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The applicability of the developed binary system of synthetic compounds in coating paste, consisting of urea-formaldehyde oligomer (2 pts. wt. to the coating paste weight) and latex (16 pts. wt.), is found. It replaces the generally used complex of natural compounds, such as modified starch (3 pts. wt.), Na-CMC (2 pts. wt.), and casein glue (1 pts. wt.), in the presence of latex (16–32 pts. wt.). The properties of the coating paste samples met the standards, as evidenced by the viscosity according to the viscometer VZ-4 (13–17 s), the content of dry substances (50–54 %) and pH (9.0–10.5). The proposed urea-formaldehyde oligomer is combined with the present components and, as compared to natural compounds, does not increase the viscosity of the coating paste, has a high cohesive force, participating in the binding of pigment particles with one another, has the necessary adhesive capacity for ensuring a stable bond of the applied coating layer with the surface of paper and cardboard, does not prevent the uniform distribution of pigment particles on the base surface, and gives stability to the coating paste. These phenomena can be explained by the supplementary presence of positively charged nitrogen-containing groups (amine and amide) in the urea formaldehyde oligomer. The latter contribute to the enhancement of cohesive and adhesive interactions in coating pastes and coatings composed of them. Assessment of a section of the coated paper (cardboard) showed that one part of the binder adjoins the base (paper, cardboard) penetrating into its pores and capillaries, the other surrounds the pigment particles, and the third occupies (completely or partially) the spaces between the particles. An increase in the surface resistance to plucking and breaking length by 6.0–8.5 and 15–20 %, respectively, is shown on the samples of light-coated newsprint and polygraphic cardboard. This allows considering the urea-formaldehyde oligomer as an alternative to natural compounds. Herewith, whiteness (85–87 %) and smoothness (250–265 s) meet the requirements. Changing the formulation of the coating paste is economically justified, since material costs for the production of coated paper and cardboard products are reduced by 1–2 %.For citation: Chornaya N.V., Bogdanovich N.I., Karpova S.V., Misyurov O.A. Application of Urea-Formaldehyde Oligomer for Quality Improvment of Paper and Cardboard Products. Lesnoy Zhurnal [Russian Forestry Journal], 2020, no. 6, pp. 182–193. DOI: 10.37482/0536-1036-2020-6-182-193

Recently, the interest in active packaging utilization has increased with population growth, food demand and new consumer trend like food delivery services. This new system, however, requires the use of additives to extend the food product quality and safety as well as in maintaining the shelf-life. This study was to prepare the antimicrobial paper from I. cylindrica coated anionic nanocellulose crosslinked cationic to create a system with the ability to actively control microbe growth in the packaging materials. The process involved pulping of I. cylindrica using semi-chemical and soda chemical method. The antimicrobial paper was prepared by printing the pulp suspension in 60 g/m2 grammage in mold followed by the spray of anionic nanocellulose and subsequent soaking of the paper in cationic solution. The results showed the I. cylindrica paper coated anionic nanocellulose crosslinked with H+ and Al3+ cations were successfully produced. The paper produced was also observed to have antimicrobial activity against Gram-negative of E. coli and S. typhi as well as Gram-positive of S. aureus and B. subtilis bacteria. Furthermore, the best coating method was found on antimicrobial paper coated anionic nanocellulose crosslinked Al3+ as evidenced by smoother and compact surface structure.

Soft, skin-mounted microfluidic devices can collect microliter volumes of eccrine sweat and are capable of in situ real-time analysis of different biomarkers to assess physiological state and health. Chrono-analysis of sweat can be implemented to monitor temporal variations of biomarker concentrations over a certain period of interest. Conventional methods used to capture sweat or some of the newly developed microfluidic platforms for sweat collection and analysis are based on absorbent pads. They suffer from evaporation, leading to considerable deviations in the concentration of the biomarkers. Here, a paperintegrated microfluidic device is presented for sequential analysis of sweat that is easy to fabricate and does not include air exits for each reservoir, which reduces undesirable effects of sweat evaporation. Furthermore, the high capillary force of filter paper is leveraged to route the liquid into the chambers in a sequential fashion and allow further chemical analysis. The employed design of the paper-embedded microfluidic device successfully samples and analyzes artificial sweat sequentially for flow rates up to 5 ?L min?1 without showing any leakage. We demonstrated the performance of the device, employing colorimetric assays for chrono-analysis of glucose standard solutions at concentrations in the range of 10– 100 mM and pH of sweat during exercise. The results reveal the presented approach's functionality and potential to analyze the concentration of biomarkers over a certain period sequentially., Scientific and Technological Research Council of Turkey (TÜBİTAK); European Union (EU); Horizon 2020; Marie Sklodowska-Curie Individual Fellowship

The scalable fabrication of flexible membranes for efficient oil/water separation is in high demand but still significantly underdeveloped. Here, we present a flexible membrane using Ti3C2Tx (MXene) as the functional layer on conventional print paper as the substrate. With a simple coating process using MXene ink, we developed a highly hydrophilic and oleophobic membrane with an underwater oil contact angle of 137°. Such a simple membrane shows outstanding flexibility and robustness, and demonstrates a facile approach for membrane scale-up using MXene ink on low-cost print paper. The membrane shows high separation efficiency for oil/water emulsions, of over 99%, and a high water permeation flux of over 450 L per m2 per h per bar. We demonstrate the excellent anti-fouling property of this membrane by cleaning the membranes without chemicals. These low-cost, highly efficient, anti-fouling membranes can provide new opportunities for industrial oil/water separation applications. Other information Published in: RSC Advances License: https://creativecommons.org/licenses/by-nc/3.0 See article on publisher's website: http://dx.doi.org/10.1039/c9ra02129a

The paper discusses a self tuning control algorithm for a multivariable plant applied to a grammage cross profile control of a paper machine. The plant model represents the steady-state couplings as well as the dynamics behaviour of the system. The control algorithm handles special situations including the case where the numper of measurments is not equal to the numper of actuators and the case where special actuators are locked. The whole identification algorithm with a specical filter and an estimation of the required measurment accuary for a succesful identification of the steady-state couplings will be discussed. The paper shows how to proof the stability of the control system including the cases of locked actuators and identification errors. Finally, the whole conrol system is verified by in house simulations and at a real plant. The obtained control results are discussed.

The main environmental risks in the area of landfills are considered, all aspects of their technological reclamation using waste from the Baikal PPM are discussed. The data on the creation of soil and grounds using lignin-destroying microbiological preparations are presented. The final stage of the remediation of the Solzan landfill is the creation of cadastral maps 8, 9, 10 modern forest nurseries on the site, protected by flood and mudflow protection structures.

Maturity of vermicomposted end products obtained from citronella bagasse (CB) and a mixture of citronella bagasse and paper mill sludge (CB + PMS) was determined employing the epigeic earthworm species Eisenia fetida. Two of the primary biological indicators—enzyme assay and germination index—were used for evaluation of vermicompost maturity. The enzyme assay includes the changes in dehydrogenase and urease activities in the final products. The test for germination index was performed on two economically important plant species Abelmoschus esculentus and Solanum melongena. The results revealed a significant increase in dehydrogenase and urease activities in the vermicompost samples over the raw materials and traditional compost. The enhancement was recorded 215.63–225.63% in dehydrogenase and 149.89–249.31% for urease in the end products obtained after 45 days of experimental trials. Further, the higher values of germination index in the vermicompost treatments as against the control confirm the suitability and stability of the vermicomposted final products.

Energy isan important in put for economic and industrial development and anindispensable production input for the continuation of the production process.In a very large part of economic and social life, electrical energy is widelyused because of its easy usage and other advantages. The aim of this study isto investigate the effect of the production of paper and paper products and thegross national product, which is an indicator of economic growth, on theconsumption of electricity by panel data analysis. For this purpose, a paneldata set was established for 20 OECD countries between 2006 and 2016 fromEurostat and Wordbank. Cross-sectional dependence, heteroskedasticity andautocorrelation assumptions were tested for the model and deviations from theassumptions were observed. Parameters were estimated using the Driscoll-Kraayestimators, which are resistant to these deviations. As a result of theanalysis, it was found that an increase of 1% in the production of paper andpaper products increased the electrical energy consumption by 0.22%, the increaseof 1% in the per capita gross domestic product increased approximately 0.62% inelectricity consumption., Enerji,ekonomik ve endüstriyel kalkınma için önemli ve üretim sürecinin devamı içinvazgeçilmez bir üretim girdisidir. Kolay kullanım ve diğer avantajlarısebebiyle ekonomik ve sosyal yaşamın oldukça geniş bir bölümünde yaygın olarakelektrik enerjisinden yararlanılmaktadır. Bu çalışmanın amacı, kağıt ve kağıtürünleri üretimi ve ekonomik büyümenin bir göstergesi olan gayri safi millihasılanın elektrik enerjisi tüketimi üzerindeki etkisini panel veri analizi ileincelemektir. Bu amaç doğrultusunda, Eurostat ve Wordbank’tan elde edilen2006-2016 yılları arasında 20 OECD ülkesi için panel veri seti oluşturulmuştur.Model için yatay kesit bağımlılığı, değişen varyans ve otokorelasyonvarsayımları sınanmış ve varsayımlardan sapma olduğu görülmüştür. Bu sapmalaradirençli Driscoll-Kraay tahmin edici kullanılarak parametreler tahminedilmiştir. Analiz sonucunda, kağıt ve kağıt ürünleri üretiminde meydana gelecek%1’lik bir artış elektrik enerjisi tüketimini %0.22 oranında, kişi başıgayri safi milli hasıladaki %1’lik bir artışın ise elektrik tüketimindeyaklaşık olarak %0.62 dolayında arttırdığı bulgusuna ulaşılmıştır.

A new type of polydimethylsiloxane-based paper transparentizing agent was prepared via a combined method. The performance of the transparentizing agent was investigated systematically by adding and dipping, with use of the surface sizing device of a paper machine. Optimum performance was found at 30% concentration of the transparentizing agent and 30 to 45 °C of dipping temperature. Under the optimal conditions, the transparentizing t agent achieved a rapid penetration in the base paper and filled in the pores of the paper, to be further effectively adsorbed and retained on the fiber surface. The transparency of test paper reached as high as 76±0.97 %, which was 37±1.4% higher than that of the control. However, the addition of transparentizing agent reduced the mechanical strength of paper slightly. The as-prepared transparentizing agent was found to exhibit excellent application stability and biodegradability when applied in the paper machine，When used as plastic film, the transparent paper would lose its strength completely after eight weeks. The resulting transparent paper can be used to develop paper-based film and other related plant based transparent/ translucent paper, which has great potential in replacing plastic products and eliminating white pollution.

Influence of the thermochemical processing (the cook) conditions and of the milling on characteristic of the waste paper with polyurethan and polyaziridin was studied. The waste paper was reduced to the degree size of the particles 5...8 mm in mill of the dry grind and chemical processing under higher temperature (to 70 °C) by solution, contain sodium persulfate and hydroxide; duty of water 6. Duration of cook varied from 1 to 5 hours, expense of persulfate sodium varied from 2 to 12%, hydroxide sodium – from 0.5 to 3% from mass of the waste-papers. The secondary fiber was obtaining by breaking-up of the pulp in the hydropulper. The dependency of the length and factor of the form of the secondary fiber from conditions cook was absent. The slight width increasing of the fibers with the higher pH of cooking liquor was determined: from 26.5 мкм under pH 3–4 to 29 мкм under pH 8–9. The conjectural reason is swelling of the cell wall. The waste paper milling was executed in the «stream-barrier» machine. The strength properties of the paper correspond with the feature, inherent of the secondary pulp.

Today, the paper industry is faced with a global deficiency of raw wood materials, so alternative sources of virgin cellulose fibres are playing an important role in paper production. Agricultural countries produce large quantities of crop farming by-products such as straw, which is an interesting alternative raw material for cellulose fibres. Straw is used in many industries because of its numerous advantages: animal food industry, biofuel industry, construction industry and as artistic material. The potential use of straw production residues is of great importance in paper and printing industry. The focus of this research is on triticale straw, which was used as a non-wood fibre source for paper production. Namely, triticale straw was converted into semi-chemical pulp and was combined with recycled wood pulp in order to produce alternative laboratory papers. The usability of this kind of laboratory papers in printing industry was analysed based on line reproduction quality. This research evaluated and analysed line reproduction quality based on four line attributes: width, blurriness and raggedness. The results of this research proved that triticale pulp in laboratory papers has equal influence on line printing quality as the recycled wood pulp.

The alarming global deforestation rate has great impacts on the output of the Pulp and paper Industry since wood is the principal papermaking fiber material. Although, generally, bamboo is an alter...

Phenol compounds are used in many industrial areas. Due to their high toxicity and stability, phenol compounds are carcinogenic to humans and animals even at low concentrations during their production and use. For this reason, the removal of phenol contaminants is both necessary and beneficial. Water pollution caused by phenols is one of the most serious problems globally, threatening both people and the environment. Increasing industrial and human activities have led to an increase in wastewater discharge into water resources. These phenolic chemicals are harmful, and although there are different methods used, it is very important to find new materials and effective methods to remove these pollutants from water. This study aimed to convert the phenols purified from water using tyrosinase paste to a less harmful state by making an enzymatic biofilter for phenol removal, thanks to the polyaniline structure we formed on the filter paper, to ensure phenol retention. While this process took place, FeCl3 solution was used as the reactor material, and aniline was turned into polyaniline with FeCl3 solution in HCl. While these processes are being carried out, it is aimed to prepare the most efficient biofilter by using the components that make up the experiment at different concentrations. By calculating the % efficiency of the catechols, absorbance values were measured before and after filtration. It was revealed that the highest percentage of biofilter activity was formed using 0.15 M aniline, 10 KU tyrosinase enzyme, and 1% chitosan concentrations., Fenol bileşikleri birçok endüstriyel alanda kullanılmaktadır. Yüksek toksisiteleri ve kararlılıkları nedeniyle, üretimleri ve kullanımları sırasında düşük konsantrasyonlarda bile insanlar ve hayvanlar için kanserojendir. Bu nedenle fenol kirleticilerinin uzaklaştırılması oldukça gereklidir. Fenollerin neden olduğu su kirliliği, hem insanları hem de çevreyi tehdit eden, küresel olarak en ciddi sorunlardan biridir. Artan endüstriyel ve insan faaliyetleri, atık suların su kaynaklarına deşarjının artmasına neden olmuştur. Bu fenolik bileşiklerin farklı yöntemler ve etkili yöntemler ile uzaklaştırılması çok önemlidir. Bu çalışmada, filtre kağıdı üzerinde oluşturduğumuz polianilin ve tirozinaz enzimi ile oluşturulan biyofiltre yapısı sayesinde fenolün tutulmasını ve enzimatik bir reaksiyon ile daha az zararlı hale dönüştürülmesi amaçlanmaktadır. Bu işlem yapılırken reaktör malzemesi olarak FeCl3 çözeltisi kullanılmış ve anilin, HCl içinde FeCl3 çözeltisi ile polianilin haline getirilmiştir. Bu işlemler yapılırken deneyi oluşturan bileşenler farklı konsantrasyonlarda kullanılarak en verimli biyofiltrenin hazırlanması hedeflenmiştir. Fenolik bileşenlerin giderimlerinde oluşturulan biyofiltrelerin % etkinlikleri hesaplanırken filtrasyon öncesi ve sonrası absorbans değerleri ölçülmüştür. En yüksek biyofiltre aktivitesi yüzdesinin 0.15 M anilin, 10 KU tirozinaz enzimi ve %1 kitosan konsantrasyonları kullanılarak oluşturulduğu belirlenmiştir.

The Institute of Digital Engineering (IDE), Loughborough University, University of Bath and the University of Warwick launched the digital twin initiative funded by the Advanced Propulsion Centre UK (APC) to develop a definition that can be applied to multiple sectors and which incorporates the unique requirements of the automotive and mobility sectors, derived from engagement with academia and industry. This digital twin initiative culminates in the form of this white paper. In it we present: a digital twin definition, an overview of the current state-of-the-art in digital twins, several case studies to demonstrate the art of the possible, and critical considerations to define value for money metrics for digital twins.

Cleaner production of sugars and pulp from renewable feedstocks has captured significant scientific attention in the recent past because they can be used for various end applications. In the papermaking industry, a major fraction of hemicellulosic sugars is lost during the pulping. The present study aims at retrieving these hemicellulosic sugars through alkali-, hot-water-, and acid-mediated extraction prior to pulping, which otherwise would have been lost during pulping and washing of pulp. These retrieved sugars can be used as feedstocks for renewable energy and value-added products. Different pretreatments were applied, aided with varying temperature, chemical concentrations, and time. Substantial amounts of total reducing sugars (TRSs) up to 21.98, 13.2, and 15.01% were extracted prior to pulping by acid, alkali, and hot-water pretreatments. Compositions of mono sugars present in the treated liquor were also characterized and confirmed by high-performance liquid chromatography analysis. The morphological changes in the wheat straw after pre-extraction were studied using the field emission gun scanning electron microscopy technique. Pulping of untreated and pretreated wheat straw was carried out at different alkali charges (12, 14, and 16% NaOH). Among all, acid-pretreated straw showed an increase in pulp yield by 10.9% at a 16% alkali charge. Physical strength properties of different pulps were further examined. Alkali- and hot-water-pretreated straw pulp retained 94.26 and 83.16% tensile indices and 92.43 and 87.02% burst indices, respectively. An increase in tear index up to 4.32, 2.01, and 2.30% for alkali-, hot-water-, and acid-pretreated straw pulp was achieved, respectively. Hot-water- and alkali-pretreated wheat straw was observed to be conducive for paper production. The integrated use of wheat straw for extraction of underutilized sugars and pulp production in this way may serve as a key stepping stone for future biorefinery designs in pulp and paper mills.

Uzbekistan is bare of forests and it takes the fifth place in the world in terms of cotton production, and the third place in terms of silk production after China and India. According to the government program the expansion of the land area for mulberry plantations boosts the growth of silk production causing an increase in the total amount of wastes, i.e. branches of mulberry trees industrially useless after the removal of leaves. Their use as a raw material for the cellulose pulp production is relevant, since it is aimed at solving not only the resource, but also the environmental problem. The bark was cut off from the mulberry branches and soaked in water for some time after which its exterior hard layer was scraped off and divided into the rough exterior layer and the softer inner layer. The inner layer was boiled for several hours. The boiled bast, after washing with water, was grinded in a laboratory grinding machine under the following conditions: mass concentration – 1 %, temperature – 22 °С. A given amount of lint cotton cellulose (grinding degree – 45 °SR) was added to the grinded bast. Paper molds with the mass of 80 g/m2 were obtained in laboratory conditions using a sheet-making apparatus. It was found out that the obtained paper that contains cotton cellulose pulp and inner layer of mulberry branch bark has low whiteness which depends on whiteness of the added fibers. It has been established that adding the cellulose pulp of the inner layer of mulberry branch bark at a grinding degree of 30 °SR contributes to the production of strong paper. It is recommended to add up to 30 % of cellulose pulp from the inner layer of mulberry branch bark to paper pulp as further addition adversely affects the paper whiteness.For citation: Babakhanova Kh.A., Galimova Z.K., Abdunazarov M.M., Ismailov I.I. Cellulose Pulp from Mulberry Branch Bark for the Paper Industry. Lesnoy Zhurnal [Russian Forestry Journal], 2020, no. 5, pp. 193–200. DOI: 10.37482/0536-1036-2020-5-193-200

There is a pressing need around the world to develop novel functional biodegradable materials to separate oil/water mixtures and emulsions completely. Recently, superhydrophilicity and underwater superoleophobicity materials have been attracted attention due to their high efficiency in oil/water separation. However, it is still a challenge to prepare materials that combine oil/water separation and water purification in an environment-friendly way. In this work, biodegradable starch-based nanospheres (SNPs) coated filter paper was prepared in a low-cost, simple, and environmentally friendly manner. The SNPs coating could not only help to change the wettability of the substrate material but also build the hierarchical micro and nano structures which are conducive to separation and purification process. After modification by coating SNPs, the filter paper exhibited excellent performance in a wide range of oil/water mixtures or emulsions separation and the wettability of the filter paper could be regulated by adjusting the pH value. The modified filter paper presented good recyclability after several separation process. Furthermore, the as-prepared filter paper could also remove water-soluble contaminants during the oil/water separation process, thus realizing to combine separation and purification process in one single step. This biodegradable starch-based separating material with good separation performance, stability and recyclability has significant application potential in practical separation and purification process.

Starch and derivatives thereof have proven their usefulness in paper coating processes. Among these derivatives, cationic starch has been widely used in the paper industry as a flocculation, dispersion and ink fixing agent. In another context, nanoscale cellulosic materials have been shown to improve the strength, retention of fillers, the barrier properties of packaging paper products, and printing qualities. This review summarizes the recent studies on the general components used in paper coating, describes the conventional and alternative synthetic processes of cationic starches and nanocellulose, and deals with their current and potential applications in papermaking, focusing primarily on surface treatments. Moreover, environmental applications have been considered to expand the understanding and usefulness of these materials. Further research on modified polysaccharides is encouraged to replace, in a feasible way, petro-based components of coating formulations, and to provide paper surfaces with new properties.

Process-monitoring laboratories in the pulp and paper industry generally use a combination of wet chemical analyses and physical measurements to certify the fitness of a production pulp for a specific end-use. These laboratory tests require time and the effort of trained personnel, limiting their utility for real-time process control. Here we show that Raman probes of unrefined cellulosic pulps, well-suited to the online measurement of in-process materials, can predict the quality attributes of manufactured papers. The accuracy of prediction improves when the covariance is modelled in a reduced measurement space selected by a data-driven, feature-selection technique referred to as a Template Oriented Genetic Algorithm (TOGA). TOGA, combined with discrete wavelet transform (DWT), isolates functional-group features that correlate best with mechanical properties paper derived from refined pulp. Paper makers refine market pulps to build sheet strength using a beating process that decreases freeness as it increases fibre-fibre bonding. Methods demonstrated here predict manufactured sheet properties obtainable after any specified degree of refining from the Raman spectrum of an unrefined pulp. This analysis capacity will enable both vendors of market pulp and makers of sheet paper to specify in advance the amount of beating required to produce a desired product, thereby saving cost and conserving resources.

The pulp and paper industry has a great impact in the world. It has been manufactured for ages and ages, it is still booming up as industry in small scale and large scale levels. Despite the fact that they produce printing and writing papers, paper rolls, packaging material etc. they also produce large amount of waste materials from their Industry by Manufacturing. This when left untreated leads to environmental pollution, harsh contamination and so on. As every industry has its own waste water treatment methods to recycle, reuse and reduce pollution. This Industry also has its own criteria to carry out the process of waste water treatment, yet it lags in being efficient in it. By the sources collected and compared with other kinds of industries it is listed that pulp and paper manufacturing industry is one of the top most industries to produce large volumes of waste water which has degradable organics at higher level. Hence this paper aims to study the manufacturing process, waste water components released and its effect on environment, the treatment methods carried out and how it can be improvised efficiently in forthcoming days

The article gives the consideration to the properties of paper with the addition of pulp mass from the waste of the pharmaceutical industry, namely licorice root after removing extraction. Licorice roots were dried to air-dry state after extraction, cleaned of wastes and cut into fragments 10–30 mm long, then subjected to pulping with 2–4% NaOH solution at a hydro module 1 : 5, at a temperature of 95–98 °С for 60–90 minutes. After washing with hot water, they are bleached in an alkaline medium with a solution of hydrogen peroxide at a consumption of 3–4% of the mass of absolutely dry cellulose, hydro module 1: 5, temperature 70–95 °C for 60–90 minutes. After washing, grinding to a gristing degree of ~60°ShR, prepared castings weighting 80–90 g/m2 on a leaf-casting mashine. Physical, mechanical and optical properties of experimental castings are determined. Revealed that the addition of malt mass of the cotton contributes to the formation of dense orderly structures of the paper sheet, as short fibers of licorice filled the gaps between the long fibers of cotton pulp, thereby reducing the pore volume and reactive surface availability and receipt paper with the highest mechanical strength. Adding malt mass to cotton mass at a ratio of 10 : 2 is optimal, further replenishment contributes to an increase in sorption absorption, that is, to obtain paper with a porous structure, which is not desirable for high-quality reproduction.

An industry compatible chemo-refining approach was tested for preparation of micro-nanofibrillated cellulose (MNFC) from bleached softwood pulp using sodium meta-periodate and sodium chlorite as oxidizers followed by refining in Valley beater. SEM and FTIR analyses confirmed micro-nano scale fibrillation and chemical functional group modification in laboratory prepared MNFC, respectively. The water retention value, carboxyl content and viscosity of MNFC were found comparable with imported NFC as reference (R-NFC). To evaluate MNFC as strength enhancer for paper properties, 5% MNFC addition to bleached mixed hardwood pulp showed 6% reduction in bulk with 36%, 24% and 97% increment in breaking length, burst index and double fold of the handsheets, respectively without affecting tear index and optical properties than the control. Surface properties were also improved. Pulp drainability (37°SR) after MNFC addition was found suitable for papermaking. These laboratory results confirmed the potential of MNFC as a suitable strength additive for paper quality improvement.

Paper grade pulp production across the globe is dominated by the kraft process using different lignocellulosic raw materials. Delignification is achieved around 90% using different chemical treatments. A bottleneck for complete delignification is the presence of residual covalent bonds that prevail between lignin and carbohydrate even after severe chemical pulping and oxygen delignification steps. Different covalent bonds are present in native wood that sustain drastic pulping conditions. In this study, 100% birch wood was used for producing paper grade pulp, and the lignin carbohydrate bonds were analyzed at different stages of the kraft cook. The lignin carbohydrate bonds that were responsible for residual lignin retention in unbleached pulp were compared and analyzed with the original lignin-carbohydrate complex (LCC) bonds in native birch wood. It was shown that lignin remaining after pulping and oxygen delignification was mainly bound to xylan, whereas the lignin bound to glucomannan was for the most part degraded.

In this study, Rhododendron luteum and Rhododendron ponticum were evaluated as raw material for pulp and paper production. 12 different sodium borohydride (NaBH4) added cooking trials were performed for each sample and kraft method was used for pulp production. Pulp properties, such as yield, kappa number and viscosity, and physical properties, such as breaking length and burst index, were determined for each trial. Besides, the effects of active alkali and NaBH4 on the pulp and paper properties were also examined. Optimum cooking conditions were obtained by using 18 % active alkali for NaBH4-free cooking experiments and 0.5 % NaBH4 and 18 % active alkali for NaBH4-added cooking experiments. In NaBH4-added pulping condition, the screened yield, kappa number and viscosity of R. luteum were found to be 43.4 %, 40.1 and 949 cm3/g1, respectively. The respective values for R. ponticum were 41.9 %, 44.5 and 885 cm3/g1. The screened yields of R. luteum and R. ponticum increased by about 2.8 % and 5.3 %, respectively, with 5 % addition of NaBH4 compared to NaBH4-free cooking experiments. Furthermore, with the addition of NaBH4, the kappa numbers decreased while the viscosity increased. The physical properties of the produced papers were also improved by using NaBH4 in cooking liquor. According to the obtained results, it was found that R. luteum and R. ponticum species can be evaluated for pulp and paper production., U ovom je radu istražena mogućnost uporabe biljaka Rhododendron luteum i Rhododendron ponticum kao sirovine za proizvodnju celuloze i papira. Za svaki uzorak provedeno je 12 različitih ispitivanja kuhanja s natrijevim borhidridom (NaBH4), a celuloza je proizvedena kraft postupkom. Za svako ispitivanje određena su svojstva celuloze poput prinosa, kappa broja i viskoznosti, te fizička svojstva kao što su duljina lomljenja i indeks pucanja papira. Osim toga, ispitani su učinci aktivne lužine i NaBH4 na svojstva celuloze i papira. Optimalni uvjeti kuhanja postignuti su upotrebom 18 % aktivne lužine za eksperimentalno kuhanje bez NaBH4 i upotrebom 0,5 % NaBH4 i 18 % aktivne lužine za eksperimentalno kuhanje s dodatkom NaBH4. U proizvodnji celuloze iz biljke R. luteum s dodatkom NaBH4 utvrđeno je da prinos prosijavanja iznosi 43,4 %, da je kappa broj 40,1, a viskoznost 949 cm3/g, dok su vrijednosti za celulozu dobivenu iz biljke R. ponticum redom 41,9 %, 44,5 i 885 cm3/g. Prinos prosijavanja biljaka R. luteum i R. ponticum uz dodatak 5 % NaBH4 povećao se oko 2,8 % i 5,3 % u usporedbi s eksperimentalnim kuhanjem bez dodatka NaBH4. Nadalje, uz dodatak NaBH4 smanjuju se kappa brojevi, a viskoznosti se povećavaju. Fizička svojstva proizvedenih papira također se poboljšavaju dodavanjem NaBH4 tekućini za kuhanje. Iz dobivenih je rezultata utvrđeno da se biljke R. luteum i R. ponticum mogu upotrebljavati u proizvodnji celuloze i papira.

The work presented in this paper is focussed on study of structure and properties of coating layers based on natural pigments (ground calcium carbonate and clay) and butadiene acrylonitrile latex as binder in correlation with functional properties of the final coated paper. It is quantified the influence of binder content and pigment type on the structural and liquids penetration properties of coating layer. The obtained results confirm that by increasing of binder content in the coating formulations a reduced efficiency of light-scattering and increased roughness for coated surfaces is obtained. At the high binder amounts (over 15 pph), the coating layer porosity is reduced and as result a lower liquids penetration in the coated papers is obtained.

The search for non-wood fibers as alternative to the limited wood fiber resources is highly imperative in the pulp and paper-based industries. This is due to growing environmental concern as a result of excessive deforestation. This study aimed at investigating the pulp and paper potentials of pineapple crown (Ananas comosus), sandbox (Hura crepitans), pino macho (Pinus caribaea), elephant grass (Pennissetum purpureum) and teak (Tectona grandis) leaves. Chemical properties (holocellulose, cellulose, hemicellulose, ash contents, hot water and 1% NaOH solubilities) were determined using the relevant TAPPI test and chlorite methods, while the physical properties were determined after the pulping processes. Fourier transform-infrared spectroscopic (FT-IR) analyses of intrinsic functional groups of the paper sheets produced from the pulps of the waste plant leaves were determined. In addition, scanning electron microscope (SEM-EDX) analyses of the morphological characteristic and elemental compositions of the resulting hand sheet surfaces were also examined. P. caribaea has the highest lignin (80.22 ± 0.012%) and cellulose (72.30 ± 0.012%) contents with lowest 1% NaOH solubility (15.20 ± 0.05%) values. A .comosus has the highest hemicellulose (21.73 ± 0.1%) and moisture (75.00 ± 0.12%) contents with lowest ash values (5.01 ± 0.15%). The fibre lengths and the Runkel ratio of the resulting pulps were of the order, A. comosus > P. purpureum > P. caribaea > H. crepitans > T. grandis and A. comosus

The efficiency of xylano-pectinolytic enzymes, co-produced by a single microbial strain Bacillus pumilus, was analysed for the recycling of mixed office waste paper through deinking and compared with the alkaline chemical deinking method. Enzymes showed maximum deinking at pH 8.5, pulp consistency of 10%, xylanase-pectinase dose of 12 and 4 IU per gram pulp, respectively, after 120 min of deinking period, and temperature at 50 °C. A chemi-enzymatic approach was employed with xylano-pectinolytic enzymes and various concentrations of deinking chemicals, which showed that enzyme-treated mixed office waste pulp requires only 40% chemicals for deinking, in order to get the almost same level of various handsheets properties, as obtained by the chemical method with 100% chemicals. Similarly, the effluent load of BOD and COD contents was also decreased by 17.90 and 19.75%. This combinational approach of deinking significantly improved the various properties of the handsheets and resulted in gain of 7.5, 9.38, 6.33 and 11.65% in tear factor, burst factor, breaking length and viscosity of the handsheets, while the effective residual ink concentration analysis of deinked handsheets of mixed office waste paper showed deinking efficiency of 22.45%, which revealed the removal of ink particles during enzymatic deinking steps.

The present study was undertaken to know the effect of common mixed pulp and paper mill effluent discharge released from century pulp and paper mill Lalkuan, Nainital Uttarakhand on the blood morphology of Heteropneustes fossilis (Singhi). The various morphological changes were observed in the specimen, randomly collected with the help of cast net from (3 sites) different locations. The maximum changes were observed in the specimen collected from site 3 in compare to site 1 and 2 respectively. The formation of inclusion bodies, sickle cells, Cabot rings and ovalocytes were recorded along with nuclear fusion, membrane disruption and cell clumping of blood cells in the specimen collected from the site 3 (i.e. nearer to source of discharge) while in the specimen collected from site 2, the formation of tear drop cell, target cells, spherocytes and bi-nucleated cells were recorded along with the activity of cell clumping. The changes were found less in the specimen collected from site 1 in compare to the specimen of site 2 and 3 i.e. formation of ovalocytes, spherocytes and microcytes with the activity of membrane degeneration and agglutination in blood cells.

Considering that optical properties play a very important role in the printing industry, this research focused on analysing the optical properties (opacity, whiteness, brightness and yellowness) of laboratory made papers from recycled wood pulp, with the addition of different straw contents, coated with titanium dioxide white ink. Titanium dioxide white ink was applied on laboratory papers to achieve optical characteristics as those of commercial papers recommended by ISO 12647. All the coated laboratory papers presented whiteness within the recommendations of the standard. Almost all the coated papers made with the addition of straw pulp achieved satisfactory optical properties, especially those containing 10% and 20% straw pulp. Coated laboratory papers containing 10% and 20% wheat pulp were comparable to commercial paper and reached a similar value of brightness, while their opacity and yellowness values were even better than those of commercial paper. In order to preserve the natural appearance of papers made with the addition of straw pulp, it is possible to conduct selective white printing as background for high-quality printing.

With the increasing popularity of coated paper, it has been more widely used in printing, publishing, product packaging and commercial promotion. However, coated paper is prone to cracks after printing and folding which exposes to a white area which is referred to as fold cracking. This study investigated the coating properties of paper and coating factors influencing the fold cracking and aimed to provide guidance on how to reduce the problems of fold cracking. This paper mainly discusses the effects of pigment proportion, binder dosage, solids content, coating thickness and calendering pressure on fold cracking of coated paper after printing. Experiments show that when the coating consisted entirely of calcium carbonate, the degree of fold cracking is most serious. With the addition of kaolin, the fold cracking reduces. When the ratio of the number of parts of calcium carbonate to kaolin is 25/75, the area of fold cracking reaches its minimum value of 10.28 %. With increasing solids content of the coating, the fold cracking decreases initially and then increases. When the solids content is 55 %, the fold cracking reaches a minimum. Increased latex content reduced coating thickness and an increase in calendering pressure gradually reduce the degree of fold cracking.

This study aimed to evaluate eggshell wastes, which have the potential to turn into high value-added products in paper industry. Membrane-removed eggshell wastes were subjected to certain processes of washing, drying, grinding, and sieving. The final product of eggshell calcium carbonate (ECC) was used in office paper production as filler, and its possible effect on physical and optical properties of papers was investigated. Mixed office wastes were turned pulp using as raw material of office paper production. Moreover, the effects of ECC was compared with the use of industrial calcium carbonates of ground (GCC) and precipitated (PCC) forms as filler. Breaking lengths of the papers were shown to reduce up to 65.2, 76.6, and 64.1% by a 30% usage of GCC, PCC, and ECC fillers, respectively. PCC and GCC were more effective in improved optical properties of papers than ECC. The brightness values were measured to be 96.8, 98.4, and 93.1 ISO% with a 30% dosage of GCC, PCC, and ECC fillers, respectively. These results suggested that ECC can be used as filler in paper industry.

Absorption capacity is a key feature of toilet tissue papers. Several parameters can affect their final absorption capacities, such as pulp composition, stock preparation, number of sheets, additives, bulk, grammage, and converting process parameters, such as the embossing operation. In this work, the absorption capacities of four different 2-ply industrial toilet tissue papers, as well as the respective base papers from the mother-reel was compared using the immersion method according to ISO 12625-8 (2010). Previously, these samples were characterized in terms of morphology, grammage, thickness, and bulk. It was concluded that the embossing operation noticeably increased the thickness and bulk of toilet tissue paper. Furthermore, it was also verified that among the various toilet tissue paper samples there was not a noticeable variation in the time of water absorption because the samples revealed similar morphology and porosity. However, it was found that the bulk increased more than 150%, resulting in an increase of water absorption capacity over 60%.

Paper-based packaging is widely employed in industries ranging from food to beverages to pharmaceuticals because of its attractive advantages of biodegradability, recyclability, good strength, low cost, and lightweight. However, paper products usually have poor water barrier resistance properties because of paper and fibers porous microstructure. In this study, an ecofriendly water-resistant (hydrophobic) oil from biological origin, namely, palm kernel oil (PKO) was used to coat paper by using a facile and cost-effective dip-casting approach. PKO formulation was prepared by mixing with a solvent and furfuryl alcohol (FA). The water resistance, structural properties, and thermal and mechanical properties of the coated papers obtained under different processing conditions were reported and compared to understand the performance of coated paper. Contact angle (CA), Fourier transform infrared (FTIR), and thermal gravimetry (TGA) were used for analysis and characterization of coated papers. Data from contact angle measurements showed that the PKO formulation could considerably improve the liquid water barrier property of the paper, with a measured water contact angle (CA) of ∼120° and reduce the water vapor transmission rate (WVTR) by 22%. This novel, green, low-cost, and water-resistant paper coating made with biological and biodegradable oil is a potential candidate for replacing petroleum-based coatings used in a broad range of applications and will also be able to make an additional full use of the palm kernel oil.

The study is a first investigation of the feasibility to preserve recycled fillers (e.g. calcium carbonate, kaolin) from deinking paper sludge for newspaper production using an alternative approach respect to the actual methods. Deinking paper sludge was incinerated at 575 °C. The thermal stability of the incinerated sludge (ash) was evaluated by infrared analysis. Subsequently, the resulting ash was bleached by sodium dithionite. The particle size of the ashes was analysed by laser diffraction. The effect of recycled fillers on recycled paper pulp, after blending, was evaluated by the analysis of the physical and optical properties of the obtained paper sheets. Analysis showed the conservation of the calcium carbonate and other fillers’ molecular structure, both after incineration of the sludge and after bleaching. The dithionite treatment of the ashes resulted in ISO brightness levels of more than 70. The brightness was stable over one month. Paper sheets made by blending the bleached ashes with recycled paper showed an improvement of brightness and opacity but a decrease in terms of porosity and breaking length compared to paper sheets made without any filler. The proposed method still requires further studies to evaluate the economical application but offers an opportunity for the recycling of inorganic materials and valorisation of the sludge.

Based on publications related to the use of micro- and nanofibrillated cellulose (MNFC) in papermaking applications, three sets of parameters (intrinsic and extrinsic variables, furnish composition, and degree of dispersion) were proposed. This holistic approach intends to facilitate understanding and manipulation of the main factors describing the colloidal behavior in systems comprising of MNFC, pulp fibers, and additives, which directly impact paper product performance. A preliminary techno-economic assessment showed that cost reductions driven by the addition of MNFC in paper furnishes could be as high as USD 149 per ton of fiber (up to 20% fiber reduction without adverse effects on paper’s strength) depending on the cost of papermaking fibers. It was also determined that better performance in terms of strength development associated with a higher degree of MNFC fibrillation offset its high manufacturing cost. However, there is a limit from which additional fibrillation does not seem to contribute to further strength gains that can justify the increasing production cost. Further research is needed regarding raw materials, degree of fibrillation, and combination with polyelectrolytes to further explore the potential of MNFC for the reduction of weight of paper products.

The paper presents the results of the analysis on measured parameters of harmonics at the node of the high-voltage network. The measurements were made at the node connecting the pulp-and-paper mill to the 220 kV supply network. This load is nonlinear and has a large capacity. Particular attention is paid to the distributions of the current and voltage harmonics. The paper clearly shows probabilistic properties of the measured parameters of harmonics

The thriving development of the paper industry leaves behind a great amount of pulp and paper mill sludge (PPMS), which constitutes a considerable source of pollution. Experts estimate that...

The present study investigated the Ethiopian sugarcane bagasse during its delignification via the sulfur-free soda pulping process and bleaching by the single-stage hydrogen peroxide process. The multilevel categoric experimental design was used to assess the effects of the three independent process variables (pulping temperature, NaOH concentration and time) on the pulp yield and kappa number, during the soda pulping process. The effect of the independent bleaching variables (bleaching temperature, time and H2O2 concentration) on the pulp yield, brightness and whiteness was assessed by using the response surface methodology (central composite experimental design). The soda pulps from the Ethiopian sugarcane bagasse were of varying yield and kappa number and hence were classified according to the sugarcane bagasse providing the highest pulp yield (pulp-SA) with 88.07% and that providing the lowest pulp yield (pulp-SB) with 85.17%. Their corresponding kappa numbers were 16.73 and 8.27, respectively. The brightness and whiteness for the pulp-SA were 62.02% and 84.43%, respectively, whereas for the pulp-SB, the corresponding values were 71.86% and 90.47%, respectively. The study further shows that the paper produced from the pulp-SA had higher mechanical properties. Thus, the promising valorization of the Ethiopian sugarcane bagasse for paper production using the adopted methodology, namely the soda pulping and single-stage hydrogen peroxide bleaching routes, is validated.

A series of industrial experimental tests on the freeze treatment of colloidal sludge lignin precipitates was carried out under natural conditions. Changes in the physical and chemical properties of the precipitates were studied. It is established that three fractions are formed following the freeze treatment of colloidal sludge lignin precipitates, including demineralized water (up to 25 %), mineralized water (up to 15 %) and a restructured colloidal precipitate (up to 60 %). The total volume of the precipitate is shown to decrease to 40 %. Freezing precipitation of colloidal lignin slurry of "the Baikal Pulp and Paper Mill" leads to a decrease in toxicity from the third to the fifth class of danger. On the basis of frozen sediments, the lignin sludge of OJSC Baikal Pulp and Paper Mill with the addition of other waste from the Baikal region, a fertile soil was obtained that corresponds to GOST R 54651-2011 "Organic fertilizers on the basis of sewage sludge. Specifications".

The study describes the preparation of pulp and nanocellulose from non-wood plant materials, as well as an improved properties of paper and cardboard for mass production. The pulps from wheat straw, kenaf and flax fibers were prepared by the environmentally friendly organosolv method—cooking in a solution of isobutanol or peracetic acid. The organosolv pulps used to prepare nanocellulose had traces of lignin and mineral substances. The process of hydrolysis of the investigated organosolv pulps was optimal when carried out under the following conditions: 43% sulfuric acid, temperature 60 °C, hydrolysis time 90 min and ultrasonic treatment 60 min. Using the methods of SEM, XRD, TEM, AFM and TGA, the structure and properties of organosolv pulps and nanocellulose were studied. The use of nanocellulose in bulk and on the surface of mass types of paper and cardboard—paper for corrugation, offset paper, recycled containerboard and cardboard for flat layers of corrugated cardboard were investigated. We established the positive effect of nanocellulose application on the physical and mechanical properties of paper and cardboard. Low consumption of nanocellulose allows production of the paper and cardboard with properties that meet the requirements to appropriate standards and replacement of synthetic reinforcing materials.

Introduction. Pulp and paper enterprises accumulate large volumes of industrial waste buried in special accumulation cells. In order to choose a technology for treating above-sludge waters, we need to monitor their composition, which depends on the history of cells’ filling and their subsequent use. Methods. In the course of the study, we applied inductively coupled plasma mass spectrometry (ICP-MS). Results. We determined the content of 72 chemical elements in above-sludge water of 11 cells at Baykalsk Pulp and Paper Mill and 4 open water flows near industrial waste landfills, and performed a cluster analysis of the sample composition. As a result, we revealed the peculiarities of water composition, related to the history of cell filling and subsequent pilot experiments. It has been found that the cells with non-disturbed sediments have cleaner water. Out of 16 chemical elements subject to limitation (Na, Al, P, S, Cl, K, Cr, Mn, Fe, Ni, Cu, Zn, Sr, Mo, Cd, Pb), 11 elements exceed the limits established for wastewater discharged into water bodies within the ecological zones of the Baikal Natural Territory. Each cell is characterized by its own set of elements exceeding maximum allowable concentrations (MAC) and by the extent of such excess. Conclusion. Pilot experiments with cell sediments (joint grouting, drying, dewatering in press-filters) result in the disturbance of the “water/sediment” balance and increase the concentrations of most elements in above-sludge waters. The maximum amounts of elements (6–7) exceeding the MAC values are observed in water in the cells with disturbed sediments, water in the zone of ash slurry discharge, ash and sludge-lignin cells with industrial and household waste. When choosing a technology and procedures for treating above-sludge waters, it is necessary to take into account the specifics of their composition. Using the polluted water flow running into Lake Baikal during catastrophic floods in the summer of 2019 as an example, we show that it is possible to use multi-element ICP-MS analysis to search for sources of pollution from industrial facilities.

Enormous quantities of bagasse are being used as raw material in agro based large integrated pulp and paper mills. Anaerobic technology is an effective means of biodegradation of organic substance in wastewater and energy production of biogas that can be used as an alternative fuel. This study illustrates the effect of HRT on performance of lab scale hybrid upflow anaerobic sludge blanket (HUASB) reactor on treatment of pulp and paper mill bagasse wash water. The lab scale HUASB reactor was designed for an effective volume of 0.013 m3 with bio balls as packing media at the top of reactor and operated under mesophilic condition. After startup period, the reactor was operated with HRTs of 23.55, 15.98, 12.00, 10.03 and 7.97 h for the average influent COD concentrations of 2503.6 mg/L, 3918 mg/L, 5432 mg/L, 6608 mg/L and 7996 mg/L respectively. The results showed that the maximum COD removal efficiencies and TSS removal efficiencies were in the range of 68.60–92.19% and 89.56–94.66% respectively. The minimum and maximum biogas yield of 0.32 and 0.53 m3/kg CODa were obtained at influent concentration of 2503.6 mg/L and 7996 mg/L respectively.

Research is devoted to the problem of recycling waste of the Baikal Pulp and Paper Mill, whose activity has caused serious damage to the ecological environment of Lake Baikal and its environs. Grouting waste production is currently the most effective possible decision to the problem of pollutants, such as sludge-lignin and ash, in water objects and groundwater. The results on the grouting of liquid and solid waste from the Baikal Pulp and Paper Mill, represented by sludge lignin and ash, are presented. Cement, liquid glass, colloidal silica, ammonium persulfate, hydrogen peroxide were used as the main hardeners. Samples were formed by mixing the original waste with astringent. The strength in time, shrinkage, resistance to water were studied. Samples formed on the basis of colloidal silica solution have a maximum uniaxial compressive strength of 0.4 - 0.5 MPa, on the basis of liquid glass—0.2 - 0.3 MPa. Adding fine sand increases the strength by 1.5 - 1.7 times. Samples based on ammonium persulfate and hydrogen peroxide do not have sufficient strength. Adding fine quartz sand increases the strength up to 1.0 - 1.2 MPa.

The pulp and paper industry utilizes more biomass for stationary heat and power than any other industry in the United States. In total, pulp and paper mills in the US emit ∼150 million metric tons of CO2 each year, of which 77% is biogenic. Thus, the pulp and paper industry has significant potential to indirectly remove atmospheric CO2 through bioenergy with CO2 capture and storage (BECCS). In addition, avenues for CO2 utilization exist in pulp and paper processing. Here, we analyze the technical and economic potential of integrating carbon capture, utilization, and sequestration (CCUS) technologies at pulp and paper mills in the US through top-down, industry-wide screening and bottom-up, chemical process modeling techniques. We estimate costs of capturing and transporting CO2 from pulp and paper mills using post-combustion amine chemisorption in the year 2026 with application of the existing federal tax credit for carbon capture and sequestration (Section 45Q). Costs are highly dependent on scenario-specific details, such as waste heat or power generation at the mill, idling or stranded assets, and proximity to suitable geologic storage opportunities. Some CCS implementation scenarios produce significant economic returns for pulp and paper mills, indicating a near-term opportunity to accelerate CCS in the US. Finally, we qualitatively assess alternative techniques for CO2 capture through process innovation, and opportunities for CO2 utilization at pulp and paper mills.

Refereed/Peer-reviewed At a paper manufacturing mill (PML) that had been previously part of an integrated pulp (bisulphite) and paper mills industry, cyanobacterial blooms were observed in the mill’s aerated stabilization basin (ASB) ponds at about 3 years after pulping had been discontinued. This study aimed to determine the factors that led to bloom occurrences and potential control strategies applicable to the paper manufacturing mill’s, aerated stabilization basin system that discharges wastewaters into a coastal lake. Following discontinuation of pulping, the colour of the wastewaters reduced to low levels (~ 10 Hazen units or less), while the levels of nutrient remained potentially supportive of cyanobacteria growth with total phosphorus at ~ 0.1 mg/L and total nitrogen at > 2.5 mg/L. Incidences of blooms in the ABS were associated with preceding average monthly rainfalls and wind speeds being less (~ 44% and ~ 7%, respectively) and average direct sunlight hours being greater (~ 9%) than the long-term average values. Zinc was investigated for control of cyanobacteria as this metal is less toxic to aquatic organisms and microflora than copper algaecides. In laboratory culture trials, zinc was found to inhibit growth of M. aeruginosa (strain MIC338) and Pseudanabaena sp. when dosed at ~ 2.5 mg/L. The inhibition of cyanobacteria by zinc was found to vary between ASB pond samples which had different in situ chlorophyll a levels. This study found that the PML wastewaters investigated can be supportive of cyanobacterial growth to bloom levels after discontinuation of pulping processes and that zinc has potential as a cyanobacteria control agent.

The present research deals with multivariate regression modeling of heavy metals uptake by cultivated Eichhornia crassipes (water hyacinth: WH) in the wastewater of paper and pulp processing industry. The WH plants were grown in different treatments of wastewater of paper and pulp processing industry (25, 50, 75, and 100%), while the control experiment was performed using borewell water. The influence of pH and metal quantity in the wastewater of paper and pulp processing industry over effective metal accumulation (∆Y: mg kg− 1) by WH was statistically modeled. Results showed that the established models had high R2 (

An innovative approach for preparing hemp fibers from hemp hurds for use in tissue and towel grades of paper is described. Hemp hurds are a low value by-product of industrial hemp processing that are generally used for animal bed litter. Tissue paper was fabricated from hemp hurd fibers by following three pulping processes: autohydrolysis (hydrothermal), sodium carbonate-based defibration, and high yield kraft pulping, and benchmarked against hardwood pulp. To meet industrial standards, hardwood and hemp pulp fibers were mixed at a dry mass ratio of 75:25, from which tissue paper sheets were prepared. Desirable tissue paper properties, such as water absorption, burst resistance, softness, and tensile strength (dry and wet), were measured and compared. Characterization of morphological and chemical properties of tissue handsheets was conducted with SEM and time-of-flight-secondary ion mass spectrometry (ToF-SIMS). The combined kraft pulped hardwood and autohydrolyzed hemp pulp fibers displayed improvements in tensile index, burst resistance, and softness of tissue handsheets compared to only kraft hardwood pulp handsheets without adversely impacting water absorption. Hardwood fibers showed a sparse distribution of surface lignin compared to hemp fibers using the same defibration. This technology can lead to a variety of eco-friendly tissue paper products that are not only highly energy efficient, but avoid harsh chemical processing.

Coatings based on pigment and polymer binders are applied on paper surfaces to improve their surface, optical, and printing properties. Besides the coating composition, the structure and properties of the coated papers are influenced by the coating layer consolidation upon drying. In this study, the influence of drying conditions on the structure and properties of coating layers based on natural pigments (clay) and polymer binders (butadiene acrylonitrile latex) has been analyzed. Using a laboratory rod Mayer device, the coatings were applied as thin layer (about 15&ndash, 16 g/m2) on the paper surface and samples of coated paper were dried at 20 and 105 &deg, C temperatures. The optical, structural, and water absorption properties of the coating layer were evaluated by the measurement of gloss, opacity, void fraction, light scattering, and contact angle. The obtained results highlighted that both the drying temperature and latex content in the coating color have a synergic effect on the coated paper quality.

Highlights • Pulp and paper mills generate huge amount of wastewater. • Physicochemical processes have several limitations to treat wastewater. • Integrated microbial based technology improves the quality of wastewater. • Eco-friendly MBBR process creates opportunity for reuse of treated wastewater., From the beginning of the paper-making process, the pulp and paper industry has utilized a large amount of water and generated a vast amount of highly polluted wastewater. The paper industry faces global pressure to reduce water use and lower environmental pollution. However, traditional physicochemical methods of wastewater treatment need high energy input, and their ecological impact is questionable. Due to the zero discharged policy, the industries urgently require novel eco-friendly, sustainable, and efficient treatment techniques. Microbial technology is the most recommended option to treat wastewater and support sustainable growth. The present article describes the overview of traditional and novel methods, including membrane bioreactor (MBR) and moving-bed biofilm reactor (MBBR) technology's with their current state and their limits for treating pulp and paper wastewater. It is expected to integrate the novel methods with advanced hybrid technology to fulfill wastewater treatment criteria and prospects. Furthermore, coupling MBR and MBBR technology make energy and water recovery possible, and recycling wastewater will be economically and environmentally feasible., Graphical abstract Image, graphical abstract

The aim of the study is to analyze the results of ecological monitoring of the aquatic biota of the river. Vychegda and their practical use on the example of water-intensive pulp and paper production. The availability of the results of our own studies of the actual values of the monthly biomasses of phytoplankton and zooplankton made it possible to assess the difference between the use of actual and literary data. According to actual data, the damage from the death of phytoplankton is 4.5 times lower, and of zooplankton – 97 times lower, compared with the results of calculations using literature data.