1. Recycling process and proto-kimberlite melt metasomatism in the lithosphere-asthenosphere boundary beneath the Amazonian Craton recorded by garnet xenocrysts and mantle xenoliths from the Carolina kimberlite
- Author
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Gervasoni, Fernanda, Jalowitzki, Tiago, Rocha, Marcelo Peres, Weska, Ricardo Kalikowski, Novais-Rodrigues, Eduardo, de Freitas Rodrigues, Rodrigo Antonio, Bussweiler, Yannick, Rocha Barbosa, Elisa Soares, Berndt, Jasper, Dantas, Elton Luiz, Souza, Valmir da Silva, Klemme, Stephan, Gervasoni, Fernanda, Jalowitzki, Tiago, Rocha, Marcelo Peres, Weska, Ricardo Kalikowski, Novais-Rodrigues, Eduardo, de Freitas Rodrigues, Rodrigo Antonio, Bussweiler, Yannick, Rocha Barbosa, Elisa Soares, Berndt, Jasper, Dantas, Elton Luiz, Souza, Valmir da Silva, and Klemme, Stephan
- Abstract
Here we present new data on the major and trace element compositions of silicate and oxide minerals from mantle xenoliths brought to the surface by the Carolina kimberlite, Pimenta Bueno Kimberlitic Field, which is located on the southwestern border of the Amazonian Craton. We also present Sr-Nd isotopic data of garnet xenocrysts and whole-rocks from the Carolina kimberlite. Mantle xenoliths are mainly clinopyroxenites and garnetites. Some of the clinopyroxenites were classified as GPP-PP-PKP (garnet-phlogopite peridotite, phlogopite-peridotite, phlogopite-K-richterite peridotite) suites, and two clinopyroxenites (eclogites) and two garnetites are relicts of an ancient subducted slab. Temperature and pressure estimates yield 855-1102 degrees C and 3.6-7.0 GPa, respectively. Clinopyroxenes are enriched in light rare earth elements (LREE) (La-N/Yb-N = 5-62; Ce-N/Sm-N = 1-3; where N = primitive mantle normalized values), they have high Ca/Al ratios (10-410), low to medium Ti/Eu ratios (742-2840), and low Zr/Hf ratios (13-26), which suggest they were formed by metasomatic reactions with CO2-rich silicate melts. Phlogopite with high TiO2 (>2.0 wt.%), Al2O3 (>12.0 wt.%), and FeOt (5.0-13.0 wt.%) resemble those found in the groundmass of kimberlites, lamproites and lamprophyres. Conversely, phlogopite with low TiO2 (<1.0 wt.%) and lower Al2O3 (<12.0 wt.%) are similar to those present in GPP-PP-PKP, and in MARID (mica-amphibole-rutile-ilmenite-diopside) and PIC (phlogopite-ilmenite-clinopyorxene) xenoliths. The GPP-PP-PKP suite of xenoliths, together with the clinopyroxene and phlogopite major and trace element signatures suggests that an intense proto-kimberlite melt metasomatism occurred in the deep cratonic lithosphere beneath the Amazonian Craton. The Sr-Nd isotopic ratios of pyrope xenocrysts (G3, G9 and G11) from the Carolina kimberlite are characterized by high Nd-143/Nd-144 (0.51287-0.51371) and epsilon Nd (+4.55 to +20.85) accompanied with enriched Sr-87/Sr-86 (0.7
- Published
- 2022