Search

Studies on the hydrological response to continuous extreme and asymptotic climate change can improve our ability to cope with intensified water-related problems. Most of the literature focused on the runoff response to climate change, while neglecting the impacts of the potential variation in the active catchment water storage capacity (ACWSC) that plays an essential role in the transfer of climate inputs to the catchment runoff. This study aims to systematically identify the response of the ACWSC to a long-term meteorological drought and asymptotic climate change. First, the time-varying parameter is derived to reflect the ACWSC periodic and abrupt variations in both drought and non-drought periods. Second, the change points and varying patterns of the ACWSC are analyzed based on the Bayesian change point analysis with multiple evaluation criteria. Finally, various catchment properties and climate characteristics are used to explore the possible relationship between these variables and the temporal variation characteristics of the ACWSC. The catchments that suffered from a prolonged meteorological drought in southeast Australia were selected as the case study. Results indicate that: (1) the increase in amplitude change in the ACWSC is observed in 83/92 catchments during the prolonged drought period, and significant shifts in the mean value of the ACWSC are detected in 77/92 catchments; (2) the average response time of the ACWSC for all 92 catchments with significant changes is 641.3 d; (3) the values of the ACWSC changed significantly in the catchments with small areas, low elevations, small slope ranges, large forest coverage, and high soil water-holding capacities. This study could enhance our understanding of the variations in catchment property under climate change.

Herein, a novel biosorbent originated from sugar beet pulp (SBP) was synthesized by microwave-assisted esterification with maleic anhydride (MA) and further decorated with ferric hydroxide. Characterization methods including FT-IR, SEM, XRD, Zeta potential, BET, TG and XPS were used to determine anticipative modification of SBP. The co-modified product of SBP (FMSBP) was applied for the cationic methylene blue (MB) dye removal and the optimization of experimental parameters such as biosorbent dosage, initial pH, contact time, initial MB concentration and temperature were investigated. Biosorption equilibrium followed the Langmuir isotherm model with a theoretical maximum biosorption capacity of 641.3 mg g−1 and the pseudo-second-order kinetic model was more suitable to describe kinetic data, while thermodynamic calculations indicated a spontaneous and exothermic biosorption process. Surface complexation and electrostatic interactions were involved in biosorption mechanisms, and the superior biosorption performance of FMSBP was achieved within 150 min at pH 8. Furthermore, FMSBP was demonstrated for the successful application in simulated real wastewater treatment, and the removal efficiency of MB remained above 70% after six desorption-resorption cycles, indicating a stable and promising biosorbent for decontamination of wastewater containing cationic dye.

Multi-principal element alloys and high-entropy alloys (HEAs) are emerging metallic materials with unprecedented structures and properties for various applications. In this study, we tuned the microstructure and mechanical performance of a recently designed high-performance Co-rich TRIP-HEA via thermomechanical processing (TMP). The microstructures of the HEA after various TMP routines were characterized, and their correlation with room-temperature tensile performance was clarified. The results showed that grain refinement is an effective strategy for enhancing strength while retaining satisfactory ductility. The formation of incoherent precipitates slightly improves the strength but inevitably sacrifices the ductility, which needs to be considered for optimizing the TMPs. The room temperature tensile yield strength and ultimate tensile strength were increased from 254.6 to 641.3 MPa and from 702.5 to 968.4 MPa, respectively, but the tensile elongation retains a satisfactory value of 68.8%. We herein provide important insights into the regulation of the microstructure and mechanical properties of TRIP-HEAs.

In the recent past, the COVID-19 epidemic has impeded global economic progress and, by extension, all of society. This type of pandemic has spread rapidly, posing a threat to human lives and the economy. Because of the growing scale of COVID-19 cases, employing artificial intelligence for future prediction purposes during this pandemic is crucial. Consequently, the major objective of this research paper is to compare various deep learning forecasting algorithms, including auto-regressive integrated moving average, long short-term memory, and conventional neural network techniques to forecast how COVID-19 would spread in Saudi Arabia in terms of the number of people infected, the number of deaths, and the number of recovered cases. Three different time horizons were used for COVID-19 predictions: short-term forecasting, medium-term forecasting, and long-term forecasting. Data pre-processing and feature extraction steps were performed as an integral part of the analysis work. Six performance measures were applied for comparing the efficacy of the developed models. LSTM and CNN algorithms have shown superior predictive precision with errors of less than 5% measured on available real data sets. The best model to predict the confirmed death cases is LSTM, which has better RMSE and R2 values. Still, CNN has a similar comparative performance to LSTM. LSTM unexpectedly performed badly when predicting the recovered cases, with RMSE and R2 values of 641.3 and 0.313, respectively. This work helps decisionmakers and health authorities reasonably evaluate the status of the pandemic in the country and act accordingly.

Inspiratory muscle training (IMT) is effective in improving postural stability and balance in different clinical populations. However, there is no evidence of these effects in soccer players. A single-blind, two-arm (1:1), randomized, placebo-controlled pilot study on 14 soccer players was performed with the main aim of assessing the effect of IMT on static balance, and secondarily, of examining changes in the respiratory muscle function. The experimental group (EG) received an IMT program with progressive intensity, from 20% to 80%, of the maximal inspiratory pressure (MIP). The sham group (SG) performed the same program with a fixed load of 20% of the MIP. Static balance and respiratory muscle function variables were assessed. A two-factor analysis of variance for repeated measures was used to assess differences after training. Statistical significance was set at p < 0.05. Significant increases were observed in the EG on length of sway under eyes open (from 2904.8 ± 640.0 to 3522.4 ± 509.0 mm, p = 0.012) and eyes closed (from 3166.2 ± 641.3 to 4173.3 ± 390.8 mm, p = 0.004). A significant increase in the maximal voluntary ventilation was observed for both groups (EG p = 0.005; SG p = 0.000). No significant differences existed between the groups. IMT did not improve the static balance in a sample of soccer players. Conducting a high-scale study is feasible and could refine the results and conclusions stemming from the current pilot study.

Recent studies suggest that seaweed extracts are a significant source of bioactive compounds comparable to the dietary phytochemicals such as onion and tea extracts. The exploration of natural antioxidants that attenuate oxidative damage is important for developing strategies to treat obesity-related pathologies. The objective of this study was to screen the effects of seaweed extracts of 49 species on adipocyte differentiation and reactive oxygen species (ROS) production during the adipogenesis in 3T3-L1 adipocytes, and to investigate their total phenol contents and 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical scavenging activities. Our results show that high total phenol contents were observed in the extracts of Ecklonia cava (see Table 1 for taxonomic authors) (681.1 ± 16.0 μg gallic acid equivalents [GAE] · g(-1) ), Dictyopteris undulata (641.3 ± 70.7 μg GAE · g(-1) ), and Laurencia intermedia (560.9 ± 48.1 μg GAE · g(-1) ). In addition, DPPH radical scavenging activities were markedly higher in Sargassum macrocarpum (60.2%), Polysiphonia morrowii (55.0%), and Ishige okamurae (52.9%) than those of other seaweed extracts (P < 0.05). Moreover, treatment with several seaweed extracts including D. undulata, Sargassum micracanthum, Chondrus ocellatus, Gelidium amansii, Gracilaria verrucosa, and Grateloupia lanceolata significantly inhibited adipocyte differentiation and ROS production during differentiation of 3T3-L1 preadipocytes. Furthermore, the production of ROS was positively correlated with lipid accumulation (R(2) = 0.8149). According to these preliminary results, some of the seaweed extracts can inhibit ROS generation, which may protect against oxidative stress that is linked to obesity. Further studies are required to determine the molecular mechanism between the verified seaweeds and ROS, and the resulting effects on obesity. [Table: see text].

Aims Chronic heart failure (CHF) is frequently associated with a decreased haemoglobin level, whereas the mechanism remains largely unknown. Methods and results One hundred consecutive CHF patients without anaemia or renal dysfunction based on non-cardiac reasons were enrolled. We explored determinants of anaemia (as iron parameters, erythropoietin, hepcidin and kidney function) including red cell volume (RCV) (by a 51 Cr assay) as well as related markers and plasma volume. The influence of each factor on haemoglobin concentrations was determined in a multiple regression model. Mean haemoglobin concentrations were 11.7 +/- 0.8 mg/dL in anaemic CHF patients and 14.4 +/- 1.2 mg/dL in non-anaemic patients. Corrected reticulocytes were lower in anaemic patients (35.1 +/- 15.7 vs. 50.3 +/- 19.2 G/L, P = 0.001), but the RCV was not reduced (1659.3 +/- 517.6 vs. 1826.4 +/- 641.3 mL, P = 0.194). We found that plasma volumes were significantly higher in anaemic CHF patients (70.0 +/- 2.4 vs. 65.0 +/- 4.0%, P0.001). Plasma volume was the best predictor of haemoglobin concentrations in the regression model applied (B = -0.651, P0.001, R(2) = 0.769). Conclusion Haemodilution appears to be the most potent factor for the development of low haemoglobin levels in patients with CHF. Our data support an additional independent, but minor influence of iron deficiency on haemoglobin concentrations in CHF patients.

Integrated petrographic and chemical analysis of zircon, garnet and rutile from ultrahigh-temperature (UHT) granulites in the Anapolis–Itaucu Complex, Brazil, is used to constrain the significance of zircon ID-TIMS U–Pb geochronological data. Chondrite-normalized rare earth element (REE) profiles of zircon cores have positive-sloping heavy-REE patterns, commonly inferred to be magmatic, whereas unambiguous metamorphic grains and overgrowths have flat to slightly negatively sloping heavy-REE patterns. However, in one sample, a core of zircon interpreted as having formed prior to garnet crystallization and a metamorphic zircon formed within microstructures involving garnet breakdown both display elevated heavy-REE (and Y) with positive-sloping patterns. DREE(zrc/grt) partition coefficients suggest an approximation to equilibrium between zircon and garnet cores, although progressive enrichment in heavy REE towards garnet rims occurs in two of the samples investigated. Titanium-in-zircon thermometry indicates zircon growth during both the prograde and post-peak evolution, but not at peak temperatures of the UHT metamorphism. By contrast, zirconium-in-rutile thermometry of inclusions armoured by garnet records crystallization temperatures, based on the upper end of the interquartile range of the data, of ∼890 to 870 °C and maximum temperature around 980 °C, indicating prograde and retrograde growth close to and after peak conditions. Rutile located in retrograde microstructures records crystallization temperatures of 850 to 820 °C. Rutile intergrown with ilmenite and included within orthopyroxene, which is associated with exsolved zircon, records temperatures ∼760 °C, consistent with Ti-in-zircon crystallization temperatures. ID-TIMS U–Pb geochronological data from two of the four samples investigated define upper intercept ages of 641.3 ± 8.4 Ma (MSWD 0.91) and 638.8 ± 2.5 Ma (MSWD 1.03) that correlate with periods of zircon growth along the prograde segment of the P–T path. Individual zircon U–Pb dates retrieved from all samples range from 649 to 634 Ma, indicating a maximum duration of c. 15 Myr for the UHT event. This period is interpreted as recording modest thickening of hot backarc lithosphere located behind the Arenopolis Arc at the edge of the Sao Francisco Craton consequent upon terminal collision of the Parana Block with the arc during the amalgamation of West Gondwana.