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The timing of the onset of magnetochron M0r and its duration are disputed, reflecting both a limited set of radioisotopic dates and uncertain magnetostratigraphic correlations. We present a chronostratigraphic framework for a reversed polarity interval based on two chronometers (40Ar/39Ar, U-Pb) and newly published paleomagnetic data from the Qingshan Group, Jiaolai Basin, China. Bayesian modeling of U-Pb zircon and 40Ar/39Ar sanidine dates suggests a minimum duration of 540 ± 37 k.y. (95% credible interval) for the reversed polarity interval. These findings are compatible with an astrochronologic age model for M-sequence seafloor magnetic anomalies, indicating that the reversely magnetized sediments correspond to magnetochron M0r rather than the shorter chron “M-1r.” Integration of U-Pb and 40Ar/39Ar ages constrains the onset of M0r to 120.29 ± 0.09 Ma, which is ~1 m.y. younger than that inferred in the current geologic time scale (GTS 2020). This finding also implies that the Cretaceous normal superchron (CNS) began at 119.70 ± 0.12 Ma and that the average seafloor spreading rate during the CNS was ~3.5% higher than that inferred from GTS 2020. It also suggests that oceanic anoxic event 1a began at 119.40 ± 0.12 Ma, thereby providing an updated chronologic basis for exploring the primary trigger of this carbon cycle perturbation.

The Wilkins Peak Member (WPM) of the Green River Formation in Wyoming, USA, comprises alternating lacustrine and alluvial strata that preserve a record of terrestrial climate during the early Eocene climatic optimum. We use a Bayesian framework to develop age-depth models for three sites, based on new 40Ar/39Ar sanidine and 206Pb/238U zircon ages from seven tuffs. The new models provide two- to ten-fold increases in temporal resolution compared to previous radioisotopic age models, confirming eccentricity-scale pacing of WPM facies, and permitting their direct comparison to astronomical solutions. Starting at ca. 51 Ma, the median ages for basin-wide flooding surfaces atop six successive alluvial marker beds coincide with short eccentricity maxima in the astronomical solutions. These eccentricity maxima have been associated with hyperthermal events recorded in marine strata during the early Eocene. WPM strata older than ca. 51 Ma do not exhibit a clear relationship to the eccentricity solutions, but accumulated 31%−35% more rapidly, suggesting that the influence of astronomical forcing on sedimentation was modulated by basin tectonics. Additional high-precision radioisotopic ages are needed to reduce the uncertainty of the Bayesian model, but this approach shows promise for unambiguous evaluation of the phase relationship between alluvial marker beds and theoretical eccentricity solutions.

The 40Ar/39Ar dating method is among the most versatile of geochronometers, having the potential to date a broad variety of K-bearing materials spanning from the time of Earth’s formation into the historical realm. Measurements using modern noble-gas mass spectrometers are now producing 40Ar/39Ar dates with analytical uncertainties of ~0.1%, thereby providing precise time constraints for a wide range of geologic and extraterrestrial processes. Analyses of increasingly smaller subsamples have revealed age dispersion in many materials, including some minerals used as neutron fluence monitors. Accordingly, interpretive strategies are evolving to address observed dispersion in dates from a single sample. Moreover, inferring a geologically meaningful “age” from a measured “date” or set of dates is dependent on the geological problem being addressed and the salient assumptions associated with each set of data. We highlight requirements for collateral information that will better constrain the interpretation of 40Ar/39Ar data sets, including those associated with single-crystal fusion analyses, incremental heating experiments, and in situ analyses of microsampled domains. To ensure the utility and viability of published results, we emphasize previous recommendations for reporting 40Ar/39Ar data and the related essential metadata, with the amendment that data conform to evolving standards of being findable, accessible, interoperable, and reusable (FAIR) by both humans and computers. Our examples provide guidance for the presentation and interpretation of 40Ar/39Ar dates to maximize their interdisciplinary usage, reproducibility, and longevity.

This paper documents a tidally incised, mudstone-prone tributary valley fill linked to a trunk valley in the backwater limit of the Turonian Notom Delta of the Ferron Sandstone Member, Utah. High-resolution 3D photogrammetry models were used to correlate a 20-m-deep valley between 32 measured sections over a 1 km2 area. A GPS survey and GIS geostatistical tools were used to restore the morphology of the tributary valley. The restored valley floor is interpreted as a surface of tidal erosion, based on the overlying facies and surface morphology. Morphological similarities exist between this tributary valley and modern analogs observed in northern Australia, the Memramcook tributary in the Bay of Fundy, and Pleistocene sediments in the Gulf of Thailand. 40Ar/39Ar dating of sanidine crystals using multi-collector mass spectrometry allow for a re-evaluation of depositional rates and timing of 32 fluvial aggradation cycles (FACs) and 9 fluvial-aggradation cycle sets (FAC sets) in this sequence. The new dates show that the entire sequence was deposited in 15 ± 5 kyr, and show that Milankovitch cycles cannot account for the internal complexity of this fluvial stratigraphy, indicating likely autogenic control of the FAC sets. The lateral extent of FACs in floodplain deposits mapped in outcrop are correlated over tens to hundreds of meters, and scale to estimated channel widths reflecting the autogenic control. FAC sets can be correlated for up to 10 km along depositional strike, which suggest controls unrelated to the dynamics of individual channels and may show some elements of allogenic climate-driven processes.

Since the publication of 40Ar/39Ar dates from Cretaceous bentonites in the Western Interior Basin by J.D. Obradovich in 1993 and in Japan by J.D. Obradovich and colleagues in 2002, improvements in the 40Ar/39Ar method have included a shift to astronomically calibrated ages for standard minerals and development of a new generation of multi-collector mass spectrometers. Thus, the 40Ar/39Ar chronometer can yield results that are synchronous with U-Pb zircon dates and astrochronologic age models for Cretaceous strata. Ages determined by Obradovich have ± 2σ analytical uncertainties of ± 400 ka (excluding J value or systematic contributions) that have been used to discriminate stratigraphic events at ca. 1 Ma resolution. From among several dozen sanidine samples, 32 of which were dated by Obradovich in 1993, we present new multi-collector 40Ar/39Ar ages that reduce the average analytical uncertainties by nearly an order of magnitude. These new ages (where the uncertainties also include the contribution of the neutron fluence J value) include: Topmost Bentonite, Mowry Shale, Kaycee, Wyoming, USA, 97.52 ± 0.09 Ma Clay Spur Bentonite, Mowry Shale, Casper, Wyoming, 98.17 ± 0.11 Ma Arrow Creek Bentonite, Colorado Shale, Montana, USA, 99.12 ± 0.14 Ma Upper Newcastle Sandstone, Black Hills, Wyoming, 99.49 ± 0.07 Ma Middle Newcastle Sandstone, Black Hills, Wyoming, 99.58 ± 0.12 Ma Shell Creek Shale, Bighorn Basin, Crow Reservation, Wyoming, 99.62 ± 0.07 Ma Shell Creek Shale, Bighorn Basin, Greybull, Wyoming, 99.67 ± 0.13 Ma Shell Creek Shale, Bighorn Basin, Lander, Montana, 100.07 ± 0.07 Ma Muddy Sandstone, Wind River Basin, Wyoming, 101.23 ± 0.09 Ma Thermopolis Shale, Bighorn Basin, Wyoming, 101.36 ± 0.11 Ma Vaughn Member, Blackleaf Formation, Sweetgrass Arch, Montana, 102.68 ± 0.07 Ma Taft Hill Member, Blackleaf Formation, Sweetgrass Arch, Montana, 103.08 ± 0.11 Ma Base of the Skull Creek Shale, Black Hills, Wyoming, 104.87 ± 0.10 Ma Thermopolis Shale, Bighorn Basin, Wyoming, 106.37 ± 0.11 Ma A new U-Pb zircon age of 104.69 ± 0.07 Ma from the Skull Creek Shale at Dinosaur Ridge, Colorado, USA, is close to the new 40Ar/39Ar age of the Skull Creek Shale in the Black Hills, Wyoming, but 5 m.y. is missing in the unconformity between the Skull Creek Shale of the Black Hills and the overlying Newcastle Sandstone. Considering the average total uncertainties that include decay constant and standard age or tracer composition for the 40Ar/39Ar (± 0.19 Ma) and the U-Pb (± 0.13 Ma) ages does not alter this finding. Moreover, the lower Thermopolis Shale in the Bighorn Basin is 1.5 Ma older than the Skull Creek Shale in the Black Hills. The 100.07 ± 0.07 Ma Shell Creek Bentonite in Montana is close to the Albian–Cenomanian boundary age of 100.2 ± 0.2 Ma of Obradovich and colleagues from Hokkaido, Japan, and 100.5 ± 0.5 Ma adopted in the 2012 geological time scale of J.G. Ogg and L.A. Hinnov. Our findings indicate that correlations based on similarity of lithology, without independent radioisotopic ages or detailed biostratigraphic constraints, can be problematic or invalid. There is much more time missing in unconformities than has been previously recognized in these important, petroleum-bearing reservoir strata.

Controls on high-frequency sequences formed during super-greenhouse conditions in the Late Cretaceous Western Interior Seaway remain equivocal because of the active foreland basin tectonic setting and the lack of direct evidence of polar glaciations to support a glacio-eustatic origin. This paper quantifies eustatic sea-level changes based on high-resolution sequence stratigraphic analysis and improved chronometry of shallow marine deposits of the Late Cretaceous Gallup Sandstone in New Mexico, USA. Backstripping techniques remove tectonic and compactional subsidence and enable quantification of the magnitude of eustatic sea-level change, that allow evaluation of the dominant controls on the high-frequency sequences to resolve the role of orbitally controlled, climate-driven eustasy versus tectonics. Sixty-five parasequences, constituting 29 parasequence sets and 12 sequences are identified in the ∼1.2 m.y. duration of the Late Cretaceous Gallup system. New 40Ar/39Ar dating of bentonites constrains the durations of the individual parasequences, parasequence sets, and sequences, and that these match Milankovitch periodicity, indicating an orbital climate control. The magnitudes of sea-level changes between parasequences range between −28 m and +22 m, which are compatible with hypotheses of both aquifer and glacio-eustasy. Aquifer-eustasy predicts a reciprocal relationship between floodplain cycles and shallow marine sequences, such that aquifer drawdown and falling water tables should correlate to rising sea levels (highstands), whereas increased aquifer storage and rising water tables should correlate to falling sea levels (lowstands). Our preliminary observations show synchronous, versus reciprocal, relationships that may be more compatible with a glacio-eustatic origin. The results of this study support the hypothesis that the Cretaceous greenhouse was marked by high-frequency, low-amplitude glaciations driven by orbital climate cycles, but further work is required to evaluate the contribution of aquifer-eustasy.

The crater and proximal effects of the largest known young meteorite impact on Earth have eluded discovery for nearly a century. We present 4 lines of evidence that the 0.79-Ma impact crater of the Australasian tektites lies buried beneath lavas of a long-lived, 910-km3 volcanic field in Southern Laos: 1) Tektite geochemistry implies the presence of young, weathered basalts at the site at the time of the impact. 2) Geologic mapping and 40Ar-39Ar dates confirm that both pre- and postimpact basaltic lavas exist at the proposed impact site and that postimpact basalts wholly cover it. 3) A gravity anomaly there may also reflect the presence of a buried ∼17 × 13-km crater. 4) The nature of an outcrop of thick, crudely layered, bouldery sandstone and mudstone breccia 10-20 km from the center of the impact and fractured quartz grains within its boulder clasts support its being part of the proximal ejecta blanket. Ministry of Education (MOE) National Research Foundation (NRF) Published version This work was funded primarily by the Earth Observatory of Singapore, which receives most of its funding from the National Research Foundation Singapore and the Singapore Ministry of Education under the Research Centers of Excellence initiative. We acknowledge and appreciate the participation and generosity of the Department of Mineral Resources and Environment, Thailand, the Department of Geology and Mines, Lao PDR, and the Facility for Analysis, Characterisation, Testing, and Simulation at Nanyang Technological University.

Within extended orogens, records that reflect the driving processes and dynamics of early extension are often overprinted by subsequent orogenic collapse. The Copper Mountains of northeastern Nevada preserve an exceptional record of hinterland extensional deformation and high-elevation basin formation, but current geochronology and thermochronology are insufficient to relate this to broader structural trends in the region. This extension occurred concurrent with volcanism commonly attributed to Farallon slab removal. We combine thermochronology of both synextensional hanging-wall strata and footwall rocks to comprehensively evaluate the precise timing and style of this deformation. Specifically, we apply (U-Th)/(He-Pb) double dating of minerals extracted from Eocene–Oligocene Copper Basin strata with multi-mineral (U-Th)/He and 40Ar/39Ar thermochronology of rocks sampled across an ∼20 km transect of the Copper Mountains. We integrate basement and detrital thermochronology records to comprehensively evaluate the timing and rates of hinterland extension and basin sedimentation. Cooling and U-Pb crystallization ages show the Coffeepot Stock, which spans the width of the Copper Mountains, was emplaced at ca. 109–108 Ma, and then cooled through the 40Ar/39Ar muscovite and biotite closure temperatures by ca. 90 Ma, the zircon (U-Th)/He closure temperature between ca. 90 and 70 Ma, and the apatite (U-Th)/He closure temperature between 43 and 40 Ma. Detrital apatite and zircon (U-Th)/(He-Pb) double dating of late Eocene fluvial and lacustrine strata of the Dead Horse Formation and early Oligocene fluvial strata of the Meadow Fork Formation, both deposited in Copper Basin, shows that Early Cretaceous age detrital grains have a cooling history that is analogous to proximal intrusive rocks of the Coffeepot Stock. At ca. 38 Ma, cooling and depositional ages for Copper Basin strata reveal rapid exhumation of proximal source terranes (cooling rate of ∼37 °C/m.y.); in these terranes, 8–12 km of slip along the low-angle Copper Creek normal fault exhumed the Coffeepot Stock in the footwall. Late Eocene–early Oligocene slip along this fault and an upper fault splay, the Meadow Fork fault, created a half graben that accommodated ∼1.4 km of volcaniclastic strata, including ∼20 m of lacustrine strata that preserve the renowned Copper Basin flora. Single-crystal sanidine 40Ar/39Ar geochronology of interbedded tuffs in Copper Basin constrains the onset of rapid exhumation to 38.0 ± 0.9 Ma, indicating that surface-breaching extensional deformation was coincident with intense proximal volcanism. Coarse-grained syndeformational sediments of the Oligocene Meadow Fork Formation were deposited just prior to formation of an extensive regional Oligocene–Miocene unconformity and represent one of the most complete hinterland stratigraphic records of this time. We interpret this history of rapid late Eocene exhumation across the Copper Mountains, coeval volcanism, and subsequent unconformity formation to reflect dynamic and thermal effects associated with Farallon slab removal. The final phase of extension is recorded by late, high-angle normal faults that cut and rotate the early middle Miocene Jarbidge Rhyolite sequence, deposited unconformably in the hanging wall. These results provide an independent record of episodic Paleogene to Miocene exhumation documented in Cordilleran metamorphic core complexes and establish that substantial extension occurred locally in the hinterland prior to province-wide Miocene extensional break-up.

Basins in orogenic hinterlands are directly coupled to crustal thickening and extension through landscape processes and preserve records of deformation that are unavailable in footwall rocks. Following prolonged late Mesozoic–early Cenozoic crustal thickening and plateau construction, the hinterland of the Sevier orogen of western North America underwent late Cenozoic extension and formation of metamorphic core complexes. While the North American Cordillera is one of Earth’s best-studied orogens, estimates for the spatial and temporal patterns of initial extensional faulting differ greatly and thus limit understanding of potential drivers for deformation. We employed (U-Th)/(He-Pb) double dating of detrital zircon and (U-Th)/He thermochronology of detrital apatite from precisely dated Paleogene terrestrial strata to quantify the timing and magnitude of exhumation and explore the linkages between tectonic unroofing and basin evolution in northeastern Nevada. We determined sediment provenance and lag time evolution (i.e., the time between cooling and deposition, which is a measure of upper-crustal exhumation) during an 8 m.y. time span of deposition within the Eocene Elko Basin. Fluvial strata deposited between 49 and 45 Ma yielded Precambrian (U-Th)/He zircon cooling ages (ZHe) with 105–740 m.y. lag times dominated by unreset detrital ages, suggesting limited exhumation and Proterozoic through early Eocene sediment burial (1 km/m.y., indicative of rapid, large-magnitude extensional faulting and metamorphic core complex formation. Contemporaneous with this acceleration of hinterland exhumation, syntectonic freshwater lakes developed in the hanging wall of the Ruby Mountains–East Humboldt Range metamorphic core complex at ca. 43 Ma. Volcanism driven by Farallon slab removal migrated southward across northeastern Nevada, resulting in voluminous rhyolitic eruptions at 41.5 and 40.1 Ma, and marking the abrupt end of fluvial and lacustrine deposition across much of the Elko Basin. Thermal and rheologic weakening of the lithosphere and/or partial slab removal likely initiated extensional deformation, rapidly unroofing deeper crustal levels. We attribute the observed acceleration in exhumation, expansion of sedimentary basins, and migrating volcanism across the middle Eocene to record the thermal and isostatic effects of Farallon slab rollback and subsequent removal of the lowermost mantle lithosphere.

Fluctuations in depositional conditions during the onset of severe climate events in Earth history predispose stratigraphic archives to hiatuses, often hindering complete reconstructions of paleoclimate events and their triggers. Several studies have proposed that a hiatus of unknown duration exists at the base of Oceanic Anoxic Event 2 (OAE2) in the North American Western Interior Basin at the base Turonian global boundary stratotype section and point (GSSP) in Pueblo, Colorado, which potentially influences integrated radioisotopic, biostratigraphic, and astrochronologic age models of the Cenomanian-Turonian boundary interval. To quantify the duration of this hiatus, refine the chronology of OAE2, and assess marine geochemical perturbations associated with the onset of the event, we present new 40Ar/39Ar dates from regional bentonites along with a new proximal-distal chemostratigraphic transect of the epeiric Western Interior Basin (WIB), including initial osmium isotope (Osi) and stable carbon isotope (δ13C) data. The new 40Ar/39Ar age determinations confirm and further constrain previous estimates of Cenomanian-Turonian boundary timing. Further, the regional chemostratigraphic synthesis demonstrates the conformity of the OAE2 successions correlated to Pueblo, shows that the duration of the lag between the onset of the Osi and δ13C excursions is ∼60 k.y., and thus constrains the magnitude of the pre-OAE2 hiatus in Pueblo to less than this value. The new astronomically tuned, conformable Osi record across the onset of OAE2 captures a geologically rapid onset of large igneous province volcanism, consistent with other records, such that the addition of CO2 to the ocean-atmosphere system may have driven changes in marine carbonate chemistry. Additionally, the refined chronostratigraphy of OAE2 and the Cenomanian-Turonian boundary in the central WIB improves correlation with other records, such as those in the Eagle Ford Group, Texas. The correlations highlight that discrepancies among OAE2 age models from globally distributed sections commonly stem from differing definitions of the event and uncertainties associated with astronomical tuning, in addition to stratigraphic preservation.

Shallow high-silica granites provide a window into processes that may precede many styles of rhyolitic volcanic eruptions., Rhyolitic melt that fuels explosive eruptions often originates in the upper crust via extraction from crystal-rich sources, implying an evolutionary link between volcanism and residual plutonism. However, the time scales over which these systems evolve are mainly understood through erupted deposits, limiting confirmation of this connection. Exhumed plutons that preserve a record of high-silica melt segregation provide a critical subvolcanic perspective on rhyolite generation, permitting comparison between time scales of long-term assembly and transient melt extraction events. Here, U-Pb zircon petrochronology and 40Ar/39Ar thermochronology constrain silicic melt segregation and residual cumulate formation in a ~7 to 6 Ma, shallow (3 to 7 km depth) Andean pluton. Thermo-petrological simulations linked to a zircon saturation model map spatiotemporal melt flux distributions. Our findings suggest that ~50 km3 of rhyolitic melt was extracted in ~130 ka, transient pluton assembly that indicates the thermal viability of advanced magma differentiation in the upper crust.

The Tuya-Kawdy region of northern British Columbia is well established as a place where glaciation and volcanism overlapped in space. However, no modern work has integrated observations from the region’s volcanic and glacial deposits with geochronologic constraints to summarize how they might overlap in time. Here, we provide a general overview of such characteristics and 23 new 40Ar/39Ar eruption ages of glaciovolcanic deposits ranging from 4.3 Ma to 63 ka to constrain the timing, location, and minimum thicknesses and distributions of coincident ice. Subaerial lava fields interspersed with glaciovolcanism record periods of ice-sheet absence in presumably warmer climate conditions. These generally coincide with interglacial marine isotope stages. Many of the volcanoes have a secondary record of posteruption glacial modification, cirques, erratics, and mega-lineations, which document later climate changes up to the present. We used edifice-based terrain analysis to reconstruct changes to local minimum Cordilleran ice-sheet thicknesses, extents, and flow directions at specific locations and times during the late Pliocene and the Pleistocene.

The Eocene Huitrera Formation of northwestern Patagonia, Argentina, is renowned for its diverse, informative, and outstandingly preserved fossil biotas. In northwest Chubut Province, at the Laguna del Hunco locality, this unit includes one of the most diverse fossil floras known from the Eocene, as well as significant fossil insects and vertebrates. It also includes rich fossil vertebrate faunas at the Laguna Fría and La Barda localities. Previous studies of these important occurrences have provided relatively little sedimentological detail, and radioisotopic age constraints are relatively sparse and in some cases obsolete. Here, we describe five fossiliferous lithofacies deposited in four terrestrial depositional environments: lacustrine basin floor, subaerial pyroclastic plain, vegetated, waterlogged pyroclastic lake margin, and extracaldera incised valley. We also report several new 40Ar/39Ar age determinations. Among these, the uppermost unit of the caldera-forming Ignimbrita Barda Colorada yielded a 40Ar/39Ar age of 52.54 ± 0.17 Ma, ∼6 m.y. younger than previous estimates, which demonstrates that deposition of overlying fossiliferous lacustrine strata (previously constrained to older than 52.22 ± 0.22 Ma) must have begun almost immediately on the subsiding ignimbrite surface. A minimum age for Laguna del Hunco fossils is established by an overlying ignimbrite with an age of 49.19 ± 0.24 Ma, confirming that deposition took place during the early Eocene climatic optimum. The Laguna Fría mammalian fauna is younger, constrained between a valley-filling ignimbrite and a capping basalt with 40Ar/39Ar ages of 49.26 ± 0.30 Ma and 43.50 ± 1.14 Ma, respectively. The latter age is ∼4 m.y. younger than previously reported. These new ages more precisely define the age range of the Laguna Fría and La Barda faunas, allowing greatly improved understanding of their positions with respect to South American mammal evolution, climate change, and geographic isolation., Centro de Investigaciones Geológicas

40Ar/39Ar geochronology relies on magnetic sector mass spectrometers to determine relative isotopic abundances. Ongoing technological developments within noble gas mass spectrometers over the last decade have led to analysis of increasingly smaller samples and higher precision, but also result in more complex data correction and interpretation. We describe a new multi-collector noble gas spectrometer, the Isotopx NGX-600, that is configured to optimize 40Ar/39Ar measurements. The NGX-600 is equipped with 9 Faraday collectors and one ion counting electron multiplier. Each Faraday is equipped with Isotopx ATONA® amplifier technology, enabling measurements spanning a dynamic range of amplified beam current from below 10−16 A to above 10−9 A. The performance of the NGX-600 is evaluated using both a conventional Nier-type ion source, and a next generation low temperature ion source, which allows for trap current variation from 200 μA to 1000 μA. We have performed over 3000 analyses of atmospheric argon to: (1) assess optimal measurement and integration times for blanks, baselines, and air aliquots of various ion intensities, (2) quantify the sensitivity via measurements of first principles 40Ar/39Ar standards, (3) compare the sensitivity between the conventional and new low temperature Nier-type ion sources, and (4) evaluate corrections associated with inter-Faraday biases, instrumental mass bias, and Faraday-multiplier gain. In addition to optimization experiments, we report a comparative analysis of both single crystal fusion and incremental heating data from Quaternary volcanic rocks obtained using both the 5-collector Nu Instruments Noblesse and the NGX-600 spectrometers.

Figures S1–S15 and Tables S1–S2.

Long-term fluvial incision processes and corresponding geomorphic evolution are difficult to quantify, especially in complex systems affected by lithological and tectonic factors. Volcanic landscapes offer the most appropriate environment for the study of landscape evolution, as there is a clear starting time of formation and the lithology is homogenous. In the present study we aim to: (1) analyse the interplay of construction and incision processes throughout eruptive activity; (2) study fluvial erosion processes; (3) analyse sedimentary and volcanic lithological responses to channel erosion; and (4) calculate the incision rates in young basaltic bedrock. We have integrated existing and new 40Ar/39Ar ages of lava flows with estimates of channel geometry and tectonic activity, and considered process geomorphology concepts, to fully understand evolution of a bedrock channel incised at the boundary between basalts and sedimentary rocks with coeval active volcanic processes forcing drainage evolution. Our findings indicate that the Sa'ar basin evolution is controlled by: (1) rock strength of the mixed lithology; (2) alternating cycles of volcanic activity followed by erosion and incision; and (3) the Plio-Pleistocene uplift of Mt. Hermon. The carbonate slopes composing the southern flank of Mt. Hermon are moderate (18–26%) while the basalt slopes deriving from the Golan Heights are much steeper (26–51%). The highly erodible sedimentary rocks at Mt. Hermon's piedmont accelerated river incision, shaping a 650 m wide by 100 m deep canyon. Inside the canyon, the steep channel slope (8.6%) enables downstream movement of large boulders, including autochthonous mega-blocks (D90 size > 2.5 m); 24 knickpoints were identified using DS plots, developed within a knick zone over a distance of 6 km. The brittle and porous structure of the rubbly and blocky interflow layers (clinkers), interbedded between two massive basalt flows, enhances erosion and accelerates scouring of the plunge-pool bottom and walls. Three volcanic phases shaped the Sa'ar basin: (1) The 3.25 Ma Cover Basalt flowed over large areas of the Levant and reached up to the northern Golan; (2) Dalwe Basalt was emplaced between ~ 1.2 Ma and ~ 750 ka, from vents including Mt. Qatzaa and Mt. Odem, and extended to Mt. Hermon covering sedimentary cuestas; (3) Ein Zivan Basalt (including the Sa'ar Lava Flow – the youngest basalt flow known in Israel) erupted before ~ 110–120 ka and quickly accumulated at least three distinct flows into the deeply incised Paleo-Sa'ar canyon, refilling the canyon to a height of ~ 50 m. Rates of incision are consistent with other rivers draining the Golan Heights. The total incision rate of the Sa'ar channel during the last 760 ka is at least 19.7 cm/ka. Over the past 100 ka, the incision rate was 22–30 cm/ka and the back-erosion of the Sa'ar highest knickpoint occurred at 68 cm/ka. Our findings reflect the latest evolution history of a special, mixed lithology channel, developed at the border of a large basaltic province, in an active tectonic environment. The results suggest that fluvial adjustment of basalt-limestone rivers is determined first by the interplay of construction and incision processes throughout alternating cycles of volcanic activity and quiescence. The lithology is an extremely important factor determining the type and rate of erosion. While the tectonic factor might determine the basin relief and slope, the lithological factor accelerates erosion and river incision.

The Andean Southern Volcanic Zone comprises > 30 active arc front volcanoes that grew over periods of hundreds of thousands of years. Quantifying the rates at which these volcanoes grow is key to appreciating geological hazards, clarifying petrologic evolution, and exploring possible relationships between volcanism, ice loading, and climate. The integration of precise geochronology and geologic mapping, together with new lava compositions and volume estimates, reveal the evolution of the Antuco-Sierra Velluda volcanic complex at 37.2°S. Thirty-one new 40Ar/39Ar age determinations illuminate a punctuated eruptive history that spans at least 430 kyr. Sierra Velluda comprises ~ 130 km3 and began to grow prior to 426.8 ka. A lacuna in the volcanic record between 343.5 and 150.4 ka coincides with glaciations associated with marine isotope stages (MIS) 10 and 8, although shallow intrusions were emplaced at 207.0 and 190.0 ka. Antuco began to grow rapidly on the northeast flank of Sierra Velluda, erupting > 60 km3 of lava during three phases: (1) an early phase that began at 150.4 ka, (2) a post-MIS 2 phase between 16.3 and 6.2 ka, and (3) a post-sector collapse phase after 6.2 ka. Volcanism has been continuous during the last 100 kyr, with an average rate of cone growth during this period of ~ 0.46 km3/kyr that has accelerated by about 50% during the past 6 kyr. Whereas Sierra Velluda erupted basaltic andesitic to andesitic (53.5 to 58.7 wt% SiO2) lavas, during the last expansion of glaciers between ~ 130 and 17 ka, Early Antuco erupted a wider spectrum of lavas, ranging from basaltic andesite to dacite (52.0 to 64.5 wt% SiO2). Notably, eruptions following the last glacial termination at 17 ka produced basalts and basaltic andesites (50.9–53.7% SiO2), and following the 6.2 ka cone collapse they have been exclusively olivine basalt (50.9–53.0% SiO2) with > 5 wt% MgO. Thermodynamic and trace element modeling suggests that lavas from Sierra Velluda and Early Antuco reflect extensive fractional crystallization of parental basaltic magmas with low water content (~ 1 wt%) at pressures between 0.9 and 1.5 kbar. In contrast, eruptions following rapid deglaciation tapped asthenospheric mantle-derived basalt that has been extensively modified by assimilation of partial melts of lower crustal rocks.

Hinterland basins can accumulate high resolution archives of orogenic processes and continental climate, but are challenging to reconstruct due to tectonic overprinting and the inherent complexity of their lithofacies assemblages. The Cordilleran hinterland of northeast Nevada has been interpreted to have overlain a flattened Farallon slab from the Late Cretaceous to Eocene. Slab removal and advection of asthenospheric mantle beneath Nevada have been invoked to explain a southwestward migrating wave of Eocene to Oligocene volcanism and proposed as a driver for topographic uplift. However, the timing of slab removal and possible subsequent delamination of North American lithospheric mantle can only ambiguously be related to the surface record. Subsequent Neogene extension and basin filling has complicated the correlation and interpretation of strata that record these events. Here we apply single crystal sanidine 40Ar/39Ar geochronology to 26 ash beds in northeast Nevada to reconstruct Paleogene geographic and hydrologic evolution. We use these ages and legacy geochronology to compare lithofacies and isotope proxy records of meteoric waters to regional tectonics and global climate, and assess competing tectonic interpretations for lake basin formation. Lakes formed locally prior to ca. 48.7 Ma in northeast Nevada, coeval with foreland lakes of the Green River Formation. The most expansive phase of lacustrine deposition resulted in onlap onto locally derived fluvial deposits and folded Paleozoic bedrock, and occurred between ca. 43.4 and ca. 40.8 Ma. Elko Formation strata exhibit a basin-wide transition from fluvial-lacustrine to fluctuating profundal lithofacies at ca. 42.7 Ma, suggesting a shift towards regional hydrologic closure. The stromatolitic upper Elko Formation is intercalated with ash fall tuffs and several partially welded to unwelded ignimbrites from increasingly proximal volcanism. Elko Formation deposition ended by ca. 40.4 Ma. 40Ar/39Ar ages for seven ash beds in the Dead Horse Formation at Copper Basin in northern Elko County indicate intermittent ash bed deposition between 45.2 Ma and 38.6 Ma, and an episode of lacustrine deposition between 39.8 Ma and 38.6 Ma that post-dates the main phase of Lake Elko. δD values of volcanic glass sampled from dated ash beds reflect changes in the hydrogen isotope compositions of local Eocene waters, and systematically vary by 80–102‰ according to their depositional environment. The Elko Formation and overlying volcanic strata are overlain regionally by a pronounced unconformity of ∼20 m.y. In the Copper Basin area, deposition continued locally into the Oligocene in the hanging wall of a ductile detachment. The geochronologic and isotopic framework presented here permits reanalysis of the Pinon Range carbonate proxy record that was previously interpreted to record both regional uplift and the middle Eocene climatic optimum. New data suggest instead that isotope values of hydration waters within the Elko Formation were strongly influenced by evaporation, and a change from lacustrine to non-lacustrine conditions can account for the δ 18 O shift that was interpreted to reflect regional uplift. Moreover, the end of Elko Formation deposition predated the middle Eocene climatic optimum. We interpret the overall record of drainage ponding and paleovalley inundation, progressively more evaporative lacustrine conditions, increasingly proximal volcanism, and subsequent prolonged unconformity to reflect the surface effects of progressive NE to SW removal of the Farallon slab.

New geochronologic data from midcontinental Laurentia demonstrate that emplacement of the 1476–1470 Ma Wolf River granitic batholith was not an isolated igneous event, but was accompanied by regional metamorphism, deformation, and sedimentation. Evidence for such metamorphism and deformation is best seen in siliciclastic sedimentary rocks of the Baraboo Interval, which were deposited closely following the 1.65–1.63 Ga Mazatzal orogeny. In Baraboo Interval strata, muscovite parallel to slatey cleavage, in hydrothermal veins, in quartzite breccia, and in metamorphosed paleosol yielded 40Ar/39Ar plateau ages of 1493–1465 Ma. In addition, U–Th–total Pb dating of neoblastic overgrowths on detrital monazite gave an age of 1488 ± 20 Ma, and recrystallized hematite in folded metapelite gave a mean U/Th–He age of 1411 ± 39 Ma. Post-Baraboo, arkosic polymictic conglomerate, which contains detrital zircon with a minimum peak age of 1493 Ma, was intruded by a 1470 Ma granite porphyry at the northeastern margin of the Wolf River batholith. This episode of magmatism, regional deformation and metamorphism, and sedimentation, which is designated herein as the Baraboo orogeny, provides a midcontinental link between the Picuris orogeny to the southwest and the Pinware orogeny to the northeast, completing the extent of early Mesoproterozoic (Calymmian) orogenesis for 5000 km along the southern margin of Laurentia. This transcontinental orogen is unique among Precambrian orogenies for its great width (~1600 km), the predominance of ferroan granites derived from partial melting of lower continental crust, and the prevalence of regional high T-P metamorphism related to advective heating by granitic magmas emplaced in the middle to upper crust.

Accurate and precise ages of large silicic eruptions are critical to calibrating the geologic timescale and gauging the tempo of changes in climate, biologic evolution, and magmatic processes throughout Earth history. The conventional approach to dating these eruptive products using the 40Ar/39Ar method is to fuse dozens of individual feldspar crystals. However, dispersion of fusion dates is common and interpretation is complicated by increasingly precise data obtained via multicollector mass spectrometry. Incremental heating of 49 individual Bishop Tuff (BT) sanidine crystals produces 40Ar/39Ar dates with reduced dispersion, yet we find a 16-ky range of plateau dates that is not attributable to excess Ar. We interpret this dispersion to reflect cooling of the magma reservoir margins below ∼475 °C, accumulation of radiogenic Ar, and rapid preeruption remobilization. Accordingly, these data elucidate the recycling of subsolidus material into voluminous rhyolite magma reservoirs and the effect of preeruptive magmatic processes on the 40Ar/39Ar system. The youngest sanidine dates, likely the most representative of the BT eruption age, yield a weighted mean of 764.8 ± 0.3/0.6 ka (2σ analytical/full uncertainty) indicating eruption only ∼7 ky following the Matuyama−Brunhes magnetic polarity reversal. Single-crystal incremental heating provides leverage with which to interpret complex populations of 40Ar/39Ar sanidine and U-Pb zircon dates and a substantially improved capability to resolve the timing and causal relationship of events in the geologic record.

Earth’s last magnetic field reversal was complex, with excursions at 795 and 784 ka before a final polarity flip at 773 ka., Reversal of Earth’s magnetic field polarity every 105 to 106 years is among the most far-reaching, yet enigmatic, geophysical phenomena. The short duration of reversals make precise temporal records of past magnetic field behavior paramount to understanding the processes that produce them. We correlate new 40Ar/39Ar dates from transitionally magnetized lava flows to astronomically dated sediment and ice records to map the evolution of Earth’s last reversal. The final 180° polarity reversal at ~773 ka culminates a complex process beginning at ~795 ka with weakening of the field, succeeded by increased field intensity manifested in sediments and ice, and then by an excursion and weakening of intensity at ~784 ka that heralds a >10 ka period wherein sediments record highly variable directions. The 22 ka evolution of this reversal suggested by our findings is mirrored by a numerical geodynamo simulation that may capture much of the naturally observed reversal process.

New 40Ar/39Ar ages and paleomagnetic data are presented from a wide range of ignimbrites and lava flows from the region east of the Atacama Desert in the northern Chilean part of Central Volcanic Zone of the Andes. Eight dacitic to rhyolitic ignimbrites, 12 lava flows and one shallow intrusion were dated by the 40Ar/39Ar incremental heating method, and are the first 40Ar/39Ar ages reported for these units. Ignimbrites range in age from 4.2 Ma to 0.5 Ma, with the ~100 km3 Puripicar ignimbrite dated at 4.18 ± 0.02 Ma, the ~2500 km3 Atana ignimbrite, one of the largest ignimbrites in the world, at 3.99 ± 0.02 Ma, and the Purico ignimbrite at 0.99 ± 0.03 Ma. The new 40Ar/39Ar ages fall within the uncertainty limits of published K-Ar dates for the Purico, Patao and Puripicar tuffs but are different at the 95% confidence level for Atana and Talabre tuffs. Isochron ages from the 12 lava flows range from 3.5 Ma to 0.1 Ma, with 11 of the flows younger than 2.5 Ma. One lava sample and the shallow intrusion are from the Plio-Pleistocene magnetite-rich El Laco volcanic complex, and give ages of 2.18 ± 0.03 Ma and 1.83 ± 0.09 Ma respectively. Paleomagnetic directions from 49 sites (23 ignimbrites and 26 lava flows) provide a mean direction of I = −43.8°, D = 352.7° with α95 = 10.0°, and a corresponding mean pole position of −81.1° and 179.1°. Normal directions are predominantly from lava flows and have steeper than expected inclinations (ΔI = 15.3°) whereas reverse sites are mostly ignimbrites and yield directions close to the geo-axial dipole field (ΔI = −3.6°). Paleosecular variation studies on a selection of 39 sites yield an angular standard deviation of site poles about the mean pole of 18.5°, considerably larger than predicted by current models of magnetic field variation with latitude.

Recent ICDP drilling and deep basin volcanic exploration of 3000 m below the surface in the Songliao Basin (SB) have highlighted the 3-D delineation of the basin. The integrated new data led us to reevaluate the basin tectonics, for which the basin type, basin evolution and a number of geodynamic aspects have been controversial topics. We outline the position of a main lithospheric scale detachment fault beneath the SB, based on apparent crustal scale displacements, Moho breaks, the thinning of the Moho transition zone beneath the SB and the changing mantle thickness. This fault interpretation is consistent with simple shear as the rift mechanism. Based on a comprehensive analysis of the tectonic setting, underlying crust, structural style, sequence stratigraphy, subsidence history and volcanism, we propose an active continental margin model for the SB which shows some similarities to aulacogens but also notable differences. Situated between two Late Mesozoic active continental margins, the northern/northwestern Mongol–Okhotsk and the eastern Sikhote-Alin orogenic belts, the Cretaceous basin evolved on a pre-Triassic structurally weak basement mosaic. Its development began with regional mega-rifting from 150 to 105 Ma, followed by significant sagging between 105 and 79.1 Ma and ended with regional uplift and basin inversion from 79.1 to 64 Ma. Three regional angular unconformities separate the basin fill into three respective tectono-stratigraphic sequences. (1) The syn-rift stage is characterized by widespread fault-bounded grabens and volcanogenic successions, corresponding upward to the Huoshiling, Shahezi and Yingcheng Formations. (2) The post-rift stage includes the Denglouku, Quantou, Qignshankou, Yaojia and Nenjiang Formations. It is a special feature that the subsidence rate is abnormally high (mean of 103 m/Ma), and that flood basalt erupted along an axial wrench fault zone, associated with several marine intervals from the mid-Turonian to early Campanian (K 2 qn to K 2 n), possibly (not certainly) indicating incipient sea floor spreading characterized by Moho breaks along the basin axis in the SB around 88 Ma. Stretching stopped abruptly at approximately 79.1 Ma and was followed by uplift and rapid erosion (− 145 m/Ma). (3) Recorded by the Sifangtai and Mingshui Formations the structural inversion stage included a continuous depocenter migration to the northwest. The basin was shrinking to demise as a result of changing subduction parameters of the Pacific subduction zone. In addition to the three tectonic basin cycles, a cyclic basin fill pattern exists with three volcanic basin fill intervals of Huoshiling, Yingcheng, and upper Qingshankou Formations that alternate with sedimentary basin fill intervals of Shahezi, Dengloukou-Quantou, and Yaojia-Nenjiang Formations. When determining the subsidence rates, we observed not only anomalously fast subsidence but also found an intricate link between the subsidence rate and type of basin fill. After each volcanic interval, the subsidence rates increased in a cyclic fashion during the sedimentary intervals. Thus, there is a system of three different types of important, basin-wide geological cycles that controlled the evolution of the SB. The subsidence rate was especially high (up to 199 m/Ma) after the last volcanic episode at 88 Ma. In addition to thermal subsidence and loading by the basin fill as causative processes, we also consider magmatic processes related to asthenospheric upwelling beneath the SB. They involve the roof collapse of shallow, depleted magma chambers, the igneous accretion of initially hot, dense, basic rocks, and lithospheric delamination beneath the SB. The difference in the subsidence rates during the volcanic and sedimentary intervals may in part also have been due to heating-related uplift during the volcanic intervals. The particularly high subsidence during the Late Cretaceous sedimentary cycles was partly increased by transtension. We put forward a general model for active continental margin basins. They are generally similar to aulacogens but display the following differences. In active continental margin basins, rifting depends on the subduction parameters that may cause strong to mild extension in the giant marginal region. The geochemical composition of the volcanic rocks is more calc-alkaline in nature because they are suprasubduction-related. These basins will eventually enter a post-rift sag stage that involves thermal subsidence. However, the basin will still be near an active continental margin, and, thus, some dip- and/or strike-slip faulting may occur coevally, depending on the subduction parameters. Sag cycles in active continental margin basins will likely include volcanism. Basin inversion will after all affect active continental margin basins. Such basins strike parallel to the respective continental margin. Thus, basin inversion by subduction/collision may be more intense than in the case of aulacogens, which do not tend to strike parallel to the continental margin. Basin inversion may also precede a collision due to changing subduction parameters. Subsidence behavior may also differ because many aspects of subsidence may be at work. Subsidence curves in active continental margin basins may be fairly individual. The application of our model only requires settings with the presence of one Pacific margin type.

The rewards from resolving the tempo of magmatic, paleobiologic, paleoclimatic, and tectonic processes at better than the per mil level of precision have spurred a quest within the geochronology community to improve the precision, accuracy, and calibration of several chronometers, including the 40 Ar/ 39 Ar variant of the K-Ar clock. A new generation of multi-collector mass spectrometers for 40 Ar/ 39 Ar geochronology provides the means to address these issues, as well as to evaluate the ages of 40 Ar/ 39 Ar standards and key marker horizons deposited by large volume, caldera-forming supereruptions in the western U.S. at unprecedented temporal resolution. We highlight the utility of a 5-collector Noblesse mass spectrometer that has a sufficiently high mass resolving power to distinguish 36 Ar + H 35 Cl from a 36 Ar + H 35 Cl + 12 C 3 sum peak at m/e 36, maintains a remarkably low and stable background, and thus yields 40 Ar/ 39 Ar dates of exceptionally high precision. We have calibrated a reference gas and developed a simple analytical routine involving one peak hop, both of which are used to evaluate detector-bias correction factors. Because the 40 Ar/ 39 Ar chronometer is a relative dating technique that relies on calibration against mineral standards of known age, precise and accurate determination of the ages of these standards, and verification of isotopic composition and homogeneity, is essential. We present results from both total fusion and incremental heating experiments on single crystals of the widely used Alder Creek (ACs) and Fish Canyon (FCs) sanidine standards. Several recent, independent, measurements of ACs using multi-collector mass spectrometers, including those presented herein, favor an age of 1.1864 ± 0.0003/0.0012 Ma (95% confidence analytical/full external uncertainty), that is > 1% younger than the widely used value obtained by Nomade et al. (2005) using a single collector mass spectrometer. Incremental-heating experiments on single crystals of FCs most commonly do not yield plateau ages, instead many crystals appear to be affected by Ar loss or excess Ar. Our findings, obtained using ion counters, independently confirm those recently obtained using a multiple-Faraday detectors or a combination of Faraday and ion counting detectors. Thus, careful consideration must be given to using FCs in future high-precision 40 Ar/ 39 Ar calibrations of the geologic timescale. Notwithstanding, 40 Ar/ 39 Ar dating of sanidine using the 5- collector Noblesse can now provide leverage critical to interpreting the large range of U–Pb zircon dates commonly found in rhyolitic lavas and tuffs.