1. Optical Amplification at 1.5 µm in Er III Coordination Polymer-Doped Waveguides Based on Intramolecular Energy Transfer.
- Author
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Shi X, Man Y, He Y, Xu H, Zhang B, Yu D, Lin Z, Lv Z, Zhao Z, Zhang L, Chen Y, and Zhang D
- Abstract
9,9-bis (diphenylphosphorylphenyl) fluorene (FDPO) and dibenzotetrathienoacene (DBTTA), are synthesized as the neutral and anionic ligands, respectively, to prepare the Er
III coordination polymer [Er(DBTTA)3 (FDPO)]n . Based on the intramolecular energy transfer, optical gains at 1.5 µm are demonstrated in [Er(DBTTA)3 (FDPO)]n -doped polymer waveguides under excitations of low-power light-emitting diodes (LEDs) instead of laser pumping. A ligand-sensitization scheme between organic ligands and Er3+ ions under an excitation of an ultraviolet (UV) LED is established. Relative gains of 10.5 and 8.5 dB cm-1 are achieved at 1.53 and 1.55 µm, respectively, on a 1-cm-long SU-8 channel waveguide with a cross-section of 2 × 3 µm2 and a 1.5-µm-thick [Er(DBTTA)3 (FDPO)]n -doped polymethylmethacrylate (PMMA) as upper cladding. The ErIII coordination polymer [Er(DBTTA)3 (FDPO)]n can be conveniently integrated with various low-loss inorganic waveguides to compensate for optical losses in the C-band window. Moreover, by relying on the intramolecular energy transfer and UV LED top-pumping technology, it is easy to achieve coupling packaging of erbium-doped waveguide amplifiers (EDWAs) with pump sources in planar photonic integrated chips, effectively reducing the commercial costs., (© 2024 The Author(s). Advanced Science published by Wiley‐VCH GmbH.)- Published
- 2024
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