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The science and interface chemistry between the arsenic (As) anions and the different adsorbent systems have been gaining interest in recent years in environmental remediation applications. Metal-oxides and the corresponding hybrid systems have shown promising performance as novel adsorbents in various treatment technologies. The abundance, surface chemistry, high surface area (active-centres), various synthesis and functionalization methodologies, and good recyclability make these metal oxide-based nanomaterials as potential remediating agents for As oxyanions. This work critically reviews eight different platforms focused on the arsenic contamination issue, where the first classification describes the origin of arsenic contamination and presents geographical and demo-graphical considerations. The following section briefs the state-of-the-art remediation techniques for arsenic treatment with a comparative evaluation. An emphasized discussion has been provided regarding the adsorption and classification of various metal oxide adsorbents. In the next classification, various multi-synergism abilities like Redox activity, Surface functional groups, Surface area/morphology, Heterogeneous catalysis, Reactive oxygen species, Photo-catalytic/electro-catalytic reactions, and Electrosorption are detailed. The classification of various characterization tools for accessing the arsenic remediation qualitatively and quantitatively are given in the fifth chapter. The first-of-its-kind dedicated analysis has been given on the surface complexation aspects of the arsenic speciation onto various metal adsorbent systems using synchrotron results, surface-complexation modeling, and molecular simulation (e.g., DFT) in the sixth chapter. The current sensing applications of these novel nano-material systems for arsenic determination using colorimetric and electrochemical-based analytical tools and a note about the economic parameters, i.e., regeneration aspects of various adsorbent systems/the sustainable applications of the treated sludge materials, are provided in the final sections. This work makes a critical analysis of 'Environmental Nanotechnology' towards 'Arsenic Treatment'., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

Copper-based ternary metal oxide (i.e., Cu0.52Al0.01Fe0.47O4) impregnated reduced graphene oxide nanohybrid is verified for microbial and arsenic treatment. Growth inhibition of colonies are observed around 99.99% (E. coli), and 99.83% (S. aureus) at 10-20 μg/mL of hybrid dosage, respectively. The inhibition rates for both the colonies are increased to 99.9998% at 80 μg/mL. TEM images have shown insight of cell-content/lipid leakage behavior after inoculating with the hybrid. The efficient hindrance towards microbial colony growth is attributed to better charge transfer, reactive oxygen species generation, and metal-ion release. Maximum arsenic sorption capacities are observed around 248 and 314 mg/g for As(III), and As(V), respectively (C i  ~ 500 ppm). Surface morphology studies onto arsenic adsorption are reported with atomic force microscope, and FT-IR/Raman analysis. A detailed discussion onto individual spectra of As 3d spectra confirmed the occurrence of redox transformation in arsenic species [As(III)]. The variation in the quantity (at. %) of oxygen functional groups in O1s spectra (i.e., M-O, M-OH, and -OH 2 ) onto the hybrid supported the ligand-exchange behavior. Cyclic voltammetry study in arsenic electrolytes (10 µM - 1 mM) provides the occurrence of various in-situ electrochemical reactions supporting the redox activity. A significant electromagnetic wave absorption characteristics of the present hybrid is proposed with plausible airborne antimicrobial-agent abilities., (© 2022. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

The understanding of mechanistic insights in environmental remediation and mitigation systems is attracting larger attention, in recent days. Here in, aluminium substituted copper ferrite impregnated rGO hybrid (CAF-rGO) is verified to understand the adsorption/electrosorption mechanism of arsenic in aqueous systems. Near-surface study (XPS: As 3d, Cu 2p, Fe 2p, Al 2p, O 1s, C 1s) proposes redox, and ligand exchange reactions between contaminant, and CAF-rGO. Adsorption capacities are observed around 128.8 mg g -1 [As(III)], 153.5 mg g -1 [As(V)] with Freundlich model isotherms. Kinetics study follows the PSO model with influence of solar light (> 420 nm). Cyclic voltammetry (CV) analysis in different molarity conditions observed with signals around +0.1 and -0.6 V confirm the redox abilities, and N 2 /O 2 purged environments understood that electrosorption occurred through both reduction and sorption. Electrosorption study with pH variation shows the effect of protonation on the redox activity of individual arsenic species. Consistent signal around -0.6 ± 0.05 V in all the CV plots (i.e., Molarity, Environment, pH) recommends the usage of CAF-rGO for arsenic mitigation. Possible influence of photo-current (∼40 μA/cm 2 at ∼ 0 V) towards As(III/V) decontamination is understood though photoelectrochemical analysis. Impedance plot shows low-resistance and better diffusion of arsenic oxy-anions during light irradiation. Synergistic nature of CAF-rGO generates reactive oxygen species (i.e., ● OH/ ● O 2 - / 1 O 2 ) in mitigating highly toxic As(III) species is also detailed in the present work., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier Ltd. All rights reserved.)

Arsenic mitigation behavior in aqueous systems is being evaluated for Mn-Al-Fe, Cu-Al-Fe nano adsorbents. Morphological, and vibrational spectroscopy analysis are observed with As-OH, and As-O surface complexes. XPS study of individual As(3d) spectra at different parameters is observed with multiplet peak behavior attributed to redox behavior of Mn-Al-Fe, Cu-Al-Fe. Significant proportions of As(0) signal (∼25 at.% in pH 7, ∼78 at.% in pH 2, ∼58 at.% in pH 12) implicate an environmentally stable behavior of these adsorbents to address the arsenic leaching issue. Adsorption kinetics are observed with Pseudo Second Order (PSO) model, and Freundlich model supported multilayer adsorption behavior is observed for adsorption isotherms. Trace metal voltammetry studies are observed with 75-90 % of As(III) mitigation in aliquot samples. Detailed study of Mn(2p), Cu(2p), Fe(2p), and O(1 s) spectra explains redox active, and surface ligand exchange synergism in arsenic adsorption. Low equilibrium concentrations (Ce < 10 ppb) in As(V) systems (C i ∼ 100 and 500 ppb) indicate the drinking water application of these systems. Cyclic-voltammetry (CV) studies implicate the mitigation and immobilization of arsenic species onto adsorbent by both reduction, and sorption phenomenon., (Copyright © 2018 Elsevier B.V. All rights reserved.)

The present study is about surface complexation behavior of arsenic species adsorbed onto ternary metal oxide adsorbents (Ni-Al-Fe, Co-Al-Fe, Mn-Al-Fe, and Cu-Al-Fe). The analysis is carried out by X-ray absorption spectroscopy (XAS) tool. XANES (μ(E) vs. E) spectra close to the absorption edge (i.e., As K-edge) of all samples are observed along with the As(III) and As(V) standards. The first derivative of XANES for Ni-As(V), and Cu-As(V) samples agree with that of As(V) standards, respectively. Whereas, As(III) adsorbed adsorbent systems (i.e., Ni, Co, Mn, and Cu) are observed with mixed oxidation state of arsenic. A total of 65-85 % is observed with initial oxidation state (As(III) or As(V)), and remaining 15-35 % is observed with modified oxidation state (As(V) or As(III)) that explains the occurrence of possible charge transfer. EXAFS analysis shows the As-O bond distances in the range of 1.7-1.8 Å. The corresponding As-M bond distances are around 2.7, 3.2, and 3.6 Å which confirms the formation various edge sharing ( 2 E), and corner sharing ( 2 C, 1 V) surface complexes. Surface coverage is understood as an important parameter as bidentate attachments ( 2 E, 2 C) are evident in As(III), and As(V), but monodentate attachments ( 1 V) are only observed in As(V)., (Copyright © 2018 Elsevier B.V. All rights reserved.)

Arsenic [As(III) and As(V)] adsorption on aluminum substituted cobalt ferrite (Co-Al-Fe) ternary metal oxide adsorbent is reported by means of qualitative and quantitative spectroscopy tools. IR and Raman active signals were observed around 810-920 cm -1 band indicate different As-OH complexed and As-O uncomplexed stretching vibrations on to the adsorbent. The adsorption behavior of arsenic (III and V) onto these adsorbents is studied as a function of contact time, different concentrations, and pH conditions. The kinetics study on adsorption were performed to understand nature of adsorption which supports the Pseudo Second Order (PSO) model. The adsorption isotherms study indicates Freundlich type of adsorption. The maximum adsorption capacity of Co-Al-Fe adsorbent is observed around 130 and 76 mg g -1 for As(III) and As(V) systems, respectively. Detailed XPS study of As 3d, Fe 2p, Co 2p, and O 1s spectra has been reported in explaining the redox behavior and ligand exchange reactions in supporting arsenic adsorption mechanism.