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As a promising technology, plasma-assisted combustion (PAC) has attracted many researchers to explore the effect of PAC on improving the combustion in propulsion devices, such as scramjet, detonation engines, internal engines, and so on. In this chapter, we aim to exhibit the influence of quasi-DC discharge plasma on the operating performance of scramjet combustor and find the internal mechanisms, which may contribute to the development of PAC technology in supersonic combustion. For case one, a plasma filament is generated upstream of fuel jet through quasi-DC discharge in a scramjet combustor; for case two, the plasma is formed across the backward facing step of a flame holding cavity to improve the flame stabilization of the cavity in the scramjet combustor. The two cases are investigated in detail through three-dimensional numerical simulation based on the dominant thermal blocking mechanism. Important parameters including temperature distribution, separation zone, water production, stagnation pressure loss, combustion efficiency, cavity drag, mass exchange rate, and cavity oscillating characteristics are obtained and analyzed. It shows that the quasi-DC discharge plasma does benefit for the improvement of the combustion in a scramjet combustor.