1. Charge transfer and magnetotransport properties of Sr1-La Ru1-Co O3 epitaxial thin films
- Author
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Wang, Changan, Zhang, Hongbin, Deepak, Kumar, Chen, Chao, Dash, Umasankar, Kumar, D., Lee, Kyoungjun, Suraj, T.S., Rao, M.S. Ramachandra, Chae, Seung Chul, Fouchet, A., Lee, Suyoun, Prellier, Wilfrid, Jung, Chang Uk, Laboratoire de cristallographie et sciences des matériaux (CRISMAT), École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Normandie Université (NU)-Centre National de la Recherche Scientifique (CNRS)-Université de Caen Normandie (UNICAEN), Normandie Université (NU)-Institut de Chimie du CNRS (INC), Université de Caen Normandie (UNICAEN), Normandie Université (NU)-Normandie Université (NU)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche sur les Matériaux Avancés (IRMA), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Rouen Normandie (UNIROUEN), Normandie Université (NU)-Institut national des sciences appliquées Rouen Normandie (INSA Rouen Normandie), Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Rouen Normandie (UNIROUEN), Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS), Hankuk University of Foreign Studies (HUFS), Seoul National University [Seoul] (SNU), Indian Institute of Technology Madras (IIT Madras), and Korea Advanced Institute of Science and Technology (KAIST)
- Subjects
Materials science ,Magnetoresistance ,SrRuO3 ,02 engineering and technology ,Substrate (electronics) ,010402 general chemistry ,Epitaxy ,01 natural sciences ,LaCoO3 ,Charge transfer ,X-ray photoelectron spectroscopy ,Electrical resistivity and conductivity ,Materials Chemistry ,Antiferromagnetism ,[CHIM]Chemical Sciences ,Magnetotransport ,Thin film ,ComputingMilieux_MISCELLANEOUS ,[PHYS]Physics [physics] ,Condensed matter physics ,Mechanical Engineering ,Exchange interaction ,Metals and Alloys ,[CHIM.MATE]Chemical Sciences/Material chemistry ,021001 nanoscience & nanotechnology ,Epitaxial thin film ,0104 chemical sciences ,Mechanics of Materials ,0210 nano-technology - Abstract
International audience; We studied the electronic and magnetotransport properties of Sr1-xLaxRu1-xCoxO3 epitaxial thin films (0 ≤ x ≤ 0.30) grown on atomically flat SrTiO3 (001) substrates. The epitaxial strain from the SrTiO3 substrate would give compressive strain on Sr1-xLaxRu1-xCoxO3 when the film has the same amount of charge transfer as that observed in the bulk sample. If the epitaxial strain applied by the SrTiO3 substrate overrides the charge transfer, it can block half the amount of charge transfer. However, the observed unit cell volume and X-ray photoelectron spectroscopy data clearly reveal that the amount of charge transfer in our epitaxial thin film is approximately the same as that observed in the previously reported bulk samples. The saturation magnetization decreased for all Sr1-xLaxRu1-xCoxO3 thin films, with an increase in the antiferromagnetic behavior. The zero-field resistivity value of all the compositions increased systematically, with a higher resistivity observed at x = 0.30 (ρ(T = 10 K) 450 mΩ cm). A large negative magnetoresistance of up to ∼24.8% was also observed at x = 0.30 (H = 9 T, T = 10 K). We tried to explain our data in terms of super exchange interaction added to existing double exchange interaction between Ru–Co networks.
- Published
- 2020