Search

Groundwater (GW) is sensitive to climate change (CC), and the effects have become progressively more evident in recent years. Many studies have examined the effects of CC on GW quantity. Still, there is growing interest in assessing the qualitative impacts of CC, especially on GW temperature (GWT), and the consequences of these impacts. This study aimed to systematically review recently published papers on CC and GWT, determine the impacts of CC on GWT, and highlight the possible consequences. The Scopus and Web of Science databases were consulted, from which 144 papers were obtained. After an initial screening for duplicate papers, a second screening based on the titles and abstracts, and following an analysis of topic applicability to this subject after examining the full text, 44 studies were included in this review. The analysed scientific literature, published in 29 different journals, covered all five continents from 1995 to 2023. This review indicated that the subject of GWT variations due to CC is of global interest and has attracted significant attention, especially over the past two decades, with many studies adopting a multidisciplinary approach. A general increase in GWT was noted as a primary effect of CC (especially in urban areas); furthermore, the implications of this temperature increase for contaminants and GW-dependent ecosystems were analysed, and various applications for this increase (e.g. geothermal) were evaluated. This review highlights that GWT is vulnerable to CC and that the consequences can be serious and worthy of further investigation., Competing Interests: The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (© 2024 The Authors.)

Built-up areas are known to heavily impact the thermal regime of the shallow subsurface. In many cities, the answer to densification is to increase the height and depth of buildings, which leads to a steady growth in the number of underground car parks. These underground car parks are heated by waste heat from car engines and are typically several degrees warmer than the surrounding subsurface, which makes them a heat source for ambient subsurface and groundwater. Thus, the objective of this study is to investigate the thermal impact of 31 underground car parks in six cities and to upscale the thermal impact that underground car parks have on the subsurface in Berlin, Germany. Underground car parks have daily, weekly, and seasonal temperature patterns that respond to air circulation and traffic frequency, resulting in net heat fluxes of 0.3 to 15.5 W/m 2 at the measured sites. For the studied underground car parks in Berlin, the emitted annual thermal energy is about 0.65 PJ. Recycling this waste heat with geothermal heat pumps would provide a sustainable alternative for green energy and counteract the urban heat island by cooling of the shallow subsurface., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 The Authors. Published by Elsevier B.V. All rights reserved.)

Shallow aquifers beneath cities are highly influenced by anthropogenic heat sources, resulting in the formation of extensive subsurface urban heat islands. In addition to anthropogenic factors, natural factors also influence the subsurface temperature. However, the effect of individual factors is difficult to capture due to high temporal dynamics in urban environments. Particularly in the case of shallow aquifers, seasonal temperature fluctuations often override the influence of existing heat sources or sinks. For the city of Munich, we identify the dominant anthropogenic and natural influences on groundwater temperature and analyse how the influences change with increasing depth in the subsurface. For this purpose, we use depth temperature profiles from 752 selected groundwater monitoring wells. Since the measurements were taken at different times, we developed a statistical approach to compensate for the different seasonal temperature influences using passive heat tracing. Further, we propose an indicator to spatially assess the thermal stress on the aquifer. A multiple regression analysis of four natural and nine anthropogenic factors identified surface sealing as the strongest and the district heating grid as a weak but significant warming influence. The natural factors, aquifer thickness, depth-to-water and Darcy velocity show a significant cooling influence on the groundwater temperature. In addition, we show that local drivers, like thermal groundwater uses, surface waters and underground structures do not significantly contribute to the city-wide temperature distribution. The subsequent depth-dependent analysis revealed that the influence of aquifer thickness and depth-to-water increases with depth, whereas the influence of Darcy velocity decreases, and surface sealing and the heating grid remain relatively constant. In conclusion, this study shows that the most critical factor for the mitigation of future groundwater warming in cities is to minimize further sealing of the ground, to restore the permeability of heavily sealed areas and to retain open landscapes., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 The Authors. Published by Elsevier B.V. All rights reserved.)

Riverbank filtration is a natural aquifer-based process. The nitrogen dynamics in a riverbank filtration system are affected by many factors, including temperature, water quality, and travel time, which cannot be quantified easily. In this study, a field experiment was conducted to investigate nitrogen transport during riverbank filtration. The HYDRUS-2D software package was used to investigate and quantify the factors that affect the fate of nitrogen. The effects of temperature, water quality, and travel time on nitrate transport were considered. The model was calibrated and validated using field experimental data from the river water and groundwater during riverbank filtration at different periods. The results showed that HYDRUS-2D adequately simulated nitrate transport during riverbank filtration. The denitrification rate constant exhibited a positive exponential relationship with temperature. An empirical formula describing this relationship in riverbank filtration was developed and validated. In addition, the denitrification rate can be quantified within a specified temperature data range under field conditions. Compared with indoor experimental conditions, for the same temperature, there was a 10-fold increase in the denitrification rate constant under field conditions. The results showed that most of the nitrate removal occurred in the riparian zone at high temperatures during riverbank filtration. We concluded that the fate of nitrate in the riparian zone is strongly controlled by groundwater temperature. Travel time also plays an important role in nitrate removal during riverbank filtration., Competing Interests: Declaration of competing interest No conflict of interest exists in the submission of this manuscript, and manuscript is approved by all authors for publication. I would like to declare on behalf of my co-authors that the work described was original research that has not been published previously, and not under consideration for publication elsewhere, in whole or in part. All of the authors have read and approved the paper and it has not been published previously nor is it being considered by any other peer-reviewed journal. Our study does not involve human subjects. We deeply appreciate your consideration of our manuscript, and we look forward to receiving comments from the reviewers. If you have any queries, please don't hesitate to contact me at the address below., (Copyright © 2021. Published by Elsevier B.V.)

Thermal use of the shallow subsurface and its aquifers (< 400 m) is steadily increasing. Currently, more than 2800 aquifer thermal energy storage (ATES) systems are operating worldwide alongside more than 1.2 million ground source heat pump (GSHP) systems in Europe alone. These rising numbers of shallow geothermal energy (SGE) systems will put additional pressure on typically vulnerable groundwater systems. Hitherto, suitable criteria to control the thermal use of groundwater in national and international legislations are often still at a preliminary state or even non-existing. While the European Union (EU) Water Framework Directive (WFD) defined the release of heat into the groundwater as pollution in the year 2000, the cooling of groundwater for heating purposes is not explicitly mentioned yet. In contrast, some national legislations have stricter guidelines. For example, in Germany, detrimental changes in physical, chemical and biological characteristics have to be avoided. In the Swiss water ordinance, it is even recommended that the groundwater biocenosis should be kept in natural state. However, exact definitions of 'detrimental changes' and 'natural state' are still missing. Hence, the current study provides an overview on natural and affected thermal groundwater conditions and international and national legislations of the thermal use of groundwater. Also, it presents recent studies on groundwater ecosystems and proposes a sustainable policy framework for the thermal use of groundwater. In addition to geothermal heat sources, other anthropogenic heat sources such as climate change, underground car parks, heated basements, district heating systems, land fills, wastewater treatment plants and mining are considered, although no legislation on these anthropogenic heat sources and their impact on groundwater is currently in place. Finally, we intend to answer the above question and provide recommendations for the further discussions on the joint use of shallow groundwater systems for drinking water production and thermal use., (Copyright © 2021 Elsevier B.V. All rights reserved.)

Denitrification is a key microbial-mediated reaction buffering the impact of agriculturally-derived nitrate loads. Groundwater denitrification capacity is often assessed by measuring the magnitude and patterns of dinitrogen excess, although this method can be biased by dissolved gasses exsolution and ebullition. To address this issue, shallow groundwater was sampled in two field sites via nested mini-wells on a monthly basis over an entire hydrological year and analysed for dissolved gasses, nitrate and physical parameters. Both sites are located in lowland areas of the Po River basin (Italy) and are characterized by intensive agriculture. The GUA site, a freshwater paleo-river environment, with a low content of organic matter (SOM) and oxic sub-oxic groundwater. The BAN site, a reclaimed brackish swamp environment, with abundant SOM and sulphidic-methanogenic groundwater. Groundwater samples evidenced a general deficit of dinitrogen and Argon concentrations, because of ebullition induced by a total dissolved gasses pressure exceeding the hydrostatic pressure. Ebullition was recorded only during winter at the reclaimed brackish soil and was triggered by methane exsolution. While in summer both sites were affected by ebullition because of the water table drawdown. Denitrification evaluated using dinitrogen excess via dinitrogen-Argon ratio technique, was not only affected by gas exsolution, but also by groundwater temperature fluctuations. In fact, the latter induced large biases in the calculated N 2 excess even in the freshwater paleo-river environment. For these reasons, dinitrogen excess estimate with standard methods resulted to be unreliable in both lowland environments and a modified method is here presented to overcome this issue., (Copyright © 2019 Elsevier B.V. All rights reserved.)

Over the last century, the vast majority of peatlands in Europe have experienced substantial transformation as a result of drainage works that led to an imbalance in the natural hydrologic regime as well as changes in vegetation composition. The ongoing study aims to reconstruct the natural hydrologic regime of peatlands and restore their typical vegetation communities. In this study, we examine the variability of groundwater levels and groundwater temperature in raised bogs located in the Bieszczady Mts. in southern Poland. Both groundwater table levels and groundwater temperature serve to characterise the hydrology of peatlands, which in turn is critical for plant growth and rates of relevant biochemical processes. Our objective is to determine the predominant scale of intra-annual variability in time series and identify their potential sources by assessing the adaptive response of peat bogs to key changes in weather conditions. For this purpose, data obtained from 9 monitoring wells located in peat bogs, with a varying degree of degradation, were used. Fluctuations in time series and potential linkages between selected variables were analysed in the frequency domain using the continuous wavelet transform. The results show that peat bogs exhibit a relatively high stability of groundwater table levels and groundwater temperature despite meaningful changes in weather conditions. The most visible response of peat bogs to weather conditions was observed in summer and autumn. Our study demonstrates that degraded peat bogs experience the largest decrease in groundwater table levels and more frequent fluctuations. In contrast, groundwater temperature remained stable throughout the year at all the studied bog sites., (Copyright © 2017. Published by Elsevier B.V.)

Groundwater flow advects heat, and thus, the deviation of subsurface temperatures from an expected conduction-dominated regime can be analysed to estimate vertical water fluxes. A number of analytical approaches have been proposed for using heat as a groundwater tracer, and these have typically assumed a homogeneous medium. However, heterogeneous thermal properties are ubiquitous in subsurface environments, both at the scale of geologic strata and at finer scales in streambeds. Herein, we apply the analytical solution of Shan and Bodvarsson (2004), developed for estimating vertical water fluxes in layered systems, in 2 new environments distinct from previous vadose zone applications. The utility of the solution for studying groundwater-surface water exchange is demonstrated using temperature data collected from an upwelling streambed with sediment layers, and a simple sensitivity analysis using these data indicates the solution is relatively robust. Also, a deeper temperature profile recorded in a borehole in South Australia is analysed to estimate deeper water fluxes. The analytical solution is able to match observed thermal gradients, including the change in slope at sediment interfaces. Results indicate that not accounting for layering can yield errors in the magnitude and even direction of the inferred Darcy fluxes. A simple automated spreadsheet tool (Flux-LM) is presented to allow users to input temperature and layer data and solve the inverse problem to estimate groundwater flux rates from shallow (e.g., <1 m) or deep (e.g., up to 100 m) profiles. The solution is not transient, and thus, it should be cautiously applied where diel signals propagate or in deeper zones where multi-decadal surface signals have disturbed subsurface thermal regimes.

Human activity directly influences ambient air, surface and groundwater temperatures. The most prominent phenomenon is the urban heat island effect, which has been investigated particularly in large and densely populated cities. This study explores the anthropogenic impact on the thermal regime not only in selected urban areas, but on a countrywide scale for mean annual temperature datasets in Germany in three different compartments: measured surface air temperature, measured groundwater temperature, and satellite-derived land surface temperature. Taking nighttime lights as an indicator of rural areas, the anthropogenic heat intensity is introduced. It is applicable to each data set and provides the difference between measured local temperature and median rural background temperature. This concept is analogous to the well-established urban heat island intensity, but applicable to each measurement point or pixel of a large, even global, study area. For all three analyzed temperature datasets, anthropogenic heat intensity grows with increasing nighttime lights and declines with increasing vegetation, whereas population density has only minor effects. While surface anthropogenic heat intensity cannot be linked to specific land cover types in the studied resolution (1km×1km) and classification system, both air and groundwater show increased heat intensities for artificial surfaces. Overall, groundwater temperature appears most vulnerable to human activity, albeit the different compartments are partially influenced through unrelated processes; unlike land surface temperature and surface air temperature, groundwater temperatures are elevated in cultivated areas as well. At the surface of Germany, the highest anthropogenic heat intensity with 4.5K is found at an open-pit lignite mine near Jülich, followed by three large cities (Munich, Düsseldorf and Nuremberg) with annual mean anthropogenic heat intensities >4K. Overall, surface anthropogenic heat intensities >0K and therefore urban heat islands are observed in communities down to a population of 5000., (Copyright © 2017 Elsevier B.V. All rights reserved.)

The article studies the detection of the leakage passage of leachate in a waste landfill dam. The leachate of waste landfill has its own features, like high conductivity, high chroma and an increasing temperature, also, the horizontal flow velocity of groundwater on the leakage site increases. This article proposes a comprehensive tracing method to identify the leakage site of an impermeable membrane by using these features. This method has been applied to determine two leakage sites of the Yahu municipal solid waste landfill site in Pingshan District, Shenzhen, China, which shows that there are two leachate leakage passages in the waste landfill dam A between NZK-2 and NZK-3, and between NZK-6 and NZK-7., (© The Author(s) 2015.)