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The objective of the study is to evaluate modified-carbon screen-printed working electrodes (SPE) combined with square wave anodic stripping voltammetry (SWASV) to determine electrolabile and total copper in soils with the perspective to assess the environmental hazard resulting from copper anthropogenic contamination. The voltammetric method was investigated using a mineralized certified reference soil such that it can be assumed that the copper was totally under electrolabile form in the solution of mineralized soil. In optimal conditions, a copper recovery of 97% and a relative standard deviation (RSD) of 9% were found. The limits of detection and quantification for copper were 0.4 and 1.3 μg L(-1), respectively. Finally, the method was applied on soil leachates, which allowed evaluating the cupric transfer from the soil to the leachates and quantifying the electrolabile copper part in leachates.

A new method using cheap homemade dual-electrodes has been developed to measure the antioxidant capacity of phenolic compounds. These micro-sized electrodes are elaborated by successive screen-printing of conductive ink and insulator layers and are then used as generator/collector sensors. Cyclic voltammetry and chronoamperometry with a bipotentiostat have been used to test and characterize these sensors. The antioxidant capacity values found by this new method are compared with a classical method (using a macro-sized electrode) to demonstrate its reliability.

In this work, we have undertaken the construction of a screen-printed electrode modified by a specific membrane to protect the working surface from interferences during the analysis of trace metals by anodic stripping voltammetry. Different crown-ethers selected for their metals affinity have been incorporated into a membrane then deposed on the working surface of the electrode. Each modified electrode has been first tested in an acidified KNO3 10(-1) mol L(-1) solution (pH 2) doped by free Cd2+ and Pb2+ ions. The response and selectivity of the modified electrodes have been investigated according to different parameters: (i) the substrates (commercial ink or carbon based homemade ink), (ii) the electrode support (polystyrene or transparency film) and (iii) crown-ethers nature (dibenzo-24-crown-8 and tetrathiacyclododecane 12-crown-4). The influence of the substrate on the response of the electrode is clearly demonstrated. Homemade ink appears as the most appropriate substrate to modify the working surface of the screen-printed electrode by a crown-ether based membrane. The effect of the composition of the membrane has been shown too. The best membrane developed showed a detection limit of 0.6 x 10(-8) mol L(-1) for Cd and 0.8 x 10(-8) mol L(-1) for Pb and a quantification limit of 10(-8) mol L(-1) for Cd and 2 x 10(-8) mol L(-1) for Pb. This method, which integrates the extraction, preconcentration and measurement, was successfully applied to environmental samples without pretreatment.