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The Central Andes of South America host the largest known lithium resources in a confined area, but the primary lithium sources of the salar deposits and the mobilisation process of lithium are still a matter of speculation. Chemical weathering at or near the surface and leaching in hydrothermal systems of the active magmatic arc are considered the two main mechanisms of Li extraction from the source rock. The lithium and strontium isotope composition of typical salar deposits offer insights into the processes on how Li brine deposits in Andean evaporites are formed. Data from the Salar de Pozuelos indicate near-surface chemical weathering in a cold and dry climate as the dominant mobilisation process of Li, with evaporation being responsible for the enrichment. The Cenozoic ignimbrites are the favoured source rock for the Li, with subordinate additions from the Palaeozoic basement. The identification of the source rocks is supported by radiogenic Nd and Pb and stable B isotope data from salar deposits. A comparison with other Li brine and salt deposits in the Altiplano-Puna Plateau and its western foothills places the Salar de Pozuelos as an endmember of Li solubilisation by chemical weathering with only minor hydrothermal mobilisation of Li., Universität Bremen (1013)

The chemical composition of metasediments is a valuable source of paleogeographic information about the protolith's sedimentary environment. Here, we compile major- and trace-element whole-rock data, including B contents, and 10/11 B-isotope ratios from the Permo-Triassic metasedimentary cover of the Pfitsch–Mörchner basin, overlying the Variscan basement in the western Tauern Window, Eastern Alps (Austria and Italy). The basement consists of orthogneiss (“Zentralgneis”, metamorphosed Variscan granitoids with intrusion ages between 305 and 280 Ma), and the roof pendant consists of granites (amphibolites, paragneiss, and minor serpentinites). The Zentralgneis is partly hydrothermally altered into pyrite quartzite with high Al–S contents, low Na–Sr–Ca–Mg contents, and very strong depletion of the light rare earth elements. Comparison with published detailed mapping of this and other time-equivalent basins in the western Tauern Window, with radiometric age data in the literature, and with unmetamorphosed basins in the South Alpine realm yields a late Permian to Early Triassic age of sedimentation. Although during Alpine metamorphism all rocks were strongly deformed, the whole-rock chemical compositions of the metasediments were not pervasively changed during deformation. We show that the sediments were deposited in a small, probably lacustrine–fluviatile, intramontane basin, under arid to semi-arid climatic conditions. The sequence starts with metaconglomerates, which can be interpreted as a mixture of the different basement rocks, based on a combination of major-element ratios Na2O / (Na2O + K2O) and MgO / (MgO + Fe2O3) with concentrations of trace elements Cr, V, and Ni. The sequence is overlain by a fining-upwards sequence of clastic sediments, in which the behavior of K, Rb, and Sr allows the reconstruction of intense diagenetic K–B metasomatism, which raised the K2O contents up to ∼ 10 wt %. The average B content of 218 µg g−1 is well above the B content of common sediments, and the B-isotope composition reaches extremely low values of down to −33 ‰ δ11B. The top of the sequence is a lazulite quartzite, interpreted as a former conglomeratic phosphatic sandstone, which marks the transition from a closed Permian basin to an open Triassic basin. Within the clastic sequence, the presence of hydrothermal tourmalinite veins documents a hydrothermal event after deposition but before the onset of Alpine metamorphism. A metamorphosed mafic dike swarm in the orthogneiss indicates a post-Variscan event of basaltic magmatism, and this event is tentatively correlated with increased heat flow in the Triassic basin and hydrothermal activity. A consistent conceptual model of this basin and its diagenetic modifications, based on a combination of geochemical data with petrographical and field information, provides the geodynamic context of the European margin at the onset of the Alpine orogeny.

Three tourmaline reference materials sourced from the Harvard Mineralogical and Geological Museum (schorl 112566, dravite 108796 and elbaite 98144), which are already widely used for the calibration of in situ boron isotope measurements, are characterised here for their oxygen and lithium isotope compositions. Homogeneity tests by secondary ion mass spectrometry (SIMS) showed that at sub‐nanogram test portion masses, their 18O/16O and 7Li/6Li isotope ratios are constant within ± 0.27‰ and ± 2.2‰ (1s), respectively. The lithium mass fractions of the three materials vary over three orders of magnitude. SIMS homogeneity tests showed variations in 7Li/28Si between 8% and 14% (1s), which provides a measure of the heterogeneity of the Li contents in these three materials. Here, we provide recommended values for δ18O, Δ’17O and δ7Li for the three Harvard tourmaline reference materials based on results from bulk mineral analyses from multiple, independent laboratories using laser‐ and stepwise fluorination gas mass spectrometry (for O), and solution multi‐collector inductively coupled plasma‐mass spectroscopy (for Li). These bulk data also allow us to assess the degree of inter‐laboratory bias that might be present in such data sets. This work also re‐evaluates the major element chemical composition of the materials by electron probe microanalysis and investigates these presence of a chemical matrix effect on SIMS instrumental mass fractionation with regard to δ18O determinations, which was found to be, Key Points: Three widely available tourmaline reference materials are characterized for δ7Li, δ17O and δ18O, while new EPMA and SIMS measurements refine their major element compositions. SIMS data document homogeneity for these isotope ratios. SIMS matrix effect causes bias of 1.9‰ between elbaite and schorl, whereas silicate glass shows even more severe bias., U.S. National Science Foundation, Natural Environment Research Council http://dx.doi.org/10.13039/501100000270, US Department of Energy http://dx.doi.org/10.13039/100000015