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A method is presented to measure the decay rate of the first excited vibrational state of polar molecular ions being part of a Coulomb crystal in a cryogenic linear Paul trap . Speci f- ically, we have monitored the decay of the |ν=1,J=1> X towards the |ν=0,J=0> X level in MgH + by saturated laser excitation of the |ν=0,J=2> X - |ν =1,J=1> X transition followed by state selective reso nance - enhanced two - photon dissociation out of the |ν=0,J=2> X level. The technique can be extended to other simple molecular ions and it enables the determination, with an accur a- cy at the few percent level , of decay rates and thus absorption strengths.

We demonstrate resolved sideband laser cooling of a single 40Ca+ ion in a macroscopic linear radio frequency trap with a radial diagonal electrode spacing of 7 mm and an rf drive frequency of just 3.7 MHz. For an oscillation frequency of 585 kHz along the rf-field-free axis, a ground state population of 99+-1% has been achieved, corresponding to a temperature of only 6 microkelvin. For several oscillation frequencies in the range 285 - 585 kHz, heating rates below one motional quantum per second have been measured at room temperature. The lowest measured heating power is about an order of magnitude lower than reported previously in room temperature, as well as cryogenically cooled traps., Comment: 4 figures

We demonstrate the implementation of a spin qubit with a single Ca ion in a micro ion trap. The qubit is encoded in the Zeeman ground state levels mJ=+1/2 and mJ=-1/2 of the S1/2 state of the ion. We show sideband cooling close to the vibrational ground state and demonstrate the initialization and readout of the qubit levels with 99.5% efficiency. We employ a Raman transition close to the S1/2 - P1/2 resonance for coherent manipulation of the qubit. We observe single qubit rotations with 96% fidelity and gate times below 5mus. Rabi oscillations on the blue motional sideband are used to extract the phonon number distribution. The dynamics of this distribution is analyzed to deduce the trap-induced heating rate of 0.3(1) phonons/ms.

We report on the loading of large ion Coulomb crystals into a linear Paul trap incorporating a high-Finesse optical cavity (F~3200). We show that, even though the 3-mm diameter dielectric cavity mirrors are placed between the trap electrodes and separated by only 12 mm, it is possible to produce in situ ion Coulomb crystals containing more than 100.000 calcium ions of various isotopes and with lengths of up to several millimeters along the cavity axis. We show that the number of ions inside the cavity mode is in principle high enough to achieve strong collective coupling between the ion Coulomb crystal and the cavity field. The results thus represent an important step towards ion trap based Cavity Quantum ElectroDynamics (CQED) experiments using cold ion Coulomb crystals.

We report on the observations of three-dimensional long-range ordered structures in the central $^{40}$Ca$^+$ ion component of $^{40}$Ca$^+$--$^{44}$Ca$^+$ two-species ion Coulomb crystals in a linear Paul trap. In contrast to long-range ordering previously observed in single species crystals, the structures observed are strikingly persistent and always of one specific type in one particular orientation. Molecular dynamics simulations strongly indicate that these characteristics are a hitherto unpredicted consequence of the co-axial cylindrical symmetry of the central ion component of the Coulomb crystal and the radio frequency quadrupole trapping field., Comment: Abstract and conclusion changed. Fig. 4 corrected

Using a technique based on production of ion Coulomb crystals, the isotope shifts of the 4s(2) S-1(0)-->4s5p P-1(1) transition for all naturally occurring isotopes of calcium as well as the hyperfine splitting of the 4s5p P-1(1) state in Ca-43 have been measured. The field shift and specific mass shift coefficients as well as the hyperfine structure constants for Ca-43 have been derived from the data.

Using a technique based on production of ion Coulomb crystals, the isotope shifts of the 4s2 1S0 -> 4s5p 1P1 transition for all naturally occurring isotopes of calcium as well as the hyperfine splitting of the 4s5p 1P1 state in Ca-43 have been measured. The field shift and specific mass shift coefficients as well as the hyperfine structure constants for Ca-43 have been derived from the data., Comment: 6 pages,6 figures, to be published in Phys. Rev. A

Using a technique based on production of ion Coulomb crystals, the isotope shifts of the 4s2 1S0 -> 4s5p 1P1 transition for all naturally occurring isotopes of calcium as well as the hyperfine splitting of the 4s5p 1P1 state in Ca-43 have been measured. The field shift and specific mass shift coefficients as well as the hyperfine structure constants for Ca-43 have been derived from the data., 6 pages,6 figures, to be published in Phys. Rev. A

The translational motion of molecular ions can be effectively cooled sympathetically to translational temperatures below 100 mK in ion traps through Coulomb interactions with laser-cooled atomic ions. The ro-vibrational degrees of freedom, however, are expected to be largely unaffected during translational cooling. We have previously proposed schemes for cooling of the internal degrees of freedom of such translationally cold but internally hot heteronuclear diatomic ions in the simplest case of ^1-Sigma electronic ground state molecules. Here we present a significant simplification of these schemes and make a generalization to the most frequently encountered electronic ground states of heteronuclear molecular ions: ^1-Sigma, ^2-Sigma, ^3-Sigma and ^2-Pi. The schemes are relying on one or two laser driven transitions with the possible inclusion of a tailored incoherent far infrared radiation field., Comment: 16 pages, 13 figures

The translational motion of molecular ions can be effectively cooled sympathetically to temperatures below 100 mK in ion traps through Coulomb interactions with laser-cooled atomic ions. The distribution of internal rovibrational states, however, gets in thermal equilibrium with the typically much higher temperature of the environment within tens of seconds. We consider a concept for rotational cooling of such internally hot, but translationally cold heteronuclear diatomic molecular ions. The scheme relies on a combination of optical pumping from a few specific rotational levels into a ``dark state'' with redistribution of rotational populations mediated by blackbody radiation., Comment: 4 pages, 5 figures

Sympathetic Coulomb crystallization of highly charged ions, retrapped in a cryogenic radiofrequency trap, is demonstrated by an over seven orders-of-magnitude decrease in motional temperature.