1. Tailoring an HSO 4 - anion hybrid receptor based on a phenazine derivative.
- Author
-
Qi XN, Dong HQ, Yang HL, Qu WJ, Zhang YM, Yao H, Lin Q, and Wei TB
- Subjects
- Anions chemistry, Fluorescence, Molecular Structure, Particle Size, Phenazines chemical synthesis, Sulfites chemical synthesis, Surface Properties, Phenazines chemistry, Sulfites chemistry
- Abstract
A catechol-functionalized phenazine imidazole (PD) was tailored with 2,3-diaminophenazine and 3,4-dihydroxy benzaldehyde, and it served as a hybrid acceptor for capturing HSO
4 - anions. The selectivity and sensitivity of the PD receptor for anion sensing were studied. It was found that the PD receptor could not only display a preferable sensitivity to HSO4 - ions with a "turn-off" fluorescence response, but also have a strong anti-interference ability toward other common anions, especially basic anions such as CH3 COO- , HPO4 2- , and H2 PO4 - . The anion recognition mechanism of PD towards HSO4 - is based on multiple hydrogen bond interactions. Finally, the strips for anion detection were prepared, which were verified to be a convenient and high-efficiency test kit for detecting HSO4 - ions with the naked eye.- Published
- 2020
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