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Masterarbeit Universität Innsbruck 2024

The Integrated Ocean Drilling Program conducted Expedition 343 and 343T, named the Japan Trench Fast Drilling Project (JFAST), to drill through the plate boundary fault that ruptured during the 2011 Mw 9.0 Tohoku earthquake in the area with the largest fault slip displacement near the Japan trench. Analyses of breakouts observed from borehole C0019B produced postearthquake stress states above the plate boundary fault between the subducting Pacific plate and overriding North American plate. To supplement the lack of stress data below the rupture zone of the earthquake, we conducted core-based three-dimensional stress measurements by the anelastic strain recovery (ASR) method using four whole-round core samples of sediments, of which three samples were located above, but one sample was located below the plate boundary fault in borehole C0019E. As a result of the stress measurements, the postearthquake three-dimensional stress magnitudes at ∼802 and ∼828 meters below seafloor (mbsf) across the plate boundary fault at ∼820 mbsf reveal a normal faulting stress regime. The differences between the three-dimensional intermediate principal stress and the minimum principal stress at the two depths are less than 1 MPa, suggesting a complete release of horizontal tectonic stresses that accumulated before the earthquake. In addition, the maximum horizontal stress S[Hmax] azimuth N115°E at ∼828 mbsf below the plate boundary fault from ASR measurements shows consistency with the S[Hmax] azimuth N139 ± 23°E (mean ± standard deviation) at ∼550–810 mbsf from breakout analyses above the fault. Taken together with the similar stress magnitudes at ∼802 and ∼828 mbsf, we interpret that the postearthquake stress states are almost the same in the sediments above and below the plate boundary fault. In other words, the stress state in terms of both orientation and magnitude is continuous across the fault. At a shallower depth of ∼177 mbsf in the slope sediments, the ASR stress data reveal a

During International Ocean Discovery Program Expedition 392, three sites were drilled on the Agulhas Plateau and one site was drilled in the Transkei Basin in the Southwest Indian Ocean. This region was positioned at paleolatitudes of ~53°–61°S during the Late Cretaceous (van Hinsbergen et al., 2015) (100–66 Ma) and within the new and evolving gateway between the South Atlantic, Southern Ocean, and southern Indian Ocean basins. Recovery of basement rocks and sedimentary sequences from the Agulhas Plateau sites and a thick sedimentary sequence in the Transkei Basin provides a wealth of new data to (1) determine the nature and origin of the Agulhas Plateau; (2) significantly advance the understanding of how Cretaceous temperatures, ocean circulation, and sedimentation patterns evolved as CO2 levels rose and fell and the breakup of Gondwana progressed; (3) document long-term paleoceanographic variability through the Late Cretaceous and Paleogene; and (4) investigate geochemical interactions between igneous rocks, sediments, and pore waters through the life cycle of a large igneous province (LIP). Importantly, postcruise analysis of Expedition 392 drill cores will allow testing of competing hypotheses concerning Agulhas Plateau LIP formation and the role of deep ocean circulation changes through southern gateways in controlling Late Cretaceous–early Paleogene climate evolution.

The Oligocene-Miocene (~34-5 Ma) was likely characterized by globally relatively warm temperatures, high and variable CO2 levels (300-750 ppm) and fluctuating Antarctic ice volumes, and can thus function as a past analogues for future climates, considering the projected atmospheric CO2 concentrations for the end of this century and beyond. Yet, fundamental questions remain about the past Southern Ocean structure and its role in the (in)stability of Antarctic ice-sheets from this critical deep time slice. With my collaborators, in this thesis, I provide this context by reconstructing the latitudinal SST gradients, variability and position of ocean frontal systems and oceanic environmental conditions of Tasmanian Gateway and Drake Passage regions of the Southern Ocean from the Late Eocene until Late Miocene (37-5 Ma) using new TEX86-based SSTs and dinoflagellate cyst assemblage data. By quantifying Oligocene to Miocene oceanic conditions from critical locations around Antarctica we provide new insights for an improved mechanistic understanding of Southern Ocean paleoceanographic evolution. This involves new reconstructions of Southern Ocean circulation and frontal system migrations during past warm Oligocene and Miocene climates, which shows us how the southern polar ocean operates under warmer-than-present-day conditions. The information on Southern Ocean sea surface temperature and ecology/environment provided in this thesis can be used as fundamental boundary condition to improve model simulations and to test the fitness of models simulating past oceanographic conditions.

© The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in D’Angelo, T., Goordial, J., Poulton, N., Seyler, L., Huber, J., Stepanauskas, R., & Orcutt, B. Oceanic crustal fluid single cell genomics complements metagenomic and metatranscriptomic surveys with orders of magnitude less sample volume. Frontiers in Microbiology, 12, (2022): 738231, https://doi.org/10.3389/fmicb.2021.738231., Fluids circulating through oceanic crust play important roles in global biogeochemical cycling mediated by their microbial inhabitants, but studying these sites is challenged by sampling logistics and low biomass. Borehole observatories installed at the North Pond study site on the western flank of the Mid-Atlantic Ridge have enabled investigation of the microbial biosphere in cold, oxygenated basaltic oceanic crust. Here we test a methodology that applies redox-sensitive fluorescent molecules for flow cytometric sorting of cells for single cell genomic sequencing from small volumes of low biomass (approximately 103 cells ml–1) crustal fluid. We compare the resulting genomic data to a recently published paired metagenomic and metatranscriptomic analysis from the same site. Even with low coverage genome sequencing, sorting cells from less than one milliliter of crustal fluid results in similar interpretation of dominant taxa and functional profiles as compared to ‘omics analysis that typically filter orders of magnitude more fluid volume. The diverse community dominated by Gammaproteobacteria, Bacteroidetes, Desulfobacterota, Alphaproteobacteria, and Zetaproteobacteria, had evidence of autotrophy and heterotrophy, a variety of nitrogen and sulfur cycling metabolisms, and motility. Together, results indicate fluorescence activated cell sorting methodology is a powerful addition to the toolbox for the study of low biomass systems or at sites where only small sample volumes are available for analysis., The borehole observatories that form the backbone of this project were funded by the Integrated Ocean Drilling Program (IODP, now the International Ocean Discovery Program), the United States National Science Foundation (NSF), and the Gordon and Betty Moore Foundation (grant GBMF1609). Cruise AT39-01 was funded by the NSF (OCE-1634025 to C. Geoff Wheat). Analyses were funded by the NSF (OCE-1536623 to BO; OIA-1826734 to RS, NP, and BO; and OCE-16435208 and OCE-1745589 to JH), the NSF-funded Center for Dark Energy Biosphere Investigations (C-DEBI) Science and Technology Center (via subawards from OIA-0939564 to BO and JH), and the NASA Exobiology program (80NSSC19K0466 to BO). This is C-DEBI publication 571.

© The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Pieterek, B., Ciazela, J., Boulanger, M., Lazarov, M., Wegorzewski, A., Pańczyk, M., Strauss, H., Dick, H. J. B., Muszyński, A., Koepke, J., Kuhn, T., Czupyt, Z., & France, L. Sulfide enrichment along igneous layer boundaries in the lower oceanic crust: IODP Hole U1473A, Atlantis Bank, Southwest Indian Ridge. Geochimica et Cosmochimica Acta, 320, (2022): 179–206, https://doi.org/10.1016/j.gca.2022.01.004., Reactive porous or focused melt flows are common in crystal mushes of mid-ocean ridge magma reservoirs. Although they exert significant control on mid-ocean ridge magmatic differentiation, their role in metal transport between the mantle and the ocean floor remains poorly constrained. Here we aim to improve such knowledge for oceanic crust formed at slow-spreading centers (approximately half of present-day oceanic crust), by focusing on specific igneous features where sulfides are concentrated. International Ocean Discovery Program (IODP) Expedition 360 drilled Hole U1473A 789 m into the lower crust of the Atlantis Bank oceanic core complex, located at the Southwest Indian Ridge. Coarse-grained (5–30 mm) olivine gabbro prevailed throughout the hole, ranging locally from fine- (<1 mm), to very coarse-grained (>30 mm). We studied three distinct intervals of igneous grain size layering at 109.5–110.8, 158.0–158.3, and 593.0–594.4 meters below seafloor to understand the distribution of sulfides. We found that the layer boundaries between the fine- and coarse-grained gabbro were enriched in sulfides and chalcophile elements. On average, sulfide grains throughout the layering were composed of pyrrhotite (81 vol.%; Fe1-xS), chalcopyrite (16 vol.%; CuFeS2), and pentlandite (3 vol.%; [Ni,Fe,Co]9S8), which reflect paragenesis of magmatic origin. The sulfides were most commonly associated with Fe-Ti oxides (titanomagnetites and ilmenites), amphiboles, and apatites located at the interstitial positions between clinopyroxene, plagioclase, and olivine. Pentlandite exsolution textures in pyrrhotite indicate that the sulfides formed from high-temperature sulfide liquid separated from mafic magma that exsolved upon cooling. The relatively homogenous phase proportion within sulfides along with their chemical and isotopic compositions throughout the studied intervals further support the magmatic origin of sulfide enrichment at the layer boundaries. The studied magmatic layers were lik, This research was funded by National Science Centre Poland (PRELUDIUM 12 no. 2016/23/N/ST10/00288), Graduate Academy of the Leibniz Universität Hannover (60421784), and ECORD Research Grant to J. Ciazela, as well as Deutsche Forschungsgemeinschaft (KO1723/23-1) to J. Koepke and H. Strauss. J. Ciazela is additionally supported within the START program of the Foundation for Polish Science (FNP). This is CRPG contribution No. 2813.

© The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in D’Angelo, T., Goordial, J., Poulton, N., Seyler, L., Huber, J., Stepanauskas, R., & Orcutt, B. Oceanic crustal fluid single cell genomics complements metagenomic and metatranscriptomic surveys with orders of magnitude less sample volume. Frontiers in Microbiology, 12, (2022): 738231, https://doi.org/10.3389/fmicb.2021.738231., Fluids circulating through oceanic crust play important roles in global biogeochemical cycling mediated by their microbial inhabitants, but studying these sites is challenged by sampling logistics and low biomass. Borehole observatories installed at the North Pond study site on the western flank of the Mid-Atlantic Ridge have enabled investigation of the microbial biosphere in cold, oxygenated basaltic oceanic crust. Here we test a methodology that applies redox-sensitive fluorescent molecules for flow cytometric sorting of cells for single cell genomic sequencing from small volumes of low biomass (approximately 103 cells ml–1) crustal fluid. We compare the resulting genomic data to a recently published paired metagenomic and metatranscriptomic analysis from the same site. Even with low coverage genome sequencing, sorting cells from less than one milliliter of crustal fluid results in similar interpretation of dominant taxa and functional profiles as compared to ‘omics analysis that typically filter orders of magnitude more fluid volume. The diverse community dominated by Gammaproteobacteria, Bacteroidetes, Desulfobacterota, Alphaproteobacteria, and Zetaproteobacteria, had evidence of autotrophy and heterotrophy, a variety of nitrogen and sulfur cycling metabolisms, and motility. Together, results indicate fluorescence activated cell sorting methodology is a powerful addition to the toolbox for the study of low biomass systems or at sites where only small sample volumes are available for analysis., The borehole observatories that form the backbone of this project were funded by the Integrated Ocean Drilling Program (IODP, now the International Ocean Discovery Program), the United States National Science Foundation (NSF), and the Gordon and Betty Moore Foundation (grant GBMF1609). Cruise AT39-01 was funded by the NSF (OCE-1634025 to C. Geoff Wheat). Analyses were funded by the NSF (OCE-1536623 to BO; OIA-1826734 to RS, NP, and BO; and OCE-16435208 and OCE-1745589 to JH), the NSF-funded Center for Dark Energy Biosphere Investigations (C-DEBI) Science and Technology Center (via subawards from OIA-0939564 to BO and JH), and the NASA Exobiology program (80NSSC19K0466 to BO). This is C-DEBI publication 571.

Reactive porous or focused melt flows are common in crystal mushes of mid-ocean ridge magma reservoirs. Although they exert significant control on mid-ocean ridge magmatic differentiation, their role in metal transport between the mantle and the ocean floor remains poorly constrained. Here we aim to improve such knowledge for oceanic crust formed at slow-spreading centers (approximately half of present-day oceanic crust), by focusing on specific igneous features where sulfides are concentrated. International Ocean Discovery Program (IODP) Expedition 360 drilled Hole U1473A 789 m into the lower crust of the Atlantis Bank oceanic core complex, located at the Southwest Indian Ridge. Coarse-grained (5–30 mm) olivine gabbro prevailed throughout the hole, ranging locally from fine- (<1 mm), to very coarse-grained (>30 mm). We studied three distinct intervals of igneous grain size layering at 109.5–110.8, 158.0–158.3, and 593.0–594.4 meters below seafloor to understand the distribution of sulfides. We found that the layer boundaries between the fine- and coarse-grained gabbro were enriched in sulfides and chalcophile elements. On average, sulfide grains throughout the layering were composed of pyrrhotite (81 vol.%; Fe1-xS), chalcopyrite (16 vol.%; CuFeS2), and pentlandite (3 vol.%; [Ni,Fe,Co]9S8), which reflect paragenesis of magmatic origin. The sulfides were most commonly associated with Fe-Ti oxides (titanomagnetites and ilmenites), amphiboles, and apatites located at the interstitial positions between clinopyroxene, plagioclase, and olivine. Pentlandite exsolution textures in pyrrhotite indicate that the sulfides formed from high-temperature sulfide liquid separated from mafic magma that exsolved upon cooling. The relatively homogenous phase proportion within sulfides along with their chemical and isotopic compositions throughout the studied intervals further support the magmatic origin of sulfide enrichment at the layer boundaries. The studied magmatic layers were lik

Ice loss in the Southern Hemisphere has been greatest over the past 30 years in West Antarctica. The high sensitivity of this region to climate change has motivated geologists to examine marine sedimentary records for evidence of past episodes of West Antarctic Ice Sheet (WAIS) instability. Sediments accumulating in the Scotia Sea are useful to examine for this purpose because they receive iceberg-rafted debris (IBRD) sourced from the Pacific- and Atlantic-facing sectors of West Antarctica. Here we report on the sedimentology and provenance of the oldest of three cm-scale coarse-grained layers recovered from this sea at International Ocean Discovery Program Site U1538. These layers are preserved in opal-rich sediments deposited ∼1.2 Ma during a relatively warm regional climate. Our microCT-based analysis of the layer's in-situ fabric confirms its ice-rafted origin. We further infer that it is the product of an intense but short-lived episode of IBRD deposition. Based on the petrography of its sand fraction and the Phanerozoic 40Ar/39Ar ages of hornblende and mica it contains, we conclude that the IBRD it contains was likely sourced from the Weddell Sea and/or Amundsen Sea embayment(s) of West Antarctica. We attribute the high concentrations of IBRD in these layers to "dirty" icebergs calved from the WAIS following its retreat inland from its modern grounding line. These layers also sit at the top of a ∼366-m thick Pliocene and early Pleistocene sequence that is much more dropstone-rich than its overlying sediments. We speculate this fact may reflect that WAIS mass-balance was highly dynamic during the ∼41-kyr (inter)glacial world.

Reactive porous or focused melt flows are common in crystal mushes of mid-ocean ridge magma reservoirs. Although they exert significant control on mid-ocean ridge magmatic differentiation, their role in metal transport between the mantle and the ocean floor remains poorly constrained. Here we aim to improve such knowledge for oceanic crust formed at slow-spreading centers (approximately half of present-day oceanic crust), by focusing on specific igneous features where sulfides are concentrated. International Ocean Discovery Program (IODP) Expedition 360 drilled Hole U1473A 789 m into the lower crust of the Atlantis Bank oceanic core complex, located at the Southwest Indian Ridge. Coarse-grained (5–30 mm) olivine gabbro prevailed throughout the hole, ranging locally from fine- (<1 mm), to very coarse-grained (>30 mm). We studied three distinct intervals of igneous grain size layering at 109.5–110.8, 158.0–158.3, and 593.0–594.4 meters below seafloor to understand the distribution of sulfides. We found that the layer boundaries between the fine- and coarse-grained gabbro were enriched in sulfides and chalcophile elements. On average, sulfide grains throughout the layering were composed of pyrrhotite (81 vol.%; Fe1-xS), chalcopyrite (16 vol.%; CuFeS2), and pentlandite (3 vol.%; [Ni,Fe,Co]9S8), which reflect paragenesis of magmatic origin. The sulfides were most commonly associated with Fe-Ti oxides (titanomagnetites and ilmenites), amphiboles, and apatites located at the interstitial positions between clinopyroxene, plagioclase, and olivine. Pentlandite exsolution textures in pyrrhotite indicate that the sulfides formed from high-temperature sulfide liquid separated from mafic magma that exsolved upon cooling. The relatively homogenous phase proportion within sulfides along with their chemical and isotopic compositions throughout the studied intervals further support the magmatic origin of sulfide enrichment at the layer boundaries. The studied magmatic layers we

The equatorial eastern Indian Ocean hosts a diffuse plate boundary, where widespread deformation accommodates the relative motion between the Indian, Australian and Capricorn sub-plates. We integrate IODP Expedition 362 borehole data, which for the first time provides an accurate, ground-truthed chronostratigraphy of the sedimentary sequence east of the Ninety East Ridge (NER), with 2D seismic reflection profiles and multibeam bathymetry to assess the styles of faulting between the NER and the Sunda subduction zone, timing of activity and comparison with physical and rheological properties. We identify four distinct fault sets east of the NER in the northern Wharton Basin. N-S (350-010°) orientated faults, associated with the N-S fracture zones formed at the now extinct Wharton spreading centre, are still active and have been continuously active since at least 10 Ma. NNE- and WNW-trending fault fabrics develop between the fracture zones. The orientations and likely sense of displacement on these three sets of faults defines a Riedel shear system responding to ∼NNE-SSW left-lateral strike-slip activity at depth, demonstrated by the recent 2012 great intraplate earthquakes. We also find evidence of ∼NE-SW reverse faults, similar in style to E-W reverse faults observed west of the NER, where reverse faulting is more dominant. We show that the activity of this strike-slip system increased ca. 7-9 Ma, contemporaneous with reverse faulting and intraplate deformation west of the NER.

Pre-Quaternary paleoclimate studies in Australia mainly focus on terrestrial records from the southeastern part of the continent. IODP Expedition 356 drilled on the northwestern Australian shelf, yielding Miocene-Pleistocene paleoclimate records in an area where climate archives are scarce. Postexpedition research revealed a dry-to-humid transition across the latest Miocene and early Pliocene (start of the "Humid Interval"). However, the complex tectonic history of the area makes these interpretations challenging. In this study, we investigate late Miocene to early Pliocene sediment cores from two sites that are only 100 km apart but situated in two adjacent basins (Northern Carnarvon and Roebuck Basins). Combining lithofacies study, time series analysis of potassium content (K wt%), and calcareous nannofossil abundance counts (N/g), this work disentangles the complex interplay between basin evolution and climate change between 6.1 and 4 Ma. Overall, the investigated proxies show high correlation between both sites, except during 6.1-5.7 Ma. During this interval, Site U1463 records a gradual increase in K wt%, correlated with basin deepening, whereas Site U1464 records an abrupt rise in K wt% at similar to 6 Ma. We explain this diachronicity by differential basin subsidence. The tectonic interplay with our paleorecords makes it difficult to pinpoint the exact onset of the "Humid Interval," but we conclude that K wt% and coccolith abundances at Site U1464 indicate that a fluvial deposition system was already established since at least 6 Ma. This age is consistent with data supporting a southward movement of the Intertropical Convergence Zone rain belt at similar to 7 Ma.

Paper I Pre-Quaternary paleoclimate studies in Australia mainly focus on terrestrial records from the southeastern part of the continent. IODP Expedition 356 drilled on the northwestern Australian shelf, yielding Miocene-Pleistocene paleoclimate records in an area where climate archives are scarce. Post-expedition research revealed a dry-to–humid transition across the latest Miocene and early Pliocene (start of the “Humid Interval”). However, the complex tectonic history of the area makes these interpretations challenging. In this study, we investigate late Miocene to early Pliocene sediment cores from two sites that are only 100 km apart, but situated in two adjacent basins (Northern Carnarvon and Roebuck Basins). Combining lithofacies study, time-series analysis of potassium content (K wt%) and calcareous nannofossil abundance counts (N/g), this work disentangles the complex interplay between basin evolution and climate change between 6.1-4 million years ago (Ma). Overall, the investigated proxies show high correlation between both sites, except during 6.1-5.7 Ma. During this latest Miocene interval, Site U1463 records a gradual increase in K wt%, correlated with basin deepening, whereas Site U1464 records an abrupt rise in K wt% at ~6 Ma. We explain this diachronicity by differential basin subsidence. The tectonic interplay with our paleorecords makes it difficult to pinpoint the exact onset of the “Humid Interval”, but we conclude that high K wt% and coccolith abundances at Site U1464 indicate that humidity was already enhanced since at least 6 Ma. This age is consistent with data supporting a southward movement of the Intertropical Convergence Zone rain belt at ~7 Ma. Paper II The early Pliocene was a warm period with increased ocean primary productivity, as part of a global paleoceanographic event called the late Miocene-early Pliocene biogenic bloom (~9-3.5 Ma). Many tectonic and paleoclimatic mechanisms, mainly linked to an increase and redistribution of nut

Pre-Quaternary paleoclimate studies in Australia mainly focus on terrestrial records from the southeastern part of the continent. IODP Expedition 356 drilled on the northwestern Australian shelf, yielding Miocene-Pleistocene paleoclimate records in an area where climate archives are scarce. Postexpedition research revealed a dry-to-humid transition across the latest Miocene and early Pliocene (start of the "Humid Interval"). However, the complex tectonic history of the area makes these interpretations challenging. In this study, we investigate late Miocene to early Pliocene sediment cores from two sites that are only 100 km apart but situated in two adjacent basins (Northern Carnarvon and Roebuck Basins). Combining lithofacies study, time series analysis of potassium content (K wt%), and calcareous nannofossil abundance counts (N/g), this work disentangles the complex interplay between basin evolution and climate change between 6.1 and 4 Ma. Overall, the investigated proxies show high correlation between both sites, except during 6.1-5.7 Ma. During this interval, Site U1463 records a gradual increase in K wt%, correlated with basin deepening, whereas Site U1464 records an abrupt rise in K wt% at similar to 6 Ma. We explain this diachronicity by differential basin subsidence. The tectonic interplay with our paleorecords makes it difficult to pinpoint the exact onset of the "Humid Interval," but we conclude that K wt% and coccolith abundances at Site U1464 indicate that a fluvial deposition system was already established since at least 6 Ma. This age is consistent with data supporting a southward movement of the Intertropical Convergence Zone rain belt at similar to 7 Ma.

Pre-Quaternary paleoclimate studies in Australia mainly focus on terrestrial records from the southeastern part of the continent. IODP Expedition 356 drilled on the northwestern Australian shelf, yielding Miocene-Pleistocene paleoclimate records in an area where climate archives are scarce. Postexpedition research revealed a dry-to-humid transition across the latest Miocene and early Pliocene (start of the "Humid Interval"). However, the complex tectonic history of the area makes these interpretations challenging. In this study, we investigate late Miocene to early Pliocene sediment cores from two sites that are only 100 km apart but situated in two adjacent basins (Northern Carnarvon and Roebuck Basins). Combining lithofacies study, time series analysis of potassium content (K wt%), and calcareous nannofossil abundance counts (N/g), this work disentangles the complex interplay between basin evolution and climate change between 6.1 and 4 Ma. Overall, the investigated proxies show high correlation between both sites, except during 6.1-5.7 Ma. During this interval, Site U1463 records a gradual increase in K wt%, correlated with basin deepening, whereas Site U1464 records an abrupt rise in K wt% at similar to 6 Ma. We explain this diachronicity by differential basin subsidence. The tectonic interplay with our paleorecords makes it difficult to pinpoint the exact onset of the "Humid Interval," but we conclude that K wt% and coccolith abundances at Site U1464 indicate that a fluvial deposition system was already established since at least 6 Ma. This age is consistent with data supporting a southward movement of the Intertropical Convergence Zone rain belt at similar to 7 Ma.

In the IODP 372A proposal, working hypotheses used with respect to actively deforming gas hydrate‐bearing landslides were based on an initial calculation considering gas hydrate to occur in fresh water. This initial inaccuracy leads to predict the base of methane hydrate stability zone (MHSZ) to be at around 162 meters below the seafloor (mbsf) at site U1517 while it is expected to be between 85 and 128 mbsf. It is most interesting that important negative chloride anomalies were measured well below the theoretical MHSZ without direct evidence of the presence of gas hydrate. These anomalies are usually a strong indication of gas hydrate occurrence. This initial inaccurate hypothesis provides the opportunity to evaluate the effectiveness of the indirect salinity detection method to quantify gas hydrate.

The equatorial eastern Indian Ocean hosts a diffuse plate boundary, where widespread deformation accommodates the relative motion between the Indian, Australian and Capricorn sub-plates. We integrate IODP Expedition 362 borehole data, which for the first time provides an accurate, ground-truthed chronostratigraphy of the sedimentary sequence east of the Ninety East Ridge (NER), with 2D seismic reflection profiles and multibeam bathymetry to assess the styles of faulting between the NER and the Sunda subduction zone, timing of activity and comparison with physical and rheological properties. We identify four distinct fault sets east of the NER in the northern Wharton Basin. N-S (350-010°) orientated faults, associated with the N-S fracture zones formed at the now extinct Wharton spreading centre, are still active and have been continuously active since at least 10 Ma. NNE- and WNW-trending fault fabrics develop between the fracture zones. The orientations and likely sense of displacement on these three sets of faults defines a Riedel shear system responding to ∼NNE-SSW left-lateral strike-slip activity at depth, demonstrated by the recent 2012 great intraplate earthquakes. We also find evidence of ∼NE-SW reverse faults, similar in style to E-W reverse faults observed west of the NER, where reverse faulting is more dominant. We show that the activity of this strike-slip system increased ca. 7-9 Ma, contemporaneous with reverse faulting and intraplate deformation west of the NER.

Northern Zealandia lies between Australia, New Zealandia, and New Caledonia. It has an area of 3,000,000 km2 and is made up of bathymetric rises and troughs with typical water depths of 1000 to 4000 m. I use 39,309 line km of seismic-reflection profiles tied to recent International Ocean Discovery Program (IODP) drilling and three boreholes near the coast of New Zealand to investigate stratigraphic architecture and assess the petroleum prospectivity of northern Zealandia. Sparse sampling requires that stratigraphic and petroleum prospectivity inferences are drawn from better-known basins in New Zealand, Australia, New Caledonia, TimorLeste and Papua New Guinea. Five existing seismic-stratigraphic units are reviewed. Zealandia Seismic Unit U3 is sampled near New Zealand and may contain Jurassic Muhiriku Group coals. Elsewhere, Seismic Unit 3 may have oil-prone equivalents of the Jurassic Walloon Coal Measure in eastern Australia; or may contain Triassic-Jurassic marine source rocks, as found in offshore Bonaparte Basin, onshore Timor-Leste, and the Papuan Basin in Papua New Guinea. Seismic Unit U2b (Mid-Cretaceous) is syn-rift and may contain coal measures, as found in Taranaki-Aotea Basin and New Caledonia. Seismic Unit U2a (Late Cretaceous to Eocene) contains coaly source rocks in the southeastern part of the study area, and may also contain marine equivalent carbonaceous mudstone, as found at Site IODP U1509. Unit U2a is transgressive, with coaly source rocks and reservoir sandstones near its base, and clay, marl and chalk above that provides a regional seal. Seismic Unit U1b (Eocene-Oligocene) is mass-transport complexes and basin floor fans related to a brief phase of convergent deformation that created folds in the southern part of the study area and regionally uplifted ridges to create new sediment source areas. Basin floor fans may contain reservoir rock and Eocene folding created structural traps. Seismic Unit U1a is Oligocene and Neogene chalk, calcareous o

Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 21(3), (2020): e2019GC008847, doi:10.1029/2019GC008847., To learn more about magnetic properties of the lower ocean crust and its contributions to marine magnetic anomalies, gabbro samples were collected from International Ocean Discovery Program Hole U1473A at Atlantis Bank on the Southwest Indian Ridge. Detailed magnetic property work links certain magnetic behaviors and domain states to specific magnetic mineral populations. Measurements on whole rocks and mineral separates included magnetic hysteresis, first‐order reversal curves, low‐temperature remanence measurements, thermomagnetic analysis, and magnetic force microscopy. Characteristics of the thermomagnetic data indicate that the upper ~500 m of the hole has undergone hydrothermal alteration. The thermomagnetic and natural remanent magnetization data are consistent with earlier observations from Hole 735B that show remanence arises from low‐Ti magnetite and that natural remanent magnetizations are up to 25 A m−1 in evolved Fe‐Ti oxide gabbros, but are mostly <1 A m−1. Magnetite is present in at least three forms. Primary magnetite is associated with coarse‐grained oxides that are more frequent in the upper part of the hole. This magnetic population is linked to dominantly “pseudo‐single‐domain” behavior that arises from fine‐scale lamellar intergrowths within the large oxides. Deeper in the hole the magnetic signal is more commonly dominated by an interacting single‐domain assemblage most likely found along crystal discontinuities in olivine and/or pyroxene. A third contribution is from noninteracting single‐domain inclusions within plagioclase. Because the concentration of the highly magnetic, oxide‐rich gabbros is greatest toward the surface, the signal from coarse oxides will likely dominate the near‐bottom magnetic anomaly signal at Atlantis Bank., This work used samples and data provided by the International Ocean Discovery Program. Funding was provided by the U.S. Science Support Program (J.B.). I.L. has benefited from a Smithsonian Edward and Helen Hintz Secretarial Scholarship. We thank the members of the IODP Expedition 360 Science Party, and the captain and crew of the JOIDES Resolution. Part of this work was done as a Visiting Fellow at the Institute for Rock Magnetism (IRM) at the University of Minnesota. The IRM is made possible through the Instrumentation and Facilities program of the National Science Foundation, Earth Sciences Division, and by funding from the University of Minnesota. We would like to thank IRM staff M. Jackson, P. Solheid, and D. Bilardello for their generous assistance. Many thanks to A. Butula, K. Vernon, and J. Marquardt for their assistance with rock magnetic measurements at UWM and to L. McHenry for assistance with XRD. We also thank two anonymous reviewers for their thoughtful comments that improved the manuscript. Magnetic data associated with this manuscript are available in the Magnetics Information Consortium (MagIC) database at https://www.earthref.org/MagIC/doi/10.1029/2019GC008847. XRD data are available at https://zenodo.org/record/3611642., 2020-08-28

To learn more about magnetic properties of the lower ocean crust and its contributions to marine magnetic anomalies, gabbro samples were collected from International Ocean Discovery Program Hole U1473A at Atlantis Bank on the Southwest Indian Ridge. Detailed magnetic property work links certain magnetic behaviors and domain states to specific magnetic mineral populations. Measurements on whole rocks and mineral separates included magnetic hysteresis, first‐order reversal curves, low‐temperature remanence measurements, thermomagnetic analysis, and magnetic force microscopy. Characteristics of the thermomagnetic data indicate that the upper ~500 m of the hole has undergone hydrothermal alteration. The thermomagnetic and natural remanent magnetization data are consistent with earlier observations from Hole 735B that show remanence arises from low‐Ti magnetite and that natural remanent magnetizations are up to 25 A m−1 in evolved Fe‐Ti oxide gabbros, but are mostly <1 A m−1. Magnetite is present in at least three forms. Primary magnetite is associated with coarse‐grained oxides that are more frequent in the upper part of the hole. This magnetic population is linked to dominantly “pseudo‐single‐domain” behavior that arises from fine‐scale lamellar intergrowths within the large oxides. Deeper in the hole the magnetic signal is more commonly dominated by an interacting single‐domain assemblage most likely found along crystal discontinuities in olivine and/or pyroxene. A third contribution is from noninteracting single‐domain inclusions within plagioclase. Because the concentration of the highly magnetic, oxide‐rich gabbros is greatest toward the surface, the signal from coarse oxides will likely dominate the near‐bottom magnetic anomaly signal at Atlantis Bank.

Executive summary: The ANZIC Ocean Planet Workshop (14-16 April 2019) and focused Working Group sessions represent a multidisciplinary community effort that defines scientific themes and challenges for the next phase of marine research using the capabilities of current and anticipated platforms of the International Ocean Discovery Program (IODP). Attended by 75 mostly early- and mid-career participants from Australia, New Zealand, Japan, and the United States, the workshop featured nine keynote presentations. Working groups identified important themes and challenges that are fundamental to understanding the Earth system. This research relies upon ocean-going research platforms to recover geological, geobiological, and microbiological information preserved in sediment and rock beneath the seafloor and to monitor subseafloor environments through the global ocean. The workshop program was built around five scientific themes: Biosphere Frontiers, Earth Dynamics, Core to Crust, Global Climate, Natural Hazards, and Ocean Health through Time. Workshop sessions focused on these themes and developed 19 associated scientific challenges. Underpinning these are legacy samples and data, technology, engineering, education, public outreach, big data, and societal impact. Although all challenges are important, the asterisks that follow denote those of particular relevance and interest to ANZIC. Ocean Health through Time comprises the ocean’s response to natural perturbations in biogeochemical cycles*; the lateral and vertical influence of human disturbance on the ocean floor; and the drivers and proxies of evolution, extinction, and recovery of life*. Global Climate entails coupling between the climate system and the carbon cycle; the drivers, rates, and magnitudes of sea level change in a dynamic world*; the extremes, variations, drivers, and impacts of Earth’s hydrologic cycle*; and cryosphere dynamics*. Biosphere Frontiers addresses the habitable limits for life*; the compositio

In the IODP 372A proposal, working hypotheses used with respect to actively deforming gas hydrate‐bearing landslides were based on an initial calculation considering gas hydrate to occur in fresh water. This initial inaccuracy leads to predict the base of methane hydrate stability zone (MHSZ) to be at around 162 meters below the seafloor (mbsf) at site U1517 while it is expected to be between 85 and 128 mbsf. It is most interesting that important negative chloride anomalies were measured well below the theoretical MHSZ without direct evidence of the presence of gas hydrate. These anomalies are usually a strong indication of gas hydrate occurrence. This initial inaccurate hypothesis provides the opportunity to evaluate the effectiveness of the indirect salinity detection method to quantify gas hydrate.

The equatorial eastern Indian Ocean hosts a diffuse plate boundary, where widespread deformation accommodates the relative motion between the Indian, Australian and Capricorn sub-plates. We integrate IODP Expedition 362 borehole data, which for the first time provides an accurate, ground-truthed chronostratigraphy of the sedimentary sequence east of the Ninety East Ridge (NER), with 2D seismic reflection profiles and multibeam bathymetry to assess the styles of faulting between the NER and the Sunda subduction zone, timing of activity and comparison with physical and rheological properties. We identify four distinct fault sets east of the NER in the northern Wharton Basin. N-S (350-010°) orientated faults, associated with the N-S fracture zones formed at the now extinct Wharton spreading centre, are still active and have been continuously active since at least 10 Ma. NNE- and WNW-trending fault fabrics develop between the fracture zones. The orientations and likely sense of displacement on these three sets of faults defines a Riedel shear system responding to ∼NNE-SSW left-lateral strike-slip activity at depth, demonstrated by the recent 2012 great intraplate earthquakes. We also find evidence of ∼NE-SW reverse faults, similar in style to E-W reverse faults observed west of the NER, where reverse faulting is more dominant. We show that the activity of this strike-slip system increased ca. 7-9 Ma, contemporaneous with reverse faulting and intraplate deformation west of the NER.

Northern Zealandia lies between Australia, New Zealandia, and New Caledonia. It has an area of 3,000,000 km2 and is made up of bathymetric rises and troughs with typical water depths of 1000 to 4000 m. I use 39,309 line km of seismic-reflection profiles tied to recent International Ocean Discovery Program (IODP) drilling and three boreholes near the coast of New Zealand to investigate stratigraphic architecture and assess the petroleum prospectivity of northern Zealandia. Sparse sampling requires that stratigraphic and petroleum prospectivity inferences are drawn from better-known basins in New Zealand, Australia, New Caledonia, TimorLeste and Papua New Guinea. Five existing seismic-stratigraphic units are reviewed. Zealandia Seismic Unit U3 is sampled near New Zealand and may contain Jurassic Muhiriku Group coals. Elsewhere, Seismic Unit 3 may have oil-prone equivalents of the Jurassic Walloon Coal Measure in eastern Australia; or may contain Triassic-Jurassic marine source rocks, as found in offshore Bonaparte Basin, onshore Timor-Leste, and the Papuan Basin in Papua New Guinea. Seismic Unit U2b (Mid-Cretaceous) is syn-rift and may contain coal measures, as found in Taranaki-Aotea Basin and New Caledonia. Seismic Unit U2a (Late Cretaceous to Eocene) contains coaly source rocks in the southeastern part of the study area, and may also contain marine equivalent carbonaceous mudstone, as found at Site IODP U1509. Unit U2a is transgressive, with coaly source rocks and reservoir sandstones near its base, and clay, marl and chalk above that provides a regional seal. Seismic Unit U1b (Eocene-Oligocene) is mass-transport complexes and basin floor fans related to a brief phase of convergent deformation that created folds in the southern part of the study area and regionally uplifted ridges to create new sediment source areas. Basin floor fans may contain reservoir rock and Eocene folding created structural traps. Seismic Unit U1a is Oligocene and Neogene chalk, calcareous o

Pre-Quaternary paleoclimate studies in Australia mainly focus on terrestrial records from the southeastern part of the continent. IODP Expedition 356 drilled on the northwestern Australian shelf, yielding Miocene-Pleistocene paleoclimate records in an area where climate archives are scarce. Postexpedition research revealed a dry-to-humid transition across the latest Miocene and early Pliocene (start of the "Humid Interval"). However, the complex tectonic history of the area makes these interpretations challenging. In this study, we investigate late Miocene to early Pliocene sediment cores from two sites that are only 100 km apart but situated in two adjacent basins (Northern Carnarvon and Roebuck Basins). Combining lithofacies study, time series analysis of potassium content (K wt%), and calcareous nannofossil abundance counts (N/g), this work disentangles the complex interplay between basin evolution and climate change between 6.1 and 4 Ma. Overall, the investigated proxies show high correlation between both sites, except during 6.1-5.7 Ma. During this interval, Site U1463 records a gradual increase in K wt%, correlated with basin deepening, whereas Site U1464 records an abrupt rise in K wt% at similar to 6 Ma. We explain this diachronicity by differential basin subsidence. The tectonic interplay with our paleorecords makes it difficult to pinpoint the exact onset of the "Humid Interval," but we conclude that K wt% and coccolith abundances at Site U1464 indicate that a fluvial deposition system was already established since at least 6 Ma. This age is consistent with data supporting a southward movement of the Intertropical Convergence Zone rain belt at similar to 7 Ma.

Northern Zealandia lies between Australia, New Zealandia, and New Caledonia. It has an area of 3,000,000 km2 and is made up of bathymetric rises and troughs with typical water depths of 1000 to 4000 m. I use 39,309 line km of seismic-reflection profiles tied to recent International Ocean Discovery Program (IODP) drilling and three boreholes near the coast of New Zealand to investigate stratigraphic architecture and assess the petroleum prospectivity of northern Zealandia. Sparse sampling requires that stratigraphic and petroleum prospectivity inferences are drawn from better-known basins in New Zealand, Australia, New Caledonia, TimorLeste and Papua New Guinea. Five existing seismic-stratigraphic units are reviewed. Zealandia Seismic Unit U3 is sampled near New Zealand and may contain Jurassic Muhiriku Group coals. Elsewhere, Seismic Unit 3 may have oil-prone equivalents of the Jurassic Walloon Coal Measure in eastern Australia; or may contain Triassic-Jurassic marine source rocks, as found in offshore Bonaparte Basin, onshore Timor-Leste, and the Papuan Basin in Papua New Guinea. Seismic Unit U2b (Mid-Cretaceous) is syn-rift and may contain coal measures, as found in Taranaki-Aotea Basin and New Caledonia. Seismic Unit U2a (Late Cretaceous to Eocene) contains coaly source rocks in the southeastern part of the study area, and may also contain marine equivalent carbonaceous mudstone, as found at Site IODP U1509. Unit U2a is transgressive, with coaly source rocks and reservoir sandstones near its base, and clay, marl and chalk above that provides a regional seal. Seismic Unit U1b (Eocene-Oligocene) is mass-transport complexes and basin floor fans related to a brief phase of convergent deformation that created folds in the southern part of the study area and regionally uplifted ridges to create new sediment source areas. Basin floor fans may contain reservoir rock and Eocene folding created structural traps. Seismic Unit U1a is Oligocene and Neogene chalk, calcareous o

Northern Zealandia lies between Australia, New Zealandia, and New Caledonia. It has an area of 3,000,000 km2 and is made up of bathymetric rises and troughs with typical water depths of 1000 to 4000 m. I use 39,309 line km of seismic-reflection profiles tied to recent International Ocean Discovery Program (IODP) drilling and three boreholes near the coast of New Zealand to investigate stratigraphic architecture and assess the petroleum prospectivity of northern Zealandia. Sparse sampling requires that stratigraphic and petroleum prospectivity inferences are drawn from better-known basins in New Zealand, Australia, New Caledonia, TimorLeste and Papua New Guinea. Five existing seismic-stratigraphic units are reviewed. Zealandia Seismic Unit U3 is sampled near New Zealand and may contain Jurassic Muhiriku Group coals. Elsewhere, Seismic Unit 3 may have oil-prone equivalents of the Jurassic Walloon Coal Measure in eastern Australia; or may contain Triassic-Jurassic marine source rocks, as found in offshore Bonaparte Basin, onshore Timor-Leste, and the Papuan Basin in Papua New Guinea. Seismic Unit U2b (Mid-Cretaceous) is syn-rift and may contain coal measures, as found in Taranaki-Aotea Basin and New Caledonia. Seismic Unit U2a (Late Cretaceous to Eocene) contains coaly source rocks in the southeastern part of the study area, and may also contain marine equivalent carbonaceous mudstone, as found at Site IODP U1509. Unit U2a is transgressive, with coaly source rocks and reservoir sandstones near its base, and clay, marl and chalk above that provides a regional seal. Seismic Unit U1b (Eocene-Oligocene) is mass-transport complexes and basin floor fans related to a brief phase of convergent deformation that created folds in the southern part of the study area and regionally uplifted ridges to create new sediment source areas. Basin floor fans may contain reservoir rock and Eocene folding created structural traps. Seismic Unit U1a is Oligocene and Neogene chalk, calcareous o

In the IODP 372A proposal, working hypotheses used with respect to actively deforming gas hydrate‐bearing landslides were based on an initial calculation considering gas hydrate to occur in fresh water. This initial inaccuracy leads to predict the base of methane hydrate stability zone (MHSZ) to be at around 162 meters below the seafloor (mbsf) at site U1517 while it is expected to be between 85 and 128 mbsf. It is most interesting that important negative chloride anomalies were measured well below the theoretical MHSZ without direct evidence of the presence of gas hydrate. These anomalies are usually a strong indication of gas hydrate occurrence. This initial inaccurate hypothesis provides the opportunity to evaluate the effectiveness of the indirect salinity detection method to quantify gas hydrate.

The equatorial eastern Indian Ocean hosts a diffuse plate boundary, where widespread deformation accommodates the relative motion between the Indian, Australian and Capricorn sub-plates. We integrate IODP Expedition 362 borehole data, which for the first time provides an accurate, ground-truthed chronostratigraphy of the sedimentary sequence east of the Ninety East Ridge (NER), with 2D seismic reflection profiles and multibeam bathymetry to assess the styles of faulting between the NER and the Sunda subduction zone, timing of activity and comparison with physical and rheological properties. We identify four distinct fault sets east of the NER in the northern Wharton Basin. N-S (350-010°) orientated faults, associated with the N-S fracture zones formed at the now extinct Wharton spreading centre, are still active and have been continuously active since at least 10 Ma. NNE- and WNW-trending fault fabrics develop between the fracture zones. The orientations and likely sense of displacement on these three sets of faults defines a Riedel shear system responding to ∼NNE-SSW left-lateral strike-slip activity at depth, demonstrated by the recent 2012 great intraplate earthquakes. We also find evidence of ∼NE-SW reverse faults, similar in style to E-W reverse faults observed west of the NER, where reverse faulting is more dominant. We show that the activity of this strike-slip system increased ca. 7-9 Ma, contemporaneous with reverse faulting and intraplate deformation west of the NER.

Paper I Pre-Quaternary paleoclimate studies in Australia mainly focus on terrestrial records from the southeastern part of the continent. IODP Expedition 356 drilled on the northwestern Australian shelf, yielding Miocene-Pleistocene paleoclimate records in an area where climate archives are scarce. Post-expedition research revealed a dry-to–humid transition across the latest Miocene and early Pliocene (start of the “Humid Interval”). However, the complex tectonic history of the area makes these interpretations challenging. In this study, we investigate late Miocene to early Pliocene sediment cores from two sites that are only 100 km apart, but situated in two adjacent basins (Northern Carnarvon and Roebuck Basins). Combining lithofacies study, time-series analysis of potassium content (K wt%) and calcareous nannofossil abundance counts (N/g), this work disentangles the complex interplay between basin evolution and climate change between 6.1-4 million years ago (Ma). Overall, the investigated proxies show high correlation between both sites, except during 6.1-5.7 Ma. During this latest Miocene interval, Site U1463 records a gradual increase in K wt%, correlated with basin deepening, whereas Site U1464 records an abrupt rise in K wt% at ~6 Ma. We explain this diachronicity by differential basin subsidence. The tectonic interplay with our paleorecords makes it difficult to pinpoint the exact onset of the “Humid Interval”, but we conclude that high K wt% and coccolith abundances at Site U1464 indicate that humidity was already enhanced since at least 6 Ma. This age is consistent with data supporting a southward movement of the Intertropical Convergence Zone rain belt at ~7 Ma. Paper II The early Pliocene was a warm period with increased ocean primary productivity, as part of a global paleoceanographic event called the late Miocene-early Pliocene biogenic bloom (~9-3.5 Ma). Many tectonic and paleoclimatic mechanisms, mainly linked to an increase and redistribution of nut

Pre-Quaternary paleoclimate studies in Australia mainly focus on terrestrial records from the southeastern part of the continent. IODP Expedition 356 drilled on the northwestern Australian shelf, yielding Miocene-Pleistocene paleoclimate records in an area where climate archives are scarce. Postexpedition research revealed a dry-to-humid transition across the latest Miocene and early Pliocene (start of the "Humid Interval"). However, the complex tectonic history of the area makes these interpretations challenging. In this study, we investigate late Miocene to early Pliocene sediment cores from two sites that are only 100 km apart but situated in two adjacent basins (Northern Carnarvon and Roebuck Basins). Combining lithofacies study, time series analysis of potassium content (K wt%), and calcareous nannofossil abundance counts (N/g), this work disentangles the complex interplay between basin evolution and climate change between 6.1 and 4 Ma. Overall, the investigated proxies show high correlation between both sites, except during 6.1-5.7 Ma. During this interval, Site U1463 records a gradual increase in K wt%, correlated with basin deepening, whereas Site U1464 records an abrupt rise in K wt% at similar to 6 Ma. We explain this diachronicity by differential basin subsidence. The tectonic interplay with our paleorecords makes it difficult to pinpoint the exact onset of the "Humid Interval," but we conclude that K wt% and coccolith abundances at Site U1464 indicate that a fluvial deposition system was already established since at least 6 Ma. This age is consistent with data supporting a southward movement of the Intertropical Convergence Zone rain belt at similar to 7 Ma.

Recognition of coring-induced disturbance, which is essential for magnetic fabric and paleomagnetic studies of poorly lithified sediments, is generally not straightforward. Here, we report on anisotropy of magnetic susceptibility (AMS) and paleomagnetic data of the sediments from Holes U1480E and U1480H, IODP Expedition 362, west of the Sumatra subduction zone. AMS is characterized by steep minimum principal axes (Kmin) in undisturbed sediments. However, a considerable portion of the recovered sediments are affected by significant coring-induced disturbance. In these cases, we observed three AMS patterns: (1) AMS principal axes are randomly distributed for sediments with mingling and distortion of beds, (2) Kmin axes of sediments with upward-arching beds are deflected out of the splitting face of the working half, and (3) suck-in sediments are characterized by vertical Kmax axes. These deformation-dependent AMS patterns can be attributed to the realignment of mineral particles caused by the coring process and subsequent sampling procedures. Besides a low-coercivity, vertical, drilling-induced overprint, we observed a high-coercivity component that is likely a composite of the primary magnetization with a demagnetization-resistant portion of the drilling overprint. After accounting for the disturbed intervals, several polarity transitions can be identified in the undisturbed sediments which correlate well with the Pleistocene geomagnetic polarity timescale. These observations demonstrate that great caution is required when attributing geological significance to AMS and paleomagnetic data obtained from soft sediment cores, which are highly susceptible to coring-induced disturbance. In addition, AMS measurements provide a potential tool for identifying core deformation for further paleomagnetic studies.

The marine-based West Antarctic Ice Sheet (WAIS) is currently locally retreating because of shifting wind-driven oceanic currents that transport warm waters toward the ice margin, resulting in ice shelf thinning and accelerated mass loss. Previous results from geologic drilling on Antarctica’s continental margins show significant variability in ice sheet extent during the late Neogene and Quaternary. Climate and ice sheet models indicate a fundamental role for oceanic heat in controlling ice sheet variability over at least the past 20 My. Although evidence for past ice sheet variability is available from ice-proximal marine settings, sedimentary sequences from the continental shelf and rise are required to evaluate the extent of past ice sheet variability and the associated forcings and feedbacks. International Ocean Discovery Program Expedition 374 drilled a latitudinal and depth transect of five sites from the outer continental shelf to rise in the central Ross Sea to resolve Neogene and Quaternary relationships between climatic and oceanic change and WAIS evolution. The Ross Sea was targeted because numerical ice sheet models indicate that this sector of Antarctica responds sensitively to changes in ocean heat flux. Expedition 374 was designed for optimal data-model integration to enable an improved understanding of Antarctic Ice Sheet (AIS) mass balance during warmer-than-present climates (e.g., the Pleistocene “super interglacials,” the mid-Pliocene, and the Miocene Climatic Optimum). The principal goals of Expedition 374 were to Evaluate the contribution of West Antarctica to far-field ice volume and sea level estimates; Reconstruct ice-proximal oceanic and atmospheric temperatures to quantify past polar amplification; Assess the role of oceanic forcing (e.g., temperature and sea level) on AIS variability; Identify the sensitivity of the AIS to Earth’s orbital configuration under a variety of climate boundary conditions; and Reconstruc

This dissertation, as indicated by its title, is eclectic, but is united around the theme of developing and applying new geochemical approaches to answer large-scale questions in earth science. And it represents an interdisciplinary contribution, drawing on paleobiology, paleoclimate and paleoceanography as well as incorporating near surface and deep earth seismic models and signal analysis techniques to expand the range of conclusions that can be extracted from large geochemical datasets. The first two chapters focus on the marine biosphere in the geologic past. Chapter 1 presents a new high-throughput method for establishing paleo export productivity as well as evidence that increased supply of Southern Ocean water masses during glacial intervals stimulated productivity off the coast of East Africa. The method presented in Chapter 1 enabled Chapter 2, in which an unprecedented global view of marine productivity reveals a global biological “heartbeat”: marine productivity varies at the same frequencies as Earth’s orbital obliquity and precession, indicating a fundamental link between astronomical and biological processes. Chapters 3 and 4 explore the information contained in the carbon in marine sediments to better constrain the amount and form of C subducting along the Sunda margin, Indonesia and to infer a multi-phased expansion of C4 grasslands on the Indian subcontinent, indicating punctuated episodes of aridification. The final chapter traces the He isotope signature of a mantle plume from the core-mantle boundary to elucidate the processes involved in forming and sustaining continental rifting in Ethiopia and Afar. The breadth of topics covered here reflects the range of my own curiosity in pursuing what Nietzsche termed fröliche wissenschaft – joyful science.

© The Author(s), 2018. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Nguyen, D. K., Morishita, T., Soda, Y., Tamura, A., Ghosh, B., Harigane, Y., France, L., Liu, C., Natland, J. H., Sanfilippo, A., MacLeod, C. J., Blum, P., & Dick, H. J. B. (2018). Occurrence of felsic rocks in oceanic gabbros from IODP hole U1473A: Implications for evolved melt migration in the lower oceanic crust. Minerals, 8(12), 583, doi:10.3390/min8120583., Felsic rocks are minor in abundance but occur ubiquitously in International Ocean Discovery Program Hole U1473A, Southwest Indian Ridge. The trace element abundances of high-Ti brown amphibole, plagioclase, and zircon in veins, as well as the presence of myrmekitic texture in the studied felsic rocks support crystallization origin from highly-evolved melts, probably controlled by fractional crystallization. Based on geochemical criteria and texture of the mineral assemblage in felsic rocks and their relationship with host gabbros, they can be divided into three types: (1) Felsic rock with sharp boundaries is formed when felsic melt intrudes into fractures of host gabbros, resulting in minimal interaction between the melt and the wall minerals. (2) Replacive felsic rock, which is characterized by a pseudomorphic replacement of minerals in the host gabbro. This vein type is caused by the replacement of the host mineralogy by minerals in equilibrium with the felsic melts. (3) Felsic rock with diffused boundaries is formed either by infiltration of felsic melt into the solidifying gabbro body or crystallization of interstitial melts. Infiltration modes of felsic melts are likely controlled by the temperature condition of the cooling host gabbros., This contribution is part of Du Khac Nguyen’s Ph.D. coursework at Kanazawa University with the funding provided by the Ministry of Education and Training of Vietnam (MOET) under grant number 950/Q -BGD T and Kanazawa University of Japan. This work was supported by Kanazawa University SAKIGAKE project and J-DESC post-cruise support funding.

This dissertation, as indicated by its title, is eclectic, but is united around the theme of developing and applying new geochemical approaches to answer large-scale questions in earth science. And it represents an interdisciplinary contribution, drawing on paleobiology, paleoclimate and paleoceanography as well as incorporating near surface and deep earth seismic models and signal analysis techniques to expand the range of conclusions that can be extracted from large geochemical datasets. The first two chapters focus on the marine biosphere in the geologic past. Chapter 1 presents a new high-throughput method for establishing paleo export productivity as well as evidence that increased supply of Southern Ocean water masses during glacial intervals stimulated productivity off the coast of East Africa. The method presented in Chapter 1 enabled Chapter 2, in which an unprecedented global view of marine productivity reveals a global biological “heartbeat”: marine productivity varies at the same frequencies as Earth’s orbital obliquity and precession, indicating a fundamental link between astronomical and biological processes. Chapters 3 and 4 explore the information contained in the carbon in marine sediments to better constrain the amount and form of C subducting along the Sunda margin, Indonesia and to infer a multi-phased expansion of C4 grasslands on the Indian subcontinent, indicating punctuated episodes of aridification. The final chapter traces the He isotope signature of a mantle plume from the core-mantle boundary to elucidate the processes involved in forming and sustaining continental rifting in Ethiopia and Afar. The breadth of topics covered here reflects the range of my own curiosity in pursuing what Nietzsche termed fröliche wissenschaft – joyful science.

Sediment samples from the Gulf of Alaska (GOA, IODP Expedition 341, Site U1417) have been analyzed to understand present and past diagenetic processes that overprint the primary sediment composition. No Sulfate-Methane Transition Zone (SMTZ) was observed at the zone of sulfate depletion, but a >200 m thick sulfate- and methane-free sediment interval occurred between the depth of sulfate depletion (~200 m) and the onset of methanogenesis (~440 m). We suggest that this apparent gap in biogeochemical processing of organic matter is caused by anaerobic oxidation of methane fueled by sulfate which is released during dissolution of barites at the upper boundary of the methane rich layer. Beneath the methanogenic zone, at ~650 m depth, pore-water sulfate concentrations increase again, indicating sulfate supply from greater depth feeding into a deep, inverse SMTZ. A likely explanation for the availability of sulfate in the deep sub-seafloor at U1417 is the existence of a deep aquifer related to plate bending fractures, which actively transports sulfate-rich water to, and potentially along, the interface between sediments and oceanic crust. Such inverse diagenetic zonations have been previously observed in marine sediments, but have not yet been linked to subduction-related plate bending. With the discovery of a deep inverse SMTZ in an intra-oceanic plate setting and the blocking of upward methane diffusion by sulfate released from authigenic barite dissolution, Site U1417 provides new insights into sub-seafloor pore-fluid and gas dynamics, and their implications for global element cycling and the deep biosphere.

Sediment samples from the Gulf of Alaska (GOA, IODP Expedition 341, Site U1417) have been analyzed to understand present and past diagenetic processes that overprint the primary sediment composition. No Sulfate-Methane Transition Zone (SMTZ) was observed at the zone of sulfate depletion, but a >200 m thick sulfate- and methane-free sediment interval occurred between the depth of sulfate depletion (~200 m) and the onset of methanogenesis (~440 m). We suggest that this apparent gap in biogeochemical processing of organic matter is caused by anaerobic oxidation of methane fueled by sulfate which is released during dissolution of barites at the upper boundary of the methane rich layer. Beneath the methanogenic zone, at ~650 m depth, pore-water sulfate concentrations increase again, indicating sulfate supply from greater depth feeding into a deep, inverse SMTZ. A likely explanation for the availability of sulfate in the deep sub-seafloor at U1417 is the existence of a deep aquifer related to plate bending fractures, which actively transports sulfate-rich water to, and potentially along, the interface between sediments and oceanic crust. Such inverse diagenetic zonations have been previously observed in marine sediments, but have not yet been linked to subduction-related plate bending. With the discovery of a deep inverse SMTZ in an intra-oceanic plate setting and the blocking of upward methane diffusion by sulfate released from authigenic barite dissolution, Site U1417 provides new insights into sub-seafloor pore-fluid and gas dynamics, and their implications for global element cycling and the deep biosphere.

The study of ancient DNA (aDNA) from sediments (sedaDNA) offers great potential for paleoclimate interpretation, and has recently been applied as a tool to characterise past marine life and environments from deep ocean sediments over geological timescales. Using sedaDNA, palaeo-communities have been detected, including prokaryotes and eukaryotes that do not fossilise, thereby revolutionising the scope of marine micropalaeontological research. However, many studies to date have not reported on the measures taken to prove the authenticity of sedaDNA-derived data from which conclusions are drawn. aDNA is highly fragmented and degraded and extremely sensitive to contamination by non-target environmental DNA. Contamination risks are particularly high on research vessels, drilling ships and platforms, where logistics and facilities do not yet allow for sterile sediment coring, and due consideration needs to be given to sample processing and analysis following aDNA guidelines. This review clarifies the use of aDNA terminology, discusses common pitfalls and highlights the urgency behind adopting new standards for marine sedaDNA research, with a focus on sampling optimisation to facilitate the incorporation of routine sedaDNA research into International Ocean Discovery Program (IODP) operations. Currently available installations aboard drilling ships and platforms are reviewed, improvements suggested, analytical approaches detailed, and the controls and documentation necessary to support the authenticity of aDNA retrieved from deep-sea sediment cores is outlined. Beyond practical considerations, concepts relevant to the study of past marine biodiversity based on sedaDNA, and the applicability of the new guidelines to the study of other contamination-susceptible environments (permafrost and outer space) are discussed.