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9. Microporous chiral metal coordination polymers: hydrothermal synthesis, channel engineering and stability of lanthanide tartrates

Author

Thushari, S., Cha, JAK, Sung, HHY, Chui, SSY, Leung, ALF, Yen, YF, Williams, ID, Thushari, S., Cha, JAK, Sung, HHY, Chui, SSY, Leung, ALF, Yen, YF, and Williams, ID

Abstract

L-Tartrate ions can endure hydrothermal conditions up to 160 degrees C to form the robust, enantiopure open-framework coordination polymers [Ln(2)(L-TAR)(3)(H2O)(2)](3)H2O, 1; the addition of succinate results in formation of the related [Ln(2)(L-TAR)(2)(SUC)(H2O)(2)]5.5H(2)O, 2 with larger channels than 1, whereas racemic D/L-tartrate gives the more condensed [Ln(2)(D/L-TAR)(3)(H2O)(2)],3. TAR = [C4H4O6](2-).

Published
2005

11. Microporous chiral metal coordination polymers: hydrothermal synthesis, channel engineering and stability of lanthanide tartrates

Author

Thushari, S., Cha, JAK, Sung, HHY, Chui, SSY, Leung, ALF, Yen, YF, Williams, ID, Thushari, S., Cha, JAK, Sung, HHY, Chui, SSY, Leung, ALF, Yen, YF, and Williams, ID

Abstract

L-Tartrate ions can endure hydrothermal conditions up to 160 degrees C to form the robust, enantiopure open-framework coordination polymers [Ln(2)(L-TAR)(3)(H2O)(2)](3)H2O, 1; the addition of succinate results in formation of the related [Ln(2)(L-TAR)(2)(SUC)(H2O)(2)]5.5H(2)O, 2 with larger channels than 1, whereas racemic D/L-tartrate gives the more condensed [Ln(2)(D/L-TAR)(3)(H2O)(2)],3. TAR = [C4H4O6](2-).

Published
2005

12. Microporous chiral metal coordination polymers: hydrothermal synthesis, channel engineering and stability of lanthanide tartrates

Author

Thushari, S., Cha, JAK, Sung, HHY, Chui, SSY, Leung, ALF, Yen, YF, Williams, ID, Thushari, S., Cha, JAK, Sung, HHY, Chui, SSY, Leung, ALF, Yen, YF, and Williams, ID

Abstract

L-Tartrate ions can endure hydrothermal conditions up to 160 degrees C to form the robust, enantiopure open-framework coordination polymers [Ln(2)(L-TAR)(3)(H2O)(2)](3)H2O, 1; the addition of succinate results in formation of the related [Ln(2)(L-TAR)(2)(SUC)(H2O)(2)]5.5H(2)O, 2 with larger channels than 1, whereas racemic D/L-tartrate gives the more condensed [Ln(2)(D/L-TAR)(3)(H2O)(2)],3. TAR = [C4H4O6](2-).

Published
2005

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