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An experiment with a vertical slot with horizontally seeping water with a dye diffusing from below was performed to help validate and visualize the Q-equivalent model, which describes the mass transfer rate from a source into flowing water, such as that in a repository for nuclear waste. The Q-equivalent model is used for quantifying mass transport in geological repositories. However, the tracer propagated much slower and to a lesser extent than predicted by the model. It was found that the tracer gave rise to a small density gradient that induced buoyancy-driven flow, overwhelming that driven by the horizontal hydraulic gradient. This dramatically changed the mass transfer from the dye source into the water in the slot. For the release of contaminants, this can have detrimental as well as beneficial effects, depending on whether positive or negative buoyancy is induced. These observations led to an analysis of when and how density differences in a repository can influence the release and further fate of escaping radionuclides in waste repositories. This and other experiments also showed that laboratory experiments aimed at visualizing flow and mass transfer processes in fractures could be very sensitive to the heating of the dye tracers by the lighting in the laboratory., QC 20200630

The Enhanced Geothermal System in Soultz-sous-Forêts, located in the geothermal favorable Upper Rhine Graben, is a fracture-controlled reservoir that was highly investigated in the last decades generating a huge geoscientific database. Numerical reservoir models use this database to simulate the operation of the subsurface heat exchanger, yet suffer from simplifications regarding the transfer of experimental into model data, dimensional extension, and computational power and efficiency. The new extensive transient 3D simulations, based on geophysical, geological and hydraulic data, highlight the hydraulic and transport feedback of the Soultz EGS due to convective and advective fluid flow. Developed with the goal of simulating the vast tracer test data during the reservoir-testing phase in 2005, the finite element model is focusing on the main fractured zones, which connect the wells in the deep reservoir. It comprises 13 major hydraulically active faults and fractures in a 13 × 11 x 5 km extending model domain, as well as open-hole sections of the wells GPK1 to GPK4 and their casing leakages. The simulation of the tracer experiment confirms the strong heterogeneity of the reservoir and highlights the importance of a potential fractured zone, hydraulically separating the reservoir in a northern (GPK1 to 3) and southern section (GPK4). This zone tends to connect the reservoir to the main fault system by hydraulically separating GPK4 from the other wells. The calibration and sensitivity analyses provide a unique, broad understanding of the reservoir flow zones providing information on the extension of the Soultz reservoir in the future and on the fluid pathways in the deep subsurface of the Upper Rhine Graben.

Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 123 (2018): 2615-2634, doi:10.1002/2017JC013536., In this work, we use realistic isopycnal velocities with a 3-D eddy diffusivity to advect and diffuse a tracer in the Antarctic Circumpolar Current, beginning in the Southeast Pacific and progressing through Drake Passage. We prescribe a diapycnal diffusivity which takes one value in the SE Pacific west of 678W and another value in Drake Passage east of that longitude, and optimize the diffusivities using a cost function to give a best fit to experimental data from the DIMES (Diapycnal and Isopycnal Mixing Experiment in the Southern Ocean) tracer, released near the boundary between the Upper and Lower Circumpolar Deep Water. We find that diapycnal diffusivity is enhanced 20-fold in Drake Passage compared with the SE Pacific, consistent with previous estimates obtained using a simpler advection-diffusion model with constant, but different, zonal velocities east and west of 678W. Our result shows that diapycnal mixing in the ACC plays a significant role in transferring buoyancy within the Meridional Overturning Circulation., UK Natural Environment Research Council Grant Numbers: NE/F020252/1 , NE/N018028/1 , NE/J007757/1; US National Science Foundation Grant Numbers: OCE 0622825 , OCE 1232962, 2018-09-26

Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 123 (2018): 2615-2634, doi:10.1002/2017JC013536., In this work, we use realistic isopycnal velocities with a 3-D eddy diffusivity to advect and diffuse a tracer in the Antarctic Circumpolar Current, beginning in the Southeast Pacific and progressing through Drake Passage. We prescribe a diapycnal diffusivity which takes one value in the SE Pacific west of 678W and another value in Drake Passage east of that longitude, and optimize the diffusivities using a cost function to give a best fit to experimental data from the DIMES (Diapycnal and Isopycnal Mixing Experiment in the Southern Ocean) tracer, released near the boundary between the Upper and Lower Circumpolar Deep Water. We find that diapycnal diffusivity is enhanced 20-fold in Drake Passage compared with the SE Pacific, consistent with previous estimates obtained using a simpler advection-diffusion model with constant, but different, zonal velocities east and west of 678W. Our result shows that diapycnal mixing in the ACC plays a significant role in transferring buoyancy within the Meridional Overturning Circulation., UK Natural Environment Research Council Grant Numbers: NE/F020252/1 , NE/N018028/1 , NE/J007757/1; US National Science Foundation Grant Numbers: OCE 0622825 , OCE 1232962, 2018-09-26

Nitrate (NO⁻3) export can vary widely among forested watersheds with similar nitrogen loading, geology, and vegetation, which suggests the importance of understanding differing internal retention mechanisms. Transport should be studied at the hillslope scale because the hillslope is the smallest unit with spatial and temporal resolution to reflect many relevant NO⁻3 retention and transport (flow-generation) processes, and headwater forested watersheds are largely comprised of sections of hillslopes. I conducted two experiments to elucidate subsurface flow dynamics and NO⁻3 transport and retention mechanisms on a constructed experimental hillslope model. In the first experiment, I tested whether decadal pedogenetic changes in soil properties in the experimental hillslope used by Hewlett and Hibbert (1963) would lead to changes in recession flow. I repeated (twice) their seminal experiment, whose results led to the development of the Variable Source Area paradigm, by also saturating, covering, and allowing the experimental hillslope to drain until it no longer yielded water. In the historical experiment there was fast drainage for 1.5 d, followed by slow drainage for ~140 d, which led the authors to conclude that recession flow in unsaturated soil could sustain baseflow throughout droughts. This long, slow drainage period was not reproduced in my experiments. Shapes of the drainage curves in my experiments were similar to the historical curve, but slow drainage was truncated, ending after 17 and 12 d, due likely to a leak in the boundary conditions, rather than to pedogenetic changes since the historical experiment. Leakage to bedrock, analogous to the leak in the hillslope model, is a commonly observed phenomenon and this study highlights how that can reduce drainage duration and the contribution of moisture from soils to support baseflow. In the second experiment, I tested whether movement of NO⁻3, which is considered a mobile ion, would be delayed relative to movem

Thermonuclear fusion may become an attractive future power source. The most promising of all fusion machine concepts is the tokamak. Despite decades of active research, still huge tasks remain before a fusion power plant can go online. One of these important tasks deals with the interaction between the fusion plasma and the reactor wall. This work focuses on how eroded wall materials of different origin and mass are transported in a tokamak device. Element transport can be examined by injection of certain species of unique and predetermined origin, so called tracers. Tracer experiments were conducted at the TEXTOR tokamak before its final shutdown. This offered an unique opportunity for studies of the wall and other internal components: For the first time it was possible to completely dismantle such a machine and analyse every single part of reactor wall, obtaining a detailed pattern of material migration. Main focus of this work is on the high-Z metals tungsten and molybdenum, which were introduced by WF6 and MoF6 injection into the TEXTOR tokamak in several material migration experiments. It is shown that Mo and W migrate in a similar way around the tokamak and that Mo can be used as tracer for W transport. It is further shown how other materials - medium-Z (Ni), low-Z (N-15 and F), fuel species (D) - migrate and get deposited. Finally, the outcome of dust sampling studies is discussed. It is shown that dust appearance and composition depends on origin, formation conditions and that it can originate even from remote systems like the NBI system. Furthermore, metal splashes and droplets have been found, some of them clearly indicating boiling processes., QC 20151203

Thermonuclear fusion may become an attractive future power source. The most promising of all fusion machine concepts is the tokamak. Despite decades of active research, still huge tasks remain before a fusion power plant can go online. One of these important tasks deals with the interaction between the fusion plasma and the reactor wall. This work focuses on how eroded wall materials of different origin and mass are transported in a tokamak device. Element transport can be examined by injection of certain species of unique and predetermined origin, so called tracers. Tracer experiments were conducted at the TEXTOR tokamak before its final shutdown. This offered an unique opportunity for studies of the wall and other internal components: For the first time it was possible to completely dismantle such a machine and analyse every single part of reactor wall, obtaining a detailed pattern of material migration. Main focus of this work is on the high-Z metals tungsten and molybdenum, which were introduced by WF6 and MoF6 injection into the TEXTOR tokamak in several material migration experiments. It is shown that Mo and W migrate in a similar way around the tokamak and that Mo can be used as tracer for W transport. It is further shown how other materials - medium-Z (Ni), low-Z (N-15 and F), fuel species (D) - migrate and get deposited. Finally, the outcome of dust sampling studies is discussed. It is shown that dust appearance and composition depends on origin, formation conditions and that it can originate even from remote systems like the NBI system. Furthermore, metal splashes and droplets have been found, some of them clearly indicating boiling processes., QC 20151203

Thermonuclear fusion may become an attractive future power source. The most promising of all fusion machine concepts is the tokamak. Despite decades of active research, still huge tasks remain before a fusion power plant can go online. One of these important tasks deals with the interaction between the fusion plasma and the reactor wall. This work focuses on how eroded wall materials of different origin and mass are transported in a tokamak device. Element transport can be examined by injection of certain species of unique and predetermined origin, so called tracers. Tracer experiments were conducted at the TEXTOR tokamak before its final shutdown. This offered an unique opportunity for studies of the wall and other internal components: For the first time it was possible to completely dismantle such a machine and analyse every single part of reactor wall, obtaining a detailed pattern of material migration. Main focus of this work is on the high-Z metals tungsten and molybdenum, which were introduced by WF6 and MoF6 injection into the TEXTOR tokamak in several material migration experiments. It is shown that Mo and W migrate in a similar way around the tokamak and that Mo can be used as tracer for W transport. It is further shown how other materials - medium-Z (Ni), low-Z (N-15 and F), fuel species (D) - migrate and get deposited. Finally, the outcome of dust sampling studies is discussed. It is shown that dust appearance and composition depends on origin, formation conditions and that it can originate even from remote systems like the NBI system. Furthermore, metal splashes and droplets have been found, some of them clearly indicating boiling processes., QC 20151203

Thermonuclear fusion may become an attractive future power source. The most promising of all fusion machine concepts is the tokamak. Despite decades of active research, still huge tasks remain before a fusion power plant can go online. One of these important tasks deals with the interaction between the fusion plasma and the reactor wall. This work focuses on how eroded wall materials of different origin and mass are transported in a tokamak device. Element transport can be examined by injection of certain species of unique and predetermined origin, so called tracers. Tracer experiments were conducted at the TEXTOR tokamak before its final shutdown. This offered an unique opportunity for studies of the wall and other internal components: For the first time it was possible to completely dismantle such a machine and analyse every single part of reactor wall, obtaining a detailed pattern of material migration. Main focus of this work is on the high-Z metals tungsten and molybdenum, which were introduced by WF6 and MoF6 injection into the TEXTOR tokamak in several material migration experiments. It is shown that Mo and W migrate in a similar way around the tokamak and that Mo can be used as tracer for W transport. It is further shown how other materials - medium-Z (Ni), low-Z (N-15 and F), fuel species (D) - migrate and get deposited. Finally, the outcome of dust sampling studies is discussed. It is shown that dust appearance and composition depends on origin, formation conditions and that it can originate even from remote systems like the NBI system. Furthermore, metal splashes and droplets have been found, some of them clearly indicating boiling processes., QC 20151203

Thermonuclear fusion may become an attractive future power source. The most promising of all fusion machine concepts is the tokamak. Despite decades of active research, still huge tasks remain before a fusion power plant can go online. One of these important tasks deals with the interaction between the fusion plasma and the reactor wall. This work focuses on how eroded wall materials of different origin and mass are transported in a tokamak device. Element transport can be examined by injection of certain species of unique and predetermined origin, so called tracers. Tracer experiments were conducted at the TEXTOR tokamak before its final shutdown. This offered an unique opportunity for studies of the wall and other internal components: For the first time it was possible to completely dismantle such a machine and analyse every single part of reactor wall, obtaining a detailed pattern of material migration. Main focus of this work is on the high-Z metals tungsten and molybdenum, which were introduced by WF6 and MoF6 injection into the TEXTOR tokamak in several material migration experiments. It is shown that Mo and W migrate in a similar way around the tokamak and that Mo can be used as tracer for W transport. It is further shown how other materials - medium-Z (Ni), low-Z (N-15 and F), fuel species (D) - migrate and get deposited. Finally, the outcome of dust sampling studies is discussed. It is shown that dust appearance and composition depends on origin, formation conditions and that it can originate even from remote systems like the NBI system. Furthermore, metal splashes and droplets have been found, some of them clearly indicating boiling processes., QC 20151203

Thermonuclear fusion may become an attractive future power source. The most promising of all fusion machine concepts is the tokamak. Despite decades of active research, still huge tasks remain before a fusion power plant can go online. One of these important tasks deals with the interaction between the fusion plasma and the reactor wall. This work focuses on how eroded wall materials of different origin and mass are transported in a tokamak device. Element transport can be examined by injection of certain species of unique and predetermined origin, so called tracers. Tracer experiments were conducted at the TEXTOR tokamak before its final shutdown. This offered an unique opportunity for studies of the wall and other internal components: For the first time it was possible to completely dismantle such a machine and analyse every single part of reactor wall, obtaining a detailed pattern of material migration. Main focus of this work is on the high-Z metals tungsten and molybdenum, which were introduced by WF6 and MoF6 injection into the TEXTOR tokamak in several material migration experiments. It is shown that Mo and W migrate in a similar way around the tokamak and that Mo can be used as tracer for W transport. It is further shown how other materials - medium-Z (Ni), low-Z (N-15 and F), fuel species (D) - migrate and get deposited. Finally, the outcome of dust sampling studies is discussed. It is shown that dust appearance and composition depends on origin, formation conditions and that it can originate even from remote systems like the NBI system. Furthermore, metal splashes and droplets have been found, some of them clearly indicating boiling processes., QC 20151203

Fresh water scarcity is an increasing problem worldwide. Strategies to alleviate water scarcity include the use of low-quality water for irrigation. The risk of groundwater contamination by pollutants in this water is affected by soil heterogeneity and preferential flow. These risk factors can be assessed by measuring the spatio-temporal redistribution of uniformly applied water and solutes. We placed a soil monolith (height 29 cm) from an Australian vineyard on a 100-cell multi-compartment sampler (MCS). At this vineyard, treated wastewater is used in response to the severe shortage of water in the summer. We studied the leaching risk associated with heterogeneous or preferential flow by irrigating the soil column with 24 applications to simulate one year. We applied simulated rainfall as well as wastewater (which contained chloride) during summer while relying on rainfall only in winter. We compared the chloride leaching with the leaching of bromide, which was applied during one of the applications as a pulse. During the entire simulated year, leaching of solutes from the monolith was measured. The results indicate that the assumption of uniform flow would underestimate the risk for the fresh groundwater reserves: 25 % of the solutes are transported though 6 % of the soil’s cross-section. The spatial distribution of drainage and solute leaching varied little during the experiment. Consequently, the mass flux density pattern of the bromide pulse was comparable to that of the repeatedly applied chloride. However, the MCS data suggested lateral ‘escape’ from chloride to non-mobile areas, which means in the long run, considerable quantities of these solutes can build up in areas that do not receive irrigation water.

Aerated lagoons (ALs) are important variants of the pond wastewater treatment technology that have not received much attention in the literature. The hydraulic behaviour of ALs and especially the Facultative aerated lagoons (FALs) is very complex since the aeration in these systems is designed for oxygen transfer but not necessarily to create complete mixing. In this work, the energy expenditure of the aerators was studied by means of a scenario analysis. 3D CFD models (one phase and multiphase) of a 3ha FAL in a waste stabilization pond system in Cuenca (Ecuador) were built for different configurations of aerators. The thrust produced by the aerators was modelled by an external momentum source applied as velocity vectors into the pond fluid. The predictions of a single phase model were in satisfactory agreement with experimental results. Subsequently, a scenario analysis assessing several aeration schemes with different numbers of aerators in operation were tested with respect to velocity profiles and residence time distribution (RTD) curves. This analysis showed that the aeration scheme with all 10 aerators switched on produces a similar hydraulic behaviour compared to using only 6 or 8 aerators. The current operational schemes comprise of switching off some aerators during the peak hours of the day and operating all 10 aerators during night. This current practice could be economically replaced by continuously operating 4 or 6 aerators without significantly affecting the overall mixing. Furthermore, a continuous mixing regime minimises the sediment oxygen demand enhancing the oxygen levels in the pond. © 2013 Elsevier Ltd.

Despite the long history of the continuum equation approach in hydrology, it is not a necessary approach to the formulation of a physically based representation of hillslope hydrology. The Multiple Interacting Pathways ( MIPs) model is a discrete realization that allows hillslope response and transport to be simultaneously explored in a way that reflects the potential occurrence of preferential flows and lengths of pathways. The MIPs model uses random particle tracking methods to represent the flow of water within the subsurface alongside velocity distributions that acknowledge preferential flows and transition probability matrices, which control flow pathways. An initial realization of this model is presented here in application to a tracer experiment carried out in Gardsjon, Sweden. The model is used as an exploratory tool, testing several hypotheses in relation to this experiment.

Despite the long history of the continuum equation approach in hydrology, it is not a necessary approach to the formulation of a physically based representation of hillslope hydrology. The Multiple Interacting Pathways (MIPs) model is a discrete realization that allows hillslope response and transport to be simultaneously explored in a way that reflects the potential occurrence of preferential flows and lengths of pathways. The MIPs model uses random particle tracking methods to represent the flow of water within the subsurface alongside velocity distributions that acknowledge preferential flows and transition probability matrices, which control flow pathways. An initial realization of this model is presented here in application to a tracer experiment carried out in Gårdsjön, Sweden. The model is used as an exploratory tool, testing several hypotheses in relation to this experiment.

Translocation of carbon (C) and nitrogen (N) was investigated in response to shading of the seagrass Posidonia sinuosa in control (ambient light) and shade (below minimum light requirement) treatments after 10 d shading. A mature leaf was incubated in situ in 13C- and 15N-enriched seawater for 2 h and the appearance of the isotopes in the young leaf and adjacent rhizome monitored over 29 d. C and N isotopes gradually reduced in the mature leaf: of 15N contained in the entire shoot (mature leaf, young leaf and 4 cm rhizome), 95% (control) and 97% (shade) was found in the mature leaf after 2 h incubation and only 75% and 60% remained in the mature leaf after 29 d; 98% and 94% of 13C was found in the mature leaf after 2 h, and it had reduced to 36% and 44% after 29 d. This corresponded to an equal increase in the young leaf + rhizome indicating that the mature leaf is a source of these nutrients to the young leaf and rhizome. C translocation from mature leaves was not significantly affected by the shade treatment. In contrast, there was an increase in 15N taken up by the mature leaves (1.9× higher in the shade), the percent of 15N translocated to the young leaf and rhizome (24% in control and 40% in shade) and N concentration in the young leaf (1.24% control and 1.41% shade) and rhizome (0.86% control and 0.99% shade). Resorption of C and N was also estimated from changes in the total C and N content of the mature leaf over 29 d. N resorption from the mature leaf contributed up to 63% of young leaf N requirements in the control treatment but only 41% in the shade treatment.Weconclude that uptake and translocation ofNby mature leaves is a response to shading in P. sinuosa and would provide additional N to growing leaves, enhancing light harvesting efficiency.

Groundwater-lake interaction in conjunction with surface mixing and vertical exchange were quantitatively examined for the monimolimnion in a small stratified mining lake. Although the lake is shallow (4.7 m), it shows a strong meromixis. The permanent chemocline, which is connected with stable density stratification, separates the mixolimnion from the anoxic monimolimnion at a variable depth of only 0.6-1.9 m. We conducted a tracer experiment, injecting 3 µmol of anthropogenic gas SF6 into the monimolimnion. With monthly measured vertical concentration profiles extended over 2 years we detected and quantified the groundwater coupling. An exchange time close to once per year was estimated for the monimolimnion by balancing the tracer. From CTD casts and thermistor chain data we extracted additional information about mixing. For the water and tracer balances, we included the erosion of the monimolimnion surface by strong daily convective mixing in the mixolimnion during the warm period. SF6 background measurements before spiking indicate that diffusive transport through the chemocline density step must be very low, i.e., close to the molecular level. The observed seasonal variability of the chemocline depth can be considered as the result of a virtually steady inflow of groundwater, which supports the growth of the monimolimnion, and strong seasonal mixing in the mixolimnion, which acts against the stratification and erodes the monimolimnion. Over longer time scales, the chemocline is to be found at the level where erosive processes balance the recharging of the monimolimnion from groundwater.

Treatment wetlands play an important role in reducing nutrient content and heavy metals in wastewater and run-off water. The treatment efficiency strongly depends on flow pattern and residence times of the water. Here, we study the impact of different factors on water flow patterns based on a tracer experiment with tritiated water in a 2.6 ha constructed wetland pond. A 2D flow and inert transport model was used to evaluate the relative importance of bottom topography, vegetation distribution, water exchange with stagnant zones and dispersion. Results from computer simulations and independent measurements of friction losses as well as wetland geometry showed that variations in bottom topography, formed by several deep zones, decreased the variance in water residence times to a minor extent. Heterogeneity in vegetation, on the other hand, significantly contributed to the spread in water residence times and explained the multiple peaks observed in the breakthrough curves. Analyses showed that in the Ekeby treatment wetland, basin shape explained about 10% of the variance in the observed residence times, whereas vegetation explained about 60-80%. To explain all variance secondary factors were needed, such as dispersion and water exchange with stagnant zones. These were shown to contribute to the spread of residence times and primarily to the long tail of the observed breakthrough curves., QC 20100906

Treatment wetlands play an important role in reducing nitrogen content in wastewater and agricultural run-off water. The main removal process is denitrification and the removal efficiency depends on the hydrological and microbiological features of the wetland, especially in terms of water residence times and denitrification rates. The aim of this thesis was to increase the understanding of the coupled hydrological and microbiological processes regulating the denitrification capacity. This was done by applying a broad spectrum of analyses methods, including tracer experiment, water flow modeling, denitrification rate measurements, and analyses of the microbial community structures. The tracer experiment and flow modeling revealed that the wetland design, especially the vegetation, largely can affect the water residence time distributions in wetlands. In the investigated wetland, vegetation dominated the water flow, explaining 60-80% of the variance in water residence times, whereas basin shape only explained about 10% of the variance, but also mixing phenomena significantly affected the residence times and could considerably delay solutes. Measured potential denitrification rates in the wetland exhibited significant spatial variations, and the variations were best described by concentration of nitrogen in sediments and water residence time. Analyses of the denitrifying bacteria populations indicated that a few key populations dominated and that the community diversity increased with decreasing nutrient levels and increasing water residence times. Moreover, it was found that denitrification rates in terms of Menten and first order kinetics can be evaluated by fitting a mathematical expression, considering denitrification and other nitrogen transforming processes to measured product formation in nitrate limited experiments., QC 20101110

Treatment wetlands play an important role in reducing nitrogen content in wastewater and agricultural run-off water. The main removal process is denitrification and the removal efficiency depends on the hydrological and microbiological features of the wetland, especially in terms of water residence times and denitrification rates. The aim of this thesis was to increase the understanding of the coupled hydrological and microbiological processes regulating the denitrification capacity. This was done by applying a broad spectrum of analyses methods, including tracer experiment, water flow modeling, denitrification rate measurements, and analyses of the microbial community structures. The tracer experiment and flow modeling revealed that the wetland design, especially the vegetation, largely can affect the water residence time distributions in wetlands. In the investigated wetland, vegetation dominated the water flow, explaining 60-80% of the variance in water residence times, whereas basin shape only explained about 10% of the variance, but also mixing phenomena significantly affected the residence times and could considerably delay solutes. Measured potential denitrification rates in the wetland exhibited significant spatial variations, and the variations were best described by concentration of nitrogen in sediments and water residence time. Analyses of the denitrifying bacteria populations indicated that a few key populations dominated and that the community diversity increased with decreasing nutrient levels and increasing water residence times. Moreover, it was found that denitrification rates in terms of Menten and first order kinetics can be evaluated by fitting a mathematical expression, considering denitrification and other nitrogen transforming processes to measured product formation in nitrate limited experiments., QC 20101110

Treatment wetlands play an important role in reducing nitrogen content in wastewater and agricultural run-off water. The main removal process is denitrification and the removal efficiency depends on the hydrological and microbiological features of the wetland, especially in terms of water residence times and denitrification rates. The aim of this thesis was to increase the understanding of the coupled hydrological and microbiological processes regulating the denitrification capacity. This was done by applying a broad spectrum of analyses methods, including tracer experiment, water flow modeling, denitrification rate measurements, and analyses of the microbial community structures. The tracer experiment and flow modeling revealed that the wetland design, especially the vegetation, largely can affect the water residence time distributions in wetlands. In the investigated wetland, vegetation dominated the water flow, explaining 60-80% of the variance in water residence times, whereas basin shape only explained about 10% of the variance, but also mixing phenomena significantly affected the residence times and could considerably delay solutes. Measured potential denitrification rates in the wetland exhibited significant spatial variations, and the variations were best described by concentration of nitrogen in sediments and water residence time. Analyses of the denitrifying bacteria populations indicated that a few key populations dominated and that the community diversity increased with decreasing nutrient levels and increasing water residence times. Moreover, it was found that denitrification rates in terms of Menten and first order kinetics can be evaluated by fitting a mathematical expression, considering denitrification and other nitrogen transforming processes to measured product formation in nitrate limited experiments., QC 20101110

Treatment wetlands play an important role in reducing nitrogen content in wastewater and agricultural run-off water. The main removal process is denitrification and the removal efficiency depends on the hydrological and microbiological features of the wetland, especially in terms of water residence times and denitrification rates. The aim of this thesis was to increase the understanding of the coupled hydrological and microbiological processes regulating the denitrification capacity. This was done by applying a broad spectrum of analyses methods, including tracer experiment, water flow modeling, denitrification rate measurements, and analyses of the microbial community structures. The tracer experiment and flow modeling revealed that the wetland design, especially the vegetation, largely can affect the water residence time distributions in wetlands. In the investigated wetland, vegetation dominated the water flow, explaining 60-80% of the variance in water residence times, whereas basin shape only explained about 10% of the variance, but also mixing phenomena significantly affected the residence times and could considerably delay solutes. Measured potential denitrification rates in the wetland exhibited significant spatial variations, and the variations were best described by concentration of nitrogen in sediments and water residence time. Analyses of the denitrifying bacteria populations indicated that a few key populations dominated and that the community diversity increased with decreasing nutrient levels and increasing water residence times. Moreover, it was found that denitrification rates in terms of Menten and first order kinetics can be evaluated by fitting a mathematical expression, considering denitrification and other nitrogen transforming processes to measured product formation in nitrate limited experiments., QC 20101110

Treatment wetlands play an important role in reducing nitrogen content in wastewater and agricultural run-off water. The main removal process is denitrification and the removal efficiency depends on the hydrological and microbiological features of the wetland, especially in terms of water residence times and denitrification rates. The aim of this thesis was to increase the understanding of the coupled hydrological and microbiological processes regulating the denitrification capacity. This was done by applying a broad spectrum of analyses methods, including tracer experiment, water flow modeling, denitrification rate measurements, and analyses of the microbial community structures. The tracer experiment and flow modeling revealed that the wetland design, especially the vegetation, largely can affect the water residence time distributions in wetlands. In the investigated wetland, vegetation dominated the water flow, explaining 60-80% of the variance in water residence times, whereas basin shape only explained about 10% of the variance, but also mixing phenomena significantly affected the residence times and could considerably delay solutes. Measured potential denitrification rates in the wetland exhibited significant spatial variations, and the variations were best described by concentration of nitrogen in sediments and water residence time. Analyses of the denitrifying bacteria populations indicated that a few key populations dominated and that the community diversity increased with decreasing nutrient levels and increasing water residence times. Moreover, it was found that denitrification rates in terms of Menten and first order kinetics can be evaluated by fitting a mathematical expression, considering denitrification and other nitrogen transforming processes to measured product formation in nitrate limited experiments., QC 20101110

Numerous field observations show that most water flow in fractured rocks takes place in only a small part of the fractures. We call these channels. Solutes in the flowing water can diffuse in and out of stagnant water in the porous rock matrix that the flowing water contacts via the so-called flow wetted surface (FWS). In addition, the solutes can diffuse into stagnant water in the fractures themselves and from this water further into the rock matrix. For narrow channels with small FWS the transport via the stagnant water in the fracture can considerably add to the exchange of solutes between flowing water and matrix water. For sorbing solutes that interact with the micropore surfaces in the matrix the effect can be very strong. Some models that account for these processes are developed and solved using Laplace transforms. Some examples are presented that show the effects of first diffusion into stagnant waters in fractures with subsequent diffusion into the rock matrix. Effects of slit-like and tube-like channels are considered as well as the presence of intersecting fractures. The solutions are especially useful to model solute transport in complex three-dimensional channels networks where wide and narrow or even tube-like channels with widely varying flow rates combine into a multitude of different paths., QC 20100525

When protection zones for wells are delineated, it is important to acquire good knowledge about possible travel time from different points in the catchment area to the well. Often, simple analytical methods are used for estimating travel times and the assumption is made that the hydraulic conductivity is relatively homogenous within the aquifer. Nevertheless, many aquifers are strongly heterogeneous which may lead to differences between estimates and actual travel times. As a part of the process to develop improved methods for delineating protection zones for groundwater supply wells, a tracer experiment was performed in a glaciofluvial esker formation in Järlåsa. On the basis of the experiment, a numerical flow model was created for the test site. The purpose of this master’s thesis was to apply the flow model to an aquifer where the hydraulic conductivity shows great variability and should be described by a stochastic distribution. The purpose was also to determine the statistical properties of the hydraulic conductivity and to simulate the transport times and their variation from different locations in the aquifer to the pumping well. The hydraulic conductivity was estimated from grain size distributions in soil samples that were taken at various locations within the test site. The analysis of the hydraulic conductivity showed a large variation and confirmed the hypothesis that the aquifer is heterogeneous. Using the statistics, a large number of stochastic conductivity fields were created and flow simulation was performed for each realization. From the simulation result, frequency distributions of the transport times were produced describing the probability for the transit time for a water particle between a certain location in the aquifer and the pumping well. A comparison with the tracer experiment shows higher simulated transport times implying the need for improved model calibration. The conclusion is that the method used in this project is suitable for glac, När skyddsområden för grundvattentäkter skapas är det viktigt att ha god kännedom om vattnets transporttider från olika delar i tillrinningsområdet till uttagsplatsen av grundvattnet. Metoderna för att bestämma dessa tider är ofta enkla och vanligen görs antagandet att områdets hydrauliska konduktivitet är relativt homogen. Många akviferer är dock kraftigt heterogena och de verkliga transporttiderna kan då skilja sig från de uppskattade. Som ett led i metodutvecklingen för bättre avgränsning av skyddsområden genomfördes ett spårämnesförsök i en isälvsavlagring i Järlåsa. Med utgångspunkt från försöket har en numerisk flödesmodell konstruerats över försöksområdet. Syftet med examensarbetet var att tillämpa flödesmodellen i en akvifer där den hydrauliska konduktiviteten visar sådana variationer att den beskrivs bäst av en stokastisk fördelning. Vidare var syftet att bestämma den hydrauliska konduktivitetens statistiska egenskaper och att simulera transporttiderna och deras variation från olika punkter i akviferen till pumpbrunnen. Den hydrauliska konduktiviteten uppskattades utifrån kornstorleksfördelningar i jordprover som togs på en mängd platser i försöksområdet. Analysen av den hydrauliska konduktiviteten visar stora variationer i området vilket bekräftar att akviferen är heterogen. Utifrån konduktivitetens statistik genererades ett stort antal stokastiska konduktivitetsfält och transporttiderna beräknades för varje realisering. Resultatet från simuleringarna gav frekvensfördelningar för transporttiderna som beskriver sannolikheten för hur lång uppehållstid en vattenpartikel har i marken mellan en startpunkt och pumpbrunnen. Jämfört med spårämnesförsöket blev de simulerade transporttiderna något större vilket tyder på att flödesmodellen kräver en bättre kalibrering mot fältmätningar. Slutsatsen är att metodiken är lämplig för att studera vattnets transporttider i isälvsavlagringen och när ett skyddsområde skapas för den här typen av akvifer kan stokastisk modeller

When protection zones for wells are delineated, it is important to acquire good knowledge about possible travel time from different points in the catchment area to the well. Often, simple analytical methods are used for estimating travel times and the assumption is made that the hydraulic conductivity is relatively homogenous within the aquifer. Nevertheless, many aquifers are strongly heterogeneous which may lead to differences between estimates and actual travel times. As a part of the process to develop improved methods for delineating protection zones for groundwater supply wells, a tracer experiment was performed in a glaciofluvial esker formation in Järlåsa. On the basis of the experiment, a numerical flow model was created for the test site. The purpose of this master’s thesis was to apply the flow model to an aquifer where the hydraulic conductivity shows great variability and should be described by a stochastic distribution. The purpose was also to determine the statistical properties of the hydraulic conductivity and to simulate the transport times and their variation from different locations in the aquifer to the pumping well. The hydraulic conductivity was estimated from grain size distributions in soil samples that were taken at various locations within the test site. The analysis of the hydraulic conductivity showed a large variation and confirmed the hypothesis that the aquifer is heterogeneous. Using the statistics, a large number of stochastic conductivity fields were created and flow simulation was performed for each realization. From the simulation result, frequency distributions of the transport times were produced describing the probability for the transit time for a water particle between a certain location in the aquifer and the pumping well. A comparison with the tracer experiment shows higher simulated transport times implying the need for improved model calibration. The conclusion is that the method used in this project is suitable for glac, När skyddsområden för grundvattentäkter skapas är det viktigt att ha god kännedom om vattnets transporttider från olika delar i tillrinningsområdet till uttagsplatsen av grundvattnet. Metoderna för att bestämma dessa tider är ofta enkla och vanligen görs antagandet att områdets hydrauliska konduktivitet är relativt homogen. Många akviferer är dock kraftigt heterogena och de verkliga transporttiderna kan då skilja sig från de uppskattade. Som ett led i metodutvecklingen för bättre avgränsning av skyddsområden genomfördes ett spårämnesförsök i en isälvsavlagring i Järlåsa. Med utgångspunkt från försöket har en numerisk flödesmodell konstruerats över försöksområdet. Syftet med examensarbetet var att tillämpa flödesmodellen i en akvifer där den hydrauliska konduktiviteten visar sådana variationer att den beskrivs bäst av en stokastisk fördelning. Vidare var syftet att bestämma den hydrauliska konduktivitetens statistiska egenskaper och att simulera transporttiderna och deras variation från olika punkter i akviferen till pumpbrunnen. Den hydrauliska konduktiviteten uppskattades utifrån kornstorleksfördelningar i jordprover som togs på en mängd platser i försöksområdet. Analysen av den hydrauliska konduktiviteten visar stora variationer i området vilket bekräftar att akviferen är heterogen. Utifrån konduktivitetens statistik genererades ett stort antal stokastiska konduktivitetsfält och transporttiderna beräknades för varje realisering. Resultatet från simuleringarna gav frekvensfördelningar för transporttiderna som beskriver sannolikheten för hur lång uppehållstid en vattenpartikel har i marken mellan en startpunkt och pumpbrunnen. Jämfört med spårämnesförsöket blev de simulerade transporttiderna något större vilket tyder på att flödesmodellen kräver en bättre kalibrering mot fältmätningar. Slutsatsen är att metodiken är lämplig för att studera vattnets transporttider i isälvsavlagringen och när ett skyddsområde skapas för den här typen av akvifer kan stokastisk modeller

Draft rules for artificial recharge operations, which use recycled waste water as a source water, require minimum travel times to production wells in California. Deliberate tracer experiments are the accepted method for determining travel times. An example of a tracer experiment using sulfur hexafluoride is discussed at an artificial recharge site located within a regional water table depression. The study shows the complexity in interpreting travel times because of the influence of recharge rates and water production. It also demonstrates the effectiveness of recovering recharged water at spreading basins surrounded by production wells.

The euthropthication of the Baltic Sea is a threat that is beginning to be taken seriously by the governments concerned. In Sweden, regulations concerning the allowed nitrogen (N) concentration in the effluent water from wastewater treatment plants are being tightened up. The Rimbo wastewater treatment plant has been imposed to reduce the annual mean concentration of total N in the effluent water to levels below 15 mg l-1. A more and more common way to reduce the nitrogen level in wastewater is to let the water pass through a wetland. This study investigates the possibility to build this kind of wetland at the outlet of the Rimbo wastewater treatment plant. A prestudy of the topography, soil characteristics and groundwater flow indicates that the land area in question is well suited for the construction of a wetland. A proposal for the design has been made by using a physically based computer model developed in the PRIMROSE project (PRocess based Integrated Management of constructed and Riverine wetlands for Optimal control of wastewater at catchment ScalE), which is financed by the EU. Analysis of the residence time distribution (RTD) is a tool for understanding wetland design characteristics and can be used for wetland engineering such as optimizing design for best possibleefficiency in nitrogen removal. In order to characterize the performance of a wetland, it is useful to translate the RTD to a key figure representing the treatment efficiency. In this work, two types of such key figures have been used. Key figure 1 gives the hydraulic efficiency and Key figure 2 gives an estimation of the nitrogen retention by an integration of hydraulic characteristics and the chemical transformation of nitrogen. The results of this study show that constructing a wetland in Rimbo probably would be an efficient way to reduce the nitrogen level at the effluent of the wastewater plant below the limits of the regulations. In addition, a wetland would form a nice place of recreation, Övergödningen i Östersjön är ett problem som uppmärksammas alltmer. Ett led i att minska kvävebelastningen på Östersjön är ökade krav på rening i de svenska kommunala reningsverken. Rimbo avloppsreningsanläggning har blivit ålagd ett riktvärde för totalkväve på 15 mg l-1 i utgående vatten, vilket motsvarar en reningsgrad som inte uppnås idag. Ett alltmer vanligt sätt att minska föroreningshalterna är att anlägga våtmarker i anslutning till reningsverken för att efterpolera spillvattnet. Det här arbetet är en del av en förstudie till en sådan våtmark i Rimbo. En förundersökning av topografi, jordart och grundvattenflöden indikerar att det område som föreslagits i anslutning till reningsverket i Rimbo lämpar sig väl för ett våtmarksbygge. Förslag till utformning har tagits fram med hjälp av en fysikaliskt baserad modell över vattenströmning, utvecklad inom det EU-finansierade projektet PRIMROSE (PRocess based Integrated Management of constructed and Riverine wetlands for Optimal control of wastewater at catchment ScalE). Analys av vattnets uppehållstidsfördelning ger förståelse för våtmarkens egenskaper och kan därför användas vid t ex optimering av våtmarksdesign med avseende på kväverening. För att på ett enkelt sätt kunna jämföra olika våtmarkers effektivitet är det praktiskt att översätta uppehållstidsfördelningen till ett nyckeltal för reningseffekten. I det här arbetet har två olika sådana nyckeltal beräknats. Det första ger den hydrauliska effektiviteten och det andra bygger på en metod där våtmarkens interna hydraulik integreras med den kemiska omvandlingen av kväve. Nyckeltal 1 ger ett mått på hur stor del av volymen i våtmarken som används för kväverening, medan Nyckeltal 2 ger ett mått på den procentuella kväveavskiljningen. Den här förstudien visar att en våtmark sannolikt skulle vara ett utmärkt sätt att klara riktvärdet för kvävehalten vid reningsverket i Rimbo. Därutöver skulle en våtmark kunna utgöra ett positivt inslag i landskapet och öka den biologi

Draft rules for artificial recharge operations, which use recycled waste water as a source water, require minimum travel times to production wells in California. Deliberate tracer experiments are the accepted method for determining travel times. An example of a tracer experiment using sulfur hexafluoride is discussed at an artificial recharge site located within a regional water table depression. The study shows the complexity in interpreting travel times because of the influence of recharge rates and water production. It also demonstrates the effectiveness of recovering recharged water at spreading basins surrounded by production wells.

The euthropthication of the Baltic Sea is a threat that is beginning to be taken seriously by the governments concerned. In Sweden, regulations concerning the allowed nitrogen (N) concentration in the effluent water from wastewater treatment plants are being tightened up. The Rimbo wastewater treatment plant has been imposed to reduce the annual mean concentration of total N in the effluent water to levels below 15 mg l-1. A more and more common way to reduce the nitrogen level in wastewater is to let the water pass through a wetland. This study investigates the possibility to build this kind of wetland at the outlet of the Rimbo wastewater treatment plant. A prestudy of the topography, soil characteristics and groundwater flow indicates that the land area in question is well suited for the construction of a wetland. A proposal for the design has been made by using a physically based computer model developed in the PRIMROSE project (PRocess based Integrated Management of constructed and Riverine wetlands for Optimal control of wastewater at catchment ScalE), which is financed by the EU. Analysis of the residence time distribution (RTD) is a tool for understanding wetland design characteristics and can be used for wetland engineering such as optimizing design for best possibleefficiency in nitrogen removal. In order to characterize the performance of a wetland, it is useful to translate the RTD to a key figure representing the treatment efficiency. In this work, two types of such key figures have been used. Key figure 1 gives the hydraulic efficiency and Key figure 2 gives an estimation of the nitrogen retention by an integration of hydraulic characteristics and the chemical transformation of nitrogen. The results of this study show that constructing a wetland in Rimbo probably would be an efficient way to reduce the nitrogen level at the effluent of the wastewater plant below the limits of the regulations. In addition, a wetland would form a nice place of recreation, Övergödningen i Östersjön är ett problem som uppmärksammas alltmer. Ett led i att minska kvävebelastningen på Östersjön är ökade krav på rening i de svenska kommunala reningsverken. Rimbo avloppsreningsanläggning har blivit ålagd ett riktvärde för totalkväve på 15 mg l-1 i utgående vatten, vilket motsvarar en reningsgrad som inte uppnås idag. Ett alltmer vanligt sätt att minska föroreningshalterna är att anlägga våtmarker i anslutning till reningsverken för att efterpolera spillvattnet. Det här arbetet är en del av en förstudie till en sådan våtmark i Rimbo. En förundersökning av topografi, jordart och grundvattenflöden indikerar att det område som föreslagits i anslutning till reningsverket i Rimbo lämpar sig väl för ett våtmarksbygge. Förslag till utformning har tagits fram med hjälp av en fysikaliskt baserad modell över vattenströmning, utvecklad inom det EU-finansierade projektet PRIMROSE (PRocess based Integrated Management of constructed and Riverine wetlands for Optimal control of wastewater at catchment ScalE). Analys av vattnets uppehållstidsfördelning ger förståelse för våtmarkens egenskaper och kan därför användas vid t ex optimering av våtmarksdesign med avseende på kväverening. För att på ett enkelt sätt kunna jämföra olika våtmarkers effektivitet är det praktiskt att översätta uppehållstidsfördelningen till ett nyckeltal för reningseffekten. I det här arbetet har två olika sådana nyckeltal beräknats. Det första ger den hydrauliska effektiviteten och det andra bygger på en metod där våtmarkens interna hydraulik integreras med den kemiska omvandlingen av kväve. Nyckeltal 1 ger ett mått på hur stor del av volymen i våtmarken som används för kväverening, medan Nyckeltal 2 ger ett mått på den procentuella kväveavskiljningen. Den här förstudien visar att en våtmark sannolikt skulle vara ett utmärkt sätt att klara riktvärdet för kvävehalten vid reningsverket i Rimbo. Därutöver skulle en våtmark kunna utgöra ett positivt inslag i landskapet och öka den biologi

It is often advantageous to model a semi-enclosed estuarine or coastal embayment (e.g. fish farms or tidal inlets, or typhoon shelters) as a separate system within a larger water body connected to the outer sea. The water quality of the system depends crucially on its flushing time - the average time of a particle in the system. The flushing time is governed by the barotropic and baroclinic tidal exchanges between the system and the outer sea. We describe herein a general method to determine systematically the flushing time of a stratified water body via a numerical tracer experiment. Numerical solution of the 3D flow and mass transport equations for many practical problems show that the tracer mass removal process depends on the physical topography and bathymetry, tidal range and the degree of stratification in the outer sea. Field application suggests that the tracer mass variation can be well approximated by a double-exponential decay curve that can be described by three flushing coefficients. Using a simple analytical two-segment model, the flushing coefficients can be given a clear physical interpretation, and the flushing time can be easily determined in terms of the coefficients. The method is illustrated by application to a number of tidal inlets in Hong Kong, in both the dry and wet season. The connection between the numerically determined flushing time and the traditional bulk flushing time obtained from salt-balance methods is established. © 2004 Elsevier B.V. All rights reserved.

It is often advantageous to model a semi-enclosed estuarine or coastal embayment (e.g. fish farms or tidal inlets, or typhoon shelters) as a separate system within a larger water body connected to the outer sea. The water quality of the system depends crucially on its flushing time - the average time of a particle in the system. The flushing time is governed by the barotropic and baroclinic tidal exchanges between the system and the outer sea. We describe herein a general method to determine systematically the flushing time of a stratified water body via a numerical tracer experiment. Numerical solution of the 3D flow and mass transport equations for many practical problems show that the tracer mass removal process depends on the physical topography and bathymetry, tidal range and the degree of stratification in the outer sea. Field application suggests that the tracer mass variation can be well approximated by a double-exponential decay curve that can be described by three flushing coefficients. Using a simple analytical two-segment model, the flushing coefficients can be given a clear physical interpretation, and the flushing time can be easily determined in terms of the coefficients. The method is illustrated by application to a number of tidal inlets in Hong Kong, in both the dry and wet season. The connection between the numerically determined flushing time and the traditional bulk flushing time obtained from salt-balance methods is established. © 2004 Elsevier B.V. All rights reserved.

It is often advantageous to model a semi-enclosed estuarine or coastal embayment (e.g. fish farms or tidal inlets, or typhoon shelters) as a separate system within a larger water body connected to the outer sea. The water quality of the system depends crucially on its flushing time - the average time of a particle in the system. The flushing time is governed by the barotropic and baroclinic tidal exchanges between the system and the outer sea. We describe herein a general method to determine systematically the flushing time of a stratified water body via a numerical tracer experiment. Numerical solution of the 3D flow and mass transport equations for many practical problems show that the tracer mass removal process depends on the physical topography and bathymetry, tidal range and the degree of stratification in the outer sea. Field application suggests that the tracer mass variation can be well approximated by a double-exponential decay curve that can be described by three flushing coefficients. Using a simple analytical two-segment model, the flushing coefficients can be given a clear physical interpretation, and the flushing time can be easily determined in terms of the coefficients. The method is illustrated by application to a number of tidal inlets in Hong Kong, in both the dry and wet season. The connection between the numerically determined flushing time and the traditional bulk flushing time obtained from salt-balance methods is established. © 2004 Elsevier B.V. All rights reserved.

A transient storage model is evaluated using results from a tracer experiment, where a conservative and a reactive tracer (H-3 and Cr-51(III)) were injected simultaneously and monitored in stream water and bed sediment. About 76% of the chromium was lost from the stream water on the reach 30 km downstream of the injection point directly after the passage of the pulse in the flowing water. The bed sediment hosted the main part of the retained chromium. The time to washout 75% of the maximum solute uptake in the sediment was similar to 85 times longer for chromium than for tritium (i.e. similar to 45 days). It was possible to describe the sediment-water exchange with a diffusive flux formulation that could be evaluated using tritium breakthrough curves in the stream water or the tritium inventory breakthrough curves in the sediment. This experiment revealed further that observations of chromium concentrations in the sediment were essential for the quantifying of sorption properties, as it was not possible to catch accurately the time scale of sorption within the duration of the breakthrough curves in the stream water. There was a clear need for a rate-limited description of the sorption of chromium in the sediment. We found that a first-order kinetic description of the sorption process could acceptably describe the breakthrough curves in both the stream water and the bed sediment., QC 20100525

Understanding of the processes affecting solute transport in flowing water is important for the possibility to predict the evolution with time of polluted stream systems. This thesis presents tracer experiment methodology and model developments for solute transport in streams, with special focus on retention processes and their effect on solute stream transport. Results are presented from a tracer experiment in the Säva Stream, Uppland County, Sweden, where both a conservative (3H as tritiated water) and a reactive (51Cr as trivalent chromium ion) tracer were injected simultaneously. The time and length scales of the experiment were prolonged compared to previous studies, which allowed for new critical tests of different model concepts. It was found that the hyporheic exchange greatly affected the solute transport of both tracers. However, the retention of chromium was significantly more pronounced. About 76% of the injected chromium was lost from the stream water phase directly after the passage of the pulse 30 km downstream of the injection point. The inventory of chromium in the sediments indicated that the main part was retrieved in the hyporheic zone. Both a diffusive and an advective hyporheic exchange model were developed and evaluated versus independent observations in the stream water and hyporheic zone. Analytical expressions for the central temporal moments of the breakthrough curve and semi-analytical solutions for the solute concentration in the Laplace domain were derived. Both models were found useful in representing the observations. For the transport of the reactive solute, it was found essential to consider a kinetic sorption on to particulate matter in the hyporheic zone. The time needed for a wash-out of 75% of the maximum uptake in the hyporheic zone was found to be ~85 times longer for the reactive solute, compared to the conservative solute. Neglecting the sorption kinetics in the transport model yielded significant errors in the central tempo

Understanding of the processes affecting solute transport in flowing water is important for the possibility to predict the evolution with time of polluted stream systems. This thesis presents tracer experiment methodology and model developments for solute transport in streams, with special focus on retention processes and their effect on solute stream transport. Results are presented from a tracer experiment in the Säva Stream, Uppland County, Sweden, where both a conservative (3H as tritiated water) and a reactive (51Cr as trivalent chromium ion) tracer were injected simultaneously. The time and length scales of the experiment were prolonged compared to previous studies, which allowed for new critical tests of different model concepts. It was found that the hyporheic exchange greatly affected the solute transport of both tracers. However, the retention of chromium was significantly more pronounced. About 76% of the injected chromium was lost from the stream water phase directly after the passage of the pulse 30 km downstream of the injection point. The inventory of chromium in the sediments indicated that the main part was retrieved in the hyporheic zone. Both a diffusive and an advective hyporheic exchange model were developed and evaluated versus independent observations in the stream water and hyporheic zone. Analytical expressions for the central temporal moments of the breakthrough curve and semi-analytical solutions for the solute concentration in the Laplace domain were derived. Both models were found useful in representing the observations. For the transport of the reactive solute, it was found essential to consider a kinetic sorption on to particulate matter in the hyporheic zone. The time needed for a wash-out of 75% of the maximum uptake in the hyporheic zone was found to be ~85 times longer for the reactive solute, compared to the conservative solute. Neglecting the sorption kinetics in the transport model yielded significant errors in the central tempo

Understanding of the processes affecting solute transport in flowing water is important for the possibility to predict the evolution with time of polluted stream systems. This thesis presents tracer experiment methodology and model developments for solute transport in streams, with special focus on retention processes and their effect on solute stream transport. Results are presented from a tracer experiment in the Säva Stream, Uppland County, Sweden, where both a conservative (3H as tritiated water) and a reactive (51Cr as trivalent chromium ion) tracer were injected simultaneously. The time and length scales of the experiment were prolonged compared to previous studies, which allowed for new critical tests of different model concepts. It was found that the hyporheic exchange greatly affected the solute transport of both tracers. However, the retention of chromium was significantly more pronounced. About 76% of the injected chromium was lost from the stream water phase directly after the passage of the pulse 30 km downstream of the injection point. The inventory of chromium in the sediments indicated that the main part was retrieved in the hyporheic zone. Both a diffusive and an advective hyporheic exchange model were developed and evaluated versus independent observations in the stream water and hyporheic zone. Analytical expressions for the central temporal moments of the breakthrough curve and semi-analytical solutions for the solute concentration in the Laplace domain were derived. Both models were found useful in representing the observations. For the transport of the reactive solute, it was found essential to consider a kinetic sorption on to particulate matter in the hyporheic zone. The time needed for a wash-out of 75% of the maximum uptake in the hyporheic zone was found to be ~85 times longer for the reactive solute, compared to the conservative solute. Neglecting the sorption kinetics in the transport model yielded significant errors in the central tempo

Understanding of the processes affecting solute transport in flowing water is important for the possibility to predict the evolution with time of polluted stream systems. This thesis presents tracer experiment methodology and model developments for solute transport in streams, with special focus on retention processes and their effect on solute stream transport. Results are presented from a tracer experiment in the Säva Stream, Uppland County, Sweden, where both a conservative (3H as tritiated water) and a reactive (51Cr as trivalent chromium ion) tracer were injected simultaneously. The time and length scales of the experiment were prolonged compared to previous studies, which allowed for new critical tests of different model concepts. It was found that the hyporheic exchange greatly affected the solute transport of both tracers. However, the retention of chromium was significantly more pronounced. About 76% of the injected chromium was lost from the stream water phase directly after the passage of the pulse 30 km downstream of the injection point. The inventory of chromium in the sediments indicated that the main part was retrieved in the hyporheic zone. Both a diffusive and an advective hyporheic exchange model were developed and evaluated versus independent observations in the stream water and hyporheic zone. Analytical expressions for the central temporal moments of the breakthrough curve and semi-analytical solutions for the solute concentration in the Laplace domain were derived. Both models were found useful in representing the observations. For the transport of the reactive solute, it was found essential to consider a kinetic sorption on to particulate matter in the hyporheic zone. The time needed for a wash-out of 75% of the maximum uptake in the hyporheic zone was found to be ~85 times longer for the reactive solute, compared to the conservative solute. Neglecting the sorption kinetics in the transport model yielded significant errors in the central tempo

The effective transport velocity of solutes in rivers and streams is governed by transient storage in hyporheic zones in which the longitudinal advection velocity is small relative to the main stream flow velocity. Results from a simultaneous tracer experiment using a non-reactive (tritium, (H2O)-H-3) and a sorptive tracer [chromium, Cr-51(III)] have formed the basis of a more accurate interpretation of the retention characteristics of solutes in streams than previously has been possible. By using a simultaneous injection of these two tracers, it was possible to distinguish between their different behaviours. Based on estimations of fluxes, the retained mass of chromium in the storage zones along the 30-km-long study-reach was 76% after 150 h. Independent observations in the bed sediment indicated that the loss of chromium observed in the water was mainly a result of uptake into the bed sediment. To describe the transport in the stream, a model concept including solute sorption kinetics in the bed sediment was proposed. Evaluation of parameters in the model, indicated that the uptake of chromium in the bed sediment is controlled by sorption kinetics., QC 20100525