1. Trigger a multi-electron reaction by tailoring electronic structure of VO 2 toward more efficient aqueous zinc metal batteries.
- Author
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Luo P, Zhong W, Zhang W, Zhou M, Tang W, Tang H, Huang Z, Zhu D, Yu G, Chao F, Song J, Wei X, Dong S, and An Q
- Abstract
VO
2 (B) is recognized as a promising cathode material for aqueous zinc metal batteries (AZMBs) owing to its remarkable specific capacity and its unique, expansive tunnel structure, which facilitates the reversible insertion and extraction of Zn2+ . Nonetheless, challenges such as the inherent instability of the VO2 structure, poor ion/electron transport and a limited capacity due to the low redox potential of the V3+ /V4+ couple have hindered its wider application. In this study, we present a strategy to replace vanadium ions by doping Al3+ in VO2 . This approach activates the multi-electron reaction (V4+ /V5+ ), to increase the specific capacity and improve the structural stability by forming robust V5+ O and Al3+ O bonds. It also induces a local electric field by altering the local electron arrangement, which significantly accelerates the ion/electron transport process. As a result, Al-doped VO2 exhibits superior specific capacity, improved cycling stability, and accelerated electronic transport kinetics compared to undoped VO2 . The beneficial effects of heterogeneous atomic doping observed here may provide valuable insights into the improvement electrode materials in metal-ion battery systems other than those based on Zn., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Inc. All rights reserved.)- Published
- 2024
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