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Recyclable and inexpensive catalysts, waste regeneration, use of available and safe solvents are important principles of green chemistry. Therefore, in this project, biochar nanoparticles (BNPs) were synthesized by the pyrolysis method from chicken manure. Then, 3-(sulfamic acid)-propyltriethoxysilane (SAPES) was immobilized on the surface of BNPs (SAPES@BNPs). The prepared catalyst (SAPES@BNPs) was used as a commercial, practical, biocompatible and reusable catalyst in the selective oxidation of sulfides to sulfoxides. Further, the catalytic application of SAPES@BNPs was explored in the multicomponent synthesis of tetrahydrobenzo[ b ]pyrans under mild and green conditions. BNPs were characterized using SEM, TGA and XRD techniques. SAPES@BNPs were characterized using SEM, FT-IR spectroscopy, WDX, EDS, TGA, and XRD techniques. Particle size distribution was obtained by histogram graph. SAPES@BNPs can be recovered and reused several times. The purity of the products was studied using NMR spectroscopy., Competing Interests: There are no conflicts to declare., (This journal is © The Royal Society of Chemistry.)

Inexpensive, stable, selective, and recyclable nanocatalysts, waste regeneration, and utilization of safe and available solvents are of interest and important factors in laboratory science and industrial applications of green chemistry. Therefore, herein, biochar nanoparticles (BNPs) were synthesized through chicken manure pyrolysis as a novel method for waste recycling. Then, in order to improve their recyclability, the obtained BNPs were magnetized using magnetic nickel nanoparticles. Then, the surface of the biochar magnetic nanoparticles (BMNPs) was modified by (3-chloropropyl)trimethoxysilane (3-CPTMS) and further a novel neodymium Schiff-base complex was immobilized on the surface of the modified BMNPs, denoted as Nd-Schiff-base@BMNPs. The obtained supported neodymium complex was used as a practical, selective, biocompatible, commercial, and reusable heterogeneous nanocatalyst. The biochar support of this nanocatalyst was formed from pyrolysis of chicken manure; therefore, it is cheap, economically viable, green and also compatible with the principles of green chemistry. Nd-Schiff-base@BMNPs acts selectively in organic reactions and also it can easily be recovered using an external magnet and reused, which is compatible with the principles of green chemistry. This nanocatalyst was characterized by wavelength-dispersive X-ray spectroscopy (WDX), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FT-IR), inductively coupled plasma (ICP), and N 2 adsorption-desorption (BET method) techniques. In the next step, the catalytic utilization of Nd-Schiff-base@BMNPs was investigated in the homoselective synthesis of 5-substituted 1 H -tetrazole compounds from [3 + 2] cycloaddition of sodium azide (NaN 3 ) and organo-nitriles in PEG-400 as a green solvent. Utilizing PEG-400 as a solvent offers various advantages, e.g. cheap, readily available, and environmentally friendly solvent as well as rapid separation and high purity of products. Therefore, this work is fully compatible with the principles of green chemistry., Competing Interests: Authors declare no conflict of interest or competing interests., (This journal is © The Royal Society of Chemistry.)

2,3-Dihydroquinazolin-4(1 H )-one and tetrazole are a class of nitrogen-containing heterocyclic compounds that play an important role in drug design and are an important part of many biological and industrial compounds. In this study, aluminium-based ionic liquid grafted onto a biochar surface (BC/[TESPMI]AlCl 4 ) was synthesized and used as a catalyst for the synthesis of a series of biological derivatives including 2,3-dihydroquinazolin-4(1 H )-ones in ethanol at reflux conditions and tetrazoles in PEG-400 at 110 °C. All products were obtained with good selectivity and yield of 90 to 97%. The catalyst was thoroughly characterized using various techniques such as thermogravimetric analysis (TGA), energy-dispersive X-ray spectroscopy (EDX), and powder X-ray diffraction (PXRD), scanning electron microscopy (SEM), inductively coupled plasm (ICP), and transmission electron microscopy (TEM), which confirmed the successful chemical grafting. This methodology has several advantages, including shorter reaction time, high yield of product, and recyclability of the catalyst. The catalyst remained active for five reaction cycles., Competing Interests: There is no conflict of interest for authors., (This journal is © The Royal Society of Chemistry.)

Boehmite is a natural and environmentally friendly compound. Herein boehmite nanoparticles were primarily synthesized and, then, their surface were modified via 3-choloropropyltrimtoxysilane (CPTMS). Afterwards, a new samarium complex was stabilized on the surface of the modified boehmite nanoparticles (Sm-bis(PYT)@boehmite). The obtained nanoparticles were characterized using thermogravimetric analysis (TGA), energy dispersive X-ray spectroscopy (EDS), Brunauer-Emmett-Teller (BET), wavelength dispersive X-ray spectroscopy (WDX), scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FT-IR), Inductively coupled plasma mass spectrometry (ICP-MS), dynamic light scattering (DLS), and X-ray diffraction (XRD) pattern. Sm-bis(PYT)@boehmite was used as an environmentally friendly, efficient, and organic-inorganic hybrid nanocatalyst in the homoselective synthesis of tetrazoles in polyethylene glycol 400 (PEG-400) as a green solvent. Notably, Sm-bis(PYT)@boehmite is stable and has a heterogeneous nature. Thus, it can be reused for several runs without any re-activation., (© 2023. The Author(s).)

In the first part of this work, boehmite nanoparticles (BNPs) were synthesized from aqueous solutions of NaOH and Al(NO 3 ) 3 ·9H 2 O. Then, the BNPs surface was modified using 3-choloropropyltrimtoxysilane (CPTMS) and then 1,3-bis(pyridin-3-ylmethyl)thiourea ((PYT) 2 ) was anchored on the surface of the modified BNPs (CPTMS@BNPs). In the final step, a complex of cobalt was stabilized on its surface (Co-(PYT) 2 @BNPs). The final obtained nanoparticles were characterized by FT-IR spectra, TGA analysis, SEM imaging, WDX analysis, EDS analysis, and XRD patterns. In the second part, Co-(PYT) 2 @BNPs were used as a highly efficient, retrievable, stable, and organic-inorganic hybrid nanocatalyst for the formation of organic heterocyclic compounds such as tetrazole derivatives. Co-(PYT) 2 @BNPs as a novel nanocatalyst are stable and have a heterogeneous nature; therefore, they can be recovered and reused again for several consecutive runs without any re-activation., Competing Interests: There are no conflicts to declare., (This journal is © The Royal Society of Chemistry.)

In this work, mesoporous MCM-41 was modified by a new Schiff-base formed from the condensation of triethylenetatramine and 5-bromosalicylaldehyde. Then, it was used for the stabilization of lanthanum metal (La-Schiff base@MCM-41) as a homoselective, reusable, efficient and biocompatible catalyst in the synthesis of 5-substituted 1 H -tetrazole derivatives. The synthesized tetrazoles were characterized using 1 H NMR and FT-IR spectroscopy and methods to measure their physical properties. La-Schiff base@MCM-41 was characterized by using various techniques such as ICP, CHN, XRD, TGA, BET, FT-IR spectroscopy, SEM, EDS and WDX. This catalyst has good stability and a heterogeneous nature, enabling it to be easily recovered and reused several times without significant loss in catalytic activity. This present strategy has important advantages such as utilizing PEG as a green solvent, short reaction times, excellent yields, easy recycling of the catalyst and pure separation of the products. The recovered La-Schiff base@MCM-41 catalyst was characterized by using FT-IR spectroscopy, SEM and AAS., Competing Interests: There are no conflicts to declare., (This journal is © The Royal Society of Chemistry.)

Magnetic boehmite nanoparticles (Fe 3 O 4 @boehmite NPs) were synthesized from a hybrid of boehmite and Fe 3 O 4 nanoparticles. At first, boehmite nanoparticles (aluminum oxide hydroxide) were prepared via a simple procedure in water using commercially available materials such as sodium hydroxide and aluminum nitrate. Then, these nanoparticles were magnetized using Fe 3 O 4 NPs in a basic solution of FeCl 2 ·4H 2 O and FeCl 3 ·6H 2 O. Fe 3 O 4 @boehmite NPs have advantages of both boehmite nanoparticles and Fe 3 O 4 magnetic materials. Magnetic boehmite nanoparticles have been characterized by various techniques such as TEM, SEM, EDS, WDX, ICP, FT-IR, Raman, XRD and VSM. SEM and TEM images confirmed that particles size are less than 50 nm in diameter with a cubic orthorhombic structure. Then, Fe 3 O 4 @boehmite NPs were applied as a homoselective, highly efficient, cheap, biocompatibility, heterogeneous and magnetically recoverable nanocatalyst in the synthesis of 5-substituted 1 H -tetrazole derivatives. Fe 3 O 4 @boehmite NPs can be recycled for several runs in the synthesis of tetrazoles. Also, all tetrazoles were isolated in high yields, which reveals high activity of Fe 3 O 4 @boehmite NPs in the synthesis of tetrazole derivatives. Fe 3 O 4 @boehmite NPs shows a good homoselectivity in synthesis of 5-substituted 1 H -tetrazole derivatives., Competing Interests: There are no conflicts to declare., (This journal is © The Royal Society of Chemistry.)

In this work boehmite nanoparticles (BNPs) were prepared through addition of aqueous solution of NaOH to solution of Al(NO 3 ) 3 ·9H 2 O. Then, the surface of BNPs was modified by (3-chloropropyl)trimethoxysilane (CPTMS) and further tetradentate ligand (MP-bis(AMP)) was anchored on its surface. At final step, a tetradentate organometallic complex of copper was stabilized on the surface of modified BNPs (Cu(II)-MP-bis(AMP)@boehmite). These obtained nanoparticles were characterized using SEM imaging, WDX, EDS, AAS and TGA analysis, BET method, FT-IR spectroscopy, and XRD pattern. In continue, the catalytic activity of Cu(II)-MP-bis(AMP)@boehmite has been used as a much efficient, reusable and hybrid of organic-inorganic nanocatalyst in the synthesis of ether derivatives through C-O coupling reaction under palladium-free and phosphine-free conditions. Cu(II)-MP-bis(AMP)@boehmite catalyst has been recovered and reused again for several times in the synthesis of ether derivatives., (© 2022. The Author(s).)

Waste recycling and the use of recyclable and available catalysts are important principles in green chemistry in science and industrial research. Therefore in this study, biochar nanoparticles were prepared from biomass pyrolysis. Then, they were magnetized with nickel nanoparticles to improve their recycling. Further, the magnetic biochar nanoparticles (biochar-Ni MNPs) were modified by dithizone ligand and then applied for the fabrication of a ruthenium catalyst (Ru-dithizone@biochar-Ni MNPs). This nanocatalyst was characterized by high-resolution transmission electron microscopy (HRTEM), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), wavelength dispersive X-ray spectroscopy (WDX), N 2 adsorption-desorption isotherms, thermogravimetric analysis (TGA), X-ray diffraction (XRD), and vibrating sample magnetometry (VSM) techniques. The XRD studies of Ru in the nanocatalyst showed that the crystalline structure of ruthenium in the Ru-dithizone@biochar-Ni MNPs was hcp . Another principle of green chemistry is the use of safe and inexpensive solvents, the most suitable of which is water. Therefore, the catalytic activity of this catalyst was investigated as a practical, selective, and recyclable nanocatalyst in the Suzuki carbon-carbon coupling reaction in aqueous media. The VSM curve of this catalyst showed that it could be easily recovered using an external magnet, and recycled multiple times. Also, VSM analysis of the recovered catalyst indicated the good magnetic stability of this catalyst after repeated use., Competing Interests: The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (This journal is © The Royal Society of Chemistry.)

Current outbreaks of the COIVD-19 pandemic demonstrate a global threat. In this paper, a conceptual model is developed for the COVID-19 pandemic, in which the people in society are divided into Susceptible, Exposed, Minor infected (Those who need to be quarantined at home), Hospitalized (Those who are in need of hospitalization), Intensive infected (ventilator-in-need infected), Recovered and Deceased. In this paper, first, the model that is briefly called SEMHIRD for a sample country (Italy as an example) is considered. Then, exploiting the real data of the country, the parameters of the model are obtained by assuming some basis functions on the collected data and solving linear least square problems in each window of data to estimate the time-varying parameters of the model. Thus, the parameters are updated every few days, and the system behavior is modeled according to the changes in the parameters. Then, the Linear Parameter Varying (LPV) Model of COVID19 is derived, and its stability analysis is presented. In the end, the influence of different levels of social distancing and quarantine on the variation of severely infected and hospitalized people is studied., Competing Interests: The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (© 2021 Elsevier Ltd. All rights reserved.)

Catalyst species are an important class of materials in chemistry, industry, medicine, and biotechnology. Moreover, waste recycling is an important process in green chemistry and is economically efficient. Herein, magnetic graphene oxide was synthesized using nickel magnetic nanoparticles and further applied as a novel support for the fabrication of a copper catalyst. The catalytic activity of supported copper on magnetic graphene oxide (Cu-ninhydrin@GO-Ni MNPs) was investigated as a selective, practical, and reusable nanocatalyst in the synthesis of diaryl ethers and biphenyls. Some of the obtained products were identified by NMR spectroscopy. This nanocatalyst has been characterized by atomic absorption spectroscopy (AAS), scanning electron microscopy (SEM), wavelength dispersive X-ray spectroscopy (WDX), energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FT-IR), and vibrating sample magnetometer (VSM) techniques. The results obtained from SEM shown that this catalyst has a nanosheet structure. Also, XRD and FT-IR analysis show that the structure of graphene oxide and nickel magnetic nanoparticles is stable during the modification of the nanoparticles and synthesis of the catalyst. The VSM curve of the catalyst shows that this catalyst can be recovered using an external magnet; therefore, it can be reused several times without a significant loss of its catalytic efficiency. The heterogeneity and stability of this nanocatalyst during organic reactions was confirmed by the hot filtration test and AAS technique., Competing Interests: The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (This journal is © The Royal Society of Chemistry.)

Resistance of H. pylori strains to common antibiotics has been developed in different parts of the world and continues to increase. It is important to investigate the novel and efficient anti-H. pylori drugs, among which the plants would be suitable sources. Satureja bachtiarica Bunge is traditionally used as antimicrobial agent. In this study, we evaluated the antibacterial activity of S. bachtiarica Bunge essential oil against 10 clinical isolates of Helicobacter pylori by disc diffusion and agar dilution methods. The chemical composition of essential oil was analyzed by GC and GC-MS. Carvacrol (45.5%) and thymol (27.9%) were the primary constituents of oil, followed by p-cymene (4.4%), and γ-terpinene (4.0%). S. bachtiarica essential oil showed strong antibacterial activity against clinical isolates of H. pylori (17.6 ± 1.1 mm and 0.035 ± 0.13 μl/ml). Carvacrol, as the first main component, had a significant role in this effect, whereas in the presence of thymol, the antibacterial effect of carvacrol was reduced. Therefore, S. bachtiarica essential oil can be applied as an alternative agent for treatment of H. pylori infections. More studies would be required to better clarify its mechanism of action on H. pylori., (Copyright © 2014 Elsevier GmbH. All rights reserved.)