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Three nonhalogenated ionic liquids (ILs) dissolved in 2-ethylhexyl laurate (2-EHL), a biodegradable oil, are investigated in terms of their bulk and electro-interfacial nanoscale structures using small-angle neutron scattering (SANS) and neutron reflectivity (NR). The ILs share the same trihexyl(tetradecyl)phosphonium ([P6,6,6,14]+) cation paired with different anions, bis(mandelato)borate ([BMB]−), bis(oxalato)borate ([BOB]−), and bis(salicylato)borate ([BScB]−). SANS shows a high aspect ratio tubular self-assembly structure characterized by an IL core of alternating cations and anions with a 2-EHL-rich shell or corona in the bulk, the geometry of which depends upon the anion structure and concentration. NR also reveals a solvent-rich interfacial corona layer. Their electro-responsive behavior, pertaining to the structuring and composition of the interfacial layers, is also influenced by the anion identity. [P6,6,6,14][BOB] exhibits distinct electroresponsiveness to applied potentials, suggesting an ion exchange behavior from cation-dominated to anion-rich. Conversely, [P6,6,6,14][BMB] and [P6,6,6,14][BScB] demonstrate minimal electroresponses across all studied potentials, related to their different dissociative and diffusive behavior. A mixed system is dominated by the least soluble IL but exhibits an increase in disorder. This work reveals the subtlety of anion architecture in tuning bulk and electro-interfacial properties, offering valuable molecular insights for deploying nonhalogenated ILs as additives in biodegradable lubricants and supercapacitors.

Three nonhalogenated ionic liquids (ILs) dissolved in 2-ethylhexyl laurate (2-EHL), a biodegradable oil, are investigated in terms of their bulk and electro-interfacial nanoscale structures using small-angle neutron scattering (SANS) and neutron reflectivity (NR). The ILs share the same trihexyl(tetradecyl)phosphonium ([P6,6,6,14]+) cation paired with different anions, bis(mandelato)borate ([BMB]−), bis(oxalato)borate ([BOB]−), and bis(salicylato)borate ([BScB]−). SANS shows a high aspect ratio tubular self-assembly structure characterized by an IL core of alternating cations and anions with a 2-EHL-rich shell or corona in the bulk, the geometry of which depends upon the anion structure and concentration. NR also reveals a solvent-rich interfacial corona layer. Their electro-responsive behavior, pertaining to the structuring and composition of the interfacial layers, is also influenced by the anion identity. [P6,6,6,14][BOB] exhibits distinct electroresponsiveness to applied potentials, suggesting an ion exchange behavior from cation-dominated to anion-rich. Conversely, [P6,6,6,14][BMB] and [P6,6,6,14][BScB] demonstrate minimal electroresponses across all studied potentials, related to their different dissociative and diffusive behavior. A mixed system is dominated by the least soluble IL but exhibits an increase in disorder. This work reveals the subtlety of anion architecture in tuning bulk and electro-interfacial properties, offering valuable molecular insights for deploying nonhalogenated ILs as additives in biodegradable lubricants and supercapacitors.

Lubrication properties of imidazolium and phosphonium bis(oxalato)borate ionic liquids (ILs) are compared in a reciprocating sliding contact at 80 °C and 140 °C. Both the influence of the alkyl chain length and the cation architecture on friction, wear and lubricant breakdown are investigated. Imidazolium ILs showed lower friction than phosphonium ILs though only phosphonium-based ILs reduced wear. A longer alkyl chain reduced friction only in the case of the imidazolium-based ILs. Analysis of the wear scars was consistent with chemical breakdown solely of the anion. Chemical changes in the ILs after the tribotests were more pronounced for imidazolium-based ILs, and comparison of breakdown and tribofilm formation implicated catalysis by the imidazolium center, which, in turn, had a strong dependence on the surface self-assembly., Validerad;2023;Nivå 2;2023-02-13 (joosat);Funder: Australian Research Council (DP180103682)Licens fulltext: CC BY License

Lubrication properties of imidazolium and phosphonium bis(oxalato)borate ionic liquids (ILs) are compared in a reciprocating sliding contact at 80 °C and 140 °C. Both the influence of the alkyl chain length and the cation architecture on friction, wear and lubricant breakdown are investigated. Imidazolium ILs showed lower friction than phosphonium ILs though only phosphonium-based ILs reduced wear. A longer alkyl chain reduced friction only in the case of the imidazolium-based ILs. Analysis of the wear scars was consistent with chemical breakdown solely of the anion. Chemical changes in the ILs after the tribotests were more pronounced for imidazolium-based ILs, and comparison of breakdown and tribofilm formation implicated catalysis by the imidazolium center, which, in turn, had a strong dependence on the surface self-assembly., Validerad;2023;Nivå 2;2023-02-13 (joosat);Funder: Australian Research Council (DP180103682)Licens fulltext: CC BY License

A series of 19 ionic liquids (ILs) based on phosphonium and imidazolium cations of varying alkyl-chain lengths with the orthoborate anions bis(oxalato)borate [BOB](-), bis(mandelato)borate, [BMB](-) and bis(salicylato)borate, [BScB](-), are synthesized and studied using small-angle neutron scattering (SANS). All measured systems display nanostructuring, with 1-methyl-3-n-alkyl imidazolium-orthoborates forming clearly bicontinuous L-3 spongelike phases when the alkyl chains are longer than C-6 (hexyl). L-3 phases are fitted using the Teubner and Strey model, and diffusely-nanostructured systems are primarily fitted using the Ornstein-Zernicke correlation length model. Strongly-nanostructured systems have a strong dependence on the cation, with molecular architecture variation explored to determine the driving forces for self-assembly. The ability to form well-defined complex phases is effectively extinguished in several ways: methylation of the most acidic imidazolium ring proton, replacing the imidazolium 3-methyl group with a longer hydrocarbon chain, substitution of [BOB](-) by [BMB](-), or exchanging the imidazolium for phosphonium systems, irrespective of phosphonium architecture. The results suggest there is only a small window of opportunity, in terms of molecular amphiphilicity and cation:anion volume matching, for the formation of stable extensive bicontinuous domains in pure bulk orthoborate-based ILs. Particularly important for self-assembly processes appear to be the ability to form H-bonding networks, which offer additional versatility in imidazolium systems.

Lubrication properties of imidazolium and phosphonium bis(oxalato)borate ionic liquids (ILs) are compared in a reciprocating sliding contact at 80 °C and 140 °C. Both the influence of the alkyl chain length and the cation architecture on friction, wear and lubricant breakdown are investigated. Imidazolium ILs showed lower friction than phosphonium ILs though only phosphonium-based ILs reduced wear. A longer alkyl chain reduced friction only in the case of the imidazolium-based ILs. Analysis of the wear scars was consistent with chemical breakdown solely of the anion. Chemical changes in the ILs after the tribotests were more pronounced for imidazolium-based ILs, and comparison of breakdown and tribofilm formation implicated catalysis by the imidazolium center, which, in turn, had a strong dependence on the surface self-assembly.

A series of 19 ionic liquids (ILs) based on phosphonium and imidazolium cations of varying alkyl-chain lengths with the orthoborate anions bis(oxalato)borate [BOB]−, bis(mandelato)borate, [BMB]− and bis(salicylato)borate, [BScB]−, are synthesized and studied using small-angle neutron scattering (SANS). All measured systems display nanostructuring, with 1-methyl-3-n-alkyl imidazolium-orthoborates forming clearly bicontinuous L3 spongelike phases when the alkyl chains are longer than C6 (hexyl). L3 phases are fitted using the Teubner and Strey model, and diffusely-nanostructured systems are primarily fitted using the Ornstein-Zernicke correlation length model. Strongly-nanostructured systems have a strong dependence on the cation, with molecular architecture variation explored to determine the driving forces for self-assembly. The ability to form well-defined complex phases is effectively extinguished in several ways: methylation of the most acidic imidazolium ring proton, replacing the imidazolium 3-methyl group with a longer hydrocarbon chain, substitution of [BOB]− by [BMB]−, or exchanging the imidazolium for phosphonium systems, irrespective of phosphonium architecture. The results suggest there is only a small window of opportunity, in terms of molecular amphiphilicity and cation:anion volume matching, for the formation of stable extensive bicontinuous domains in pure bulk orthoborate-based ILs. Particularly important for self-assembly processes appear to be the ability to form H-bonding networks, which offer additional versatility in imidazolium systems., Licens fulltext: CC BY-NC License

Rolling element bearings, when subjected to small oscillating movements or vibrations, run the risk of being damaged by mechanisms such as Standstill Marks and False Brinelling. Damages resulting from these phenomena can decrease bearing fatigue life and increase wear-induced friction torque. These failures do not correlate well with standard life estimation approaches. Experimental studies play a crucial role in gaining knowledge in this area. The review integrates knowledge from experiments ranging from single contacts to laboratory and full-scale bearings in wind power and aerospace applications. The generalization is achieved using a non-dimensional amplitude parameter that relates rolling element travel during an oscillation to the Hertzian contact size. The review encompasses testing methods, procedures, reporting practices, result scaling, and application-specific considerations., QC 20230830

The structure and interaction of ionic liquids (ILs) influence their interfacial composition, and their arrangement (i.e., electric double-layer (EDL) structure), can be controlled by an electric field. Here, we employed a quartz crystal microbalance (QCM) to study the electrical response of two non-halogenated phosphonium orthoborate ILs, dissolved in a polar solvent at the interface. The response is influenced by the applied voltage, the structure of the ions, and the solvent polarizability. One IL showed anomalous electro-responsivity, suggesting a self-assembly bilayer structure of the IL cation at the gold interface, which transitions to a typical EDL structure at higher positive potential. Neutron reflectivity (NR) confirmed this interfacial structuring and compositional changes at the electrified gold surface. A cation-dominated self-assembly structure is observed for negative and neutral voltages, which abruptly transitions to an anion-rich interfacial layer at positive voltages. An interphase transition explains the electro-responsive behaviour of self-assembling IL/carrier systems, pertinent for ILs in advanced tribological and electrochemical contexts., QC 20230918

A statistical, energy-based approach is employed to experimentally characterize the ability of different greases to reduce friction when a point contact is subjected to repeated reciprocal displacements of smaller magnitude than the contact diameter. This approach allows the assessment of lubricant fretting performance with respect to its ability to remain within the contact and also its boundary lubrication properties. The results indicate that composition-dependent boundary lubrication properties of greases loaded with non-halogenated ionic liquids containing bis(oxalato)borate ([BOB]) and bis(mandelato)borate ([BMB]) anions can result in no detectable wear and low friction, even under conditions of moderately high pressures and where the original contact area is never fully uncovered. This discovery paves the way for the development of anti-fretting ionic greases., QC 20230621

Lubrication properties of imidazolium and phosphonium bis(oxalato)borate ionic liquids (ILs) are compared in a reciprocating sliding contact at 80 degrees C and 140 degrees C. Both the influence of the alkyl chain length and the cation architecture on friction, wear and lubricant breakdown are investigated. Imidazolium ILs showed lower friction than phosphonium ILs though only phosphonium-based ILs reduced wear. A longer alkyl chain reduced friction only in the case of the imidazolium-based ILs. Analysis of the wear scars was consistent with chemical breakdown solely of the anion. Chemical changes in the ILs after the tribotests were more pronounced for imidazolium-based ILs, and comparison of breakdown and tribofilm formation implicated catalysis by the imidazolium center, which, in turn, had a strong dependence on the surface self-assembly., QC 20230309

In boundary lubrication, formation of tribofilms and subsequent friction and wear properties are strongly influenced by lubricant affinity to the lubricating surfaces. Ionic liquids (ILs), which are composed of ions, are expected to provide enhanced surface affinity compared to molecular liquids. This is also of interest for non-ferrous surfaces such as diamond-like carbon (DLC) coatings. DLC technology is widely utilised for sliding components, but DLC performance with conventional lubricants does not always fulfil the requirements. In this study, we compare lubricating performance of two non-halogenated ILs with a common cation, trihexyl(tetradecyl)phosphonium, but different anions, bis(oxalato)borate and bis(man-delato)borate, in the steel/steel and steel/DLC contacts. The tribofilms formed and their lubrication mechanism are investigated using a wide range of surface analysis techniques: Atomic Force Microscopy (AFM), nano-indentation, SEM-EDX and X-ray Photoelectron Spectroscopy (XPS). It is demon-strated that both ILs exhibited better lubricating performance than PAO oils of similar viscosity. It is also shown that the lubricating performance is controlled by the chemical stability of ILs, surface hardness and topography. The phosphonium bis(oxalato)borate IL exhibited excellent lubricity but its performance was adversely affected by the rough and very hard DLC surface that disrupted a delicate balance between the rates of tribofilm formation and removal. A higher chemical stability of the phosphonium bis(mandelato)borate IL facilitated formation of a non-sacrificial ionic tribofilm that reduced friction to a lower extent than the phosphonium bis(oxalato)borate IL but without accelerated tribochemical wear. The results demonstrate the potential for controlling lubrication properties by tuning functional groups of anion structure and subsequent chemical reactivity of ILs with lubricated surfaces., QC 20230508

A series of 19 ionic liquids (ILs) based on phosphonium and imidazolium cations of varying alkyl-chain lengths with the orthoborate anions bis(oxalato)borate [BOB]−, bis(mandelato)borate, [BMB]− and bis(salicylato)borate, [BScB]−, are synthesized and studied using small-angle neutron scattering (SANS). All measured systems display nanostructuring, with 1-methyl-3-n-alkyl imidazolium-orthoborates forming clearly bicontinuous L3 spongelike phases when the alkyl chains are longer than C6 (hexyl). L3 phases are fitted using the Teubner and Strey model, and diffusely-nanostructured systems are primarily fitted using the Ornstein-Zernicke correlation length model. Strongly-nanostructured systems have a strong dependence on the cation, with molecular architecture variation explored to determine the driving forces for self-assembly. The ability to form well-defined complex phases is effectively extinguished in several ways: methylation of the most acidic imidazolium ring proton, replacing the imidazolium 3-methyl group with a longer hydrocarbon chain, substitution of [BOB]− by [BMB]−, or exchanging the imidazolium for phosphonium systems, irrespective of phosphonium architecture. The results suggest there is only a small window of opportunity, in terms of molecular amphiphilicity and cation:anion volume matching, for the formation of stable extensive bicontinuous domains in pure bulk orthoborate-based ILs. Particularly important for self-assembly processes appear to be the ability to form H-bonding networks, which offer additional versatility in imidazolium systems., Licens fulltext: CC BY-NC License

The structure and interaction of ionic liquids (ILs) influence their interfacial composition, and their arrangement (i.e., electric double-layer (EDL) structure), can be controlled by an electric field. Here, we employed a quartz crystal microbalance (QCM) to study the electrical response of two non-halogenated phosphonium orthoborate ILs, dissolved in a polar solvent at the interface. The response is influenced by the applied voltage, the structure of the ions, and the solvent polarizability. One IL showed anomalous electro-responsivity, suggesting a self -assembly bilayer structure of the IL cation at the gold interface, which transitions to a typical EDL structure at higher positive potential. Neutron reflectivity (NR) confirmed this interfacial structuring and compositional changes at the electrified gold surface. A cation-dominated self-assembly structure is observed for negative and neutral voltages, which abruptly transitions to an anion-rich interfacial layer at positive voltages. An interphase transition explains the electro-responsive behaviour of self-assembling IL/carrier systems, pertinent for ILs in advanced tribological and electrochemical contexts.

Rolling element bearings, when subjected to small oscillating movements or vibrations, run the risk of being damaged by mechanisms such as Standstill Marks and False Brinelling. Damages resulting from these phenomena can decrease bearing fatigue life and increase wear-induced friction torque. These failures do not correlate well with standard life estimation approaches. Experimental studies play a crucial role in gaining knowledge in this area. The review integrates knowledge from experiments ranging from single contacts to laboratory and full-scale bearings in wind power and aerospace applications. The generalization is achieved using a non-dimensional amplitude parameter that relates rolling element travel during an oscillation to the Hertzian contact size. The review encompasses testing methods, procedures, reporting practices, result scaling, and application-specific considerations.

The structure and interaction of ionic liquids (ILs) influence their interfacial composition, and their arrangement (i.e., electric double-layer (EDL) structure), can be controlled by an electric field. Here, we employed a quartz crystal microbalance (QCM) to study the electrical response of two non-halogenated phosphonium orthoborate ILs, dissolved in a polar solvent at the interface. The response is influenced by the applied voltage, the structure of the ions, and the solvent polarizability. One IL showed anomalous electro-responsivity, suggesting a self -assembly bilayer structure of the IL cation at the gold interface, which transitions to a typical EDL structure at higher positive potential. Neutron reflectivity (NR) confirmed this interfacial structuring and compositional changes at the electrified gold surface. A cation-dominated self-assembly structure is observed for negative and neutral voltages, which abruptly transitions to an anion-rich interfacial layer at positive voltages. An interphase transition explains the electro-responsive behaviour of self-assembling IL/carrier systems, pertinent for ILs in advanced tribological and electrochemical contexts.

The friction coefficient of a specific material combination is often assumed to be invariant, even in manufacturing processes, such as during the tightening of threaded fastener joints. This paper considers the impact of storage conditions on threaded fastener friction. Fasteners were stored in hot humid and sub-zero temperature conditions to study friction in the thread and underhead contacts. Four Zn-flake coatings, commonly used in the automotive industry were considered. Consequent tightening of these fasteners at room temperature revealed that storage history had a significant impact on their friction coefficients, halving under-head friction in some cases. This varied behaviour was considered to be a response to coating nano-hardness and structure and differences in adsorption/absorption of water and zinc-oxide formation during storage.

The friction coefficient of a specific material combination is often assumed to be invariant, even in manufacturing processes, such as during the tightening of threaded fastener joints. This paper considers the impact of storage conditions on threaded fastener friction. Fasteners were stored in hot humid and sub-zero temperature conditions to study friction in the thread and underhead contacts. Four Zn-flake coatings, commonly used in the automotive industry were considered. Consequent tightening of these fasteners at room temperature revealed that storage history had a significant impact on their friction coefficients, halving under-head friction in some cases. This varied behaviour was considered to be a response to coating nano-hardness and structure and differences in adsorption/absorption of water and zinc-oxide formation during storage.

The friction coefficient of a specific material combination is often assumed to be invariant in manufacturing processes such as during the tightening of threaded fastener joints. This paper considers the impact of storage conditions on threaded fastener friction. Fasteners were stored in hot humid and sub-zero temperature conditions to study friction in the thread and under-head contacts. Four Zn-flake coatings, commonly used in the automotive industry were considered. Consequent tightening of these fasteners at room temperature revealed that storage history had a significant impact on their friction coefficients, halving under-head friction in some cases. This varied behavior was considered to be a response to coating nano-hardness and structure and differences in adsorption/absorption of water and zinc-oxide formation during storage., QC 20220411

Electric vehicle motors in e-drivetrain are equipped with grease-lubricated bearings operating at both low and high speeds with frequent speed changes. The grease-bearing system must secure a long lifespan and low frictional torque to improve efficiency and sustainability. The present paper focuses on the influence of two types of thickener, lithium complex and polypropylene, on the grease lubrication performance under conditions typical for e-motors. The comparison of both thickeners is performed in terms of friction torque and energy consumption in eight long-duration experiments (337 hr). The results show that the polypropylene thickener provides 21.5% lower energy consumption compared to the lithium complex. Changes in grease rheology and degradation in the tests are analysed and correlated with the grease lubrication performance., QC 20220301

The effect of electric potential on the lubrication of a non-halogenated phosphonium orthoborate ionic liquid used as an additive in a biodegradable oil was studied. An in-house tribotronic system was built around an instrument designed to measure lubricant film thickness between a rolling steel ball and a rotating silica-coated glass disc. The application of an electric field between the steel ball and a set of customized counter-electrodes clearly induced changes in the thickness of the lubricant film: a marked decrease at negative potentials and an increase at positive potentials. Complementary neutron reflectivity studies demonstrated the intrinsic electroresponsivity of the adsorbate: this was performed on a gold-coated silicon block and made possible in the same lubricant system by deuterating the oil. The results indicate that the anions, acting as anchors for the adsorbed film on the steel surface, are instrumental in the formation of thick and robust lubricating ionic boundary films. The application of a high positive potential, outside the electrochemical window, resulted in an enormous boost to film thickness, implicating the formation of ionic multi-layers and demonstrating the plausibility of remote control of failing contacts in inaccessible machinery, such as offshore wind and wave power installations., QC 20221216

We tested two types of ball bearings with an outer diameter of 750 mm to learn more about the challenges of oscillating motions for pitch bearings. The experimental conditions are derived from aero-elastic simulations, long-term wind speed measurements and a scaling method that considers loads and pitch angles. As a result, the parameters relevant for pitch bearings are represented appropriately, and the findings are transferable to other bearing sizes. For the tested parameter sets, severe wear occurred for over 90% of the exposed contact areas after 12 500 oscillating cycles. Decreasing the number of cycles to 1250 leads to a mix of exposed areas with 13% severe wear, 32% mild wear and 55% no wear, with no apparent pattern. The results demonstrate that a comparatively small amount of consecutive cycles can lead to severe wear. A new type of bearing tested showed less wear for the selected operating conditions., QC 20220602

The friction coefficient of a specific material combination is often assumed to be invariant, even in manufacturing processes, such as during the tightening of threaded fastener joints. This paper considers the impact of storage conditions on threaded fastener friction. Fasteners were stored in hot humid and sub-zero temperature conditions to study friction in the thread and underhead contacts. Four Zn-flake coatings, commonly used in the automotive industry were considered. Consequent tightening of these fasteners at room temperature revealed that storage history had a significant impact on their friction coefficients, halving under-head friction in some cases. This varied behaviour was considered to be a response to coating nano-hardness and structure and differences in adsorption/absorption of water and zinc-oxide formation during storage.

The friction coefficient of a specific material combination is often assumed to be invariant, even in manufacturing processes, such as during the tightening of threaded fastener joints. This paper considers the impact of storage conditions on threaded fastener friction. Fasteners were stored in hot humid and sub-zero temperature conditions to study friction in the thread and underhead contacts. Four Zn-flake coatings, commonly used in the automotive industry were considered. Consequent tightening of these fasteners at room temperature revealed that storage history had a significant impact on their friction coefficients, halving under-head friction in some cases. This varied behaviour was considered to be a response to coating nano-hardness and structure and differences in adsorption/absorption of water and zinc-oxide formation during storage.

Four nonhalogenated ionic liquids (ILs) based on the same phosphonium cation are investigated in terms of the anion suitability for enhancing the lubricity of a biodegradable oil. For all test conditions, typical for industrial machine components, the lubrication is shown to be governed by nonsacrificial films formed by the physisorption of ionic species on the tribo-surfaces. The anionic structure appears to have an important role in the formation of friction modifying films. The orthoborate ILs exhibit the formation of robust ionic boundary films, resulting in reduced friction and better wear protection. On the contrary, the surface adsorption of phosphinate and phosphate ILs appears to antagonistically disrupt the intrinsic lubrication properties of the biodegradable oil, resulting in high friction and wear. Through additional investigations, it is postulated that the higher dissociation of orthoborate ILs in the biodegradable oil allows the formation of hierarchical and electrostatically overscreened layer structures with long-range order, whereas the ILs with phosphate and phosphinate anions exhibit low dissociation in biodegradable oil, possibly due to the ion pairs being surrounded by a hydrocarbon halo, which presumably results in weak adsorption to form a mixed interfacial layer with no long-range order., QC 20211108

Phosphonium ionic liquids with orthoborate anions have been studied in terms of their interfacial film formation, both physisorbed and sacrificial from chemical breakdown, in sheared contacts of varying harshness. The halogen-free anion architecture was varied through (i) the heteronuclear ring size, (ii) the hybridisation of the constituent atoms, and (iii) the addition of aryl functionalities. Time of Flight-Secondary Ion Mass Spectrometry analysis revealed the extent of sacrificial tribofilm formation allowing the relative stability of the ionic liquids under tribological conditions to be determined and their breakdown mechanisms to be compared to simple thermal decomposition. Overall, ionic liquids outperformed reference oils as lubricants; in some cases, sacrificial films were formed (with anion breakdown a necessary precursor to phosphonium cation decomposition) while in other cases, a protective, self-assembly lubricant layer or hybrid film was formed. The salicylate-based anion was the most chemically stable and decomposed only slightly even under the harshest conditions. It was further found that surface topography influenced the degree of breakdown through enhanced material transport and replenishment. This work thus unveils the relationship between ionic liquid composition and structure, and the ensuing inter- and intra-molecular interactions and chemical stability, and demonstrates the intrinsic tuneability of an ionic liquid lubrication technology., QC 20211230

The lubricating performance of trihexyl(tetradecyl)phosphonium bisoxalatoorthoborate (P-BOB) ionic liquid is analysed at 80 degrees C and 140 degrees C, and compared to an ionic liquid containing a partially hydrated version of the anion. The reduction of the anions produces oxalate complexes that contribute synergistically to lower friction. The role of oxalate in enhancing lubricity was indicated by the fact that the partially hydrated anion is a precursor orthoborate anion complexed with oxalic acid. It consequently showed the lowest friction at 80 degrees C. Upon heating, the precursor was converted into [BOB]- and displayed the same friction at 140 degrees C as the fully synthesised species. The mechanisms of the breakdown of the [BOB]- anion and formation of the tribofilm are elucidated., QC 20210720

Small oscillating amplitudes (similar to 0. 1 degrees) and larger (> 1 degrees) can both lead to wear, which complicates the evaluation of the operating conditions. In this work, a simulation model is used to discuss critical amplitudes. The parametric study, which includes 125 simulations, shows the effect of load and coefficient of friction on the frictional work density for amplitudes ranging from 0.1 to 2.5 degrees. The study concludes that the frictional work density increases with the oscillating amplitude up to a certain point, where it becomes almost constant in relation to the amplitude. This point is reached when the amplitude is so large that a continuous overlapping of the contact zone no longer occurs. It is precisely this point that marks the critical oscillation amplitude., QC 20210903

It was found that Li[BOB]center dot nH(2)O salts were not readily suitable for the synthesis of high-purity orthoborate-based tetraalkylphosphonium ionic liquids, as exemplified here for trihexyl(tetradecyl)phosphonium bis(oxalato)borate, [P-6,P-6,P-6,P-14][BOB]; along with [BOB](-), a metastable transition anionic complex (TAC) of dihydroxy(oxalato)borate with oxalic acid, [B(C2O4)(OH)(2)center dot(HOOC-COOH)](-), was also formed and passed into the ionic liquid in the course of the metathesis reaction with trihexyl(tetradecyl)phosphonium chloride. On the contrary, Na[BOB] was found to be a more suitable reagent for the synthesis of this IL, because [BOB](-) anions safely passed into the final IL without hydrolysis, when metathesis reactions were performed using aqueous-free media. Since ultra-pure Na[BOB] is not commercially available, in this work, a preparation protocol for ultra-pure (>99%) Na[BOB] was developed: (i) molar ratios of boric and oxalic acids were optimised to minimise boron-containing impurities, (ii) the Na[BOB] product was thoroughly purified by sequential washing of a fine powder product in hot acetonitrile and ethanol and (iii) characterised using powder X-ray diffraction and solid-state B-11 MAS NMR spectroscopy. The physico-chemical properties of the prepared boron-impurity-free IL, i.e., its density, viscosity, electric conductivity, glass-transition temperature and thermal stability, were found to be significantly different from those of the previously reported [P-6,P-6,P-6,P-14][BOB], containing ca. 45 mol% of TAC, [B(C2O4)(OH)(2)center dot(HOOC-COOH)](-). It was found that a high-purity [P-6,P-6,P-6,P-14][BOB] prepared in this work has a considerably lower viscosity, a higher viscosity index and a wider electro-chemical window (ECW) compared to those of the sample of [P-6,P-6,P-6,P-14][BOB] with ca. 45 mol% of TAC. Interestingly, [B(C2O4)(OH)(2)center dot(HOOC-COOH)](-) in the latter sample almost completely transformed into [BOB](-), QC 20210422

Small oscillating amplitudes (~0. 1°) and larger (> 1°) can both lead to wear, w hich complicates the evaluation of the operating conditions. In this work, a simulation model is used to discuss critical amplitudes. The parametric study, which includes 125 simulations, shows the effect of load and coefficient of friction on the frictional work density for amplitudes ranging from 0.1 to 2.5°. The study concludes that the frictional work density increases with the oscillating amplitude up to a certain point, where it becomes almost constant in relation to the amplitude. This point is reached when the amplitude is so large that a continuous overlapping of the contact zone no longer occurs. It is precisely this point that marks the critical oscillation amplitude.

We tested two types of ball bearings with an outer diameter of 750 mm to learn more about the challenges of oscillating motions for pitch bearings. The experimental conditions are derived from aero-elastic simulations, long-term wind speed measurements and a scaling method that considers loads and pitch angles. As a result, the parameters relevant for pitch bearings are represented appropriately, and the findings are transferable to other bearing sizes. For the tested parameter sets, severe wear occurred for over 90% of the exposed contact areas after 12 500 oscillating cycles. Decreasing the number of cycles to 1250 leads to a mix of exposed areas with 13% severe wear, 32% mild wear and 55% no wear, with no apparent pattern. The results demonstrate that a comparatively small amount of consecutive cycles can lead to severe wear. A new type of bearing tested showed less wear for the selected operating conditions. © 2021 The Authors. Wind Energy published by John Wiley & Sons Ltd.

We tested two types of ball bearings with an outer diameter of 750 mm to learn more about the challenges of oscillating motions for pitch bearings. The experimental conditions are derived from aero-elastic simulations, long-term wind speed measurements and a scaling method that considers loads and pitch angles. As a result, the parameters relevant for pitch bearings are represented appropriately, and the findings are transferable to other bearing sizes. For the tested parameter sets, severe wear occurred for over 90% of the exposed contact areas after 12 500 oscillating cycles. Decreasing the number of cycles to 1250 leads to a mix of exposed areas with 13% severe wear, 32% mild wear and 55% no wear, with no apparent pattern. The results demonstrate that a comparatively small amount of consecutive cycles can lead to severe wear. A new type of bearing tested showed less wear for the selected operating conditions. © 2021 The Authors. Wind Energy published by John Wiley & Sons Ltd.

Neutron reflectivity (NR) measurements have been employed to study the interfacial structuring and composition of electroresponsive boundary layers formed by an ionic liquid (IL) lubricant at an electrified gold interface when dispersed in a polar solvent. The results reveal that both the composition and extent of the IL boundary layers intricately depend on the bulk IL concentration and the applied surface potential. At the lowest concentration (5% w/w), a preferential adsorption of the IL cation at the gold electrode is observed, which hinders the ability to electro-induce changes in the boundary layers. In contrast, at higher IL bulk concentrations (10 and 20% w/w), the NR results reveal a significantly larger concentration of the IL ions at the gold interface that exhibit significantly greater electroresponsivity, with clear changes in the layer composition and layer thickness observed for different potentials. In complementary atomic force microscopy (AFM) measurements on an electrified gold surface, such IL boundary layers are demonstrated to provide excellent friction reduction and electroactive friction (known as tribotronics). In agreement with the NR results obtained, clear concentration effects are also observed. Together such results provide valuable molecular insight into the electroactive structuring of ILs in solvent mixtures, as well as provide mechanistic understanding of their tribotronic behaviours.

The effect of water on the electroactive structuring of a tribologically relevant ionic liquid (IL) when dispersed in a polar solvent has been investigated at a gold electrode interface using neutron reflectivity (NR). For all solutions studied, the addition of small amounts of water led to clear changes in electroactive structuring of the IL at the electrode interface, which was largely determined by the bulk IL concentration. At a dilute IL concentration, the presence of water gave rise to a swollen interfacial structuring, which exhibited a greater degree of electroresponsivity with applied potential compared to an equivalent dry solution. Conversely, for a concentrated IL solution, the presence of water led to an overall thinning of the interfacial region and a crowding-like structuring, within which the composition of the inner layer IL layers varied systematically with applied potential. Complementary nanotribotronic atomic force microscopy (AFM) measurements performed for the same IL concentration, in dry and ambient conditions, show that the presence of water reduces the lubricity of the IL boundary layers. However, consistent with the observed changes in the IL layers observed by NR, reversible and systematic control of the friction coefficient with applied potential was still achievable. Combined, these measurements provide valuable insight into the implications of water on the interfacial properties of ILs at electrified interfaces, which inevitably will determine their applicability in tribotronic and electrochemical contexts., QC 20210127

Neutron reflectivity (NR) measurements have been employed to study the interfacial structuring and composition of electroresponsive boundary layers formed by an ionic liquid (IL) lubricant at an electrified gold interface when dispersed in a polar solvent. The results reveal that both the composition and extent of the IL boundary layers intricately depend on the bulk IL concentration and the applied surface potential. At the lowest concentration (5% w/w), a preferential adsorption of the IL cation at the gold electrode is observed, which hinders the ability to electro-induce changes in the boundary layers. In contrast, at higher IL bulk concentrations (10 and 20% w/w), the NR results reveal a significantly larger concentration of the IL ions at the gold interface that exhibit significantly greater electroresponsivity, with clear changes in the layer composition and layer thickness observed for different potentials. In complementary atomic force microscopy (AFM) measurements on an electrified gold surface, such IL boundary layers are demonstrated to provide excellent friction reduction and electroactive friction (known as tribotronics). In agreement with the NR results obtained, clear concentration effects are also observed. Together such results provide valuable molecular insight into the electroactive structuring of ILs in solvent mixtures, as well as provide mechanistic understanding of their tribotronic behaviours., QC 20201006

Control of the interfacial structures of ionic liquids (ILs) at charged interfaces is important to many of their applications, including in energy storage solutions, sensors and advanced lubrication technologies utilising electric fields. In the case of the latter, there is an increasing demand for the study of non-halogenated ILs, as many fluorinated anions have been found to produce corrosive and toxic halides under tribological conditions. Here, the interfacial structuring of a series of four imidazolium ILs ([C(n)C(1)Im]) of varying alkyl chain lengths (n = 5, 6, 7, 10), with a non-halogenated borate-based anion ([BOB]), have been studied at charged interfaces using sum frequency generation (SFG) spectroscopy and neutron reflectivity (NR). For all alkyl chain lengths, the SFG spectra show that the cation imidazolium ring responds to the surface charge by modifying its orientation with respect to the surface normal. In addition, the combination of SFG spectra with electrochemical NR measurements reveals that the longest alkyl chain length (n = 10) forms a bilayer structure at all charged interfaces, independent of the ring orientation. These results demonstrate the tunability of IL interfacial layers through the use of surface charge, as well as effect of the cation alkyl chain length, and provide valuable insight into the charge compensation mechanisms of ILs., QC 20200622

Non-halogenated boron-based ionic liquids (ILs) composed of phosphonium cations and chelated orthoborate anions have high hydrolytic stability, low melting point and exceptional properties for various applications. This study is focused on ILs with the same type of cation, trihexyltetradecylphosphonium ([P-6,P-6,P-6,P-14](+)), and two orthoborate anions, such as bis(salicylato)borate ([BScB](-)) and bis(oxalato)borate ([BOB](-)). We compare the results of this study with our previous studies on ILs with bis(mandelato)borate ([BMB](-)) and a variety of different cations (tetraalkylphosphonium, dialkylpyrrolidinium and dialkylimidazolium). The ion dynamics and phase behavior of these ILs is studied using H-1 and B-11 pulsed-field-gradient (PFG) NMR. PFG NMR is demonstrated to be a useful tool to elucidate the dynamics of ions in this class of phosphonium orthoborate ILs. In particular, the applicability of B-11 PFG NMR for studying anions without H-1, such as [BOB](-), and the limitations of this technique to measure self-diffusion of ions in ILs are demonstrated and discussed in detail for the first time., QC 20200625

Four non-halogenated ionic liquids (ILs) with trihexyl(tetradecyl)phosphonium cation are tested as lubricant additives to polypropylene (PP) and lithium-complex (LiX) greases. In pin-on-disk tests at elevated temperatures, the addition of an IL with bis(oxalato)borate ([BOB]) anion reduces wear by up to 50% when compared to the neat LiX base grease; an IL with bis(mandelato)borate ([BMB]) anion reduces friction by up to 60% for both PP and LiX. Elemental analysis reveals that oxygen-rich tribofilms help to reduce wear in case of [BOB], while the friction reduction observed for [BMB] is likely caused by adsorption processes. We find that temperature has a pronounced effect on additive expression, yet additive concentration is of minor importance under continuous sliding conditions. In contrast, rolling-sliding experiments at 90 degrees C show that the traction performance of LiX grease is dependent on additive concentration, revealing a reduction in traction by up to 30 and 40% for [BMB]- and [BOB]-containing ILs at concentrations of 10 wt%. Finally, an IL with dicyanamide anion reduces friction and increases wear in pin-on-disk tests at room temperature, while an IL with bis-2,4,4-(trimethylpentyl)phosphinate anion increases wear, showing only limited potential as grease additives. Overall, this work demonstrates the ability of non-halogenated ILs to significantly extend grease performance limits., QC 20191210

Neutron reflectivity (NR) measurements have been employed to study the interfacial structuring and composition of electroresponsive boundary layers formed by an ionic liquid (IL) lubricant at an electrified gold interface when dispersed in a polar solvent. The results reveal that both the composition and extent of the IL boundary layers intricately depend on the bulk IL concentration and the applied surface potential. At the lowest concentration (5% w/w), a preferential adsorption of the IL cation at the gold electrode is observed, which hinders the ability to electro-induce changes in the boundary layers. In contrast, at higher IL bulk concentrations (10 and 20% w/w), the NR results reveal a significantly larger concentration of the IL ions at the gold interface that exhibit significantly greater electroresponsivity, with clear changes in the layer composition and layer thickness observed for different potentials. In complementary atomic force microscopy (AFM) measurements on an electrified gold surface, such IL boundary layers are demonstrated to provide excellent friction reduction and electroactive friction (known as tribotronics). In agreement with the NR results obtained, clear concentration effects are also observed. Together such results provide valuable molecular insight into the electroactive structuring of ILs in solvent mixtures, as well as provide mechanistic understanding of their tribotronic behaviours.

Neutron reflectivity (NR) measurements have been employed to study the interfacial structuring and composition of electroresponsive boundary layers formed by an ionic liquid (IL) lubricant at an electrified gold interface when dispersed in a polar solvent. The results reveal that both the composition and extent of the IL boundary layers intricately depend on the bulk IL concentration and the applied surface potential. At the lowest concentration (5% w/w), a preferential adsorption of the IL cation at the gold electrode is observed, which hinders the ability to electro-induce changes in the boundary layers. In contrast, at higher IL bulk concentrations (10 and 20% w/w), the NR results reveal a significantly larger concentration of the IL ions at the gold interface that exhibit significantly greater electroresponsivity, with clear changes in the layer composition and layer thickness observed for different potentials. In complementary atomic force microscopy (AFM) measurements on an electrified gold surface, such IL boundary layers are demonstrated to provide excellent friction reduction and electroactive friction (known as tribotronics). In agreement with the NR results obtained, clear concentration effects are also observed. Together such results provide valuable molecular insight into the electroactive structuring of ILs in solvent mixtures, as well as provide mechanistic understanding of their tribotronic behaviours.

Neutron reflectivity (NR) measurements have been employed to study the interfacial structuring and composition of electroresponsive boundary layers formed by an ionic liquid (IL) lubricant at an electrified gold interface when dispersed in a polar solvent. The results reveal that both the composition and extent of the IL boundary layers intricately depend on the bulk IL concentration and the applied surface potential. At the lowest concentration (5% w/w), a preferential adsorption of the IL cation at the gold electrode is observed, which hinders the ability to electro-induce changes in the boundary layers. In contrast, at higher IL bulk concentrations (10 and 20% w/w), the NR results reveal a significantly larger concentration of the IL ions at the gold interface that exhibit significantly greater electroresponsivity, with clear changes in the layer composition and layer thickness observed for different potentials. In complementary atomic force microscopy (AFM) measurements on an electrified gold surface, such IL boundary layers are demonstrated to provide excellent friction reduction and electroactive friction (known as tribotronics). In agreement with the NR results obtained, clear concentration effects are also observed. Together such results provide valuable molecular insight into the electroactive structuring of ILs in solvent mixtures, as well as provide mechanistic understanding of their tribotronic behaviours.

Neutron reflectivity (NR) measurements have been employed to study the interfacial structuring and composition of electroresponsive boundary layers formed by an ionic liquid (IL) lubricant at an electrified gold interface when dispersed in a polar solvent. The results reveal that both the composition and extent of the IL boundary layers intricately depend on the bulk IL concentration and the applied surface potential. At the lowest concentration (5% w/w), a preferential adsorption of the IL cation at the gold electrode is observed, which hinders the ability to electro-induce changes in the boundary layers. In contrast, at higher IL bulk concentrations (10 and 20% w/w), the NR results reveal a significantly larger concentration of the IL ions at the gold interface that exhibit significantly greater electroresponsivity, with clear changes in the layer composition and layer thickness observed for different potentials. In complementary atomic force microscopy (AFM) measurements on an electrified gold surface, such IL boundary layers are demonstrated to provide excellent friction reduction and electroactive friction (known as tribotronics). In agreement with the NR results obtained, clear concentration effects are also observed. Together such results provide valuable molecular insight into the electroactive structuring of ILs in solvent mixtures, as well as provide mechanistic understanding of their tribotronic behaviours.

It is demonstrated that a phosphonium orthoborate ionic liquid may serve as a wear reducing additive in biodegradable oils at steel-steel surfaces in the boundary lubrication regime. Tribological tests were performed in a bail-on-three plate configuration. A set of surface characterization techniques-SEM/EDS, FIB and white light interferometry were used to characterize surfaces following the tribotests and to observe the formation of any tribofilms. B-11 NMR was used to follow changes in the composition of the ionic-liquid-oil blends and to identify boron-containing decomposition products after the tribotests. The ionic liquid reduces the wear of steel surfaces by up to 92% compared to the neat oil at 90 degrees C; it is shown that the reduction in wear can be correlated with the formation of boron enriched patches in the boundary films., QC 20190401

The quartz crystal microbalance (QCM) has been used to study how the interfacial layer of an ionic liquid dissolved in a polar oil at low weight percentages responds to changes in applied potential. The changes in surface composition at the QCM gold surface depend on both the magnitude and sign of the applied potential. The time-resolved response indicates that the relaxation kinetics are limited by the diffusion of ions in the interfacial region and not in the bulk, since there is no concentration dependence. The measured mass changes cannot be explained only in terms of simple ion exchange; the relative molecular volumes of the ions and the density changes in response to ion exclusion must be considered. The relaxation behavior of the potential between the electrodes upon disconnecting the applied potential is more complex than that observed for pure ionic liquids, but a measure of the surface charge can be extracted from the exponential decay when the rapid initial potential drop is accounted for. The adsorbed film at the gold surface consists predominantly of ionic liquid despite the low concentration, which is unsurprising given the surtactant-like structures of (some of) the ionic liquid ions. Changes in response to potential correspond to changes in the relative numbers of cations and anions, rather than a change in the oil composition. No evidence for an electric field induced change in viscosity is observed. This work shows conclusively that electric potentials can be used to control the surface composition, even in an oil-based system, and paves the way for other ion solvent studies., QC 2020013

This study reports on the effect of cutting fluids on friction behavior of the threaded fasteners. Underhead and thread friction are measured during tightening process of the hex-head threaded fasteners coated with different zinc-based coatings: electroplated zinc, zinc flake, and electroplated zinc nickel, commonly used in the automotive industry. The tests and data analysis are conducted considering ISO 16047 as a baseline. Test conditions are set close to the actual production conditions found in the motor vehicle industry. Water-based and ester-based cutting fluids are selected to unveil their impact on the reliability of the threaded fastener joints. It is shown that a change in the underhead interface conditions from dry to lubricated drastically reduces friction for the electroplated zinc and zinc nickel coatings., QC 20220915

Using neutron reflectivity, the electro-responsive structuring of the non-halogenated ionic liquid (IL) trihexyl(tetradecyl)phosphonium-bis(mandelato)borate, [ P-6,P-6,P-6,P-14][BMB], has been studied at a gold electrode surface in a polar solvent. For a 20% w/w IL mixture, contrast matched to the gold surface, distinct Kiessig fringes were observed for all potentials studied, indicative of a boundary layer of different composition to that of the bulk IL-solvent mixture. With applied potential, the amplitudes of the fringes from the gold-boundary layer interface varied systematically. These changes are attributable to the differing ratios of cations and anions in the boundary layer, leading to a greater or diminished contrast with the gold electrode, depending on the individual ion scattering length densities. Such electro-responsive changes were also evident in the reflectivities measured for the pure IL and a less concentrated (5% w/w) IL-solvent mixture at the same applied potentials, but gave rise to less pronounced changes. These measurements, therefore, demonstrate the enhanced sensitivity achieved by contrast matching the bulk solution and that the structure of the IL boundary layers formed in mixtures is strongly influenced by the bulk concentration. Together these results represent an important step in characterising IL boundary layers in IL-solvent mixtures and provide clear evidence of electro-responsive structuring of IL ions in their solutions with applied potential.

We have studied the rheological behavior of the ionic liquid trihexyl(tetradecyl)phosphonium bis(mandelato)borate, [P66614][BMB], and compared it with that of another ionic liquid, namely trihexyl(tetradecyl)phosphonium chloride, [P66614][Cl]. The non-halogenated [P66614][BMB] has been selected as it is known to provide enhanced lubrication performance and is, consequently, of technological importance. The ionic liquid [P66614][Cl], despite its relatively simple anion, exhibits viscosities very similar to those of [P66614][BMB], making it an excellent reference fluid for the modeling study. The viscosities of the ionic liquids have been obtained by equilibrium atomistic simulations using the Green–Kubo relation, and by performing nonequilibrium shear flow simulations. The influence of the simulation system size and a reduction of the atomic charges on the viscosities of the ionic liquids are systematically studied. The atomic charges are reduced to mimic the temperature dependent charge transfer and polarization effects. It has been found that scaling the point charges with factors between 0.60 and 0.80 from full ion charges can provide reliable viscosities of [P66614][BMB], consistent with the experimentally measured viscosities within the studied temperature interval from 373 to 463 K. The viscosities of [P66614][Cl] have been obtained with scaling factors between 0.80 and 1.0 reflecting the lower polarizability and charge transfer effects of the chloride anion.

We investigate the interfacial properties of the non-halogenated ionic liquid (IL), trihexyl(tetradecyl)phosphonium bis(mandelato)borate, [P6,6,6,14][BMB], in proximity to solid surfaces, by means of surface force measurement. The system consists of sharp atomic force microscopy (AFM) tips interacting with solid surfaces of mica, silica, and gold. We find that the force response has a monotonic form, from which a characteristic steric decay length can be extracted. The decay length is comparable with the size of the ions, suggesting that a layer is formed on the surface, but that it is diffuse. The long alkyl chains of the cation, the large size of the anion, as well as crowding of the cations at the surface of negatively charged mica, are all factors which are likely to oppose the interfacial stratification which has, hitherto, been considered a characteristic of ionic liquids. The variation in the decay length also reveals differences in the layer composition at different surfaces, which can be related to their surface charge. This, in turn, allows the conclusion that silica has a low surface charge in this aprotic ionic liquid. Furthermore, the effect of temperature has been investigated. Elevating the temperature to 40 °C causes negligible changes in the interaction. At 80 °C and 120 °C, we observe a layering artefact which precludes further analysis, and we present the underlying instrumental origin of this rather universal artefact., QC 20190619

Using neutron reflectivity, the electro-responsive structuring of the non-halogenated ionic liquid (IL) trihexyl(tetradecyl)phosphonium-bis(mandelato)borate, [P6,6,6,14][BMB], has been studied at a gold electrode surface in a polar solvent. For a 20% w/w IL mixture, contrast matched to the gold surface, distinct Kiessig fringes were observed for all potentials studied, indicative of a boundary layer of different composition to that of the bulk IL-solvent mixture. With applied potential, the amplitudes of the fringes from the gold-boundary layer interface varied systematically. These changes are attributable to the differing ratios of cations and anions in the boundary layer, leading to a greater or diminished contrast with the gold electrode, depending on the individual ion scattering length densities. Such electro-responsive changes were also evident in the reflectivities measured for the pure IL and a less concentrated (5% w/w) IL-solvent mixture at the same applied potentials, but gave rise to less pronounced changes. These measurements, therefore, demonstrate the enhanced sensitivity achieved by contrast matching the bulk solution and that the structure of the IL boundary layers formed in mixtures is strongly influenced by the bulk concentration. Together these results represent an important step in characterising IL boundary layers in IL-solvent mixtures and provide clear evidence of electro-responsive structuring of IL ions in their solutions with applied potential., QC 20180212

We have studied the rheological behavior of the ionic liquid trihexyl(tetradecyl)phosphonium bis(mandelato)borate, [P-66614][BMB], and compared it with that of another ionic liquid, namely trihexyl(tetradecyl)phosphonium chloride, [P-66614][Cl]. The non-halogenated [P-66614][BMB] has been selected as it is known to provide enhanced lubrication performance and is, consequently, of technological importance. The ionic liquid [P-66614][Cl], despite its relatively simple anion, exhibits viscosities very similar to those of [P-66614][BMB], making it an excellent reference fluid for the modeling study. The viscosities of the ionic liquids have been obtained by equilibrium atomistic simulations using the Green-Kubo relation, and by performing nonequilibrium shear flow simulations. The influence of the simulation system size and a reduction of the atomic charges on the viscosities of the ionic liquids are systematically studied. The atomic charges are reduced to mimic the temperature dependent charge transfer and polarization effects. It has been found that scaling the point charges with factors between 0.60 and 0.80 from full ion charges can provide reliable viscosities of [P-66614][BMB], consistent with the experimentally measured viscosities within the studied temperature interval from 373 to 463 K. The viscosities of [P-66614][Cl] have been obtained with scaling factors between 0.80 and 1.0 reflecting the lower polarizability and charge transfer effects of the chloride anion., QC 20180514