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Heterostructures have attracted enormous interest due to the properties arising from the coupling and synergizing between multiscale structures and the promising applications in electronics, mechanics, and optics. However, it is challenging for current technologies to precisely integrate cross-scale micro/nanomaterials in three dimensions (3D). Herein, we realize the precise spatial allocation of nanoblocks on micromatrices and programmable 3D optical heterostructure patterning via printing-assisted self-assembly. This bottom-up approach fully exploits the advantages of printing in on-demand patterning, low cost, and mass production, as well as the merits of solution-based colloidal assembly for simple structuring and high-precision regulating, which facilitates the patterned integration of multiscale materials. Importantly, the luminescent nanoparticle assembly can be accurately coupled to the dye-doped polymer matrix by regulating the interface wettability, enabling facile multicolor tuning in a single heterostructure. Thus, the heterostructure can be specially encoded for anticounterfeiting and encryption applications due to the morphology-dependent and interface-coupling-induced luminescence. Moreover, with the capability to achieve single-nanoparticle resolution, these findings have great potential for designing photonic superstructures and advanced optical devices.

For a drop on a very hot solid surface, a vapor film will form beneath the drop, which has been discovered by Leidenfrost in 1756. The vapor escaping from the Leidenfrost film causes uncontrollable flows, and actuates the drop to move around. Recently, although numerous strategies have been used to regulate the Leidenfrost vapor, the understanding of surface chemistry for modulating the phase-change vapor dynamics remains incomplete. Here, we report how to rectify vapor by “cutting” the Leidenfrost film using chemically heterogeneous surfaces. We demonstrate that the segmented film cut by a Z-shaped pattern can spin a drop, since the superhydrophilic region directly contacts the drop and vaporizes the water, while a vapor film is formed on the superhydrophobic surrounding to jet vapor and reduce heat transfer. Furthermore, we reveal the general principle between the pattern symmetry design and the drop dynamics. This finding provides new insights into the Leidenfrost dynamics modulation, and opens a promising avenue for vapor-driven miniature devices.

ConspectusThe control of droplet behavior has been investigated for several centuries due to its universality and significance in nature, daily life, and industrial applications. Diverse strategies...

Significance Adjusting the floating states when objects float on water shows great potential for assembly, mineral flotation, nanostructured construction, and floating robot design, but the real-time regulation of floating states is challenging. Inspired by the different floating states of a falling fruit, we propose a facile strategy to transform the object between different floating states based on a three-segment three-phase contact line evolution. In addition, the potential of floating state transformation in solar-powered water evaporation, interface catalysis, and drug delivery is demonstrated. These findings provide insights into floating regulation and show great potential for floating-related applications.

Nonlinear elastic materials are significant for engineering and micromechanics. Droplets with the merits of easy-accessibility, diversity, and energy-absorption capability exhibit a variety of non-Hookean elastic behaviors. Herein, benefiting from the confinement of heterogeneous-wettable parallel plates, the non-Hookean mechanics of the droplet-based spring are systematically investigated. Experimental results and theoretical analysis reveal that the force generated by the spring varies nonlinearly with its deformation, and a force model is accordingly built to depict the mechanics of springs with different sized/numbered droplets and confined by different wettability patterns. Importantly, for the droplet-based spring, the droplet-plate contact area expands nonlinearly with the pressing force, which is employed to optimize the output performance of the droplet-based triboelectric nanogenerator to 226% compared with the control test. This finding deepens the understanding of the non-Hookean behavior of droplet-based springs, and sheds light on applications in energy harvesting, micromechanics, and miniature optic/electric devices.

Developing an accurate and efficient forward model of the dynamic response of pavement structure is of great significance for obtaining the design parameters of the layered pavement structure through an inverse calculation based on the measured pavement data. However, the existing algorithms rarely consider the interlayer contact. Based on the traditional spectral element method (SEM), this study proposes a new forward model to simulate the falling weight deflectometer (FWD) dynamic tests for the transversely isotropic layered pavement structure. The interfaces between the pavement layers can be imperfect, and the displacement boundary conditions are discontinuous. Moreover, the developed model considerably enhances the efficiency of the model in solving the dynamic response of transversely isotropic layered media by avoiding the infinite integration in integral transformation. Numerical examples verify the accuracy and efficiency of the model developed in this study. At the same time, an extensive parameter analysis is conducted on the interlayer contact of the pavement structure and inhomogeneity of the layered soil, which provides a reliable, numerical, theoretical basis for the design of pavement structure.