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Measurements by the Dobson ozone spectrophotometer at the British Antarctic Survey's (BAS) Halley research station form a record of Antarctic total column ozone that dates back to 1956. Due to its location, length, and completeness, the record has been, and continues to be, uniquely important for studies of long-term changes in Antarctic ozone. However, a crack in the ice shelf on which it resides forced the station to abruptly close in February of 2017, leading to a gap of two ozone hole seasons in its historic record. We develop and test a method for filling in the record of Halley total ozone by combining and adjusting overpass data from a range of different satellite instruments. Comparisons to the Dobson suggest that our method reproduces monthly ground-based total ozone values with an average difference of 1.1 ± 6.2 DU for the satellites used to fill in the 2017–2018 gap. We show that our approach more closely reproduces the Dobson measurements than simply using the raw satellite average or data from a single satellite instrument. The method also provides a check on the consistency of the provisional data from the automated Dobson used at Halley after 2018 with earlier manual Dobson data and suggests that there were likely inconsistencies between the two. The filled Halley dataset provides further support that the Antarctic ozone hole is healing, not only during September but also in January.

Measurements by the Dobson ozone spectrophotometer at the British Antarctic Survey's (BAS) Halley research station form a record of Antarctic total column ozone that dates back to 1956. Due to its location, length, and completeness, the record has been, and continues to be, uniquely important for studies of long-term changes in Antarctic ozone. However, a crack in the ice shelf on which it resides forced the station to abruptly close in February of 2017, leading to a gap of two ozone hole seasons in its historic record. We develop and test a method for filling in the record of Halley total ozone by combining and adjusting overpass data from a range of different satellite instruments. Comparisons to the Dobson suggest that our method reproduces monthly ground-based total ozone values with an average difference of 1.1 ± 6.2 DU for the satellites used to fill in the 2017–2018 gap. We show that our approach more closely reproduces the Dobson measurements than simply using the raw satellite average or data from a single satellite instrument. The method also provides a check on the consistency of the provisional data from the automated Dobson used at Halley after 2018 with earlier manual Dobson data and suggests that there were likely inconsistencies between the two. The filled Halley dataset provides further support that the Antarctic ozone hole is healing, not only during September but also in January.

Abstract. Measurements by the Dobson ozone spectrophotometer at the British Antarctic Survey's (BAS) Halley research station form a record of Antarctic total column ozone that dates back to 1956. Due to its location, length, and completeness, the record has been, and continues to be, uniquely important for studies of long-term changes in Antarctic ozone. However, a crack in the ice shelf on which it resides forced the station to abruptly close in February of 2017, leading to a gap of two ozone hole seasons in its historic record. We develop and test a method for filling in the record of Halley total ozone by combining and adjusting overpass data from a range of different satellite instruments. Comparisons to the Dobson suggest that our method reproduces monthly ground-based total ozone values with an average difference of 1.1 ± 6.2 DU for the satellites used to fill in the 2017–2018 gap. We show that our approach more closely reproduces the Dobson measurements than simply using the raw satellite average or data from a single satellite instrument. The method also provides a check on the consistency of the provisional data from the automated Dobson used at Halley after 2018 with earlier manual Dobson data and suggests that there were likely inconsistencies between the two. The filled Halley dataset provides further support that the Antarctic ozone hole is healing, not only during September but also in January.

This paper reports on consolidated ground-based validation results of the atmospheric NO2 data produced operationally since April 2018 by the TROPOspheric Monitoring Instrument (TROPOMI) on board of the ESA/EU Copernicus Sentinel-5 Precursor (S5P) satellite. Tropospheric, stratospheric, and total NO2 column data from S5P are compared to correlative measurements collected from, respectively, 19 Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS), 26 Network for the Detection of Atmospheric Composition Change (NDACC) Zenith-Scattered-Light DOAS (ZSL-DOAS), and 25 Pandonia Global Network (PGN)/Pandora instruments distributed globally. The validation methodology gives special care to minimizing mismatch errors due to imperfect spatiotemporal co-location of the satellite and correlative data, e.g. by using tailored observation operators to account for differences in smoothing and in sampling of atmospheric structures and variability and photochemical modelling to reduce diurnal cycle effects. Compared to the ground-based measurements, S5P data show, on average, (i) a negative bias for the tropospheric column data, of typically-23 % to-37 % in clean to slightly polluted conditions but reaching values as high as-51 % over highly polluted areas; (ii) a slight negative median difference for the stratospheric column data, of about-0:2 Pmolec cm-2, i.e. approx.-2 % in summer to-15 % in winter; and (iii) a bias ranging from zero to-50 % for the total column data, found to depend on the amplitude of the total NO2 column, with small to slightly positive bias values for columns below 6 Pmolec cm-2 and negative values above. The dispersion between S5P and correlative measurements contains mostly random components, which remain within mission requirements for the stratospheric column data (0.5 Pmolec cm-2) but exceed those for the tropospheric column data (0.7 Pmolec cm-2). While a part of the biases and dispersion may be due to representativeness differences such as

A three-dimensional global ozone distribution has been derived from assimilation of ozone profiles that were observed by satellites. By simultaneous assimilation of ozone profiles retrieved from the nadir looking satellite instruments Global Ozone Monitoring Experiment 2 (GOME-2) and Ozone Monitoring Instrument (OMI), which measure the atmosphere at different times of the day, the quality of the derived atmospheric ozone field has been improved. The assimilation is using an extended Kalman filter in which chemical transport model TM5 has been used for the forecast. The combined assimilation of both GOME-2 and OMI improves upon the assimilation results of a single sensor. The new assimilation system has been demonstrated by processing 4 years of data from 2008 to 2011. Validation of the assimilation output by comparison with sondes shows that biases vary between ĝ'5 and +10ĝ€̄% between the surface and 100ĝ€̄hPa. The biases for the combined assimilation vary between ĝ'3 and +3ĝ€̄% in the region between 100 and 10ĝ€̄hPa where GOME-2 and OMI are most sensitive. This is a strong improvement compared to direct retrievals of ozone profiles from satellite observations.

A three-dimensional global ozone distribution has been derived from assimilation of ozone profiles that were observed by satellites. By simultaneous assimilation of ozone profiles retrieved from the nadir looking satellite instruments Global Ozone Monitoring Experiment 2 (GOME-2) and Ozone Monitoring Instrument (OMI), which measure the atmosphere at different times of the day, the quality of the derived atmospheric ozone field has been improved. The assimilation is using an extended Kalman filter in which chemical transport model TM5 has been used for the forecast. The combined assimilation of both GOME-2 and OMI improves upon the assimilation results of a single sensor. The new assimilation system has been demonstrated by processing 4 years of data from 2008 to 2011. Validation of the assimilation output by comparison with sondes shows that biases vary between ĝ'5 and +10ĝ€̄% between the surface and 100ĝ€̄hPa. The biases for the combined assimilation vary between ĝ'3 and +3ĝ€̄% in the region between 100 and 10ĝ€̄hPa where GOME-2 and OMI are most sensitive. This is a strong improvement compared to direct retrievals of ozone profiles from satellite observations.

This overview paper highlights the successes of the Ozone Monitoring Instrument (OMI) on board the Aura satellite spanning a period of nearly 14 years. Data from OMI has been used in a wide range of applications and research resulting in many new findings. Due to its unprecedented spatial resolution, in combination with daily global coverage, OMI plays a unique role in measuring trace gases important for the ozone layer, air quality, and climate change. With the operational very fast delivery (VFD; direct readout) and near real-time (NRT) availability of the data, OMI also plays an important role in the development of operational services in the atmospheric chemistry domain.

The Ozone Monitoring Instrument (OMI) onboard NASA's Aura satellite has been providing global observations of the ozone layer and key atmospheric pollutant gases, such as nitrogen dioxide (NO2) and sulfur dioxide (SO2), since October 2004. The data products from the same instrument provide consistent spatial and temporal coverage and permit the study of anthropogenic and natural emissions on local-to-global scales. In this paper, we examine changes in SO2 and NO2 over some of the world's most polluted industrialized regions during the first decade of OMI observations. In terms of regional pollution changes, we see both upward and downward trends, sometimes in opposite directions for NO2 and SO2, for different study areas. The trends are, for the most part, associated with economic and/or technological changes in energy use, as well as regional regulatory policies. Over the eastern US, both NO2 and SO2 levels decreased dramatically from 2005 to 2015, by more than 40 and 80ĝ€%, respectively, as a result of both technological improvements and stricter regulations of emissions. OMI confirmed large reductions in SO2 over eastern Europe's largest coal-fired power plants after installation of flue gas desulfurization devices. The North China Plain has the world's most severe SO2 pollution, but a decreasing trend has been observed since 2011, with about a 50ĝ€% reduction in 2012–2015, due to an economic slowdown and government efforts to restrain emissions from the power and industrial sectors. In contrast, India's SO2 and NO2 levels from coal power plants and smelters are growing at a fast pace, increasing by more than 100 and 50ĝ€%, respectively, from 2005 to 2015. Several SO2 hot spots observed over the Persian Gulf are probably related to oil and gas operations and indicate a possible underestimation of emissions from these sources in bottom-up emission inventories. Overall, OMI observations have proved valuable in documenting rapid changes in air quality over dif

Chemical ozone destruction occurs over both polar regions in local winter–spring. In the Antarctic, essentially complete removal of lower-stratospheric ozone currently results in an ozone hole every year, whereas in the Arctic, ozone loss is highly variable and has until now been much more limited. Here we demonstrate that chemical ozone destruction over the Arctic in early 2011 was—for the first time in the observational record—comparable to that in the Antarctic ozone hole. Unusually long-lasting cold conditions in the Arctic lower stratosphere led to persistent enhancement in ozone-destroying forms of chlorine and to unprecedented ozone loss, which exceeded 80 per cent over 18–20 kilometres altitude. Our results show that Arctic ozone holes are possible even with temperatures much milder than those in the Antarctic. We cannot at present predict when such severe Arctic ozone depletion may be matched or exceeded.

Chemical ozone destruction occurs over both polar regions in local winter–spring. In the Antarctic, essentially complete removal of lower-stratospheric ozone currently results in an ozone hole every year, whereas in the Arctic, ozone loss is highly variable and has until now been much more limited. Here we demonstrate that chemical ozone destruction over the Arctic in early 2011 was—for the first time in the observational record—comparable to that in the Antarctic ozone hole. Unusually long-lasting cold conditions in the Arctic lower stratosphere led to persistent enhancement in ozone-destroying forms of chlorine and to unprecedented ozone loss, which exceeded 80 per cent over 18–20 kilometres altitude. Our results show that Arctic ozone holes are possible even with temperatures much milder than those in the Antarctic. We cannot at present predict when such severe Arctic ozone depletion may be matched or exceeded.