1. Highly stable Ag-doped Cu 2 O immobilized cellulose-derived carbon beads with enhanced visible-light photocatalytic degradation of levofloxacin.
- Author
-
Wang Y, Yang J, Zhang Z, Zhao P, Chen Y, Guo Y, and Luo X
- Subjects
- Catalysis, Photolysis, Kinetics, Water Pollutants, Chemical chemistry, Photochemical Processes, Anti-Bacterial Agents chemistry, Levofloxacin chemistry, Copper chemistry, Cellulose chemistry, Silver chemistry, Carbon chemistry, Light
- Abstract
Ag-doped Cu
2 O immobilized carbon beads (Ag/Cu2 O@CB) based composite photocatalysts have been prepared for the removal of levofloxacin, an antibiotic, from water. The photocatalysts were prepared by the processes of chemical reduction and in-situ solid-phase precipitation. The composite photocatalyst was characterized by a porous and interconnected network structure. Ag nanoparticles were deposited on Cu2 O particles to develop a metal-based semiconductor to increase the catalytic efficiency of the system and the separation efficiency of the photogenerated carriers. Cellulose-derived carbon beads (CBs) can also be used as electron storage libraries which can capture electrons released from the conduction band of Cu2 O. The results revealed that the maximum catalytic degradation efficiency of the composite photocatalyst for the antibiotic levofloxacin was 99.02 %. The Langmuir-Hinshelwood model was used to study the reaction kinetics, and the process of photodegradation followed first-order kinetics. The maximum apparent rate was recorded to be 0.0906 min-1 . The mass spectrometry technique showed that levofloxacin degraded into carbon dioxide and water in the presence of the photocatalyst. The results revealed that the easy-to-produce photocatalyst was stable and efficient in levofloxacin removing., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)- Published
- 2024
- Full Text
- View/download PDF