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Lead-free Cs2AgBiBr6 double perovskite is considered a promising alternative photovoltaic absorber to the widely-used lead halide perovskite thanks to its easy processability, high stability and reduced toxicity. Herein, we report for the first-time spray processing for the deposition of Cs2AgBiBr6 double perovskite thin films. We compare microstructural (X-ray diffraction, scanning electron microscopy) and optoelectronic (absorbance, photoluminescence, photocurrent density versus applied voltage curves, electrochemical impedance spectroscopy) properties of spray-coated film with the spin-coated benchmark. Incorporation of the spray-coated Cs2AgBiBr6 double perovskite thin films in solar cells leads to a 2.3% photoconversion efficiency with high open-circuit voltage of 1.09 V. This study highlights the suitability of ultrasonic spray deposition for the optimization of Cs2AgBiBr6 solar cells in terms of light absorption properties and charge transfer at the Cs2AgBiBr6/hole transporting layer interface.

Lead-free Cs2AgBiBr6 double perovskite is considered a promising alternative photovoltaic absorber to the widely-used lead halide perovskite thanks to its easy processability, high stability and reduced toxicity. Herein, we report for the first-time spray processing for the deposition of Cs2AgBiBr6 double perovskite thin films. We compare microstructural (X-ray diffraction, scanning electron microscopy) and optoelectronic (absorbance, photoluminescence, photocurrent density versus applied voltage curves, electrochemical impedance spectroscopy) properties of spray-coated film with the spin-coated benchmark. Incorporation of the spray-coated Cs2AgBiBr6 double perovskite thin films in solar cells leads to a 2.3% photoconversion efficiency with high open-circuit voltage of 1.09 V. This study highlights the suitability of ultrasonic spray deposition for the optimization of Cs2AgBiBr6 solar cells in terms of light absorption properties and charge transfer at the Cs2AgBiBr6/hole transporting layer interface.

We report the results of electrical resistivity measurements carried out on well-sintered La0.7Ca0.3MnO3 / Mn3O4 composite samples with almost constant composition of the magnetoresistive manganite phase (La0.7Ca0.3MnO3). A percolation threshold (fc) occurs when the La0.7Ca0.3MnO3 volume fraction is ~ 0.19. The dependence of the electrical resistivity as a function of La0.7Ca0.3MnO3 volume fraction (fLCMO) can be described by percolation-like phenomenological equations. Fitting the conducting regime (fLCMO > fc) by the percolation power law returns a critical exponent t value of 2.0 +/- 0.2 at room temperature and 2.6 +/-0.2 at 5 K. The increase of t is ascribed to the influence of the grain boundaries on the electrical conduction process at low temperature., 7 pages, 3 figures, accepted for publication in Phys. Rev. B

This paper proposes a systematic way to explore the effects of Na on Bi-2212 phase formation. The influence of sodium metal is correlated with the 2212 fraction formed in the sample. The effect on the sintering temperature and the importance of the substitution site is studied. Samples are characterized by X-ray diffraction analysis (XRD). Results clearly show that the 2212 phase content is enhanced and sintering temperatures can be lowered with regard to the undoped samples., Results to be presented at EUCAS 2005

This paper has been withdrawn, Comment: This paper has been withdrawn

This paper aims to study Na doping in Bi-2212 superconducting ceramics. Na-doped Bi-2212 samples powders with a Bi2-uSr2-vCa1-wCu2-xNayOz stoichiometry are prepared by means of thermal treatments. The intended Na substitution level, y, is fixed at 0.3. The initial content of the other ions is adopted so that Na substitution on one crystallographic site only is expected. Samples are characterized by electrical properties, X-ray diffraction analysis (XRD) and Energy Dispersive X-ray analysis (EDX). The influence of Na on the crystal chemistry and phases compatibility for 2212 materials is emphasized. Electrical resistivity results show that the critical temperature is independent of the sample initial stoichiometry. In some cases the production of a Bi-2223 phase is however enhanced., Comment: Results to be presented at EUCAS 2005

We report a detailed set of AC magnetic measurements carried out on bulk large grain La-Ca-Mn-O samples extracted from a floating zone method-grown rod. Three samples with $La_{0.78}Ca_{0.22}Mn_{0.90}O_{x}$ stoichiometry but differing in their microstructure were investigated by electrical resistivity and AC susceptibility measurements: (i) a single grain sample, (ii) a sample containing two grains and (iii) a polycrystalline sample. We show that the superimposition of DC magnetic fields during AC magnetic susceptibility measurements is an efficient way for characterizing the magnetic transition of samples with different microstructures. Whereas both single grain and polycrystalline samples display a single susceptibility peak, an additional kink structure is observed in the case of the double grain sample. The temperature dependence of the AC susceptibility measured with superimposed DC magnetic fields is analyzed in the framework of second-order phase transition ideas. The relations between the critical exponents ($\beta + \gamma$ ~ 1.5, $\delta$ ~ 2.5) are found to be close to those of the mean-field model for all samples. This is attributed to the disordering caused by unoccupied Mn sites., Comment: 25 pages, including 5 figures

Several experimental techniques have been used in order to characterize the properties of multifilamentary Bi-2223 / Ag tapes. Pristine samples were investigated by electrical resistivity, current-voltage characteristics and DC magnetic moment measurements. Much emphasis is placed on comparing transport (direct) and magnetic (indirect) methods for determining the critical current density as well as the irreversibility line and resolving usual lacks of consistency due to the difference in measurement techniques and data analysis. The effect of an applied magnetic field, with various strengths and directions, is also studied and discussed. Next, the same combination of experiments was performed on bent tapes in order to bring out relevant information regarding the intergranular coupling. A modified Brandt model taking into account different types of defects within the superconducting filaments is proposed to reconciliate magnetic and transport data., Comment: 10 pages (2 columns); 8 figures; 1 table. submitted to Supercond. Sci. Technol

Nearly a 50% decrease of resistivity \rho (T,x) due to just 4% Cu doping on the Mn site of La(2/3)Ca(1/3)Mn(1-x)Cu(x)O(3) is observed. Attributing the observed phenomenon to the substitution induced decrease of the spin polaron energy E_s(x) below the Curie point T_C(x)=T_C(0)(1-x), all data are found to be well fitted by the nonthermal coherent tunneling expression \rho (T,x) = \rho_0*exp(-\gamma M^2(T,x)) assuming M(T,x)=M_R(x)+M_0(x)*tanh{\sqrt{[T_C(x)/T]^2-1}} for the magnetization in the ferromagnetic state. The best fits through all the data points yield M_0(x)= \sqrt(1-x)M_0(0), M_R(x)=\sqrt(x)M_0(0), and E_s(x)=E_s(0)(1-x)^4 for the Cu induced modifications of the Mn spins dominated zero-temperature spontaneous magnetization, the residual paramagnetic contribution, and spin-polaron energy, respectively, with E_s(0)=0.12 eV., Comment: 3 pages (REVTEX), 2 PS figures (epsf.sty); submitted to Phys.Rev.B

From general arguments, it is shown that a magnetic Kronig-Penney model based on the thermodynamics of an Ising model can be used for describing the Colossal Magnetoresistance (CMR) phenomenon. The model considers a tunneling-like transmission process of hopping electrons through a dynamic lattice characterized by evolving magnetic clusters. In this model, correlations between the magnetic states are considered to be more relevant than the lattice strain effects for obtaining the CMR features. Physical arguments lead to the theoretical description of the intrinsic temperature and field dependences of the CMR observed in typical manganite materials., REVTEX (epsf.sty), 5 PS figures; submitted to Phys. Rev. B

We report precise measurements of the electrical resistivity in three different Bi(Pb) based granular ceramics superconductors. We show that a single critical exponent (5/6) describes the superconductivity fluctuations. Such a critical exponent indicates a fractal behavior of the superconducting path. Our results thus indicate a strict two dimensional fluctuation percolation set (below the superconductivity onset temperature 195 K down to T(c)), and provide some proof for Tarascon et al. “shell conductivity path” hypothesis. We estimate the shell thickness to be of the order of 10 angstrom.

We report on microwave measurements on DyBa$_2$Cu$_3$O$_{7-\rm\delta}$ monodomains grown by the top-seeded melt-textured technique. We measured the field increase of the surface resistance $R_{\rm s}(H)$ in the a-b plane at 48.3 GHz. Measurements were performed at fixed temperatures in the range 70 K - $T_{\rm c}$ with a static magnetic field $\mu_0H, Comment: 17 pages, 5 figures; ISS2010 proceedings, to be published as a special issue of Physica C

We present a microwave characterization of a DyBa$_{2}$Cu$_{3}$O$_{7-x}$ single domain, grown by the top-seeded melt-textured technique. We report the (a,b) plane field-induced surface resistance, $\Delta R_s(H)$, at 48.3 GHz, measured by means of a cylindrical metal cavity in the end-wall-replacement configuration. Changes in the cavity quality factor Q against the applied magnetic field yield $\Delta R_s(H)$ at fixed temperatures. The temperature range [70 K ; T_c] was explored. The magnetic field $\mu_0 H, Comment: 6 pages, 4 figures, LaTeX, submitted to Journal of Applied Physics