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The amorphous structure of (Ga2Se3)0.25(GeSe2)0.75 is investigated using a combination of anomalous X-ray scattering (AXS) and Reverse-Monte-Carlo (RMC) modeling. It was confirmed that the Ga and Ge atoms can be found exclusively in the tetrahedral configuration. The average coordination number of the Se atoms is found to be 2.34(3) due to the presence of dative bonds. The formation of Ga/Ge-Ga/Ge so-called “wrong bonds” is discussed based on a set of RMC simulations. A strong Ga-Ga second neighbor correlations indicates the formation of Ga-Se clusters within the Ga-Ge-Se glass., Amorfní struktura (Ga2Se3)0.25(GeSe2)0.75 je zkoumána kombinací anomalního rentgenového rozptylu (AXS) a modelováním pomocí reverzního Monte-Carla (RMC). Bylo potvrzeno, že Ga a Ge atomy existují exkluzivně v tetraedrické konfiguraci. Průměrné koordinační číslo atomů Se je 2.34(3) kvůli přítomnosti dativních vazeb. Tvorba Ga/Ge-Ga/Ge takzvaných „homopolárních vazeb“ je diskutována pomocí RMC simulací. Silná korelace Ga-Ga v druhé koordinační sféře naznačuje tvorbu Ga-Se klastrů uvnitř Ga-Ge-Se skla.

Core-level photoemission spectroscopy and anomalous x-ray scattering (AXS) measurements were performed for the Pd42.5Ni7.5Cu30P20 (PNCP) excellent metallic glass to investigate the chemical nature and local atomic structure, and the results were compared to those in Pd40Ni40P20 and Pd40Cu40P20. The P 2p core levels clearly separate into two states, indicating that the P atoms have two different chemical sites, which is a strong experimental proof for the existence of an elastic inhomogeneity. From the AXS close to the Pd K edge, a specific Pd-P-Pd atomic configuration was observed, which is related to the stable state in the P 2p core levels. All of the core levels measured in PNCP have the deepest binding energies among these glasses, indicating the most stable electronic states. Local structure around the P atoms is discussed by the AXS data and a metastable crystal appeared in a supercooled metallic alloy close to PNCP.

Core-level photoemission spectroscopy and anomalous x-ray scattering (AXS) measurements were performed for the Pd42.5Ni7.5Cu30P20 (PNCP) excellent metallic glass to investigate the chemical nature and local atomic structure, and the results were compared to those in Pd40Ni40P20 and Pd40Cu40P20. The P 2p core levels clearly separate into two states, indicating that the P atoms have two different chemical sites, which is a strong experimental proof for the existence of an elastic inhomogeneity. From the AXS close to the Pd K edge, a specific Pd-P-Pd atomic configuration was observed, which is related to the stable state in the P 2p core levels. All of the core levels measured in PNCP have the deepest binding energies among these glasses, indicating the most stable electronic states. Local structure around the P atoms is discussed by the AXS data and a metastable crystal appeared in a supercooled metallic alloy close to PNCP.

We propose a new description of astronomical dust emission in the spectral region from the Far-Infrared to millimeter wavelengths. Unlike previous classical models, this description explicitly incorporates the effect of the disordered internal structure of amorphous dust grains. The model is based on results from solid state physics, used to interpret laboratory data. The model takes into account the effect of absorption by Disordered Charge Distribution, as well as the effect of absorption by localized Two Level Systems. We review constraints on the various free parameters of the model from theory and laboratory experimental data. We show that, for realistic values of the free parameters, the shape of the emission spectrum will exhibit very broad structures which shape will change with the temperature of dust grains in a non trivial way. The spectral shape also depends upon the parameters describing the internal structure of the grains. This opens new perspectives as to identifying the nature of astronomical dust from the observed shape of the FIR/mm emission spectrum. A companion paper will provide an explicit comparison of the model with astronomical data., Comment: accepted in A&A, 21 pages, 9 figures

We propose a new description of astronomical dust emission in the spectral region from the Far-Infrared to millimeter wavelengths. Unlike previous classical models, this description explicitly incorporates the effect of the disordered internal structure of amorphous dust grains. The model is based on results from solid state physics, used to interpret laboratory data. The model takes into account the effect of absorption by Disordered Charge Distribution, as well as the effect of absorption by localized Two Level Systems. We review constraints on the various free parameters of the model from theory and laboratory experimental data. We show that, for realistic values of the free parameters, the shape of the emission spectrum will exhibit very broad structures which shape will change with the temperature of dust grains in a non trivial way. The spectral shape also depends upon the parameters describing the internal structure of the grains. This opens new perspectives as to identifying the nature of astronomical dust from the observed shape of the FIR/mm emission spectrum. A companion paper will provide an explicit comparison of the model with astronomical data., Comment: accepted in A&A, 21 pages, 9 figures

Using the Odin satellite, we have mapped the submillimeter emission from the 110-101 transition of ortho-water in the W3 star-forming region. A 5arcminx 5arcmin map of the W3 IRS4 and W3 IRS5 region reveals strong water lines at half the positions in the map. The relative strength of the Odin lines compared to previous observations by SWAS suggests that we are seeing water emission from an extended region. Across much of the map the lines are double-peaked, with an absorption feature at -39 km s-1; however, some positions in the map show a single strong line at -43 km s-1. We interpret the double-peaked lines as arising from optically thick, self-absorbed water emission near the W3 IRS5, while the narrower blue-shifted lines originate in emission near W3 IRS4. In this model, the unusual appearance of the spectral lines across the map results from a coincidental agreement in velocity between the emission near W3 IRS4 and the blue peak of the more complex lines near W3 IRS5. The strength of the water lines near W3 IRS4 suggests we may be seeing water emission enhanced in a photon-dominated region. Based on observations with Odin, a Swedish-led satellite project funded jointly by the Swedish National Space Board (SNSB), the Canadian Space Agency (CSA), the National Technology Agency of Finland (Tekes), and Centre National d'Études Spatiales (CNES). The Swedish Space Corporation was the industrial prime contractor and is also responsible for the satellite operation.

We present results obtained with the PRONAOS balloon-borne experiment on interstellar dust. In particular, the submillimeter / millimeter spectral index is found to vary between roughly 1 and 2.5 on small scales (3.5' resolution). This could have implications for component separation in Cosmic Microwave Background maps., Comment: 4 pages, 1 figure, proceeding of the Multi-Wavelength Cosmology conference held in Mykonos, Greece, June 2003, ed. Kluwer

We present a compilation of PRONAOS-based results concerning the temperature dependence of the dust submillimeter spectral index, including data from Galactic cirrus, star-forming regions, dust associated to a young stellar object, and a spiral galaxy. We observe large variations of the spectral index (from 0.8 to 2.4) in a wide range of temperatures (11 to 80 K). These spectral index variations follow a hyperbolic-shaped function of the temperature, high spectral indices (1.6-2.4) being observed in cold regions (11-20 K) while low indices (0.8-1.6) are observed in warm regions (35-80 K). Three distinct effects may play a role in this temperature dependence: one is that the grain sizes change in dense environments, another is that the chemical composition of the grains is not the same in different environments, a third one is that there is an intrinsic dependence of the dust spectral index on the temperature due to quantum processes. This last effect is backed up by laboratory measurements and could be the dominant one. We also briefly present a joint analysis of WMAP dust data together with COBE/DIRBE and COBE/FIRAS data., Comment: 4 pages, 2 figures, contribution to the proceedings of the Cologne-Bonn-Zermatt conference, held in Zermatt, Switzerland, Sept. 2003, eds: S. Pfalzner, C. Kramer, C. Straubmeier, and A. Heithausen, Springer-Verlag

We present here a compilation of PRONAOS-based results concerning the temperature dependence of the dust submillimeter spectral index, including data from Galactic cirrus, star-forming regions and a circumstellar envelope. We observe large variations of the spectral index (from 0.8 to 2.4) in a wide range of temperatures (12 to 80 K). These spectral index variations follow a hyperbolic-shaped function of the temperature, large spectral indices (1.5-2.4) being observed in cold regions (12-20 K) while small indices (0.8-1.6) are observed in warm regions (35-80 K). Three interpretations are proposed: one is that the grain sizes change in warm and rather dense environments, another is that the chemical composition of the grains is not the same in different environments, a third one is that there is an intrinsic dependence of the dust spectral index on the temperature due to quantum processes., Comment: 2 pages, 1 figure, proc. of the SF2A conf. held in Bordeaux, France, June 2003, eds.: F. Combes, D. Barret and T. Contini, EdP-Sciences Conf. Series, p. 97

We present a compilation of PRONAOS-based results concerning the temperature dependence of the dust submillimeter spectral index, including data from Galactic cirrus, star-forming regions, dust associated to a young stellar object, and a spiral galaxy. We observe large variations of the spectral index (from 0.8 to 2.4) in a wide range of temperatures (11 to 80 K). These spectral index variations follow a hyperbolic-shaped function of the temperature, high spectral indices (1.6-2.4) being observed in cold regions (11-20 K) while low indices (0.8-1.6) are observed in warm regions (35-80 K). Three distinct effects may play a role in this temperature dependence: one is that the grain sizes change in dense environments, another is that the chemical composition of the grains is not the same in different environments, a third one is that there is an intrinsic dependence of the dust spectral index on the temperature due to quantum processes. This last effect is backed up by laboratory measurements and could be the dominant one., Comment: 5 pages, 3 figures, Letter accepted April 2003 in A&A

We have mapped the submillimeter emission from the 1(10)-1(01) transition of ortho-water in the W3 star-forming region. A 5'x5' map of the W3 IRS4 and W3 IRS5 region reveals strong water lines at half the positions in the map. The relative strength of the Odin lines compared to previous observations by SWAS suggests that we are seeing water emission from an extended region. Across much of the map the lines are double-peaked, with an absorption feature at -39 km/s; however, some positions in the map show a single strong line at -43 km/s. We interpret the double-peaked lines as arising from optically thick, self-absorbed water emission near the W3 IRS5, while the narrower blue-shifted lines originate in emission near W3 IRS4. In this model, the unusual appearance of the spectral lines across the map results from a coincidental agreement in velocity between the emission near W3 IRS4 and the blue peak of the more complex lines near W3 IRS5. The strength of the water lines near W3 IRS4 suggests we may be seeing water emission enhanced in a photon-dominated region., Comment: Accepted to A&A Letters as part of the special Odin issue; 4 pages

We present a compilation of PRONAOS-based results concerning the temperature dependence of the dust submillimeter spectral index, including data from Galactic cirrus, star-forming regions, dust associated to a young stellar object, and a spiral galaxy. We observe large variations of the spectral index (from 0.8 to 2.4) in a wide range of temperatures (11 to 80 K). These spectral index variations follow a hyperbolic-shaped function of the temperature, high spectral indices (1.6-2.4) being observed in cold regions (11-20 K) while low indices (0.8-1.6) are observed in warm regions (35-80 K). Three distinct effects may play a role in this temperature dependence: one is that the grain sizes change in dense environments, another is that the chemical composition of the grains is not the same in different environments, a third one is that there is an intrinsic dependence of the dust spectral index on the temperature due to quantum processes. This last effect is backed up by laboratory measurements and could be the dominant one. We also briefly present a joint analysis of WMAP dust data together with COBE/DIRBE and COBE/FIRAS data., Comment: 4 pages, 2 figures, contribution to the proceedings of the Cologne-Bonn-Zermatt conference, held in Zermatt, Switzerland, Sept. 2003, eds: S. Pfalzner, C. Kramer, C. Straubmeier, and A. Heithausen, Springer-Verlag

We present here a compilation of PRONAOS-based results concerning the temperature dependence of the dust submillimeter spectral index, including data from Galactic cirrus, star-forming regions and a circumstellar envelope. We observe large variations of the spectral index (from 0.8 to 2.4) in a wide range of temperatures (12 to 80 K). These spectral index variations follow a hyperbolic-shaped function of the temperature, large spectral indices (1.5-2.4) being observed in cold regions (12-20 K) while small indices (0.8-1.6) are observed in warm regions (35-80 K). Three interpretations are proposed: one is that the grain sizes change in warm and rather dense environments, another is that the chemical composition of the grains is not the same in different environments, a third one is that there is an intrinsic dependence of the dust spectral index on the temperature due to quantum processes., Comment: 2 pages, 1 figure, proc. of the SF2A conf. held in Bordeaux, France, June 2003, eds.: F. Combes, D. Barret and T. Contini, EdP-Sciences Conf. Series, p. 97

We present results obtained with the PRONAOS balloon-borne experiment on interstellar dust. In particular, the submillimeter / millimeter spectral index is found to vary between roughly 1 and 2.5 on small scales (3.5' resolution). This could have implications for component separation in Cosmic Microwave Background maps., Comment: 4 pages, 1 figure, proceeding of the Multi-Wavelength Cosmology conference held in Mykonos, Greece, June 2003, ed. Kluwer

We present a compilation of PRONAOS-based results concerning the temperature dependence of the dust submillimeter spectral index, including data from Galactic cirrus, star-forming regions, dust associated to a young stellar object, and a spiral galaxy. We observe large variations of the spectral index (from 0.8 to 2.4) in a wide range of temperatures (11 to 80 K). These spectral index variations follow a hyperbolic-shaped function of the temperature, high spectral indices (1.6-2.4) being observed in cold regions (11-20 K) while low indices (0.8-1.6) are observed in warm regions (35-80 K). Three distinct effects may play a role in this temperature dependence: one is that the grain sizes change in dense environments, another is that the chemical composition of the grains is not the same in different environments, a third one is that there is an intrinsic dependence of the dust spectral index on the temperature due to quantum processes. This last effect is backed up by laboratory measurements and could be the dominant one., Comment: 5 pages, 3 figures, Letter accepted April 2003 in A&A

We have mapped the submillimeter emission from the 1(10)-1(01) transition of ortho-water in the W3 star-forming region. A 5'x5' map of the W3 IRS4 and W3 IRS5 region reveals strong water lines at half the positions in the map. The relative strength of the Odin lines compared to previous observations by SWAS suggests that we are seeing water emission from an extended region. Across much of the map the lines are double-peaked, with an absorption feature at -39 km/s; however, some positions in the map show a single strong line at -43 km/s. We interpret the double-peaked lines as arising from optically thick, self-absorbed water emission near the W3 IRS5, while the narrower blue-shifted lines originate in emission near W3 IRS4. In this model, the unusual appearance of the spectral lines across the map results from a coincidental agreement in velocity between the emission near W3 IRS4 and the blue peak of the more complex lines near W3 IRS5. The strength of the water lines near W3 IRS4 suggests we may be seeing water emission enhanced in a photon-dominated region., Comment: Accepted to A&A Letters as part of the special Odin issue; 4 pages

We map a 50' x 30' area in and around the M17 molecular complex with the French submillimeter balloon-borne telescope PRONAOS, in order to better understand the thermal emission of cosmic dust and the structure of the interstellar medium. The PRONAOS-SPM instrument has an angular resolution of about 3', corresponding to a size of 2 pc at the distance of this complex, and a high sensitivity up to 0.8 MJy/sr. The observations are made in four wide submillimeter bands corresponding to effective wavelengths of 200, 260, 360 and 580 um. Using an improved map-making method for PRONAOS data, we map the M17 complex and faint condensations near the dense warm core. We derive maps of both the dust temperature and the spectral index, which vary over a wide range, from about 10 K to 100 K for the temperature and from about 1 to 2.5 for the spectral index. We show that these parameters are anticorrelated, the cold areas (10-20 K) having a spectral index around 2, whereas the warm areas have a spectral index between 1 and 1.5. We discuss possible causes of this effect, and we propose an explanation involving intrinsic variations of the grain properties. Indeed, to match the observed spectra with two dust components having a spectral index equal to 2 leads to very large and unlikely amounts of cold dust. We also give estimates of the column densities and masses of the studied clumps. Three cold clumps (14-17 K) could be gravitationally unstable., Comment: 16 pages, 4 figures, accepted June 2002 in Astronomy & Astrophysics

We map a 50' x 30' area in and around the M17 molecular complex with the French submillimeter balloon-borne telescope PRONAOS, in order to better understand the thermal emission of cosmic dust and the structure of the interstellar medium. The PRONAOS-SPM instrument has an angular resolution of about 3', corresponding to a size of 2 pc at the distance of this complex, and a high sensitivity up to 0.8 MJy/sr. The observations are made in four wide submillimeter bands corresponding to effective wavelengths of 200, 260, 360 and 580 um. Using an improved map-making method for PRONAOS data, we map the M17 complex and faint condensations near the dense warm core. We derive maps of both the dust temperature and the spectral index, which vary over a wide range, from about 10 K to 100 K for the temperature and from about 1 to 2.5 for the spectral index. We show that these parameters are anticorrelated, the cold areas (10-20 K) having a spectral index around 2, whereas the warm areas have a spectral index between 1 and 1.5. We discuss possible causes of this effect, and we propose an explanation involving intrinsic variations of the grain properties. Indeed, to match the observed spectra with two dust components having a spectral index equal to 2 leads to very large and unlikely amounts of cold dust. We also give estimates of the column densities and masses of the studied clumps. Three cold clumps (14-17 K) could be gravitationally unstable., Comment: 16 pages, 4 figures, accepted June 2002 in Astronomy & Astrophysics