1. A Study of Structural Phase Transitions Using Light Scattering Techniques.
- Author
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EDINBURGH UNIV (SCOTLAND) DEPT OF PHYSICS, Taylor,W, EDINBURGH UNIV (SCOTLAND) DEPT OF PHYSICS, and Taylor,W
- Abstract
Raman and Brillouin light-scattering spectroscopy have been used to study variety of materials including Ag3AsS3 (proustite), Ag3SbS3 (pyrargyrite), NaKC4H406.4H20 (Rochelle salt), CaC4H406.4H20 (Calcium tartrate), Li2B407 (lithium diborate), BaTiO3 (barium titanate), Pb5Ge3011 (lead germanate), C3N3H3 (s-triazine) and SrTi03 (strontium titanate). Most of these materials undergo structural phase transitions of one kind of another and the spectroscopic date have been used to help identify and characterise these transitions where they exist. The presence of order-disorder phenomena is shown to be important in several instances but not necessarily directly involved in the phase-transition mechanism. In a subsidiary study a molecular crystal dynamics computer simulation has been carried out, successfully modelling the anharmonic behaviour of the crystal naphthalene.
- Published
- 1984