Search

Osmotic energy, as a renewable clean energy with huge energy density and stable yield, has received widespread attention over the past decades. Reverse electrodialysis (RED) based on ion-exchange membranes is an important method of obtaining osmotic energy from salinity gradients. The preparation of ion-exchange membranes with both high ion selectivity and ion permeability is in constant exploration. In this work, metal hydroxide-organic framework (MHOF) membranes are successfully prepared onto porous anodic aluminum oxide (AAO) membranes by a facile hydrothermal method to form Ni 2 (OH) 2 @AAO composite membranes, used for osmotic energy conversion. The surface is negatively charged with cation selectivity, and the asymmetric structure and extreme hydrophilicity enhance the ionic flux for effective capture of osmotic energy. The maximum output power density of 5.65 W m -2 at a 50-fold KCl concentration gradient is achieved, which exceeds the commercial benchmark of 5 W m -2 . Meanwhile, the composite membrane can also show good performance in different electrolyte solutions and acid-base environments. This work provides a new avenue for the construction and application of MHOF membranes in efficient osmotic energy conversion., (© 2024 Wiley‐VCH GmbH.)

It is an urgent need to develop lead-free piezoelectric energy harvesters (PEHs) to address the energy dilemma and meet environmental protection requirements. However, the low output power densities limit further promotion of lead-free PEHs for use in daily life. Here, an entropy-increasing strategy is proposed to achieve an increased output power density of 819 μW/cm 3 in lead-free potassium sodium niobate (KNN)-based piezoceramics by increasing the configuration entropy and realizing nearly two times the growth compared with low-entropy counterparts. Evolution of the energy-harvesting performance with increasing configuration entropy is demonstrated systematically, and the excellent energy-harvesting properties achieved are attributed to the enhanced lattice distortion, the flexible polarization configuration, and the high-density randomly distributed nanodomains with the entropy-increasing effect. Moreover, excellent vibration fatigue resistance and variable temperature output power characteristics were also realized in the PEH prepared by the proposed entropy-increasing material. The significant enhancement of the comprehensive energy-harvesting performance demonstrates that the construction of KNN-based ceramics with high configuration entropy represents an effective and convenient strategy to enable design of high-performance piezoceramics and thus promotes the development of advanced PEHs.

In this paper, we report on an enhancement of mm-wave power performances with a vertically scaled AlN/GaN heterostructure. An AlGaN back barrier is introduced underneath a non-intentionally doped GaN channel layer, enabling the prevention of punch-through effects and related drain leakage current under a high electric field while using a moderate carbon concentration into the buffer. By carefully tuning the Al concentration into the back barrier layer, the optimized heterostructure offers a unique combination of electron confinement and low trapping effects up to high drain bias for a gate length as short as 100 nm. Consequently, pulsed (CW) Load-Pull measurements at 40 GHz revealed outstanding performances with a record power-added efficiency of 70% (66%) under high output power density at V DS = 20 V. These results demonstrate the interest of this approach for future millimeter-wave applications.

We have fabricated a flexible, environment friendly piezoelectric nanogenerator (PENG) based on the ferroelectric Polyvinylidene fluoride (PVDF) composite incorporated with Barium titanate (BaTiO 3 ) nanowires (NWs) of piezoelectric coefficient d 33 . The single-layered PENG can deliver output power density of 10 -1 . The single-layered PENG can deliver output power density of 10 μ W cm -2 and an output voltage of 2 V with a nominal mechanical load of 1 kPa. BaTiO 3 (BTO) NWs of different concentrations were incorporated into PVDF to tune the polar phase content, internal resistance, and optimize the output power. We show that there exists a critical value of BTO NWs loading of 15 wt%, beyond which the piezoelectric energy harvesting characteristics of the PVDF nanocomposites decrease. The oxygen vacancies present in the BTO NWs surface attract the fluorine ions of PVDF chain and favour the formation of β phase. The enhanced value of dielectric constant and dielectric loss of BTO-PVDF samples in the low frequency region suggest strong interfacial polarization in the composite system. The fabricated PENG can charge a super-capacitor up to 4 V within 35 s. The origin of the high power output from the BTO (15 wt%)-PVDF composite is attributed to the combined effect of enhanced polar phase content, strong interfacial polarization, and reduced internal resistance. This study provides an effective pathway in enhancing the performance of BTO-PVDF based piezoelectric energy harvesters., (© 2022 IOP Publishing Ltd.)

A solar thermoelectric generator (STEG) that generates electricity from sunlight is expected to be a promising technology for harvesting and conversion of clean solar energy. The integration of a phase-change material (PCM) with the STEG even more enables engines to durably generate power in spite of solar radiation flux. However, its photothermal conversion and output electricity is still limited (<15 W/m 2 ) by the PCM's deficient thermal management performance, i . e ., restricted thermal conductivity and nonuniform heat-transfer behavior under concentrated sunlight radiation. In this study, a biomimetic phase-change composite, with centrosymmetric and a multidirectionally aligned boron nitride network embedded in polyethylene glycol, is tailored for the STEG via a radial ice-template assembly and infiltration strategy, which behaves in a highly and multidirectionally thermoconductive way and enables a rapid transfer of heat flux and uniform temperature distribution with respect to even a spot-like heat source. As a consequence, a powerful STEG is tactfully designed via the integration of this high-thermal-management characteristic and maximum collection of solar beams, for durable and real-environment solar-thermal-electric conversion, with its photothermal energy conversion efficiency of up to 85.1% and a high peak power density of 40.28 W/m 2 .

We report enhanced thermoelectric performance of SnTe by further increasing its intrinsic high carrier concentration caused by Sn vacancies in contrast to the traditional method. Along with In 2 Te 3 alloying, which results in an enhanced Seebeck coefficient, Li 2 Te is added to further increase the carrier concentration in order to maintain high electrical conductivity. Finally, a relatively high PF ave of ∼28 μW cm -1 K -2 in the range between 300 and 873 K is obtained in an optimized SnTe-based compound. Furthermore, nanoprecipitates with extremely high density are constructed to scatter phonons strongly, resulting in an ultralow lattice thermal conductivity of ∼0.45 W m -1 K -1 at 873 K. Given that the Z value is temperature dependent, the ( ZT ) eng and ( PF values are adopted to accurately predict the performance of this material. Taking into account the Joule and Thomson heat, output power density of ∼5.53 W cm eng values are adopted to accurately predict the performance of this material. Taking into account the Joule and Thomson heat, output power density of ∼5.53 W cm -2 and leg efficiency of ∼9.6% are calculated for (SnTe) 2.94 (In 2 Te 3 ) 0.02 -(Li 2 Te) 0.045 with a leg length of 4 mm and cold- and hot-side temperatures of 300 and 870 K, respectively., Competing Interests: The authors declare no competing interest.

Improvements in thermoelectric material performance over the past two decades have largely been based on decreasing the phonon thermal conductivity. Enhancing the power factor has been less successful in comparison. In this work, a peak power factor of ∼106 μW⋅cm -1 ⋅K -2 is achieved by increasing the hot pressing temperature up to 1,373 K in the p-type half-Heusler Nb 0.95 Ti 0.05 FeSb. The high power factor subsequently yields a record output power density of ∼22 W⋅cm -2 based on a single-leg device operating at between 293 K and 868 K. Such a high-output power density can be beneficial for large-scale power generation applications., Competing Interests: The authors declare no conflict of interest.