Search

Metallic glasses (MGs) with their intrinsic disordered atomic structure and widely controllable atomic components have recently emerged as fascinating functional materials in wastewater treatment. Compared to crystalline alloys, the less-noble atomic components in monolithic metallic glass are more efficient to be selectively dissolved during dealloying process. This work reported a facile chemical dealloying approach to fabricate a void channels-like structured MG with the elemental components of Fe73.5Si13.5B9Cu1Nb3 for methylene blue (MB) degradation. Results indicated that the dealloyed Fe73.5Si13.5B9Cu1Nb3 MGs with the void channels-like morphology presented a significant improvement of catalytic efficiency and reusability. The dye degradation reaction rate (kobs) of the dealloyed Fe73.5Si13.5B9Cu1Nb3 MGs presented 3 times higher than their as-spun MGs. More importantly, the dealloyed Fe73.5Si13.5B9Cu1Nb3 MGs can be reused up to 25 times without significantly loosing catalytic efficiency. It was also found that the dealloyed Fe73.5Si13.5B9Cu1Nb3 MGs exhibited a greater corrosion resistance in the simulated dye solution compared to the as-spun ribbons, demonstrating a robust self-healing ability in catalytic activity. This work provides a novel view for designing MG catalysts with high efficiency and stability in worldwide energy and environmental concerns.

Metallic glasses (MGs) with their intrinsic disordered atomic structure and widely controllable atomic components have recently emerged as fascinating functional materials in wastewater treatment. Compared to crystalline alloys, the less-noble atomic components in monolithic metallic glass are more efficient to be selectively dissolved during dealloying process. This work reported a facile chemical dealloying approach to fabricate a void channels-like structured MG with the elemental components of Fe73.5Si13.5B9Cu1Nb3 for methylene blue (MB) degradation. Results indicated that the dealloyed Fe73.5Si13.5B9Cu1Nb3 MGs with the void channels-like morphology presented a significant improvement of catalytic efficiency and reusability. The dye degradation reaction rate (kobs) of the dealloyed Fe73.5Si13.5B9Cu1Nb3 MGs presented 3 times higher than their as-spun MGs. More importantly, the dealloyed Fe73.5Si13.5B9Cu1Nb3 MGs can be reused up to 25 times without significantly loosing catalytic efficiency. It was also found that the dealloyed Fe73.5Si13.5B9Cu1Nb3 MGs exhibited a greater corrosion resistance in the simulated dye solution compared to the as-spun ribbons, demonstrating a robust self-healing ability in catalytic activity. This work provides a novel view for designing MG catalysts with high efficiency and stability in worldwide energy and environmental concerns.

The e-business arena is a dynamic, complex and demanding environment. It is essential to make optimal reuse of knowledge of customer services across various functional units of the enterprise. On the other hand, it is also important to ensure that the customer service staff can access and be trained up with dynamically updated knowledge that meets the changing business environment of an enterprise in customer services. However, conventional way of customer service management (CSM) is inadequate to achieve the multi-perspective of an enterprise for achieving knowledge acquisition, knowledge diffusion, business automation and business performance measurement so as to drive the continuous improvement of the customer service quality. In this paper, a multi-perspective knowledge-based system (MPKBS) is proposed for CSM. The MPKBS incorporates various artificial intelligence technologies such as case-based reasoning (CBR) and adaptive time-series model which are used for decision analysis, performance measurement and monitoring. A prototype customer service portal has been built based on the MPKBS and implemented successfully in a consultancy business.

The e-business arena is a dynamic, complex and demanding environment. It is essential to make optimal reuse of knowledge of customer services across various functional units of the enterprise. On the other hand, it is also important to ensure that the customer service staff can access and be trained up with dynamically updated knowledge that meets the changing business environment of an enterprise in customer services. However, conventional way of customer service management (CSM) is inadequate to achieve the multi-perspective of an enterprise for achieving knowledge acquisition, knowledge diffusion, business automation and business performance measurement so as to drive the continuous improvement of the customer service quality. In this paper, a multi-perspective knowledge-based system (MPKBS) is proposed for CSM. The MPKBS incorporates various artificial intelligence technologies such as case-based reasoning (CBR) and adaptive time-series model which are used for decision analysis, performance measurement and monitoring. A prototype customer service portal has been built based on the MPKBS and implemented successfully in a consultancy business.

The e-business arena is a dynamic, complex and demanding environment. It is essential to make optimal reuse of knowledge of customer services across various functional units of the enterprise. On the other hand, it is also important to ensure that the customer service staff can access and be trained up with dynamically updated knowledge that meets the changing business environment of an enterprise in customer services. However, conventional way of customer service management (CSM) is inadequate to achieve the multi-perspective of an enterprise for achieving knowledge acquisition, knowledge diffusion, business automation and business performance measurement so as to drive the continuous improvement of the customer service quality. In this paper, a multi-perspective knowledge-based system (MPKBS) is proposed for CSM. The MPKBS incorporates various artificial intelligence technologies such as case-based reasoning (CBR) and adaptive time-series model which are used for decision analysis, performance measurement and monitoring. A prototype customer service portal has been built based on the MPKBS and implemented successfully in a consultancy business.

Civil Engineering and Geosciences

Civil Engineering and Geosciences

This is an Author's Accepted Manuscript of: Wang, J. C., Liang, S. X., Jia, Z., Zhang, W. C., Wang, W. M., Liu, Y. J., . . . Zhang, L. C. (2019). Chemically dealloyed fe-based metallic glass with void channels-like architecture for highly enhanced peroxymonosulfate activation in catalysis. Journal of Alloys and Compounds, 785, 642-650. Available here © 2019. This manuscript version is made Available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0