1. Airborne quantification of upper tropospheric NOx production from lightning in deep convective storms over the United States Great Plains
- Author
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Pollack, I. B., Homeyer, C. R., Ryerson, T. B., Aikin, K. C., Peischl, J., Apel, E. C., Campos, T., Flocke, F., Hornbrook, R. S., Knapp, D. J., Montzka, D. D., Weinheimer, A. J., Riemer, D., Diskin, G., Sachse, G., Mikoviny, T., Wisthaler, A., Bruning, E., MacGorman, D., Cummings, K. A., Pickering, K. E., Huntrieser, H., Lichtenstern, M., Schlager, H., Barth, M. C., Pollack, I. B., Homeyer, C. R., Ryerson, T. B., Aikin, K. C., Peischl, J., Apel, E. C., Campos, T., Flocke, F., Hornbrook, R. S., Knapp, D. J., Montzka, D. D., Weinheimer, A. J., Riemer, D., Diskin, G., Sachse, G., Mikoviny, T., Wisthaler, A., Bruning, E., MacGorman, D., Cummings, K. A., Pickering, K. E., Huntrieser, H., Lichtenstern, M., Schlager, H., and Barth, M. C.
- Abstract
The reported range for global production of nitrogen oxides (NOx=NO+NO2) by lightning remains large (e.g., 32 to 664mol NOx flash-1), despite incorporating results from over 30 individual laboratory, theoretical, and field studies since the 1970s. Airborne and ground-based observations from the Deep Convective Clouds and Chemistry experiment in May and June 2012 provide a new data set for calculating moles of NOx produced per lightning flash, P(NOx), in thunderstorms over the United States Great Plains. This analysis utilizes a combination of in situ observations of storm inflow and outflow from three instrumented aircraft, three-dimensional spatial information from ground-based radars and satellite observations, and spatial and temporal information for intracloud and cloud-to-ground lightning flashes from ground-based lightning mapping arrays. Evaluation of two analysis methods (e.g., a volume-based approach and a flux-based approach) for converting enhancements in lightning-produced NOx from volume-based mixing ratios to moles NOx flash-1 suggests that both methods equally approximate P(NOx) for storms with elongated anvils, while the volume-based approach better approximates P(NOx) for storms with circular-shaped anvils. Results from the more robust volume-based approach for three storms sampled over Oklahoma and Colorado during DC3 suggest a range of 142 to 291 (average of 194) moles NOx flash-1 (or 117–332mol NOx flash-1 including uncertainties). Although not vastly different from the previously reported range for storms occurring in the Great Plains (e.g., 21–465mol NOx flash-1), results from this analysis of DC3 storms offer more constrained upper and lower limits for P(NOx) in this geographical region.
- Published
- 2016