modes experience higher variability over the instrumental period, which is partly ascribed to anthropogenic forcing. These features stress the paramount importance of further studying their past variations using long climate-proxy records for the progress of climate science. A.H. is supported by a Beatriu de Pinos -Marie Curie Cofund programme fellowship (2016 BP 00023) and HOLMODRIVE -North Atlantic Atmospheric Patterns influence on Western Iberia Climate: From the Lateglacial to the Present (PTDC/CTA-GEO/29029/2017) project funded by the Fundacao para a Ciencia e a Tecnologia, Portugal (FCT). A.H., S.G., and S.P-R. thank the Spanish research project PaleoModes (CGL2016-75281-C2-1-R) which provided some of their financial support. E.M.-C. contribution was funded by the project PARAMOUR (30454083) from the EOS program by the F.R.SFNRS. CMP is supported by the Royal Society (ref: DH150185). P.O. contribution has been supported by the Ramon y Cajal senior tenure programme from the Spanish Ministry of Economy and Competitiveness. L.C-B. acknowledges support from the ERC-funded project GC2.0 (Global Change 2.0: Unlocking the past for a clearer future, grant number 694481). The Spanish PTI PolarCSIC (https://www.polarcsic.es) is also acknowledged for providing partial financial support to S.G. R.M. was partially supported by the Swedish Research Council (grant DNR20138421). A. P.'s work was supported by a Science Foundation Ireland Career Development Award (17/CDA/4695), a research centre award (12/RC/2289_P2), an investigator award (16/IA/4520), and a Marine Research Programme funded by the Irish Government, cofinanced by the European Regional Development Fund (Grant-Aid Agreement No. PBA/CC/18/01). A.A.S. was supported by the Met Office Hadley Centre Climate Programme funded by BEIS and Defra. J.S. is supported by the strategic research program of Modelling the Regional and Global Earth system (MERGE) hosted by the Faculty of Science at Lund University. D.S. is supported by Blue-Action (European Union's Horizon 2020 research and innovation program, Grant Number: 727852) and EUCP (European Union's Horizon 2020 research and innovation programme under grant agreement no 776613) projects as well as by the French national program LEFE/INSU with VADEMECUM project. G. X. thanks the funding from the Chinese Scholarship Council (201704910171). This study is partly based on discussions held during the joint workshop of the CLIMOVAR group and IBCC-lo2k project, Barcelona, 25-27 September 2013. PAGES and IBCC-lo2k are thanked for supporting this workshop.

Changes in the latitudinal position and strength of the Southern Hemisphere westerlies (SHW) are thought to be tightly coupled to important climate processes, such as cross-equatorial heat fluxes, Atlantic Meridional Overturning Circulation (AMOC), the bipolar seesaw, Southern Ocean ventilation and atmospheric CO2 levels. However, many uncertainties regarding magnitude, direction, and causes and effects of past SHW shifts still exist due to lack of suitable sites and scarcity of information on SHW dynamics, especially from the last glacial. Here we present a detailed hydroclimate multiproxy record from a 36.4-18.6 kyr old lake sediment sequence on Nightingale Island (NI). It is strategically located at 37ĝF S in the central South Atlantic (SA) within the SHW belt and situated just north of the marine Subtropical Front (SF). This has enabled us to assess hydroclimate changes and their link to the regional climate development as well as to large-scale climate events in polar ice cores. The NI record exhibits a continuous impact of the SHW, recording shifts in both position and strength, and between 36 and 31 ka the westerlies show high latitudinal and strength-wise variability possibly linked to the bipolar seesaw. This was followed by 4 kyr of slightly falling temperatures, decreasing humidity and fairly southerly westerlies. After 27 ka temperatures decreased 3-4 ĝC, marking the largest hydroclimate change with drier conditions and a variable SHW position. We note that periods with more intense and southerly-positioned SHW seem to be related to periods of increased CO2 outgassing from the ocean, while changes in the cross-equatorial gradient during large northern temperature changes appear as the driving mechanism for the SHW shifts. Together with coeval shifts of the South Pacific westerlies, our results show that most of the Southern Hemisphere experienced simultaneous atmospheric circulation changes during the latter part of the last glacial. Finally we can conclude that multiproxy lake records from oceanic islands have the potential to record atmospheric variability coupled to large-scale climate shifts over vast oceanic areas..

The West Antarctic Ice Sheet (WAIS) Divide deep ice core WD2014 chronology, consisting of ice age, gas age, delta-age and uncertainties therein. The West Antarctic Ice Sheet Divide (WAIS Divide, WD) ice core is a newly drilled, high-accumulation deep ice core that provides Antarctic climate records of the past ~68 ka at unprecedented temporal resolution. The upper 2850 m (back to 31.2 ka BP; Sigl et al., 2015, Sigl et al., 2016) have been dated using annual-layer counting based on counting of annual layers observed in the chemical, dust and electrical conductivity records. The measurements were interpreted manually and with the aid of two automated methods. We validated the chronology by comparing of the cosmogenic isotope records of 10Be from WAIS Divide and 14C for IntCal13. We demonstrated that over the Holocene WD2014 was consistently accurate to better than 0.5% of the age. The chronology for the deep part of the core (below 2850m; 67.8-31.2 ka BP; Buizert et al., 2015) is based on stratigraphic matching to annual-layer-counted Greenland ice cores using globally well-mixed atmospheric methane. We calculate the WD gas age-ice age difference (Delta age) using a combination of firn densification modeling, ice-flow modeling, and a data set of d15N-N2, a proxy for past firn column thickness. The largest Delta age at WD occurs during the Last Glacial Maximum, and is 525 +/- 120 years. We synchronized the WD chronology to a linearly scaled version of the layer-counted Greenland Ice Core Chronology (GICC05), which brings the age of Dansgaard-Oeschger (DO) events into agreement with the U/Th absolutely dated Hulu Cave speleothem record.

Recently, it has been confirmed that extreme solar proton events can lead to significantly increased atmospheric production rates of cosmogenic radionuclides. Evidence of such events is recorded in annually resolved natural archives, such as tree rings [carbon-14 (C-14)] and ice cores [beryllium-10 (Be-10), chlorine-36 (Cl-36)]. Here, we show evidence for an extreme solar event around 2,610 years B.P. (similar to 660 BC) based on high-resolution Be-10 data from two Greenland ice cores. Our conclusions are supported by modeled C-14 production rates for the same period. Using existing Cl-36 ice core data in conjunction with Be-10, we further show that this solar event was characterized by a very hard energy spectrum. These results indicate that the 2,610-years B.P. event was an order of magnitude stronger than any solar event recorded during the instrumental period and comparable with the solar proton event of AD 774/775, the largest solar event known to date. The results illustrate the importance of multiple ice core radionuclide measurements for the reliable identification of short-term production rate increases and the assessment of their origins.

Recently, it has been confirmed that extreme solar proton events can lead to significantly increased atmospheric production rates of cosmogenic radionuclides. Evidence of such events is recorded in annually resolved natural archives, such as tree rings [carbon-14 (14C)] and ice cores [beryllium-10 (10Be), chlorine-36 (36Cl)]. Here, we show evidence for an extreme solar event around 2,610 years B.P. (∼660 BC) based on high-resolution 10Be data from two Greenland ice cores. Our conclusions are supported by modeled 14C production rates for the same period. Using existing 36Cl ice core data in conjunction with 10Be, we further show that this solar event was characterized by a very hard energy spectrum. These results indicate that the 2,610-years B.P. event was an order of magnitude stronger than any solar event recorded during the instrumental period and comparable with the solar proton event of AD 774/775, the largest solar event known to date. The results illustrate the importance of multiple ice core radionuclide measurements for the reliable identification of short-term production rate increases and the assessment of their origins., Proceedings of the National Academy of Sciences of the United States of America, 116 (13), ISSN:0027-8424, ISSN:1091-6490

Solar influences on climate variability are one of the most controversially discussed topics in climate research. We analyze solar forcing of flood frequency in central Europe during spring and summer on interannual to multi-centennial timescales, integrating daily discharge data of the River Ammer (southern Germany) back to AD 1926 (∼ solar cycles 16–23) and the 5500-year flood layer record from varved sediments of the downstream Ammersee. Flood frequency in the River Ammer discharge record is significantly correlated to changes in solar activity when the flood record lags the solar signal by 2–3 years (2-year lag: r = −0.375, p = 0.01; 3-year lag: r = −0.371, p = 0.03). Flood layer frequency in the Ammersee sediment record depicts distinct multi-decadal variations and significant correlations to a total solar irradiance reconstruction (r = −0.4, p 14C production rates (r = 0.37, p

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Timescale uncertainties between paleoclimate reconstructions often inhibit studying the exact timing, spatial expression and driving mechanisms of climate variations. Detecting and aligning the globally common cosmogenic radionuclide production signal via a curve fitting method provides a tool for the quasi-continuous synchronization of paleoclimate archives. In this study, we apply this approach to synchronize 10Be records from varved sediments of Tiefer See and Lake Czechowskie covering the Maunder, Homeric and 5500 a BP grand solar minima with 14C production rates inferred from the IntCal13 calibration curve. Our analyses indicate best fits with 14C production rates when the 10Be records from Tiefer See were shifted for 8 (−12∕ + 4) (Maunder Minimum), 31 (−16∕ + 12) (Homeric Minimum) and 86 (−22∕ + 18) years (5500 a BP grand solar minimum) towards the past. The best fit between the Lake Czechowskie 10Be record for the 5500 a BP grand solar minimum and 14C production was obtained when the 10Be time series was shifted 29 (−8∕ + 7) years towards present. No significant fits were detected between the Lake Czechowskie 10Be records for the Maunder and Homeric minima and 14C production, likely due to intensified in-lake sediment resuspension since about 2800 a BP, transporting old 10Be to the coring location. Our results provide a proof of concept for facilitating 10Be in varved lake sediments as a novel synchronization tool required for investigating leads and lags of proxy responses to climate variability. However, they also point to some limitations of 10Be in these archives, mainly connected to in-lake sediment resuspension processes.

Due to a lack of marine macrofossils in many sediment cores from the estuarine Baltic Sea, researchers are often forced to carry out 14C determinations on bulk sediment samples. However, ambiguity surrounding the carbon source pathways that contribute to bulk sediment formation introduces a large uncertainty into 14C geochronologies based on such samples, and such uncertainty may not have been fully considered in previous Baltic Sea studies. We quantify this uncertainty by analyzing bulk sediment 14C determinations carried out on densely spaced intervals in independently dated late-Holocene sediment sequences from two central Baltic Sea cores. Our results show a difference of ~600 14C yr in median bulk sediment reservoir age, or R(t)bulk, between the two core locations (~1200 14C yr for one core, ~620 14C yr for the other), indicating large spatial variation. Furthermore, we also find large downcore (i.e., temporal) R(t)bulk variation of at least ~200 14C yr for both cores. We also find a difference of 585 14C yr between two samples taken from the same core depth. We propose that studies using bulk sediment 14C dating in large brackish water bodies should take such spatiotemporal variation in R(t)bulk into account when assessing uncertainties, thus leading to a larger, but more accurate, calibrated age range.

Identification of the causes of past climate change requires detailed knowledge of one of the most important natural factors���solar forcing. Prior to the period of direct solar observations, radionuclide abundances in natural archives provide the best-known proxies for changes in solar activity. Here we present two independent reconstructions of changes in solar activity during the last 1000 yr, which are inferred from 10Be and 14C records. We analyse the tree-ring 14C data (SHCal, IntCal04 from 1000 to 1510 AD and annual data from 1511 to 1950 AD) and four 10Be records from Greenland ice cores (Camp Century, GRIP, Milcent and Dye3) together with two 10Be records from Antarctic ice cores (Dome Concordia and South Pole). In general, the 10Be and 14C records exhibit good agreement that allows us to obtain reliable estimates of past solar magnetic modulation of the radionuclide production rates. Differences between 10Be records from Antarctica and Greenland indicate that climatic changes have influenced the deposition of 10Be during some periods of the last 1000 yr. The radionuclide-based reconstructions of past changes in solar activity do not always agree with the sunspot record, which indicates that the coupling between those proxies is not as close as has been sometimes assumed. The tree-ring 14C record and 10Be from Antarctica indicate that recent solar activity is high but not exceptional with respect to the last 1000 yr.

Radiocarbon (14C) ages cannot provide absolutely dated chronologies for archaeological or paleoenvironmental studies directly but must be converted to calendar age equivalents using a calibration curve compensating for fluctuations in atmospheric 14C concentration. Although calibration curves are constructed from independently dated archives, they invariably require revision as new data become available and our understanding of the Earth system improves. In this volume the international 14C calibration curves for both the Northern and Southern Hemispheres, as well as for the ocean surface layer, have been updated to include a wealth of new data and extended to 55,000 cal BP. Based on tree rings, IntCal20 now extends as a fully atmospheric record to ca. 13,900 cal BP. For the older part of the timescale, IntCal20 comprises statistically integrated evidence from floating tree-ring chronologies, lacustrine and marine sediments, speleothems, and corals. We utilized improved evaluation of the timescales and location variable 14C offsets from the atmosphere (reservoir age, dead carbon fraction) for each dataset. New statistical methods have refined the structure of the calibration curves while maintaining a robust treatment of uncertainties in the 14C ages, the calendar ages and other corrections. The inclusion of modeled marine reservoir ages derived from a three-dimensional ocean circulation model has allowed us to apply more appropriate reservoir corrections to the marine 14C data rather than the previous use of constant regional offsets from the atmosphere. Here we provide an overview of the new and revised datasets and the associated methods used for the construction of the IntCal20 curve and explore potential regional offsets for tree-ring data. We discuss the main differences with respect to the previous calibration curve, IntCal13, and some of the implications for archaeology and geosciences ranging from the recent past to the time of the extinction of the Neanderthals., Radiocarbon, 62 (4), ISSN:0033-8222

Solar variability has been hypothesized to be a major driver of North Atlantic millennial-scale climate variations through the Holocene along with orbitally induced insolation change. However, another important climate driver, volcanic forcing has generally been underestimated prior to the past 2,500 years partly owing to the lack of proper proxy temperature records. Here, we reconstruct seasonally unbiased and physically constrained Greenland Summit temperatures over the Holocene using argon and nitrogen isotopes within trapped air in a Greenland ice core (GISP2). We show that a series of volcanic eruptions through the Holocene played an important role in driving centennial to millennial-scale temperature changes in Greenland. The reconstructed Greenland temperature exhibits significant millennial correlations with K+ and Na+ ions in the GISP2 ice core (proxies for atmospheric circulation patterns), and δ18O of Oman and Chinese Dongge cave stalagmites (proxies for monsoon activity), indicating that the reconstructed temperature contains hemispheric signals. Climate model simulations forced with the volcanic forcing further suggest that a series of large volcanic eruptions induced hemispheric-wide centennial to millennial-scale variability through ocean/sea-ice feedbacks. Therefore, we conclude that volcanic activity played a critical role in driving centennial to millennial-scale Holocene temperature variability in Greenland and likely beyond., Scientific Reports, 7, ISSN:2045-2322

During the last glacial period Northern Hemi-sphere climate was characterized by extreme and abrupt cli-mate changes, so-called Dansgaard–Oeschger (DO) events.Most clearly observed as temperature changes in Greenlandice-core records, their climatic imprint was geographicallywidespread. However, the temporal relation between DOevents in Greenland and other regions is uncertain due to thechronological uncertainties of each archive, limiting our abil-ity to test hypotheses of synchronous change. In contrast, theassumption of direct synchrony of climate changes forms thebasis of many timescales. Here, we use cosmogenic radionu-clides (¹⁰Be,³⁶Cl,¹⁴C) to link Greenland ice-core records toU/Th-dated speleothems, quantify offsets between the twotimescales, and improve their absolute dating back to 45 000years ago. This approach allows us to test the assumptionthat DO events occurred synchronously between Greenlandice-core and tropical speleothem records with unprecedentedprecision. We find that the onset of DO events occurs withinsynchronization uncertainties in all investigated records. Im-portantly, we demonstrate that local discrepancies remain inthe temporal development of rapid climate change for spe-cific events and speleothems. These may either be related tothe location of proxy records relative to the shifting atmo-spheric fronts or to underestimated U/Th dating uncertain-ties. Our study thus highlights the potential for misleadinginterpretations of the Earth system when applying the com-mon practice of climate wiggle matching.

Changes in the geometry of ocean meridional overturning circulation (MOC) are crucial in controlling past changes of climate and the carbon inventory of the atmosphere. However, the accurate timing and global correlation of short-term glacial-to-deglacial changes of MOC in different ocean basins still present a major challenge. The fine structure of jumps and plateaus in atmospheric and planktic radiocarbon (14C) concentration reflects changes in atmospheric 14C production, ocean–atmosphere 14C exchange, and ocean mixing. Plateau boundaries in the atmospheric 14C record of Lake Suigetsu, now tied to Hulu Cave U∕Th model ages instead of optical varve counts, provide a stratigraphic “rung ladder” of up to 30 age tie points from 29 to 10 cal ka for accurate dating of planktic oceanic 14C records. The age differences between contemporary planktic and atmospheric 14C plateaus record the global distribution of 14C reservoir ages for surface waters of the Last Glacial Maximum (LGM) and deglacial Heinrich Stadial 1 (HS-1), as documented in 19 and 20 planktic 14C records, respectively. Elevated and variable reservoir ages mark both upwelling regions and high-latitude sites covered by sea ice and/or meltwater. 14C ventilation ages of LGM deep waters reveal opposed geometries of Atlantic and Pacific MOC. Like today, Atlantic deep-water formation went along with an estuarine inflow of old abyssal waters from the Southern Ocean up to the northern North Pacific and an outflow of upper deep waters. During early HS-1, 14C ventilation ages suggest a reversed MOC and ∼1500-year flushing of the deep North Pacific up to the South China Sea, when estuarine circulation geometry marked the North Atlantic, gradually starting near 19 ka. High 14C ventilation ages of LGM deep waters reflect a major drawdown of carbon from the atmosphere. The subsequent major deglacial age drop reflects changes in MOC accompanied by massive carbon releases to the atmosphere as recorded in Antarctic ice cores. These new features of MOC and the carbon cycle provide detailed evidence in space and time to test and refine ocean models that, in part because of insufficient spatial model resolution and reference data, still poorly reproduce our data sets., Climate of the Past, 16 (6), ISSN:1814-9324, ISSN:1814-9332

The origin of two large peaks in the atmospheric radiocarbon (14C) concentration at AD 774/5 and 993/4 is still debated. There is consensus, however, that these features can only be explained by an increase in the atmospheric 14C production rate due to an extraterrestrial event. Here we provide evidence that these peaks were most likely produced by extreme solar events, based on several new annually resolved 10Be measurements from both Arctic and Antarctic ice cores. Using ice core 36Cl data in pair with 10Be, we further show that these solar events were characterized by a very hard energy spectrum with high fluxes of solar protons with energy above 100 MeV. These results imply that the larger of the two events (AD 774/5) was at least five times stronger than any instrumentally recorded solar event. Our findings highlight the importance of studying the possibility of severe solar energetic particle events., Nature Communications, 6, ISSN:2041-1723

Since it is currently not understood how changes in 14C production rate (Q), and in the carbon cycle, can be combined to explain the reconstructed atmospheric Δ14C record, we discuss possible reasons for this knowledge gap. Reviewing the literature, we exclude that changes in the content of atoms in the atmosphere, which produce cosmogenic 14C after being hit by galactic cosmic rays, might be responsible for parts of the observed differences. When combining Q with carbon cycle changes, one needs to understand the changes in the atmospheric 14C inventory, which are partially counterintuitive. For example, during the Last Glacial Maximum, Δ14C was ∼400‰ higher compared with preindustrial times, but the 14C inventory was 10% smaller. Some pronounced changes in atmospheric Δ14C do not correspond to any significant changes in the atmospheric 14C inventory, since CO2 was changing simultaneously. Using two conceptually different models (BICYCLE‐SE and LSG‐OGCM), we derive hypothetical Qs by forcing the models with identical atmospheric CO2 and Δ14C data. Results are compared with the most recent data‐based estimates of Q derived from cosmogenic isotopes. Millennial‐scale climate change connected to the bipolar seesaw is missing in the applied models, which might explain some, but probably not all, of the apparent model‐data disagreement in Q. Furthermore, Q based on either data from marine sediments or ice cores contains offsets, suggesting an interpretation deficit in the current data‐based approaches., Key Points: No important change found in the level of precursor material, which produces cosmogenic radiocarbon after being hit by galactic cosmic rays. Transient changes in the bipolar seesaw are needed in applied carbon cycle models to improve interpretation of the radiocarbon cycle. Sediment core‐ and ice core‐based radiocarbon production rates differ systematically, suggesting missing processes., Bundesministerium für Bildung und Forschung (BMBF) http://dx.doi.org/10.13039/501100002347, Swedish Research Concil, Helmholtz Association (亥姆霍兹联合会致力) http://dx.doi.org/10.13039/501100009318, https://doi.org/10.1594/PANGAEA.871273, https://www.ncdc.noaa.gov/paleo-search/study/31772, https://doi.org/10.1594/PANGAEA.914500, https://www.iceandclimate.nbi.ku.dk/data/, https://doi.org/10.1594/PANGAEA.932965

Radiocarbon dating is the most commonly used chronological tool in archaeological and environmental sciences dealing with the past 50,000 years, making the radiocarbon calibration curve one of the most important records in paleosciences. For the past 12,560 years, the radiocarbon calibration curve is constrained by high quality tree-ring data. Prior to this, however, its uncertainties increase rapidly due to the absence of suitable tree-ring 14C data. Here, we present new high-resolution 14C measurements from 3 floating tree-ring chronologies from the last deglaciation. By using combined information from the current radiocarbon calibration curve and ice core 10Be records, we are able to absolutely date these chronologies at high confidence. We show that our data imply large 14C-age variations during the Bolling chronozone (Greenland Interstadial 1e) – a period that is currently characterized by a long 14C-age plateau in the most recent IntCal13 calibration record. We demonstrate that this lack of structure in IntCal13 may currently lead to erroneous calibrated ages by up to 500 years.