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The progress of solar-driven water-splitting technology has been impeded by the limited light response capability of semiconductor materials. Despite attempts to leverage nearly 50% of infrared radiation for photothermal synergy and catalytic reaction enhancement, heat loss during liquid phase reactions results in low energy conversion efficiency. Here, the photothermally driven catalytic water-splitting system, which designs K-SrTiO 3 -loaded TiN silica wool at the water-air interface. Photocatalytic tests and density functional theory calculations demonstrate that the thermal effect transforms liquid water into water vapor, thereby reducing the reaction free energy of catalysts and improving the transmission rate of catalytic products. Hence, the hydrogen evolution rate reaches 275.46 mmol m -2  h -1 , and the solar-to-hydrogen (STH) efficiency is 1.81% under 1 sun irradiation in this gas-solid system, which is more than twice that of liquid water splitting. This novel photothermal catalytic pathway, which involves a coupled reaction of water evaporation and water splitting, is anticipated to broaden the utilization range of the solar spectrum and significantly enhance the conversion efficiency of STH., (© 2023 Wiley-VCH GmbH.)

MnO/C materials with a long lifetime and high rate performance via a biomass template strategy for the lithium ion battery (LIB) market are indispensable. Therefore, novel and efficient ways for their synthesis are urgently required to greatly alleviate the pressure of consuming nonrenewable resources. Herein, we fabricate an open hollow tubular MnO/C hybrid based on the transformation of a natural kapok fiber by hydrothermal and thermal treatment. The as-prepared hybrid material was obtained with high synthesis efficiency and exhibited an extremely stable structure attributed to the in situ growth strategy, overcoming volumetric expansion and self-aggregation of MnO. As an anode material for LIBs, this typical MnO/C electrode demonstrated a high reversible capacity of 1917 mAh · g -1 at 300 mA · g -1 and an excellent rate performance of 693.1 mAh · g -1 at 5000 mA · g -1 . More importantly, this biomass carbon-based material demonstrates a superior cycling stability of 1433.1 mAh · g -1 at a high current density of 5000 mA · g -1 after 1000 cycles. The significant electrical performance of this new type of green material is promising for the development of LIBs.