1. Understanding the Role of Triplet-triplet Annihilation in Non-fullerene Acceptor Organic Solar Cells
- Author
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Hart, Lucy J. F., Grüne, Jeannine, Liu, Wei, Lau, Tsz-ki, Luke, Joel, Chin, Yi-Chun, Jiang, Xinyu, Zhang, Huotian, Sowood, Daniel J. C., Unson, Darcy M. L., Kim, Ji-Seon, Lu, Xinhui, Zou, Yingping, Gao, Feng, Sperlich, Andreas, Dyakonov, Vladimir, Yuan, Jun, and Gillett, Alexander J.
- Subjects
FOS: Physical sciences ,Physics - Applied Physics ,Applied Physics (physics.app-ph) - Abstract
Non-fullerene acceptors (NFAs) have enabled power conversion efficiencies exceeding 19% in organic solar cells (OSCs). However, the open-circuit voltage of OSCs remains low relative to their optical gap due to excessive non-radiative recombination, and this now limits performance. Here, we consider an important aspect of OSC design, namely management of the triplet exciton population formed after non-geminate charge recombination. By comparing the blends PM6:Y11 and PM6:Y6, we show that the greater crystallinity of the NFA domains in PM6:Y11 leads to a higher rate of triplet-triplet annihilation (TTA). We attribute this to the four times larger ground state dipole moment of Y11 versus Y6, which improves the long range NFA out-of-plane ordering. Since TTA converts a fraction of the non-emissive triplet states into bright singlet states, it has the potential to reduce non-radiative voltage losses. Through a kinetic analysis of the recombination processes under 1-Sun illumination, we provide a framework for determining the conditions under which TTA may improve OSC performance. If these could be satisfied, TTA has the potential to reduce non-radiative voltage losses by up to several tens of mV and could thus improve OSC performance., Comment: 41 pages, 5 figures
- Published
- 2023
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