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We used site-level methane (CH 4 ) emissions data from over 1000 natural gas (NG) production sites in eight basins, including 92 new site-level CH 4 measurements in the Uinta, northeastern Marcellus, and Denver-Julesburg basins, to investigate CH 4 emissions characteristics and develop a new national CH 4 emission estimate for the NG production sector. The distribution of site-level emissions is highly skewed, with the top 5% of sites accounting for 50% of cumulative emissions. High emitting sites are predominantly also high producing (>10 Mcfd). However, low NG production sites emit a larger fraction of their CH 4 production. When combined with activity data, we predict that this creates substantial variability in the basin-level CH 4 emissions which, as a fraction of basin-level CH 4 production, range from 0.90% for the Appalachian and Greater Green River to >4.5% in the San Juan and San Joaquin. This suggests that much of the basin-level differences in production-normalized CH 4  emissions reported by aircraft studies can be explained by differences in site size and distribution of site-level production rates. We estimate that NG production sites emit total CH 4 emissions of 830 Mg/h (95% CI: 530-1200), 63% of which come from the sites producing <100 Mcfd that account for only 10% of total NG production. Our total CH 4 emissions estimate is 2.3 times higher than the U.S. Environmental Protection Agency's estimate and likely attributable to the disproportionate influence of high emitting sites.

Using cryogenic helium buffer-gas cooling, we have prepared dense samples of atomic lithium and molecular calcium monohydride at temperatures as low as 1 K. We have measured the Li+CaH→LiH+Ca chemical reaction, observed in both the accelerated disappearance of CaH in the presence of high densities of lithium and in the appearance of the LiH molecule.