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The project aims to test how physical deprivation (i.e., hunger) would affect state relationship orientation and then influence people's helping decisions. Trait relationship orientations are expected to moderate the effects as well. The hypotheses have been supported in a previous eye-tracking study. We are now doing a preregistered conceptual replication using another method.

This study developed a method to build relationships between chemical fractionations of heavy metals in soils and their accumulations in rice and estimate the respective contribution of each geochemical speciation in the soils from the Yangtze River Delta, China. In contaminated areas, residue and humic acid-bound fractions in soils were the main phases for most heavy metals. The mobility of heavy metals was in this following order: Cd > Pb ≈ Zn > Ni > As ≈ Cr > Hg. Transfer factors calculated by the ratios of specific fractionations of heavy metals in the soil–rice system were used to assess the capability of different metal speciation transfer from soil to rice. The carbonate and Fe/Mn oxyhydroxides bound phase had significant positive correlations with total metal concentrations in rice. Hg uptake by rice might be related to the exchangeable and carbonate-bound fractions of soil Hg. Results of PCA analysis of transfer factors estimated that the labile fractions (i.e. water soluble, exchangeable and carbonate bound) contributed more than 40% of the heavy metal accumulations in rice. Effect of organic matter and residue fraction on metals transfer was estimated to be ~ 25 to ~ 30% while contribution of humic acid and Fe/Mn oxyhydroxides-bound fractions was estimated to be ~ 20 to ~ 30%. Modified risk assessment code (mRAC) and ecological contamination index (ECI) confirmed that the soil samples were polluted by heavy metals. Soil Cd contributed more than 80% of mRAC. Contrarily, the main contributors to ECI were identified as As, Hg, Pb and Zn. The average values of total target hazard quotient (TTHQ) and Risktotal were above 1 and 10–4 respectively, implying people living in the study area were exposed to both non-carcinogenic and carcinogenic risk. As and Pb were the main contributor to high TTHQ value while As, Cd and Cr in rice contributed mostly to Risktotal value. Spatial changes of ecological risk indexes and human health risk indexes showed that the samples with high TTHQ values distributed in the area with high values of mRAC. Likewise, the area with high ECI values and with high carcinogenic risk overlapped.

Biochar and inorganic fertilizer when co‐applied have been reported to increase crop yield and enhance soil fertility. However, studies on this complementary effect on soil properties and noodle rice performance in China are still scanty. To investigate the effects of biochar application coupled with inorganic fertilizers on soil sustainability and yield and yield attributes of noodle rice, outdoor pot experiments were conducted in the early and late growing seasons in 2018. The treatment combinations were T1 (B0 t/ha + N270 kg/ha), T2 (B20 t/ha + N270 kg/ha), T3 (B40 t/ha + N270 kg/ha), T4 (B60 t/ha + N270 kg/ha), T5 (B0 t/ha + N360 kg/ha), T6 (B20 t/ha + N360 kg/ha), T7 (B40 t/ha + N360 kg/ha), and T8 (B60 t/ha + N360 kg/ha). The results compiled across the seasons showed an increase in Pn (net photosynthetic rate), grain yield, N uptake, gel consistency, amylose content (AC), and protein content in biochar‐treated pots as compared to T1. Average increases of 63.24, 63.66, 14.85, 58.0, 59.0, 22.39, and 2.9% were observed in soil porosity, moisture content, pH, organic carbon, total nitrogen, available phosphorus, and available potassium in T4 over T1 across the seasons, respectively. Root morphological characteristics such as total root length, surface area, volume, and average root diameter were significantly improved in T3, T4, T7, and T8. Starch‐related enzymes such as starch branching enzyme (SBE), starch debranching enzyme (DBE), and soluble starch synthase (SSS) were not affected significantly; however, granule‐bound starch synthase (GBSS), ADP‐glucose pyrophosphorylase (ADPG), and starch synthesis (SS) enzyme showed higher activity in 40 and 60 t B/ha across N rates. Conclusively, biochar application of 60 t/ha along with 270 kg N/ha is a promising option for improving soil quality and increasing photosynthesis, yield, and yield attributes of noodle rice.

Perfluorooctanoate (PFOA) and perfluorooctane sulfonate (PFOS) in soil aroused increasing concern, however there is little information about their transport in porous media, which is urgently needed to better control their environmental risks. In this study, saturated sand columns (considering the coupled effect of solution cation type and pH) and a two-site nonequilibrium transport model (TSM) were used to investigate the transport behaviors and mechanisms of PFOA and PFOS. Breakthrough data and the TSM parameters showed PFOA had higher mobility than PFOS, and divalent cation could inhibit their transport by increasing the nonequilibrium interactions between them and the sand. pH had little influence on PFOA migration when there was only monovalent cation in the solution since PFOA had limited affinity with the sand, however, polyvalent cation could provide additional adsorption sites for it through cation bridging and enhance the effect of pH. Differently, decreasing pH inhibited the transport of PFOS more significantly, and the effect was stronger than that of changing cation type. That proved mechanisms like hydrogen-bonding which were sensitive to solution pH played an important role in PFOS migration. These results provide important scientific basis to the remediation strategy and the migration prediction model development of PFOA and PFOS.

Li, J.; Song, Y.; Mao, C., and Li, T., 2018. Assessing the distribution characteristics of surface water geochemistry and pollution of heavy metals within soil in the Changjiang River Delta, China. In: Wang, D. and Guido-Aldana, P.A. (eds.), Select Proceedings from the 3rd International Conference on Water Resource and Environment (WRE2017). Journal of Coastal Research, Special Issue No. 84, pp. 109–113. Coconut Creek (Florida), ISSN 0749-0208.This study aimed to understand the spatial distribution and geochemical characteristics of heavy metals in soil in Changjiang River Delta, and also the impact of surface water geochemistry on the mobility of heavy metals in soil. The levels of Ca2+ and Na+ in surface water reached 80% of total cation level, ranging 33.00–97.50 mg/L and 9.00–334.90 mg/L, respectively. HCO3− was more than 50% of total anion concentration, making the type of surface water as Ca-HCO3 or Ca-Na-HCO3. The concentration of cations and anions followed the order: coastal > middle > inland. The soils were strongly polluted with Cd in this study. More than 50% of Cd concentration exceeded the standard. Spatial changes in As, Cd, and Pb levels followed the order: middle > coastal > inland, same as that for soil pH. Speciation results of heavy metals showed that more than 50% of Cd was exchangeable. Principal component analysis results showed that the change in exchangeable fraction of As, Hg, and Pb followed the same order: middle > coastal > inland. Exchangeable Cd followed a trend different from that of Cr. Three areas were characterized by the mobility of As, Hg, and Pb. Scores of samples from different areas implied the influence of surface water on the mobility of heavy metals in soil. Geochemical variation in surface water indicated the mobility of heavy metals through correlation and spatial analysis of geochemistry of surface water and speciation of heavy metals in soil.

The effects of Bacillus subtilis inoculation on the growth and Cd uptake of alfalfa were evaluated in this research using pot experiments, and the relevant biochemical mechanisms were first investigated by combined microbial diversity and nontarget metabolomics analyses. The results indicated that inoculation with alfalfa significantly decreased the amount of plant malondialdehyde (MDA) and improved the activities of plant antioxidant enzymes and soil nutrient cycling-involved enzymes, thereby promoting biomass by 29.4%. Inoculation also increased Cd bioavailability in rhizosphere soil by 12.0% and Cd removal efficiency by 139.3%. The biochemical mechanisms included enhanced bacterial diversity, transformed microbial community composition, regulated amounts of amino acids, fatty acids, carbohydrates, flavonoids and phenols in rhizosphere soil metabolites, and modulations of the corresponding Kyoto Encyclopedia of Genes and Genomes (KEGG) pathways. These responses were beneficial to microbial activity, nutrient cycling, and Cd mobilization, detoxification, and decontamination by alfalfa in soil. This study, especially the newly identified differential metabolites and metabolic pathways, provides new insights into mechanism revelation and strategy development in microbe-assisted phytomanagement of heavy metal-contaminated soils.

Consumption of crops grown in cadmium-contaminated soils is an important Cd exposure route to humans. The present study utilizes statistical analysis and in vitro digestion experiments to uncover the transfer processes of Cd from soils to the human body through rice consumption. Here, a model was created to predict the levels of bioaccessible Cd in rice grains using phytoavailable Cd quantities in the soil. During the in vitro digestion, a relatively constant ratio between the total and bioaccessible Cd in rice was observed. About 14.89% of Cd in soils was found to be transferred into rice grains and up to 3.19% could be transferred from rice grains to the human body. This model was able to sufficiently predict rice grain cadmium concentrations based on CaCl2 extracted zinc and cadmium concentrations in soils (R2 = 0.862). The bioaccessible Cd concentration in rice grains was also able to be predicted using CaCl2 extracted cadmium from soil (R2 = 0.892). The models established in this study demonstrated that CaCl2 is a suitable indicator of total rice Cd concentrations and bioaccessible rice grain Cd concentrations. The chain model approach proposed in this study can be used for the fast and accurate evaluation of human Cd exposure through rice consumption based on the soil conditions in contaminated regions.

The study evaluated source apportionment of heavy metals in vegetable samples from the potential sources of fertilizer, water and soil samples collected along the Changjiang River delta in China. The results showed that 25.72% of vegetable samples (Brassica chinensis L.) containing Pb, and Cd, Cu, Hg and Zn at relatively serious levels were from soil. Combined with principle component analysis (PCA) and cluster analysis (CA), the results of the spatial distribution of heavy metals in different environmental media indicated that fertilizer, water and soil were the main sources of heavy metals in vegetables. The results of multivariate linear regression (MLR) using partition indexes (P) showed that fertilizer contributed to 38.5%, 40.56%, 46.01%, 53.34% and 65.25% of As, Cd, Cu, Pb and Zn contents in vegetables, respectively. In contrast, 44.58% of As, 32.57% of Hg and 32.83% of Pb in vegetables came from soil and 42.78% of Cd and 66.97% of Hg contents in vegetables came from the irrigation water. The results of PCA and CA verified that MLR using P was suitable for determining source apportionment in a vegetable. A health risk assessment was performed; As, Cd and Pb contributed to more than 75% of the total hazard quotient (THQ) values and total carcinogenic risk values (Risktotal) for adults and children through oral ingestion. More than 70% of the estimated THQ and Risktotal is contributed by water and fertilizer. Therefore, it is necessary to increase efforts in screening limits/levels of heavy metals in fertilizer and irrigation water and prioritize appropriate pollution management strategies.

Xiaochigou Gold Deposit is located in the middle of Xiongershan metamorphic core complex in Qinling orogenic belt. Based on the analysis of sulfur and lead isotopes in altered rock type ores formed in the main metallogenic stage of the deposit, it is found that the δ34S of sulfur isotope of the deposit is between-3.05% and 10.93%, mostly remaining within the range of meteorite sulfur, indicating that the sulfur mainly comes from the mantle with the addition of crustal sulfur, which reflects the sulfur isotopic composition of mantle sulfur after being mixed with crustal materials. The lead isotope 206Pb/204Pb value is 17.09-17.53, 207Pb/204Pb value is 15.31-15.61, and 208Pb/204Pb value is 37.20-38.10. The variation range is not wide, belonging to normal lead range. Lead isotopic characteristic parameters and related diagrams show that the lead in ores has crust-mantle mixing characteristics. The sulfur and lead isotope compositions show that the ore-forming materials of the deposit are mainly mantle-derived materials, and the deep mantle-derived materials are mixed with crust-derived materials.

Recent applications of 3D virtual imaging techniques in human palaeontology have increased the possibilities and the accuracy of anthropological analysis. Two examples are given for the reconsideration of fossils discovered more than 20 years ago, thanks to this new technology. The Lower and Middle Pleistocene skulls from Yunxian and Nankin in China, which were damaged in the process of fossilization, have been virtually reconstructed. A detailed reinvestigation has been conducted by considering those reconstructed skulls and their unpublished characters (i.e., inner anatomical features inaccessible until now). The results of this analysis provide new information about the early hominids of China and contribute to the discussion of variability in Homo erectus. (C) 2010 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.

Crowdsourcing provides a novel and efficient paradigm to leverage numerous smartphone users to report timely information (time, location, photo, etc.) about events, enabling various urban sensing applications such as environment monitoring and public space management. Localization and photographing are two of the most important function modules in crowdsourcing based event reporting systems, which are used to tell people where and what events happen. However, the existing systems tend to localize the user instead of the event, resulting in the poor accuracy. Meanwhile, the existing event localization approaches need either complex user operation or complex computation process. For this reason, we propose a simple, effective, and light-weight approach for event localization. On the other hand, the existing systems cannot guarantee the photo authenticity, as the emerging various image editing and processing softwares have made the (malicious) photo tampering easier and easier. Accordingly, we design a novel smartphone-based photo tamper detection approach with high security. Detailed system implementation and performance evaluation are provided to verify the effectiveness of our proposed approaches.

Two fossil human crania have been found in Middle Pleistocene terrace deposits of the Han River in Yun county (Yunxian), Hubei province, China (Figs 1 and 2). These damaged but relatively complete adult specimens show a mixture of features associated both with Homo erectus and with 'archaic H. sapiens'. The Yunxian crania (Figs 3 and 4), although crushed and distorted to varying degrees, are unusual in having major elements of the basicranium, palate, face and cranial vault preserved together. The specimens reveal many details of facial and basicranial anatomy rarely seen in hominid crania of comparable antiquity. Moreover, they are the most complete crania of such great age discovered on the Asian mainland. They consequently throw new light on Middle Pleistocene hominid diversity and the relationships among regionally disparate Middle Pleistocene hominids.

PurposeThe primary purpose of this paper is to explore possible locations for parity cache within disk array model and describe the disk array model development process.Design/methodology/approachA dynamic, discrete event simulation model, based on modular, bottom‐up approach, is initiated from a single disk, and then extended on disk array.FindingsParity information within array model cannot be stored on individual disk cache, instead it should be stored in array cache. If model is used for simulation of single disk array then an approach with separate parity cache should be used, while an approach where a parity cache is part of array cache should be used for simulation of more complex storage systems with numerous arrays.Research limitations/implicationsThe proposed model does not include any read‐ahead cache policy, and only a full‐stripe writes can be performed. As a result, the model should be used only for sequential read or write of large files because then those limitations do not influence simulation output.Originality/valueThe novelty depicted in this paper is an approach, in array modelling, with parity cache merged into array cache. Also, the achieved bandwidth for the resulting simulation model differs from 1.05 to 1.7 per cent from the measured one on the experimental array.