Search

Suspensions of bimetallic nanoparticles (NPs) of Ru and Cu have been synthesized by simultaneous decomposition of two organometallic compounds in an ionic liquid. These suspensions have been characterized by Anomalous Small-Angle X-ray Scattering (ASAXS) at energies slightly below the Ru K-edge. It is found that the NPs adopt a Ru-core, a Cu-shell structure, with a constant Ru core diameter of 1.9 nm for all Ru : Cu compositions, while the Cu shell thickness increases with Cu content up to 0.9 nm. The formation of RuCuNPs thus proceeds through rapid decomposition of the Ru precursor into RuNPs of constant size followed by the reaction of the Cu precursor and agglomeration as a Cu shell. Thus, the different decomposition kinetics of precursors make possible the elaboration of core-shell NPs composed of two metals without chemical affinity.

We report what is believed to be the first diode-pumped Yb(3+): SrY(4)(SiO(4)) (3)O laser. We investigate both the cw and the mode-locked regimes. In the cw regime an average output power of 1.05 W is demonstrated for 3.6 W of incident pump power. In the femtosecond regime a pulse duration of 94 fs for an average power of 110 mW is obtained at a central wavelength of 1068 nm. This is, to our knowledge, the first femtosecond mode-locked oscillator made with an Yb-doped apatitelike crystal. These properties are related to the unique spectroscopic properties of Yb(3+) ions in this atypical apatite-family crystal.