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Development of the hydrogen economy requires the design of catalysts that increase the rate of the accompanying sluggish kinetic oxygen evolution reaction (OER). This is a key process in electrochemical energy conversion and storage, such as water splitting and metal-air batteries. The OER needs high overpotential and typically expensive precious metal-based catalysts. Therefore, designing low-cost and efficient electrocatalysts for OER is of paramount importance. In addition to focusing on the number of active sites or high specific surface area, the correlation between catalyst particle shape and performance should be considered. This work presents an electrocatalytic activity comparison of cobalt-containing carbons with different morphologies in the OER process. Employing metal-organic frameworks as carbon and metal precursors, the materials in the shape of polyhedrons, needles, unique spherical hedgehogs, and sea urchins were obtained. The effect of MOF template infiltration with additional carbon source on the physicochemical properties of electrocatalysts was also examined. The furfuryl alcohol-impregnated needle-shaped particles were characterized by a high content of cobalt active sites, surrounded by nitrogen-containing graphite layers. Electrochemical tests confirmed their best activity (overpotential 317 mV@10 mA/cm 2 ), long stability (up to 20 h), as well as low reagents diffusion limitations (Tafel slope 57 mV/dec up to 24 mA/cm 2 ). The vertically aligned structure of the catalyst contributed to improved detachment of the oxygen bubbles produced., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 The Author(s). Published by Elsevier Inc. All rights reserved.)

The effective use of the active phase is the main goal of the optimization of supported catalysts. However, carbon supports do not interact strongly with metal oxides, thus, oxidative treatment is often used to enhance the number of anchoring sites for deposited particles. In this study, we set out to investigate whether the oxidation pretreatment of mesoporous carbon allows the depositing of a higher loading and a more dispersed cobalt active phase. We used graphitic ordered mesoporous carbon obtained by a hard-template method as active phase support. To obtain different surface concentrations and speciation of oxygen functional groups, we used a low-temperature oxygen plasma. The main methods used to characterize the studied materials were X-ray photoelectron spectroscopy, transmission electron microscopy, and electrocatalytic tests in the oxygen evolution reaction. We have found that the oxidative pretreatment of mesoporous carbon influences the speciation of the deposited cobalt oxide phase. Moreover, the activity of the electrocatalysts in oxygen evolution is positively correlated with the relative content of the COO-type groups and negatively correlated with the C═O-type groups on the carbon support. Furthermore, the high relative content of COO-type groups on the carbon support is correlated with the presence of well-dispersed Co 3 O 4 nanoparticles. The results obtained indicate that to achieve a better dispersed and thus more catalytically active material, it is more important to control the speciation of the oxygen functional groups rather than to maximize their total concentration.

Dissolution of guanine in neutral solutions was obscured by peculiar behavior of guanine, indicating an apparent dependence of solubility on the amount of solid guanine used. Here, we demonstrate that the problem is caused by the formation of tiny guanine nanoparticles that tend to grow forming stable particles of ca. 800 nm size. This effect can be minimalized by using small quantities of guanine powder for dissolution. We also show that assuming a constant, independent of pH, concentration of neutral form of guanine, at 25 °C equal 25.4 μM, and applying known p K a values related to its dissociation or protonation, it is possible to calculate the concentrations of all conjugate acids and bases of guanine at the given pH value, and by summing them up, the guanine solubility.