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The origin of the chemical diversity observed around low-mass protostars probably resides in the earliest history of these systems. We aim to investigate the impact of protostellar feedback on the chemistry and grain growth in the circumstellar medium of multiple stellar systems. In the context of the ALMA Large Program FAUST, we present high-resolution (50 au) observations of CH$_3$OH, H$_2$CO, and SiO and continuum emission at 1.3 mm and 3 mm towards the Corona Australis star cluster. Methanol emission reveals an arc-like structure at $\sim$1800 au from the protostellar system IRS7B along the direction perpendicular to the major axis of the disc. The arc is located at the edge of two elongated continuum structures that define a cone emerging from IRS7B. The region inside the cone is probed by H$_2$CO, while the eastern wall of the arc shows bright emission in SiO, a typical shock tracer. Taking into account the association with a previously detected radio jet imaged with JVLA at 6 cm, the molecular arc reveals for the first time a bow shock driven by IRS7B and a two-sided dust cavity opened by the mass-loss process. For each cavity wall, we derive an average H$_2$ column density of $\sim$7$\times$10$^{21}$ cm$^{-2}$, a mass of $\sim$9$\times$10$^{-3}$ M$_\odot$, and a lower limit on the dust spectral index of $1.4$. These observations provide the first evidence of a shock and a conical dust cavity opened by the jet driven by IRS7B, with important implications for the chemical enrichment and grain growth in the envelope of Solar System analogues., Comment: 12 pages, 8 figures, 3 tables. Accepted Letter in Astronomy & Astrophysics

The ALMA interferometer has played a key role in revealing a new component of the Sun-like star forming process: the molecular streamers, i.e. structures up to thousands of au long funneling material non-axisymmetrically to disks. In the context of the FAUST ALMA LP, the archetypical VLA1623-2417 protostellar cluster has been imaged at 1.3 mm in the SO(5$_6$--4$_5$), SO(6$_6$--5$_5$), and SiO(5--4) line emission at the spatial resolution of 50 au. We detect extended SO emission, peaking towards the A and B protostars. Emission blue-shifted down to 6.6 km s$^{-1}$ reveals for the first time a long ($\sim$ 2000 au) accelerating streamer plausibly feeding the VLA1623 B protostar. Using SO, we derive for the first time an estimate of the excitation temperature of an accreting streamer: 33$\pm$9 K. The SO column density is $\sim$ 10$^{14}$ cm$^{-2}$, and the SO/H$_2$ abundance ratio is $\sim$ 10$^{-8}$. The total mass of the streamer is 3 $\times$ 10$^{-3}$ $Msun$, while its accretion rate is 3--5 $\times$ 10$^{-7}$ Msun yr$^{-1}$. This is close to the mass accretion rate of VLA1623 B, in the 0.6--3 $\times$ 10$^{-7}$ Msun yr$^{-1}$ range, showing the importance of the streamer in contributing to the mass of protostellar disks. The highest blue- and red-shifted SO velocities behave as the SiO(5--4) emission, the latter species detected for the first time in VLA1623-2417: the emission is compact (100-200 au), and associated only with the B protostar. The SO excitation temperature is $\sim$ 100 K, supporting the occurrence of shocks associated with the jet, traced by SiO., Comment: accepted by MNRAS

More than 50 per cent of solar-mass stars form in multiple systems. It is therefore crucial to investigate how multiplicity affects the star and planet formation processes at the protostellar stage. We report continuum and C18O (2–1) observations of the VLA 1623–2417 protostellar system at 50 au angular resolution as part of the ALMA (Atacama Large Millimeter/submillimeter Array) Large Program FAUST. The 1.3 mm continuum probes the discs of VLA 1623A, B, and W, and the circumbinary disc of the A1 + A2 binary. The C18O emission reveals, for the first time, the gas in the disc envelope of VLA 1623W. We estimate the dynamical mass of VLA 1623W, Mdyn = 0.45 ± 0.08 M⊙, and the mass of its disc, Mdisc ∼ 6 × 10−3 M⊙. C18O also reveals streamers that extend up to 1000 au, spatially and kinematically connecting the envelope and outflow cavities of the A1 + A2 + B system with the disc of VLA 1623W. The presence of the streamers, as well as the spatial (∼1300 au) and velocity (∼2.2 km s−1) offsets of VLA 1623W, suggests that either sources W and A + B formed in different cores, interacting between them, or source W has been ejected from the VLA 1623 multiple system during its formation. In the latter case, the streamers may funnel material from the envelope and cavities of VLA 1623AB on to VLA 1623W, thus concurring to set its final mass and chemical content.

Context. Deuterium in H-bearing species is enhanced during the early stages of star formation, however, only a small number of high spatial resolution deuteration studies exist towards protostellar objects, leaving the small-scale structures unrevealed and understudied. Aims. We aim to constrain the deuterium fractionation ratios in a Class 0/I protostellar object in formaldehyde (H2CO), which has abundant deuterated isotopologues in this environment. Methods. We observed the Class 0/I protobinary system [BHB2007] 11, whose emission components are embedded in circumstellar disks that have radii of 2-3 au, using ALMA within the context of the Large Program FAUST. The system is surrounded by a complex filamentary structure connecting to the larger circumbinary disk. In this work we present the first study of formaldehyde D-fractionation towards this source with detections of H2CO 3(0,3)-2(0,2), combined with HDCO 4(2,2)-3(2,1), HDCO 4(1,4)-3(1,3) and D2CO 4(0,4)-3(0,3). These observations enable multiple velocity components associated with the methanol hotspots also uncovered by FAUST data, as well as the external envelope, to be resolved. In addition, based on the kinematics seen in the observations of the H2CO emission, we propose the presence of a second large scale outflow. Results. HDCO and D2CO are only found in the central regions of the core while H2CO is found more ubiquitously. From radiative transfer modelling, the column densities ranges found for H2CO, HDCO and D2CO are (3-8)x10$^{14}$ cm$^{-2}$, (0.8-2.9)x10$^{13}$ cm$^{-2}$ and (2.6-4.3)x10$^{12}$ cm$^{-2}$, respectively, yielding an average D/H ratio of 0.01-0.04. Following the results of kinematic modelling, the second large scale feature is inconsistent with a streamer-like nature and we thus tentatively conclude that the feature is an asymmetric molecular outflow launched by a wide-angle disk wind., Comment: 17 pages, 15 figures

ALMA-IMF is an Atacama Large Millimeter/submillimeter Array (ALMA) Large Program designed to measure the core mass function (CMF) of 15 protoclusters chosen to span their early evolutionary stages. It further aims to understand their kinematics, chemistry, and the impact of gas inflow, accretion, and dynamics on the CMF. We present here the first release of the ALMA-IMF line data cubes (DR1), produced from the combination of two ALMA 12m-array configurations. The data include 12 spectral windows, with eight at 1.3mm and four at 3mm. The broad spectral coverage of ALMA-IMF (~6.7 GHz bandwidth coverage per field) hosts a wealth of simple atomic, molecular, ionised, and complex organic molecular lines. We describe the line cube calibration done by ALMA and the subsequent calibration and imaging we performed. We discuss our choice of calibration parameters and optimisation of the cleaning parameters, and we demonstrate the utility and necessity of additional processing compared to the ALMA archive pipeline. As a demonstration of the scientific potential of these data, we present a first analysis of the DCN (3-2) line. We find that DCN traces a diversity of morphologies and complex velocity structures, which tend to be more filamentary and widespread in evolved regions and are more compact in the young and intermediate-stage protoclusters. Furthermore, we used the DCN (3-2) emission as a tracer of the gas associated with 595 continuum cores across the 15 protoclusters, providing the first estimates of the core systemic velocities and linewidths within the sample. We find that DCN (3-2) is detected towards a higher percentage of cores in evolved regions than the young and intermediate-stage protoclusters and is likely a more complete tracer of the core population in more evolved protoclusters. The full ALMA 12m-array cubes for the ALMA-IMF Large Program are provided with this DR1 release., Comment: 75 pages (21 main body; 54 appendix), 37 figures. The ALMA-IMF DR1 line release is hosted at https://dataverse.harvard.edu/dataverse/alma-imf

We report ALMA high-angular resolution (~ 50 au) observations of the binary system SVS13-A. More specifically, we analyse deuterated water (HDO) and sulfur dioxide (SO2) emission. The molecular emission is associated with both the components of the binary system, VLA4A and VLA4B. The spatial distribution is compared to that of formamide (NH2CHO), previously analysed in the system. Deuterated water reveals an additional emitting component spatially coincident with the dust accretion streamer, at a distance larger than 120 au from the protostars, and at blue-shifted velocities (> 3 km/s from the systemic velocities). We investigate the origin of the molecular emission in the streamer, in light of thermal sublimation temperatures calculated using updated binding energies (BE) distributions. We propose that the observed emission is produced by an accretion shock at the interface between the accretion streamer and the disk of VLA4A. Thermal desorption is not completely excluded in case the source is actively experiencing an accretion burst., Comment: Accepted for publication in Faraday Discussions 2023

More than 50% of solar-mass stars form in multiple systems. It is therefore crucial to investigate how multiplicity affects the star and planet formation processes at the protostellar stage. We report continuum and C$^{18}$O (2-1) observations of the VLA 1623-2417 protostellar system at 50 au angular resolution as part of the ALMA Large Program FAUST. The 1.3 mm continuum probes the disks of VLA 1623A, B, and W, and the circumbinary disk of the A1+A2 binary. The C$^{18}$O emission reveals, for the first time, the gas in the disk-envelope of VLA 1623W. We estimate the dynamical mass of VLA 1623W, $M_{\rm dyn}=0.45\pm0.08$ M$_{\odot}$, and the mass of its disk, $M_{\rm disk}\sim6\times10^{-3}$ M$_{\odot}$. C$^{18}$O also reveals streamers that extend up to 1000 au, spatially and kinematically connecting the envelope and outflow cavities of the A1+A2+B system with the disk of VLA 1623W. The presence of the streamers, as well as the spatial ($\sim$1300 au) and velocity ($\sim$2.2 km/s) offset of VLA 1623W suggest that either sources W and A+B formed in different cores, interacting between them, or that source W has been ejected from the VLA 1623 multiple system during its formation. In the latter case, the streamers may funnel material from the envelope and cavities of VLA 1623AB onto VLA 1623W, thus concurring to set its final mass and chemical content., Comment: 10 pages, 5 figures, accepted by MNRAS

The study of the early phases of star and planet formation is important to understand the physical and chemical history of stellar systems such as our own. In particular, protostars born in rich clusters are prototypes of the young Solar System. In the framework of the Seeds Of Life In Space (SOLIS) large observational project, the aim of the present work is to investigate the origin of the previously inferred high flux of energetic particles in the protocluster FIR4 of the Orion Molecular Cloud 2 (OMC-2), which appears asymmetric within the protocluster itself. Interferometric observations carried out with the IRAM NOEMA interferometer were used to map the silicon monoxide (SiO) emission around the FIR4 protocluster. Complementary archival data from the ALMA interferometer were also employed to help constrain excitation conditions. A physical-chemical model was implemented to characterise the particle acceleration along the protostellar jet candidate, along with a non-LTE analysis of the SiO emission along the jet. The emission morphology of the SiO rotational transitions hints for the first time at the presence of a collimated jet originating very close to the brightest protostar in the cluster, HOPS-108. The NOEMA observations unveiled a possible jet in the OMC-2 FIR4 protocluster propagating towards a previously measured enhanced cosmic-ray ionisation rate. This suggests that energetic particle acceleration by the jet shock close to the protostar might be at the origin of the enhanced cosmic-ray ionisation rate, as confirmed by modelling the protostellar jet., Comment: 8 pages, 7 figures, accepted for publications in A&A

The ALMA-IMF Large Program observed the W43-MM2-MM3 ridge, whose 1.3mm and 3mm ALMA 12m array continuum images reach a 2500au spatial resolution. We used both the best-sensitivity and the line-free ALMA-IMF images, reduced the noise with the multi-resolution segmentation technique MnGSeg, and derived the most complete and most robust core catalog possible. Using two different extraction software packages, getsf and GExt2D, we identified 200 compact sources, whose 100 common sources have on average fluxes consistent to within 30%. We filtered sources with non-negligible free-free contamination and corrected fluxes from line contamination, resulting in a W43-MM2-MM3 catalog of 205 getsf cores. With a median deconvolved FWHM size of 3400au, core masses range from 0.1Msun to 70Msun and the getsf catalog is 90% complete down to 0.8Msun. The high-mass end of the core mass function (CMF) of W43-MM2-MM3 is top-heavy compared to the canonical IMF. Fitting the cumulative CMF with a single power law of the form N(>logM)\propto M^a, we measured a=-0.95\pm0.04, compared to the canonical a=-1.35 Salpeter IMF slope. The slope of the CMF is robust with respect to map processing, extraction software package, and reasonable variations in the assumptions taken to estimate core masses. We explore several assumptions on how cores transfer their mass to stars and sub-fragment to predict the IMF resulting from the W43-MM2-MM3 CMF. In stark contrast to the commonly accepted paradigm, our result argues against the universality of the CMF shape. More robust functions of the star-formation efficiency and core sub-fragmentation are required to better predict the resulting IMF, here suggested to remain top-heavy at the end of the star-formation phase. If confirmed, the IMFs emerging from starburst events could inherit their top-heavy shape from their parental CMFs, challenging the IMF universality., Comment: 28 pages, 16 figures, 6 tables, A&A accepted on 02/08/22

We present ALMA high-angular resolution ($\sim$ 50 au) observations of the Class I binary system SVS13-A. We report images of SVS13-A in numerous interstellar complex organic molecules: CH$_{\rm 3}$OH, $^{13}$CH$_{\rm 3}$OH, CH$_{\rm 3}$CHO, CH$_{\rm 3}$OCH$_{\rm 3}$, and NH$_{\rm 2}$CHO. Two hot corinos at different velocities are imaged in VLA4A (V$_{sys}$= +7.7 km s$^{-1}$) and VLA4B (V$_{sys}$= +8.5 km s$^{-1}$). From a non-LTE analysis of methanol lines we derive a gas density of 3 $\times$ 10$^8$ cm$^{-3}$, and gas temperatures of 140 K and 170 K for VLA4A and VLA4B, respectively. For the other species the column densities are derived from a LTE analysis. Formamide, which is the only N-bearing species detected in our observations, is more prominent around VLA4A, while dimethyl ether, methanol and acetaldehyde are associated with both VLA4A and VLA4B. We derive in the two hot corinos abundance ratios of $\sim$ 1 for CH$_{\rm 3}$OH, $^{13}$CH$_{\rm 3}$OH, and CH$_{\rm 3}$OCH$_{\rm 3}$, $\sim$ 2 for CH$_{\rm 3}$CHO, and $\sim$ 4 for NH$_{\rm 2}$CHO. The present dataset supports a chemical segregation between the different species inside the binary system. The emerging picture is that of an onion-like structure of the two SVS13-A hot corinos, caused by the different binding energies of the species, also supported by ad hoc quantum chemistry calculations. In addition, the comparison between molecular and dust maps suggests that the interstellar complex organic molecules emission originates from slow shocks produced by accretion streamers impacting the VLA4A and VLA4B disks and enriching the gas-phase component., Comment: 20 pages, 14 figures

Understanding the chemical past of our Sun and how life appeared on Earth is no mean feat. The best strategy we can adopt is to study newborn stars located in an environment similar to the one in which our Sun was born and assess their chemical content. In particular, hot corinos are prime targets since recent studies showed correlations between interstellar Complex Organic Molecules (iCOMs) abundances from hot corinos and comets. The ORion ALMA New GEneration Survey (ORANGES) aims to assess the number of hot corinos in the closest and best analogue to our Sun's birth environment, the OMC-2/3 filament. In this context, we investigated the chemical nature of 19 solar-mass protostars and found that 26\% of our sample sources shows warm methanol emission indicative of hot corinos. Compared to the Perseus low-mass star-forming region, where the PErseus ALMA CHEmistry Survey (PEACHES) detected $\sim 60$\% of hot corinos, the latter seem to be relatively scarce in the OMC-2/3 filament. While this suggests that the chemical nature of protostars in Orion and Perseus is different, improved statistics are needed in order to consolidate this result. If the two regions are truly different, this would indicate that the environment is likely playing a role in shaping the chemical composition of protostars., Comment: 16 pages, 8 figures, Accepted in ApJ

We studied the line emission from CH3CN and its deuterated isotopologue CH$_2$DCN towards the prototypical Class I object SVS13-A, where the deuteration of a large number of species has already been reported. Our goal is to measure the CH$_3$CN deuteration in a Class I protostar, for the first time, in order to constrain the CH$_3$CN formation pathways and the chemical evolution from the early prestellar core and Class 0 to the evolved Class I stages. We imaged CH2DCN towards SVS13-A using the IRAM NOEMA interferometer at 3mm in the context of the Large Program SOLIS (with a spatial resolution of 1.8"x1.2"). The NOEMA images have been complemented by the CH$_3$CN and CH$_2$DCN spectra collected by the IRAM-30m Large Program ASAI, that provided an unbiased spectral survey at 3mm, 2mm, and 1.3mm. The observed line emission has been analysed using LTE and non-LTE LVG approaches. The NOEMA/SOLIS images of CH2DCN show that this species emits in an unresolved area centered towards the SVS13-A continuum emission peak, suggesting that methyl cyanide and its isotopologues are associated with the hot corino of SVS13-A, previously imaged via other iCOMs. In addition, we detected 41 and 11 ASAI transitions of CH$_3$CN and CH2DCN, respectively, which cover upper level energies (Eup) from 13 to 442 K and from 18 K to 200 K, respectively. The derived [CH2DCN]/[CH3CN] ratio is $\sim$9\%. This value is consistent with those measured towards prestellar cores and a factor 2-3 higher than those measured in Class 0 protostars. Contrarily to what expected for other molecular species, the CH3CN deuteration does not show a decrease in SVS13-A with respect to measurements in younger prestellar cores and Class 0 protostars. Finally, we discuss why our new results suggest that CH3CN was likely synthesised via gas-phase reactions and frozen onto the dust grain mantles during the cold prestellar phase., Comment: 20 pages, 2 tables, 12 figures

We report a study of the low-mass Class-0 multiple system VLA 1623AB in the Ophiuchus star-forming region, using H$^{13}$CO$^+$ ($J=3-2$), CS ($J=5-4$), and CCH ($N=3-2$) lines as part of the ALMA Large Program FAUST. The analysis of the velocity fields revealed the rotation motion in the envelope and the velocity gradients in the outflows (about 2000 au down to 50 au). We further investigated the rotation of the circum-binary VLA 1623A disk as well as the VLA 1623B disk. We found that the minor axis of the circum-binary disk of VLA 1623A is misaligned by about 12 degrees with respect to the large-scale outflow and the rotation axis of the envelope. In contrast, the minor axis of the circum-binary disk is parallel to the large-scale magnetic field according to previous dust polarization observations, suggesting that the misalignment may be caused by the different directions of the envelope rotation and the magnetic field. If the velocity gradient of the outflow is caused by rotation, the outflow has a constant angular momentum and the launching radius is estimated to be $5-16$ au, although it cannot be ruled out that the velocity gradient is driven by entrainments of the two high-velocity outflows. Furthermore, we detected for the first time a velocity gradient associated with rotation toward the VLA 16293B disk. The velocity gradient is opposite to the one from the large-scale envelope, outflow, and circum-binary disk. The origin of its opposite gradient is also discussed., Comment: 27 pages, 21 figures, 2 Tables, Accepted for publication in ApJ

There is evidence that the star formation process is linked to the intricate net of filaments in molecular clouds, which may be also due to gas compression from external triggers. We studied the southern region of the Perseus NGC 1333 molecular cloud, known to be heavily shaped by similar external triggers, to shed light on the process that perturbed the filament where the Class 0 IRAS4 protostars lie. We use new IRAM-NOEMA observations of SiO and CH3OH, both known to trace violent events as shocks, toward IRAS 4A as part of the Large Program Seeds Of Life in Space (SOLIS). We detected three parallel elongated ($>$6000 au) structures, called fingers, with narrow line profiles (~1.5 $km s^{-1}$) peaked at the cloud systemic velocity, tracing gas with high density (5-20 $10^5 cm^{-3}$) and high temperature (80-160 K). They are chemically different, with the northern finger traced by both SiO and CH3OH ([CH3OH]/[SiO]~160-300), while the other two only by SiO ([CH3OH]/[SiO]$<$ 40). Among various possibilities, a train of three shocks, distanced by $>$5000 yr, would be consistent with the observations if a substantial fraction of silicon, frozen onto the grain mantles, is released by the shocks.We suggest that the shock train is due to an expanding gas bubble, coming behind NGC 1333 from the southwest and clashing against the filament, where IRAS 4A lies. Finally, we propose a solution to the two-decades long debate on the nature and origin of the widespread narrow SiO emission observed in the south part of NGC 1333, namely that it is due to unresolved trains of shocks., Comment: accepted to MNRAS, stac083

Star-forming molecular clouds are characterised by the ubiquity of intertwined filaments. The filaments have been observed in both high- and low-mass star-forming regions, and are thought to split into collections of sonic fibres. The locations where filaments converge are termed hubs, and these are associated with the young stellar clusters. However, the observations of filamentary structures within hubs at distances require a high angular resolution that limits the number of such studies conducted so far. The integral shaped filament of the Orion A molecular cloud is noted for harbouring several hubs within which no filamentary structures have been observed so far. The goal of our study is to investigate the nature of the filamentary structures within one of these hubs, which is the chemically rich hub OMC-2 FIR 4, and to analyse their emission with high density and shock tracers. We observed the OMC-2 FIR 4 proto-cluster using Band 6 of the ALMA in Cycle 4 with an angular resolution of ~0.26"(100 au). We analysed the spatial distribution of dust, the shock tracer SiO, and dense gas tracers (i.e., CH$_{3}$OH, CS, and H$^{13}$CN). We also studied gas kinematics using SiO and CH3OH maps. Our observations for the first time reveal interwoven filamentary structures within OMC-2 FIR 4 that are probed by several tracers. Each filamentary structure is characterised by a distinct velocity as seen from the emission peak of CH$_{3}$OH lines. They also show transonic and supersonic motions. SiO is associated with filaments and also with multiple bow-shock features. In addition, for the first time, we reveal a highly collimated SiO jet (~1$^{\circ}$) with a projected length of ~5200 au from the embedded protostar VLA15. Our study shows that multi-scale observations of these regions are crucial for understanding the accretion processes and flow of material that shapes star formation.

Context. In the past few years, there has been a rise in the detection of streamers, asymmetric flows of material directed toward the protostellar disk with material from outside the star's natal core. It is unclear how they affect the process of mass accretion, in particular beyond the Class 0 phase. Aims. We investigate the gas kinematics around Per-emb-50, a Class I source in the crowded star-forming region NGC 1333. Our goal is to study how the mass infall proceeds from envelope to disk scales in this source. Results. We discover a streamer delivering material toward Per-emb-50 in H$_2$CO and C$^{18}$O emission. The streamer's emission can be well described by the analytic solutions for an infalling parcel of gas along a streamline with conserved angular momentum, both in the image plane and along the line of sight velocities. The streamer has a mean infall rate of $1.3 \times 10^{ -6}$ M$_{ \odot}$ yr$^{ -1}$, $5 -10$ times higher than the current accretion rate of the protostar. SO and SO$_2$ emission reveal asymmetric infall motions in the inner envelope, additional to the streamer around Per-emb-50. Furthermore, the presence of SO$_2$ could mark the impact zone of the infalling material. Conclusions. The streamer delivers sufficient mass to sustain the protostellar accretion rate and might produce an accretion burst, which would explain the protostar's high luminosity with respect to other Class I sources. Our results highlight the importance of late infall for protostellar evolution: streamers might provide a significant amount of mass for stellar accretion after the Class 0 phase., Comment: 20 pages, 14 figures, accepted for publication in A&A

To understand the origin of the diversity observed in exoplanetary systems, it is crucial to characterize the early stages of their formation, represented by Solar-type protostars. Likely, the gaseous chemical content of these objects directly depends on the composition of the dust grain mantles formed before the collapse. Directly retrieving the ice mantle composition is challenging, but it can be done indirectly by observing the major components, such as NH3 and CH3OH at cm wavelengths, once they are released into the gas-phase during the warm protostellar stage. We observed several CH3OH and NH3 lines toward three Class 0 protostars in NGC1333 (IRAS 4A1, IRAS 4A2, and IRAS 4B), at high angular resolution (1"; ~300 au) with the VLA interferometer at 24-26 GHz. Using a non-LTE LVG analysis, we derived a similar NH3/CH3OH abundance ratio in the three protostars (<0.5, 0.015-0.5, and 0.003-0.3 for IRAS 4A1, 4A2, and 4B, respectively). Hence, we infer they were born from pre-collapse material with similar physical conditions. Comparing the observed abundance ratios with astrochemical model predictions, we constrained the dust temperature at the time of the mantle formation to be ~17 K, which coincides with the average temperature of the southern NGC 1333 diffuse cloud. We suggest that a brutal event started the collapse that eventually formed IRAS 4A1, 4A2 and 4B, which,therefore, did not experience the usual pre-stellar core phase. This event could be the clash of a bubble with NGC 1333 south, that has previously been evoked in the literature., Comment: accepted in ApJ Letters

Resolving physical and chemical structures in the vicinity of a protostar is of fundamental importance for elucidating their evolution to a planetary system. In this context, we have conducted 1.2 mm observations toward the low-mass protostellar source B335 at a resolution of 0."03 with ALMA. More than 20 molecular species including HCOOH, NH2 CHO, HNCO, CH3 OH, CH2 DOH, CHD2 OH, and CH3 OD are detected within a few 10 au around the continuum peak. We find a systematic chemical differentiation between oxygen-bearing and nitrogen-bearing organic molecules by using the principal component analysis for the image cube data. The distributions of the nitrogen-bearing molecules are more compact than those of the oxygen-bearing ones except for HCOOH. The temperature distribution of the disk/envelope system is revealed by a multi-line analysis for each of HCOOH, NH2 CHO, CH3 OH, and CH2 DOH. The rotation temperatures at the radius of 0."06 along the envelope direction of CH3OH and CH2DOH are derived to be 150-165 K. On the other hand, those of HCOOH and NH2CHO, which have a smaller distribution, are 75-112 K, and are significantly lower than those for CH3OH and CH2DOH. This means that the outer envelope traced by CH3OH and CH2DOH is heated by additional mechanisms rather than the protostellar heating. We here propose the accretion shock as the heating mechanism. The chemical differentiation and the temperature structure on a few au scale provide us with key information to further understand chemical processes in protostellar sources.

The ALMA interferometer, with its unprecedented combination of high-sensitivity and high-angular resolution, allows for (sub-)mm wavelength mapping of protostellar systems at Solar System scales. Astrochemistry has benefited from imaging interstellar complex organic molecules in these jet-disk systems. Here we report the first detection of methanol (CH3OH) and methyl formate (HCOOCH3) emission towards the triple protostellar system VLA1623-2417 A1+A2+B, obtained in the context of the ALMA Large Program FAUST. Compact methanol emission is detected in lines from Eu = 45 K up to 61 K and 537 K towards components A1 and B, respectively. LVG analysis of the CH3OH lines towards VLA1623-2417 B indicates a size of 0.11-0.34 arcsec (14-45 au), a column density N(CH3OH) = 10^16-10^17 cm-2, kinetic temperature > 170 K, and volume density > 10^8 cm-3. An LTE approach is used for VLA1623-2417 A1, given the limited Eu range, and yields Trot < 135 K. The methanol emission around both VLA1623-2417 A1 and B shows velocity gradients along the main axis of each disk. Although the axial geometry of the two disks is similar, the observed velocity gradients are reversed. The CH3OH spectra from B shows two broad (4-5 km s-1) peaks, which are red- and blue-shifted by about 6-7 km s-1 from the systemic velocity. Assuming a chemically enriched ring within the accretion disk, close to the centrifugal barrier, its radius is calculated to be 33 au. The methanol spectra towards A1 are somewhat narrower (about 4 km s-1), implying a radius of 12-24 au., Comment: MNRAS, in press

The ALMA-IMF Large Program observed the W43-MM2-MM3 ridge, whose 1.3mm and 3mm ALMA 12m array continuum images reach a 2500au spatial resolution. We used both the best-sensitivity and the line-free ALMA-IMF images, reduced the noise with the multi-resolution segmentation technique MnGSeg, and derived the most complete and most robust core catalog possible. Using two different extraction software packages, getsf and GExt2D, we identified 200 compact sources, whose 100 common sources have on average fluxes consistent to within 30%. We filtered sources with non-negligible free-free contamination and corrected fluxes from line contamination, resulting in a W43-MM2-MM3 catalog of 205 getsf cores. With a median deconvolved FWHM size of 3400au, core masses range from 0.1Msun to 70Msun and the getsf catalog is 90% complete down to 0.8Msun. The high-mass end of the core mass function (CMF) of W43-MM2-MM3 is top-heavy compared to the canonical IMF. Fitting the cumulative CMF with a single power law of the form N(>logM)\propto M^a, we measured a=-0.95\pm0.04, compared to the canonical a=-1.35 Salpeter IMF slope. The slope of the CMF is robust with respect to map processing, extraction software package, and reasonable variations in the assumptions taken to estimate core masses. We explore several assumptions on how cores transfer their mass to stars and sub-fragment to predict the IMF resulting from the W43-MM2-MM3 CMF. In stark contrast to the commonly accepted paradigm, our result argues against the universality of the CMF shape. More robust functions of the star-formation efficiency and core sub-fragmentation are required to better predict the resulting IMF, here suggested to remain top-heavy at the end of the star-formation phase. If confirmed, the IMFs emerging from starburst events could inherit their top-heavy shape from their parental CMFs, challenging the IMF universality., Comment: 28 pages, 16 figures, 6 tables, A&A accepted on 02/08/22, revised following the language referee report

Understanding the chemical past of our Sun and how life appeared on Earth is no mean feat. The best strategy we can adopt is to study newborn stars located in an environment similar to the one in which our Sun was born and assess their chemical content. In particular, hot corinos are prime targets since recent studies showed correlations between interstellar Complex Organic Molecules (iCOMs) abundances from hot corinos and comets. The ORion ALMA New GEneration Survey (ORANGES) aims to assess the number of hot corinos in the closest and best analogue to our Sun's birth environment, the OMC-2/3 filament. In this context, we investigated the chemical nature of 19 solar-mass protostars and found that 26\% of our sample sources shows warm methanol emission indicative of hot corinos. Compared to the Perseus low-mass star-forming region, where the PErseus ALMA CHEmistry Survey (PEACHES) detected $\sim 60$\% of hot corinos, the latter seem to be relatively scarce in the OMC-2/3 filament. While this suggests that the chemical nature of protostars in Orion and Perseus is different, improved statistics are needed in order to consolidate this result. If the two regions are truly different, this would indicate that the environment is likely playing a role in shaping the chemical composition of protostars., Comment: 16 pages, 8 figures, Accepted in ApJ

We present ALMA high-angular resolution ($\sim$ 50 au) observations of the Class I binary system SVS13-A. We report images of SVS13-A in numerous interstellar complex organic molecules: CH$_{\rm 3}$OH, $^{13}$CH$_{\rm 3}$OH, CH$_{\rm 3}$CHO, CH$_{\rm 3}$OCH$_{\rm 3}$, and NH$_{\rm 2}$CHO. Two hot corinos at different velocities are imaged in VLA4A (V$_{sys}$= +7.7 km s$^{-1}$) and VLA4B (V$_{sys}$= +8.5 km s$^{-1}$). From a non-LTE analysis of methanol lines we derive a gas density of 3 $\times$ 10$^8$ cm$^{-3}$, and gas temperatures of 140 K and 170 K for VLA4A and VLA4B, respectively. For the other species the column densities are derived from a LTE analysis. Formamide, which is the only N-bearing species detected in our observations, is more prominent around VLA4A, while dimethyl ether, methanol and acetaldehyde are associated with both VLA4A and VLA4B. We derive in the two hot corinos abundance ratios of $\sim$ 1 for CH$_{\rm 3}$OH, $^{13}$CH$_{\rm 3}$OH, and CH$_{\rm 3}$OCH$_{\rm 3}$, $\sim$ 2 for CH$_{\rm 3}$CHO, and $\sim$ 4 for NH$_{\rm 2}$CHO. The present dataset supports a chemical segregation between the different species inside the binary system. The emerging picture is that of an onion-like structure of the two SVS13-A hot corinos, caused by the different binding energies of the species, also supported by ad hoc quantum chemistry calculations. In addition, the comparison between molecular and dust maps suggests that the interstellar complex organic molecules emission originates from slow shocks produced by accretion streamers impacting the VLA4A and VLA4B disks and enriching the gas-phase component., Comment: 20 pages, 14 figures

We studied the line emission from CH3CN and its deuterated isotopologue CH$_2$DCN towards the prototypical Class I object SVS13-A, where the deuteration of a large number of species has already been reported. Our goal is to measure the CH$_3$CN deuteration in a Class I protostar, for the first time, in order to constrain the CH$_3$CN formation pathways and the chemical evolution from the early prestellar core and Class 0 to the evolved Class I stages. We imaged CH2DCN towards SVS13-A using the IRAM NOEMA interferometer at 3mm in the context of the Large Program SOLIS (with a spatial resolution of 1.8"x1.2"). The NOEMA images have been complemented by the CH$_3$CN and CH$_2$DCN spectra collected by the IRAM-30m Large Program ASAI, that provided an unbiased spectral survey at 3mm, 2mm, and 1.3mm. The observed line emission has been analysed using LTE and non-LTE LVG approaches. The NOEMA/SOLIS images of CH2DCN show that this species emits in an unresolved area centered towards the SVS13-A continuum emission peak, suggesting that methyl cyanide and its isotopologues are associated with the hot corino of SVS13-A, previously imaged via other iCOMs. In addition, we detected 41 and 11 ASAI transitions of CH$_3$CN and CH2DCN, respectively, which cover upper level energies (Eup) from 13 to 442 K and from 18 K to 200 K, respectively. The derived [CH2DCN]/[CH3CN] ratio is $\sim$9\%. This value is consistent with those measured towards prestellar cores and a factor 2-3 higher than those measured in Class 0 protostars. Contrarily to what expected for other molecular species, the CH3CN deuteration does not show a decrease in SVS13-A with respect to measurements in younger prestellar cores and Class 0 protostars. Finally, we discuss why our new results suggest that CH3CN was likely synthesised via gas-phase reactions and frozen onto the dust grain mantles during the cold prestellar phase., Comment: 20 pages, 2 tables, 12 figures

We report a study of the low-mass Class-0 multiple system VLA 1623AB in the Ophiuchus star-forming region, using H$^{13}$CO$^+$ ($J=3-2$), CS ($J=5-4$), and CCH ($N=3-2$) lines as part of the ALMA Large Program FAUST. The analysis of the velocity fields revealed the rotation motion in the envelope and the velocity gradients in the outflows (about 2000 au down to 50 au). We further investigated the rotation of the circum-binary VLA 1623A disk as well as the VLA 1623B disk. We found that the minor axis of the circum-binary disk of VLA 1623A is misaligned by about 12 degrees with respect to the large-scale outflow and the rotation axis of the envelope. In contrast, the minor axis of the circum-binary disk is parallel to the large-scale magnetic field according to previous dust polarization observations, suggesting that the misalignment may be caused by the different directions of the envelope rotation and the magnetic field. If the velocity gradient of the outflow is caused by rotation, the outflow has a constant angular momentum and the launching radius is estimated to be $5-16$ au, although it cannot be ruled out that the velocity gradient is driven by entrainments of the two high-velocity outflows. Furthermore, we detected for the first time a velocity gradient associated with rotation toward the VLA 16293B disk. The velocity gradient is opposite to the one from the large-scale envelope, outflow, and circum-binary disk. The origin of its opposite gradient is also discussed., Comment: 27 pages, 21 figures, 2 Tables, Accepted for publication in ApJ

There is evidence that the star formation process is linked to the intricate net of filaments in molecular clouds, which may be also due to gas compression from external triggers. We studied the southern region of the Perseus NGC 1333 molecular cloud, known to be heavily shaped by similar external triggers, to shed light on the process that perturbed the filament where the Class 0 IRAS4 protostars lie. We use new IRAM-NOEMA observations of SiO and CH3OH, both known to trace violent events as shocks, toward IRAS 4A as part of the Large Program Seeds Of Life in Space (SOLIS). We detected three parallel elongated ($>$6000 au) structures, called fingers, with narrow line profiles (~1.5 $km s^{-1}$) peaked at the cloud systemic velocity, tracing gas with high density (5-20 $10^5 cm^{-3}$) and high temperature (80-160 K). They are chemically different, with the northern finger traced by both SiO and CH3OH ([CH3OH]/[SiO]~160-300), while the other two only by SiO ([CH3OH]/[SiO]$<$ 40). Among various possibilities, a train of three shocks, distanced by $>$5000 yr, would be consistent with the observations if a substantial fraction of silicon, frozen onto the grain mantles, is released by the shocks.We suggest that the shock train is due to an expanding gas bubble, coming behind NGC 1333 from the southwest and clashing against the filament, where IRAS 4A lies. Finally, we propose a solution to the two-decades long debate on the nature and origin of the widespread narrow SiO emission observed in the south part of NGC 1333, namely that it is due to unresolved trains of shocks., Comment: accepted to MNRAS, stac083

We present the first data release of the ALMA-IMF Large Program, which covers the 12m-array continuum calibration and imaging. The ALMA-IMF Large Program is a survey of fifteen dense molecular cloud regions spanning a range of evolutionary stages that aims to measure the core mass function (CMF). We describe the data acquisition and calibration done by the Atacama Large Millimeter/submillimeter Array (ALMA) observatory and the subsequent calibration and imaging we performed. The image products are combinations of multiple 12m array configurations created from a selection of the observed bandwidth using multi-term, multi-frequency synthesis imaging and deconvolution. The data products are self-calibrated and exhibit substantial noise improvements over the images produced from the delivered data. We compare different choices of continuum selection, calibration parameters, and image weighting parameters, demonstrating the utility and necessity of our additional processing work. Two variants of continuum selection are used and will be distributed: the "best-sensitivity" data, which include the full bandwidth, including bright emission lines that contaminate the continuum, and "cleanest", which select portions of the spectrum that are unaffected by line emission. We present a preliminary analysis of the spectral indices of the continuum data, showing that the ALMA products are able to clearly distinguish free-free emission from dust emission, and that in some cases we are able to identify optically thick emission sources. The data products are made public with this release., Comment: Data released on Zenodo at https://zenodo.org/record/5598066. Accepted for publication in A&A

The ALMA-IMF Large Program imaged a total noncontiguous area of 53pc2, covering 15 extreme, nearby protoclusters of the Milky Way. They were selected to span relevant early protocluster evolutionary stages. Our 1.3mm and 3mm observations provide continuum images that are homogeneously sensitive to point-like cores with masses of 0.2 and 0.6Msun, respectively, with a matched spatial resolution of 2000au. We also detect lines that probe the protocluster structure, kinematics, chemistry, and feedback over scales from clouds to filaments to cores. We classify ALMA-IMF protoclusters as Young, Intermediate, or Evolved based on the amount of dense gas in the cloud that has potentially been impacted by HII regions. The ALMA-IMF catalog contains 700 cores that span a mass range of 0.15-250Msun at a typical size of 2100au. We show that this core sample has no significant distance bias and can be used to build core mass functions at similar physical scales. Significant gas motions, which we highlight here in the G353.41 region, are traced down to core scales and can be used to look for inflowing gas streamers and to quantify the impact of the possible associated core mass growth on the shape of the CMF with time. Our first analysis does not reveal any significant evolution of the matter concentration from clouds to cores or from the youngest to more evolved protoclusters, indicating that cloud dynamical evolution and stellar feedback have for the moment only had a slight effect on the structure of high-density gas in our sample. Furthermore, the first-look analysis of the line richness toward bright cores indicates that the survey encompasses several tens of hot cores, of which we highlight the most massive in the G351.77 cloud. Their homogeneous characterization can be used to constrain the emerging molecular complexity in protostars of high to intermediate masses., Comment: 27 pages, 9 figures, accepted for publication by A&A

Hot corinos are compact regions around solar-mass protostellar objects that are very rich in interstellar complex organic molecules (iCOMs). They are believed to represent the very early phases of our Solar System's birth, which was very likely also characterized by rich organic chemistry. While most of the studied hot corinos are either isolated or born in a loose protocluster, our Sun was born in a densely packed star cluster, near massive stars whose ultraviolet radiation must have contributed to shaping the evolution of the surrounding environment. In addition, internal irradiation from energetic particles ($>$10 Mev), whose imprint is seen today in the products of short-lived radionuclides in meteoritic material, is also known to have occurred during the Solar System formation. How did all these conditions affect the chemistry of the proto-Sun and its surroundings is still an open question. To answer this question, we studied HOPS-108, the hot corino located in the protosolar analogue OMC-2 FIR4. The study was carried out with ALMA at 1.3mm with an angular resolution of $\sim$100 AU. We detected 11 iCOMs such as CH$_{3}$OH HCOOCH$_{3}$ and CH$_{3}$OCH$_{3}$. Our results can be summarized as follows: (1) an enhancement of HCOOCH3 with respect to other hot corinos, (2) a [CH$_{3}$OCH$_{3}$]/[HCOOCH$_{3}$] abundance ratio of $\sim$0.2 marginally deviating from the usual trend seen in other sources ([CH$_{3}$OCH$_{3}$]/[HCOOCH$_{3}$] $\sim$1), (3) a [CH$_{2}$DOH]/[CH$_{3}$OH] ratio of 2.5\% which is lower than what is seen in Perseus and Ophiuchus hot corinos ($\sim$7\%-9\%) and similar to that seen in HH212 another source located in Orion. This might result from different physical conditions in the Orion molecular complex compared to other regions.

Isotopic fractionation is an important tool to investigate the chemical history of our Solar System (SS). In particular, the isotopic fraction of nitrogen (14N/15N) is lower in comets and other pristine SS bodies with respect to the value measured for the protosolar nebula, suggesting a local chemical enrichment of 15N during the SS formation. Therefore, interferometric studies of nitrogen fractionation in SS precursors are imperative for us to obtain clues about our astrochemical origins. In this work, we investigated the variation of the 14N/15N ratio in one of the closest analogues of the environment in which the SS was born: the protocluster OMC-2 FIR4. We present the first comparison at high angular resolution between HCN and N2H+ using interferometric data. We analysed observations of the HCN isotopologues H13CN and HC15N in the OMC-2 FIR4 protocluster, specifically the transitions H13CN (1-0) and HC15N (1-0), from NOEMA within the context of the IRAM Seeds Of Life In Space Large Program. We combined our results with analysis of archival data obtained with ALMA of N2H+ and its 15N isotopologues. Our results show a small regional variation in the ratio for HCN from ~250 to 500. The ratios in the central regions of FIR4, where the candidate protostars are located, are largely consistent (~300). They also show little variation from the part of the protocluster known to harbour a high cosmic-ray ionisation rate, to the portion with lower rate. We also found a small variation in the ratio of N2H+ across different regions from ~200 to ~400. These results suggest that local changes in the physical parameters occurring on small linear scales probed by our observations do not seem to affect the 14N/15N ratio in either HCN or N2H+ and hence that this is independent of the molecule used. Moreover, the high level of irradiation due to cosmic rays does not affect the N-fractionation either.

The spectral energy distribution (SED) in the millimetre (mm) to centimetre (cm) range is a useful tool for characterising the dust in protostellar envelopes as well as free-free emission from the protostar and outflow. While many studies have been carried out towards low- and high-mass protostars, little exists so far about solar-type protostars in high-mass star-forming regions, which are likely to be representatives of the conditions where the Solar System was born. We focus here on the OMC-2/3 solar-type protostars, which are bounded by nearby HII regions and which are, therefore, potentially affected by the high-UV illumination. We aim to understand whether the small-scale structure ($\leq$1000 au) and the evolutionary status of these solar-type protostars are affected by the nearby HII regions, as is the case for the large-scale ($\leq$10$^4$ au) gas chemical composition. We used ALMA in the 1.3 mm band (246.2 GHz) to image the continuum of 16 OMC-2/3 solar-type protostars, with an angular resolution of 0.25$''$ (100 au). We completed our data with archival data from the VANDAM survey of Orion Protostars at 333 and 32.9 GHz, respectively, to construct the dust SED, extract several dust parameters and to assess whether free-free emission is contaminating their dust SED in the cm range. From the mm to cm range dust SED, we found low dust emissivity spectral indexes ($\beta < 1$) for the majority of our source sample and free-free emission towards only 5 of the 16 sample sources. We were also able to confirm or correct the evolutionary status of the source sample. Finally, we did not find any dependence of the source dust parameters on their location in the OMC-2/3 filament. Our results show that the small-scale dust properties of the OMC-2/3 protostars are not affected by the high- UV illumination from the nearby HII regions., Comment: 30 pages, 14 figures, Accepted for publication in A&A

We have observed the young protostellar system NGC 2264 CMM3 in the 1.3 mm and 2.0 mm bands at a resolution of about 0.1$"$ (70 au) with ALMA. The structures of two distinct components, CMM3A and CMM3B, are resolved in the continuum images of both bands. CMM3A has an elliptical structure extending along the direction almost perpendicular to the known outflow, while CMM3B reveals a round shape. We have fitted two 2D-Gaussian components to the elliptical structure of CMM3A and CMM3B, and have separated the disk and envelope components for each source. The spectral index $\alpha$ between 2.0 mm and 0.8 mm is derived to be 2.4-2.7 and 2.4-2.6 for CMM3A and CMM3B, respectively, indicating the optically thick dust emission and/or the grain growth. A velocity gradient in the disk/envelope direction is detected for CMM3A in the CH$_3$CN, CH$_3$OH, and $^{13}$CH$_3$OH lines detected in the 1.3 mm band, which can be interpreted as the rotation of the disk/envelope system. From this result, the protostellar mass of CMM3A is roughly evaluated to be $0.1- 0.5$ $M_\odot$ by assuming Keplerian rotation. The mass accretion rate is thus estimated to be $5\times10^{-5}$ - 4 $\times$ $10^{-3}$ $M_\odot$ yr$^{-1}$, which is higher than typical mass accretion rate of low-mass protostars. The OCS emission line shows a velocity gradient in both outflow direction and disk/envelope direction. A hint of outflow rotation is found, and the specific angular momentum of the outflow is estimated to be comparable to that of the disk. These results provide us with novel information on the initial stage of a binary/multiple system., Comment: Accepted for publication in the Astrophysical Journal, 21 pages, 12 figures

Feedback from active galactic nuclei (AGN) has proven to be a critical ingredient in the current picture of galaxy assembly and growth. However, observational constraints on AGN-driven outflows face technical challenges and as a result, the cold molecular gas outflow properties of type-1 AGN are not well known. We present new IRAM NOrthern Extended Milimeter Array (NOEMA) observations of CO (1-0) in F07599+6508, Z11598$-$0112, F13342+3932, and PG1440+356, all nearby type-1 AGN and ultraluminous infrared galaxies (ULIRGs). We achieve spatial resolution of 1-3 arcsec corresponding to physical scales of 2--8~kpc and spectral resolution of 15-60 km s$^{-1}$ which enables updated CO (1-0) redshifts and a detailed morphological view of the cold molecular gas in these sources. The CO (1-0) luminosities, $L_{CO}^{\prime}$, are in the range 2-12$\times 10^9$ K km s$^{-1}$ pc$^{2}$ and inferred molecular gas masses, $M$(H$_2$), are in the range 2-9$\times 10^9$ M$_{\odot}$. The velocity fields and gas distributions do not unambiguously identify any of these sources as having outflows. However, Z11598$-$0112 has signs of infalling material and after the subtraction of a rotating disk model PG 1440+356 shows complex kinematics in the residuals that may indicate an outflow or warped disk., Comment: 20 pages, 10 figures, accepted for publication in MNRAS

The Class 0 protostar IRAS 16293$-$2422 Source A is known to be a binary system (A1 and A2) or even a multiple system, which processes a complex outflow structure. We have observed this source in the C$^{34}$S, SO, and OCS lines at 3.1 mm with the Atacama Large Millimeter/submillimeter Array (ALMA). A substructure of this source is traced by our high angular-resolution observation (0\farcs12; 20 au) of the continuum emission. The northwest-southeast (NW-SE) outflow on a 2\arcsec\ scale is detected in the SO ($J_N$ = $2_2$--$1_1$) line. Based on the morphology of the SO distribution, this bipolar outflow structure seems to originate from the protostar A1 and its circumstellar disk, or the circummultiple structure of Source A. The rotation motion of the NW-SE outflow is detected in the SO and OCS emissions. We evaluate the specific angular momentum of the outflowing gas to be $(8.6 - 14.3) \times 10^{-4}$ km s$^{-1}$ pc. If the driving source of this outflow is the protostar A1 and its circumstellar disk, it can be a potential mechanism to extract the specific angular momentum of the disk structure. These results can be a hint for the outflow launching mechanism in this source. Furthermore, they provide us with an important clue to resolve the complicated structure of IRAS 16293$-$2422 Source A., Comment: 48 pages, 8 figs

We present the first data release of the ALMA-IMF Large Program, which covers the 12m-array continuum calibration and imaging. The ALMA-IMF Large Program is a survey of fifteen dense molecular cloud regions spanning a range of evolutionary stages that aims to measure the core mass function (CMF). We describe the data acquisition and calibration done by the Atacama Large Millimeter/submillimeter Array (ALMA) observatory and the subsequent calibration and imaging we performed. The image products are combinations of multiple 12m array configurations created from a selection of the observed bandwidth using multi-term, multi-frequency synthesis imaging and deconvolution. The data products are self-calibrated and exhibit substantial noise improvements over the images produced from the delivered data. We compare different choices of continuum selection, calibration parameters, and image weighting parameters, demonstrating the utility and necessity of our additional processing work. Two variants of continuum selection are used and will be distributed: the "best-sensitivity" data, which include the full bandwidth, including bright emission lines that contaminate the continuum, and "cleanest", which select portions of the spectrum that are unaffected by line emission. We present a preliminary analysis of the spectral indices of the continuum data, showing that the ALMA products are able to clearly distinguish free-free emission from dust emission, and that in some cases we are able to identify optically thick emission sources. The data products are made public with this release., Comment: Data released on Zenodo at https://zenodo.org/record/5702966. Accepted for publication in A&A

The ALMA-IMF Large Program imaged a total noncontiguous area of 53pc2, covering 15 extreme, nearby protoclusters of the Milky Way. They were selected to span relevant early protocluster evolutionary stages. Our 1.3mm and 3mm observations provide continuum images that are homogeneously sensitive to point-like cores with masses of 0.2 and 0.6Msun, respectively, with a matched spatial resolution of 2000au. We also detect lines that probe the protocluster structure, kinematics, chemistry, and feedback over scales from clouds to filaments to cores. We classify ALMA-IMF protoclusters as Young, Intermediate, or Evolved based on the amount of dense gas in the cloud that has potentially been impacted by HII regions. The ALMA-IMF catalog contains 700 cores that span a mass range of 0.15-250Msun at a typical size of 2100au. We show that this core sample has no significant distance bias and can be used to build core mass functions at similar physical scales. Significant gas motions, which we highlight here in the G353.41 region, are traced down to core scales and can be used to look for inflowing gas streamers and to quantify the impact of the possible associated core mass growth on the shape of the CMF with time. Our first analysis does not reveal any significant evolution of the matter concentration from clouds to cores or from the youngest to more evolved protoclusters, indicating that cloud dynamical evolution and stellar feedback have for the moment only had a slight effect on the structure of high-density gas in our sample. Furthermore, the first-look analysis of the line richness toward bright cores indicates that the survey encompasses several tens of hot cores, of which we highlight the most massive in the G351.77 cloud. Their homogeneous characterization can be used to constrain the emerging molecular complexity in protostars of high to intermediate masses., Comment: 27 pages, 9 figures, accepted for publication by A&A

Hot corinos are compact regions around solar-mass protostellar objects that are very rich in interstellar complex organic molecules (iCOMs). They are believed to represent the very early phases of our Solar System's birth, which was very likely also characterized by rich organic chemistry. While most of the studied hot corinos are either isolated or born in a loose protocluster, our Sun was born in a densely packed star cluster, near massive stars whose ultraviolet radiation must have contributed to shaping the evolution of the surrounding environment. In addition, internal irradiation from energetic particles ($>$10 Mev), whose imprint is seen today in the products of short-lived radionuclides in meteoritic material, is also known to have occurred during the Solar System formation. How did all these conditions affect the chemistry of the proto-Sun and its surroundings is still an open question. To answer this question, we studied HOPS-108, the hot corino located in the protosolar analogue OMC-2 FIR4. The study was carried out with ALMA at 1.3mm with an angular resolution of $\sim$100 AU. We detected 11 iCOMs such as CH$_{3}$OH HCOOCH$_{3}$ and CH$_{3}$OCH$_{3}$. Our results can be summarized as follows: (1) an enhancement of HCOOCH3 with respect to other hot corinos, (2) a [CH$_{3}$OCH$_{3}$]/[HCOOCH$_{3}$] abundance ratio of $\sim$0.2 marginally deviating from the usual trend seen in other sources ([CH$_{3}$OCH$_{3}$]/[HCOOCH$_{3}$] $\sim$1), (3) a [CH$_{2}$DOH]/[CH$_{3}$OH] ratio of 2.5\% which is lower than what is seen in Perseus and Ophiuchus hot corinos ($\sim$7\%-9\%) and similar to that seen in HH212 another source located in Orion. This might result from different physical conditions in the Orion molecular complex compared to other regions.

Isotopic fractionation is an important tool to investigate the chemical history of our Solar System (SS). In particular, the isotopic fraction of nitrogen (14N/15N) is lower in comets and other pristine SS bodies with respect to the value measured for the protosolar nebula, suggesting a local chemical enrichment of 15N during the SS formation. Therefore, interferometric studies of nitrogen fractionation in SS precursors are imperative for us to obtain clues about our astrochemical origins. In this work, we investigated the variation of the 14N/15N ratio in one of the closest analogues of the environment in which the SS was born: the protocluster OMC-2 FIR4. We present the first comparison at high angular resolution between HCN and N2H+ using interferometric data. We analysed observations of the HCN isotopologues H13CN and HC15N in the OMC-2 FIR4 protocluster, specifically the transitions H13CN (1-0) and HC15N (1-0), from NOEMA within the context of the IRAM Seeds Of Life In Space Large Program. We combined our results with analysis of archival data obtained with ALMA of N2H+ and its 15N isotopologues. Our results show a small regional variation in the ratio for HCN from ~250 to 500. The ratios in the central regions of FIR4, where the candidate protostars are located, are largely consistent (~300). They also show little variation from the part of the protocluster known to harbour a high cosmic-ray ionisation rate, to the portion with lower rate. We also found a small variation in the ratio of N2H+ across different regions from ~200 to ~400. These results suggest that local changes in the physical parameters occurring on small linear scales probed by our observations do not seem to affect the 14N/15N ratio in either HCN or N2H+ and hence that this is independent of the molecule used. Moreover, the high level of irradiation due to cosmic rays does not affect the N-fractionation either.

The spectral energy distribution (SED) in the millimetre (mm) to centimetre (cm) range is a useful tool for characterising the dust in protostellar envelopes as well as free-free emission from the protostar and outflow. While many studies have been carried out towards low- and high-mass protostars, little exists so far about solar-type protostars in high-mass star-forming regions, which are likely to be representatives of the conditions where the Solar System was born. We focus here on the OMC-2/3 solar-type protostars, which are bounded by nearby HII regions and which are, therefore, potentially affected by the high-UV illumination. We aim to understand whether the small-scale structure ($\leq$1000 au) and the evolutionary status of these solar-type protostars are affected by the nearby HII regions, as is the case for the large-scale ($\leq$10$^4$ au) gas chemical composition. We used ALMA in the 1.3 mm band (246.2 GHz) to image the continuum of 16 OMC-2/3 solar-type protostars, with an angular resolution of 0.25$''$ (100 au). We completed our data with archival data from the VANDAM survey of Orion Protostars at 333 and 32.9 GHz, respectively, to construct the dust SED, extract several dust parameters and to assess whether free-free emission is contaminating their dust SED in the cm range. From the mm to cm range dust SED, we found low dust emissivity spectral indexes ($\beta < 1$) for the majority of our source sample and free-free emission towards only 5 of the 16 sample sources. We were also able to confirm or correct the evolutionary status of the source sample. Finally, we did not find any dependence of the source dust parameters on their location in the OMC-2/3 filament. Our results show that the small-scale dust properties of the OMC-2/3 protostars are not affected by the high- UV illumination from the nearby HII regions., Comment: 30 pages, 14 figures, Accepted for publication in A&A

We have observed the young protostellar system NGC 2264 CMM3 in the 1.3 mm and 2.0 mm bands at a resolution of about 0.1$"$ (70 au) with ALMA. The structures of two distinct components, CMM3A and CMM3B, are resolved in the continuum images of both bands. CMM3A has an elliptical structure extending along the direction almost perpendicular to the known outflow, while CMM3B reveals a round shape. We have fitted two 2D-Gaussian components to the elliptical structure of CMM3A and CMM3B, and have separated the disk and envelope components for each source. The spectral index $\alpha$ between 2.0 mm and 0.8 mm is derived to be 2.4-2.7 and 2.4-2.6 for CMM3A and CMM3B, respectively, indicating the optically thick dust emission and/or the grain growth. A velocity gradient in the disk/envelope direction is detected for CMM3A in the CH$_3$CN, CH$_3$OH, and $^{13}$CH$_3$OH lines detected in the 1.3 mm band, which can be interpreted as the rotation of the disk/envelope system. From this result, the protostellar mass of CMM3A is roughly evaluated to be $0.1- 0.5$ $M_\odot$ by assuming Keplerian rotation. The mass accretion rate is thus estimated to be $5\times10^{-5}$ - 4 $\times$ $10^{-3}$ $M_\odot$ yr$^{-1}$, which is higher than typical mass accretion rate of low-mass protostars. The OCS emission line shows a velocity gradient in both outflow direction and disk/envelope direction. A hint of outflow rotation is found, and the specific angular momentum of the outflow is estimated to be comparable to that of the disk. These results provide us with novel information on the initial stage of a binary/multiple system., Comment: Accepted for publication in the Astrophysical Journal, 21 pages, 12 figures

Feedback from active galactic nuclei (AGN) has proven to be a critical ingredient in the current picture of galaxy assembly and growth. However, observational constraints on AGN-driven outflows face technical challenges and as a result, the cold molecular gas outflow properties of type-1 AGN are not well known. We present new IRAM NOrthern Extended Milimeter Array (NOEMA) observations of CO (1-0) in F07599+6508, Z11598$-$0112, F13342+3932, and PG1440+356, all nearby type-1 AGN and ultraluminous infrared galaxies (ULIRGs). We achieve spatial resolution of 1-3 arcsec corresponding to physical scales of 2--8~kpc and spectral resolution of 15-60 km s$^{-1}$ which enables updated CO (1-0) redshifts and a detailed morphological view of the cold molecular gas in these sources. The CO (1-0) luminosities, $L_{CO}^{\prime}$, are in the range 2-12$\times 10^9$ K km s$^{-1}$ pc$^{2}$ and inferred molecular gas masses, $M$(H$_2$), are in the range 2-9$\times 10^9$ M$_{\odot}$. The velocity fields and gas distributions do not unambiguously identify any of these sources as having outflows. However, Z11598$-$0112 has signs of infalling material and after the subtraction of a rotating disk model PG 1440+356 shows complex kinematics in the residuals that may indicate an outflow or warped disk., Comment: 20 pages, 10 figures, accepted for publication in MNRAS

The Class 0 protostar IRAS 16293$-$2422 Source A is known to be a binary system (A1 and A2) or even a multiple system, which processes a complex outflow structure. We have observed this source in the C$^{34}$S, SO, and OCS lines at 3.1 mm with the Atacama Large Millimeter/submillimeter Array (ALMA). A substructure of this source is traced by our high angular-resolution observation (0\farcs12; 20 au) of the continuum emission. The northwest-southeast (NW-SE) outflow on a 2\arcsec\ scale is detected in the SO ($J_N$ = $2_2$--$1_1$) line. Based on the morphology of the SO distribution, this bipolar outflow structure seems to originate from the protostar A1 and its circumstellar disk, or the circummultiple structure of Source A. The rotation motion of the NW-SE outflow is detected in the SO and OCS emissions. We evaluate the specific angular momentum of the outflowing gas to be $(8.6 - 14.3) \times 10^{-4}$ km s$^{-1}$ pc. If the driving source of this outflow is the protostar A1 and its circumstellar disk, it can be a potential mechanism to extract the specific angular momentum of the disk structure. These results can be a hint for the outflow launching mechanism in this source. Furthermore, they provide us with an important clue to resolve the complicated structure of IRAS 16293$-$2422 Source A., Comment: 48 pages, 8 figs

To date, about two dozen low-mass embedded protostars exhibit rich spectra with lines of complex organic molecule (COM). These protostars seem to possess different enrichment in COMs. However, the statistics of COM abundance in low-mass protostars are limited by the scarcity of observations. This study introduces the Perseus ALMA Chemistry Survey (PEACHES), which aims at unbiasedly characterizing the chemistry of COMs toward the embedded (Class 0/I) protostars in the Perseus molecular cloud. Of 50 embedded protostars surveyed, 58% of them have emission from COMs. A 56%, 32%, and 40% of the protostars have CH$_3$OH, CH$_3$OCHO, and N-bearing COMs, respectively. The detectability of COMs depends neither on the averaged continuum brightness temperature, a proxy of the H$_2$ column density, nor on the bolometric luminosity and the bolometric temperature. For the protostars with detected COMs, CH$_3$OH has a tight correlation with CH$_3$CN, spanning more than two orders of magnitude in column densities normalized by the continuum brightness temperature, suggesting a chemical relation between CH$_3$OH and CH$_3$CN and a large chemical diversity in the PEACHES samples at the same time. A similar trend with more scatter is also found between all identified COMs, hinting at a common chemistry for the sources with COMs. The correlation between COMs is insensitive to the protostellar properties, such as the bolometric luminosity and the bolometric temperature. The abundance of larger COMs (CH$_3$OCHO and CH$_3$OCH$_3$) relative to that of smaller COMs (CH$_3$OH and CH$_3$CN) increases with the inferred gas column density, hinting at an efficient production of complex species in denser envelopes., Comment: 55 pages, 9 tables, 24 figures. Updated after publication in ApJ. Figure 18 appears as a figure set in ApJ

We have observed the very low-mass Class 0 protostar IRAS 15398-3359 at scales ranging from 50 au to 1800 au, as part of the ALMA Large Program FAUST. We uncover a linear feature, visible in H2CO, SO, and C18O line emission, which extends from the source along a direction almost perpendicular to the known active outflow. Molecular line emission from H2CO, SO, SiO, and CH3OH further reveals an arc-like structure connected to the outer end of the linear feature and separated from the protostar, IRAS 15398-3359, by 1200 au. The arc-like structure is blue-shifted with respect to the systemic velocity. A velocity gradient of 1.2 km/s over 1200 au along the linear feature seen in the H2CO emission connects the protostar and the arc-like structure kinematically. SO, SiO, and CH3OH are known to trace shocks, and we interpret the arc-like structure as a relic shock region produced by an outflow previously launched by IRAS 15398-3359. The velocity gradient along the linear structure can be explained as relic outflow motion. The origins of the newly observed arc-like structure and extended linear feature are discussed in relation to turbulent motions within the protostellar core and episodic accretion events during the earliest stage of protostellar evolution.

The study of hot corinos in Solar-like protostars has been so far mostly limited to the Class 0 phase, hampering our understanding of their origin and evolution. In addition, recent evidence suggests that planet formation starts already during Class I phase, which, therefore, represents a crucial step in the future planetary system chemical composition. Hence, the study of hot corinos in Class I protostars has become of paramount importance. Here we report the discovery of a hot corino towards the prototypical Class I protostar L1551 IRS5, obtained within the ALMA Large Program FAUST. We detected several lines from methanol and its isopotologues ($^{13}$CH$_{\rm 3}$OH and CH$_{\rm 2}$DOH), methyl formate and ethanol. Lines are bright toward the north component of the IRS5 binary system, and a possible second hot corino may be associated with the south component. The methanol lines non-LTE analysis constrains the gas temperature ($\sim$100 K), density ($\geq$1.5$\times$10$^{8}$ cm$^{-3}$), and emitting size ($\sim$10 au in radius). All CH$_{\rm 3}$OH and $^{13}$CH$_{\rm 3}$OH lines are optically thick, preventing a reliable measure of the deuteration. The methyl formate and ethanol relative abundances are compatible with those measured in Class 0 hot corinos. Thus, based on the present work, little chemical evolution from Class 0 to I hot corinos occurs., Comment: 6 pages, 2 figures

After almost 20 years of hunting, only about a dozen hot corinos, hot regions enriched in interstellar complex organic molecules (iCOMs), are known. Of them, many are binary systems with the two components showing drastically different molecular spectra. Two obvious questions arise. Why are hot corinos so difficult to find and why do their binary components seem chemically different? The answer to both questions could be a high dust opacity that would hide the molecular lines. To test this hypothesis, we observed methanol lines at centimeter wavelengths, where dust opacity is negligible, using the Very Large Array interferometer. We targeted the NGC 1333 IRAS 4A binary system, for which one of the two components, 4A1, has a spectrum deprived of iCOMs lines when observed at millimeter wavelengths, while the other component, 4A2, is very rich in iCOMs. We found that centimeter methanol lines are similarly bright toward 4A1 and 4A2. Their non-LTE analysis indicates gas density and temperature ($\geq2\times10^6$ cm$^{-3}$ and 100--190 K), methanol column density ($\sim10^{19}$ cm$^{-2}$) and extent ($\sim$35 au in radius) similar in 4A1 and 4A2, proving that both are hot corinos. Furthermore, the comparison with previous methanol line millimeter observations allows us to estimate the optical depth of the dust in front of 4A1 and 4A2, respectively. The obtained values explain the absence of iCOMs line emission toward 4A1 at millimeter wavelengths and indicate that the abundances toward 4A2 are underestimated by $\sim$30\%. Therefore, centimeter observations are crucial for the correct study of hot corinos, their census, and their molecular abundances., Comment: 9 pages, 3 figures, 2 Tables - Published in ApJ Letters

Aims: A unique environment to study how interstellar Complex Organic Molecules (iCOMs) can be formed is the shocked gas along low-mass protostellar outflows, as the dust mantles composition is sputtered into the gas phase. The chemical richness in these environments has been so far studied only in the L1157 blue shifted outflow. Methods: To understand if the L1157-B1 case is unique, we imaged the NGC 1333 IRAS 4A outflows using the NOEMA (NOrthern Extended Millimeter Array) interferometer as part of the IRAM SOLIS (Seeds Of Life in Space) Large Program and compared the observations with the GRAINOBLE+ gas phase astrochemical model. Results: Several iCOMs were detected in the IRAS 4A outflows: methanol (CH$_3$OH), acetaldehyde (CH$_3$CHO), formamide (NH$_2$CHO) and dimethyl ether (CH$_3$OCH$_3$), all sampling upper excitation energy up to $\sim$30 K. We found a significant chemical differentiation between the IRAS 4A1 outflow, showing a richer molecular content, and the IRAS 4A2 one. The CH$_3$OH/CH$_3$CHO abundance ratio is lower by a factor $\sim$4 in the former; furthermore the ratio in both outflows is lower by a factor $\sim$10 with respect to hot corinos values. Conclusions: After L1157-B1, IRAS 4A outflow is now the second outflow to show an evident chemical complexity. Given that CH$_3$OH is a grain surface species, GRAINOBLE+ reproduced our observations assuming acetaldehyde formation in gas phase by the reaction of ethyl radical (CH$_3$CH$_2$) with atomic oxygen. Moreover, the chemical differentiation between the two outflows suggests that the IRAS 4A1 outflow is likely younger than the IRAS 4A2 one. Further investigation is needed to constrain the age of the outflow and observations of even younger shocks are necessary and future spectroscopic studies on CH$_3$CH$_2$ are needed to be able to observe this species and provide strong constraints on the CH$_3$CHO formation., Comment: 12 pages, 7 figures, 5 tables

L1157-B1 is one of the outflow shocked regions along the blue-shifted outflow driven by the Class 0 protostar L1157-mm, and is an ideal laboratory to study the material ejected from the grains in very short timescales, i.e. its chemical composition is representative of the composition of the grains. We imaged $^{28}$SiO, $^{29}$SiO and $^{30}$SiO J = 2-1 emission towards L1157-B1 and B0 with the NOrthern Extended Millimeter Array (NOEMA) interferometer as part of the Seeds of Life in Space (SOLIS) large project. We present here a study of the isotopic fractionation of SiO towards L1157-B1. Furthermore, we use the high spectral resolution observations on the main isotopologue, $^{28}$SiO, to study the jet impact on the dense gas. We present here also single-dish observations obtained with the IRAM 30m telescope and Herschel-HIFI. We carried out a non-LTE analysis using a Large Velocity Gradient (LVG) code to model the single-dish observations. From our observations we can show that (i) the (2-1) transition of the main isotopologue is optically thick in L1157-B1 even at high velocities, and (ii) the [$^{29}$SiO/$^{30}$SiO] ratio is constant across the source, and consistent with the solar value of 1.5. We report the first isotopic fractionation maps of SiO in a shocked region and show the absence of a mass dependent fractionation in $^{29}$Si and $^{30}$Si across L1157-B1. A high-velocity bullet in $^{28}$SiO has been identified, showing the signature of a jet impacting on the dense gas. With the dataset presented in this paper, both interferometric and single-dish, we were able to study in great detail the gas shocked at the B1a position and its surrounding gas., Comment: Accepted for publication in A&A

Context. Low-mass protostars drive powerful molecular outflows that can be observed with mm and sub-mm telescopes. Various sulfuretted species are known to be bright in shocks and could be used to infer the physical and chemical conditions throughout the observed outflows. Aims. The evolution of sulfur chemistry is studied along the outflows driven by the NGC1333-IRAS4A protobinary system located in the Perseus cloud to constrain the physical and chemical processes at work in shocks. Methods. We observed various transitions from OCS, CS, SO, and SO$_2$ towards NGC1333-IRAS4A in the 1.3, 2, and 3mm bands using the IRAM NOEMA array and we interpreted the observations through the use of the Paris-Durham shock model. Results. The targeted species clearly show different spatial emission along the two outflows driven by IRAS4A. OCS is brighter on small and large scales along the south outflow driven by IRAS4A1, whereas SO$_2$ is detected rather along the outflow driven by IRAS4A2 that is extended along the north east - south west (NE-SW) direction. Column density ratio maps estimated from a rotational diagram analysis allowed us to confirm a clear gradient of the OCS/SO$_2$ column density ratio between the IRAS4A1 and IRAS4A2 outflows. SO is detected at extremely high radial velocity up to 25 km/s relative to the source velocity, clearly allowing us to distinguish the two outflows on small scales. Conclusions. The observed chemical differentiation between the two outflows of the IRAS4A system could be explained by a different chemical history. The outflow driven by IRAS4A1 is likely younger and more enriched in species initially formed in interstellar ices, such as OCS, and recently sputtered into the shock gas. In contrast, the longer and likely older outflow triggered by IRAS4A2 is more enriched in species that have a gas phase origin, such as SO$_2$., Comment: Accepted for publication in A&A

Context: Solar-like protostars are known to be chemically rich, but it is not yet clear how much their chemical composition can vary and why. So far, two chemically distinct types of Solar-like protostars have been identified: hot corinos, which are enriched in interstellar Complex Organic Molecules (iCOMs), such as methanol (CH$_3$OH) or dimethyl ether (CH$_3$OCH$_3$), and Warm Carbon Chain Chemistry (WCCC) objects, which are enriched in carbon chain molecules, such as butadiynyl (C$_4$H) or ethynyl radical (CCH). However, none of these have been studied so far in environments similar to that in which our Sun was born, that is, one that is close to massive stars. Aims: In this work, we search for hot corinos and WCCC objects in the closest analogue to the Sun's birth environment, the Orion Molecular Cloud 2/3 (OMC-2/3) filament located in the Orion A molecular cloud. Methods: We obtained single-dish observations of CCH and CH$_3$OH line emission towards nine Solar-like protostars in this region. As in other, similar studies of late, we used the [CCH]/[CH$_3$OH] abundance ratio in order to determine the chemical nature of our protostar sample. Results: Unexpectedly, we found that the observed methanol and ethynyl radical emission (over a few thousands au scale) does not seem to originate from the protostars but rather from the parental cloud and its photo-dissociation region, illuminated by the OB stars of the region. Conclusions: Our results strongly suggest that caution should be taken before using [CCH]/[CH$_3$OH] from single-dish observations as an indicator of the protostellar chemical nature and that there is a need for other tracers or high angular resolution observations for probing the inner protostellar layers., Comment: A&A, in press, 15 pages, 10 figures, 1 appendice (13 pages, 9 figures)

Aim: In the past, observations of protostellar shocks have been able to set constraints on the formation route of formamide (NH2CHO), exploiting its observed spatial distribution and comparison with astrochemical model predictions. In this work, we follow the same strategy to study the case of acetaldehyde (CH3CHO). Method: To this end, we used the data obtained with the IRAM-NOEMA interferometer in the framework of the Large Program SOLIS to image the B0 and B1 shocks along the L1157 blueshifted outflow in methanol (CH3OH) and acetaldehyde line emission. Results: We imaged six CH3OH and eight CH3CHO lines which cover upper level energies up to 30 K. Both species trace the B0 molecular cavity as well as the northern B1 portion, i.e. the regions where the youngest shocks (1000 yr) occurred. The CH$_3$OH and CH$_3$CHO emission peaks towards the B1b clump, where we measured the following column densities and relative abundances: 1.3 x 10^16 cm-2 and 6.5 x 10-6 (methanol), and 7 x 10^13 cm-2 and 3.5 x 10-8 (acetaldehyde). We carried out a non-LTE LVG analysis of the observed CH3OH line: the average kinetic temperature and density of the emitting gas are Tkin = 90 K and nH2 = 4 x 10^5 cm-3, respectively. The CH3OH and CH3CHO abundance ratio towards B1b is 190, varying by less than a factor 3 throughout the whole B0-B1 structure. Conclusions: The comparison of astrochemical model predictions with the observed methanol and acetaldehyde spatial distribution does not allow to distinguish whether acetaldehyde is formed on the grain mantles or rather on the gas-phase, as its gas-phase formation, dominated by the reaction of ethyl radical (CH3CH2) with atomic oxygen, is very fast. Observations of acetaldehyde in younger shocks, e.g. 10^2 yr old, or/and of the ethyl radical, whose frequencies are not presently available, are necessary to settle the issue., Comment: A&A, in press