Search

Herein, the nanolignin-containing cellulose nanofibrils (LCNF)-enabled ratiometric fluorescent bio-nanocomposite film is developed. Interestingly, the inclusion of LCNF in the cellulose-based film enhances the detecting performance of food freshness, such as high sensitivity to biogenic amines (BAs) (limit of detection (LOD) of up to 1.83 ppm) and ultrahigh discernible fluorescence color difference (ΔE = 113.11). The underlying mechanisms are the fluorescence resonance energy transfer (FRET), π - π interaction, and cation - π interaction between LCNF and fluorescein isothiocyanate (FITC), as well as the increased hydrophobicity due to lignin, which increases the interactions of amines with FITC. Its color stability (up to 28 days) and mechanical property (49.4 Mpa) are simultaneously improved. Furthermore, a smartphone based detecting platform is developed to achieve access to food safety. This work presents a novel technology, which can have a great potential in the field of food packaging and safety., Competing Interests: Declaration of competing interest It is the original work of the authors. All the authors mutually agree that it should be submitted to Food Chemistry The manuscript has not been published or presented elsewhere in part or in entirety and is not under consideration by another journal. The authors declare that they have no conflict of interests. There is no research involving Human Participants and/or Animals., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Metal-organic frameworks (MOFs) have attracted much attention owing to their tuneable structures, high surface areas, and good functionalization. Nanoreactors derived from various MOFs are now widely used in heterogeneous catalysis, electrocatalysis and photocatalysis. The nanoarchitectures of MOFs and their derivatives have a great impact on mass and energy transfer pathways, thus affecting the activity and selectivity of the catalysts. In this review, we intend to provide a universal survey of reported methods to synthesize MOF-based core-satellite, core-shell, yolk-shell and hollow-shell structures or their derivatives in recent years and present a continuous evolution among them. We hope that this review could provide some perspectives for exploring new facile methods to prepare different hierarchical nanoarchitectures of MOFs or their derivatives.

Enhancing the antimicrobial activity of high-efficiency particulate air (HEPA) filters while maintaining filtration efficiency and pressure drop is currently an urgent issue for preventing the spread of pathogenic microorganisms. Herein, inspired by vines which can enwind fences to fix as well as decorate them, a flexible antimicrobial chitin nanofiber (ChNF@CuO x ) was fabricated and loaded onto the rigid glass fiber (GF) skeleton of a HEPA filter. Through the physical interaction, ChNF@CuO x was spontaneously enwound on GF, and ChNF@CuO x itself interweaved to form a new nanonetwork between the GF skeleton. The obtained antimicrobial air filter (ChNF@CuO x /GF) with a unique nanonetwork increased the filtration efficiency of the HEPA filter. Meanwhile, it possessed excellent inactivation ability against Staphylococcus aureus , Escherichia coli , and Candida albicans due to the urchin-like in situ grown CuO x on the ChNF. In particular, the oxygen vacancies generated unexpectedly in CuO x enabled it to produce reactive oxygen species. After eight cycles of antimicrobial assays, the antimicrobial rates of bacteria were higher than 99.5%, and those of fungi were greater than 98.3%. The successful synthesis of antimicrobial fibers and the construction of multidimensional nanoscale structures through a simple postprocessing method provide a new design mentality for antimicrobial functionalization for HEPA filters.

Circular bacteriocins are known for their structural stability and effective antimicrobial properties, positioning them as potential natural food preservatives. However, their widespread application is impeded by restricted availability. This research developed a total biosynthesis platform for circular bacteriocins, with a focus on AS-48 by involving recombinant production of the linear precursor in Escherichia coli , followed by enzymatic cyclization of the precursor into cyclic AS-48 using the ligase butelase-1 in vitro . An important discovery is that, aside from fusion tags, the C-terminal motif LE and LEKKK also could affect the expression yield of the precursor. This biosynthesis platform is both versatile and high-yielding, achieving yields of 10-20 mg/L of AS-48. Importantly, the biosynthetic AS-48 exhibited a secondary structure and antimicrobial activities comparable to those of the native molecules. As such, this work proposes an effective synthetic approach for circular bacteriocins, facilitating their advancement and application in the food industry.

As millions of tons of kraft lignin are being wasted, a potential application is to use its crosslinking reactions to build thermosetting bio adhesives. However, the crosslinking reactions between lignin molecules are not fully understood. The present study aims to elucidate the crosslinking reactions of the model lignin compound guaiacylglycerol-β-guaiacyl ether (GGE) via one-step hydroxymethylation/ amination with formaldehyde and diethylenetriamine (DETAM), or one-step glyoxylation/ amination with glyoxal and DETAM via liquid NMR techniques such as 1 H NMR, 13 C NMR, 2D 1 H- 13 C, and 1 H- 15 N HSQC NMR. Specifically, the 2D 1 H- 13 C HSQC NMR spectra confirm the presence of -CH 2 -NH- with a chemical shift of 1 H 2.6-3.6/ 13 C 40-60 ppm, and the formation of methylene linkages via the crosslinking reaction. Also, the 2D 1 H- 15 N HSQC NMR spectra clearly detect the formation of amide and imine bonds at 1 H 7.8/ 15 N 110 and 1 H 8.07/ 15 N 121.5 ppm from the crosslinked GGE., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Ltd.)

Background: Cellulose nanofiber (CNF) is an ideal Pickering emulsion stabilizer because of its high aspect ratio and flexibility. CNF was hydrophobically modified by dodecenyl succinic anhydride and used to stabilize the simulated food emulsion system containing insect protein. The prepared dodecenyl succinate nanofiber (D-CNFs) was characterized by contact angle and laser particle size analyzer. The stability of the emulsion system under different conditions was characterized by zeta potential and appearance observation. Lastly, in vitro digestion simulation experiments were carried out to investigate whether the addition of D-CNFs had an effect on the digestion and absorption of oil., Results: The modification process for dodecenyl succinic anhydride to CNFs was that the system temperature was 40 °C, the system pH value was 8.5 and the reaction time was 6 h. The water contact angle of the modified CNFs increased to 83.2 ± 0.9°. D-CNFs were introduced into the simulated food emulsion system containing insect protein. The increase in the concentration of D-CNFs in the aqueous phase promoted the stability of the simulated emulsion system. Increasing the ratio of insect protein was not conducive to the stability of the emulsion. The final fat digestibility of the emulsion with D-CNFs was lower than that of the emulsion without D-CNFs., Conclusion: Overall, the analysis and characterization results show the potential of the modified CNF as a food simulant emulsion stabilizer containing insect protein, which can be used for the development of specific functional foods. © 2024 Society of Chemical Industry., (© 2024 Society of Chemical Industry.)

High-strength, lightweight, ultrathin, and flexible electromagnetic interference (EMI) shielding materials with a high shielding effectiveness (SE) are essential for modern integrated electronics. Herein, cellulose nanofibrils (CNFs) are employed to homogeneously disperse graphene nanoplates (GNPs) into an aramid nanofiber (ANF) network and silver nanowire (AgNW) network, respectively, producing high-performance nanopapers. These nanopapers, featuring nacre-mimetic microstructures and layered architectures, exhibited high tensile strength (601.11 MPa) and good toughness (103.56 MJ m -3 ) with a thickness of only 24.58 μm. Their specific tensile strength reaches 447.59 MPa·g -1 ·cm 3 , which is 1.74 times that of titanium alloys (257 MPa·g -1 ·cm 3 ). The AgNW/GNP composite conductive layers exhibit an electrical conductivity of 12010.00 S cm -1 , providing the nanopapers with great EMI shielding performance, achieving an EMI SE of 63.87 dB and an EMI SE/t of 25978.80 dB cm -1 . The nanopapers also show reliable durability, retaining a tensile strength of 500.96 MPa and an EMI SE of 57.59 dB after 120,000 folding cycles. Additionally, they have a good electrical heating performance with a fast response time, low driving voltage, effective deicing capability, and reliable heating capacity in water. This work presents a strategy to develop a high-performance nanopaper, showing great potential for applications in electromagnetic compatibility, national defense, smart electronics, and human health.

Metal-organic frameworks, a type of porous architecture, have caught wide attention for their pore-rich and special metal-active centres. However, the non-conductive MOFs show limitations in lithium-sulfur batteries (LSBs). Herein, we first synthesized a lamellar nickel-based MOF and subsequently conducted pre-carbonization to attain a conductive Ni-carbon (Ni@C) catalyst. On account of the retained three-dimensional architecture and elevated conductivity, using Ni@C as the interlayer can realize polysulfide-regulated and kinetically promoted LSBs. This work offers a viable strategy to extend the implementation of MOFs in state-of-the-art LSB systems.

Utilizing advanced multiple channels for information encryption offers a powerful strategy to achieve high-capacity and highly secure data protection. Cellulose nanocrystals (CNCs) offer a sustainable resource for developing information protection materials. In this study, we present an approach that is easy to implement and adapt for the covalent attachment of various fluorescence molecules onto the surface of CNCs using the Mannich reaction in aqueous-based medium. Through the use of the Mannich reaction-based surface modification technique, we successfully achieved multi-color fluorescence in the resulting CNCs. The resulting CNC derivatives were thoroughly characterized by two dimensional heteronuclear single quantum coherence nuclear magnetic resonance (2D HSQC NMR) spectroscopy, Fourier transform infrared (FT-IR) spectroscopy and X-ray photoelectron (XPS) spectroscopy. Notably, the optical properties of CNCs were well maintained after modification, resulting in films exhibiting blue and red structural colors. This enables the engineering of highly programmable and securely encoded anti-counterfeit labels. Moreover, subsequent coating of the modified CNCs with MXene yielded a highly secure encrypted matrix, offering advanced security and encryption capabilities under ultraviolet, visible, and near-infrared wavelengths. This CNC surface-modification enables the development of multimodal security labels with potential applications across various practical scenarios., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Robust, conductive and flexible electrode materials have been the focus of attention in portable, wearable electronics. However, it is still a significant challenge to achieve synergistic development of multiple properties simultaneously. Herein, we propose a combination of microscale design and nanostructures strategy to prepare MXene/cellulose nanofiber-poly (3,4-ethylenedioxythiphoenes):polystyrene sulfonate (Ti 3 C 2 T x /CNF-PEDOT:PSS, TC-P) hybrid film by a simple in-situ polymerization and vacuum filtration process. CNF serves as the supporting skeleton of PEDOT:PSS, effectively mitigating its self-aggregation and structural deformation due to the expansion/contraction of the polymer network. And the CNF-PEDOT:PSS composite is capable to open up the interlayer space of Ti 3 C 2 T x , which reduces the self-stacking of Ti 3 C 2 T x nanosheets. The strong interactions among the three components enable the hybrid film electrode to possess both flexibility and high electrochemical properties. As a result, the film electrode exhibits a remarkable tensile strength of 77.4 MPa and an excellent conductivity of 162.5 S cm -1 , as well as an outstanding areal specific capacitance of 896 mF cm -2 at 4 mA cm -2 . Moreover, the assembled symmetric supercapacitor (SSC) device displays a large areal energy density of 62 µWh cm -2 at a power density of 800 µW cm -2 and demonstrates a long cycle life with 85.1 % capacitance retention after 10,000 GCD cycles. This study provides an effective strategy to balance mechanical flexibility and electrochemical properties, providing an inspiration to prepare flexible electrodes that are widely applied in a new generation of portable, wearable electronics., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Inc. All rights reserved.)

Chemical modification is a reliable and efficient strategy for designing cellulose-based functional materials. Herein, porous quaternized cellulose beads (QCBs) as cationic superabsorbent were fabricated by homogeneous in-situ chemical grafting cellulose molecular chains with glycidyl trimethylammonium chloride (GTAC) in tetraethylammonium hydroxide (TEAOH)/urea aqueous solution followed by acetic acid induced regeneration. The influence of GTAC dosage on the physicochemical-structural properties of cationic QCBs was deeply investigated. Results revealed that cotton liner could well-dissolved in TEAOH/urea aqueous solution, leading to a homogeneous and efficient quaternization medium for cellulose, thereby giving the high DS and positive charge density for quaternized cellulose. NMR results demonstrated the main substitution of GTAC groups at 2-OH and 6-OH positions of the cellulose chains during quaternization reaction. With increasing GTAC dosage, the network skeleton of QCBs gradually transformed from thick fibrils to thin aggregates, as well as enhanced pore volumes and hydrophilicity. Accordingly, QCBs-1.5 with high pore volume (99.70 cm 3 /g) exhibited excellent absorption capacity and efficiency, absorbing 122.32 g of water and 0.45 g of moisture per gram of the beads in 20 min. This work not only offers a simple strategy for the homogeneous quaternization modification of cellulose, but also provides a porous cellulose-based cationic superabsorbent material., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Due to the unsatisfactory mechanical properties of natural polymer-based conductive hydrogels, their applications are limited. Shaanxi Biangbiang noodles can be toughened by applying external mechanical forces through stretching and beating movements; this process provides inspiration for the preparation of high-strength hydrogels. In this paper, we propose a strategy for the preparation of ultrastrong and ultratough conductive hydrogels by directional prestretching and solvent exchange. Neatly arranged fiber bundles containing many intermolecular hydrogen bonds and metal ion coordination bonds are successfully constructed inside the prepared hydrogels. The hydrogel has exceptional mechanical properties, with a fracture stress exceeding 50 MPa, fracture strain approaching 105 %, fracture toughness exceeding 30 MJ m -3 , and high conductivity reaching 11.738 ± 0.06 mS m -1 . Impressively, the hydrogel can maintain its high mechanical properties after being frozen at an ultralow temperature of -80 °C for 7 days. Compared with other tough hydrogels, natural tendons and synthetic rubbers, the hydrogel exhibits excellent mechanical properties. The cellulose-based conductive hydrogel prepared in this study can be applied to robotic soft tissues (such as the Achilles tendon) that require high strength and are operated in extreme environments., Competing Interests: Declaration of competing interest The authors declare no competing financial interest., (Copyright © 2024. Published by Elsevier Ltd.)

The green synthesis strategy for cellulose-containing hydrogel electrolytes is significant for effectively managing resources, energy, and environmental concerns in the contemporary world. Herein, we propose an all-green strategy using AlCl 3 /ZnCl 2 /H 2 O solvent to create cellulose/polyacrylamide-based hydrogel (AZ-Cel/PAM) with expanded hierarchical topologies. The aqueous AlCl 3 /ZnCl 2 facilitates the efficient dissolution of cellulose at room temperature, and the dispersed Al 3+ -Zn 2+ ions autocatalytic system catalyzes in-situ polymerization of acrylamide (AM) monomer. This expands the AM network within the cellulose framework, forming multiple bonding interactions and stable ion channels. The resulting hybrid hydrogel exhibits improved mechanical properties (tensile strength of 56.54 kPa and compressive strength of 359.43 kPa) and enhanced ionic conductivity (1.99 S/m). Furthermore, it also demonstrates excellent adhesion, freeze resistance (-45 °C), and water retention capabilities. Quantum simulations further clarify the mechanical composition and ion transport mechanism of AZ-Cel/PAM hydrogels. The assembled supercapacitor with the hydrogel electrolyte, demonstrates an ideal area-specific capacitance of 203.80 mF/cm 2 . This all-green strategy presents a novel approach to developing sustainable energy storage devices., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Inc. All rights reserved.)

The production of hydrogen through seawater electrolysis has recently garnered increasing concern. However, hydrogen evolution reaction (HER) by alkaline seawater electrocatalysis is severely impeded by the slow H 2 O adsorption and H* binding kinetics at industrial current densities. Herein, a face-centered cubic/hexagonal close packed (fcc/hcp) NiRu alloy heterojunction was fabricated on Ni foam (N doped NiRu-inf/NF) by a low-temperature nitrogen plasma activation. Simultaneously, nitrogen atoms are introduced into the alloy to facilitate d-p hybridization. When N doped NiRu-inf/NF is integrated into a dual-electrode cell for urea-assisted seawater electrolysis, it achieves 100 mA cm -2 with an ultra-low voltage of 1.36 V and excellent stability. Density functional theory (DFT) verifies that the robust d-p hybridization among Ni, Ru and N exhibits more energy level matching for H 2 O molecule adsorption at the Ru sites, while simultaneously reducing the interaction between H* and Ni sites in N-doped NiRu-inf., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Inc.)

The pulp and paper industry generates vast quantities of paper sludge, posing significant environmental challenges due to its disposal in landfills or incineration. This study explores the potential of valorizing paper sludge by incorporating it into particleboard production. It aims to optimize sludge content and particle size to enhance board properties-a novel approach to waste management in the wood composites industry. Through systematic variation of sludge content (0-25%) and particle size (< 0.5 to > 2 mm), we assessed the mechanical and physical properties such as internal bond strength (IB), modulus of rupture (MOR), modulus of elasticity (MOE), water absorption (WA), and thickness swelling (TS). The findings indicate that incorporating paper sludge at moderate levels (5-15%) with optimized particle sizes (< 1 mm) significantly improves the mechanical properties of the particleboard, including increased IB, MOR, and MOE while reducing WA and TS. Principal Component Analysis (PCA) further supported these results, revealing that higher-density boards with enhanced mechanical properties absorb less water, highlighting the interrelationship between structural integrity and moisture resistance. The PCA also identified thickness swelling as an independent factor, suggesting that while mechanical properties can be optimized, additional strategies are needed to control swelling. In conclusion, this study demonstrates that up to 15% paper sludge can be effectively used in particleboard production without compromising quality, provided particle size is carefully controlled. This approach not only offers a sustainable solution for managing paper sludge but also contributes to the development of eco-friendly composite materials, aligning with circular economy principles., (© 2024. The Author(s).)

Biodegradable polylactic acid (PLA) nanofibrous mats prepared by electrospinning serve as suitable packaging materials. However, their practical applications are limited by their weak mechanical properties, poor thermal stability, and high cost. In this study, green and low-cost lignin-containing cellulose nanocrystals (LCNCs) with different lignin contents were developed and employed as reinforced materials to synergistically enhance the thermal, mechanical, and hydrophobic properties of PLA electrospun nanofibrous mats. The presence of moderate lignin improved the interfacial compatibility between the LCNCs and PLA, resulting in excellent mechanical properties of the nanofibrous mats. Compared to pure PLA mats, the tensile strength of the composites reached up to 21.0 MPa, representing a 6.6-fold increase. Its toughness was synchronously enhanced by 16 times, reaching a maximum of 3.6 MJ/m 3 . The maximum decomposition temperature of PLA/LCNCs electrospun nanofibrous mats increased from 339 °C to 365 °C. Furthermore, the increase in lignin in the LCNCs positively contributed to improving the hydrophobicity of the PLA/LCNCs electrospun nanofibrous mats. This bio-based strategy of LCNCs employed in the enhancement of fully bio-based PLA nanofibrous mats offers a viable approach for the advancement of packaging films., Competing Interests: Declaration of competing interest We declare that we have no financial and personal relationships with other people or organizations that can inappropriately influence this work, there is no professional or other personal interest of any nature or kind in any product, service and/or company that could be construed as influencing the position presented in, or the review of, the manuscript entitled., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Diabetic wounds are prone to recurrent infections, often leading to delayed healing. To address this challenge, we developed a chitin-copper sulfide (CuS@CH) composite sponge, which combines bacterial trapping with near-infrared (NIR) activated phototherapy for treating infected diabetic wounds. CuS nanoparticles were synthesized and incorporated in situ within the sponge using a chitin assisted biomineralization strategy. The positively charged chitin surface effectively adhered bacteria, while NIR irradiation of CuS generated reactive oxygen species (ROS) heat and Cu 2+ to rapidly damage the trapped bacteria. This synergistic effect resulted in an exceptional antibacterial performance against E. coli (∼99.9%) and S. aureus (∼99.3%). The bactericidal mechanism involved NIR-induced glutathione oxidation, membrane lipid peroxidation, and increased membrane permeability. In diabetic mouse models, the CuS@CH sponge accelerated the wound healing of S. aureus infected wounds by facilitating collagen deposition and reducing inflammation. Furthermore, the sponge demonstrated good biocompatibility. This dual-functional platform integrating bacterial capture and NIR-triggered phototherapy shows promise as an antibacterial wound dressing to promote healing of infected diabetic wound.

Conductive hydrogels have been increasingly employed to construct wearable mechanosensors due to their excellent mechanical flexibility close to that of soft tissues. In this work, piezoelectric hydrogels are prepared through free radical copolymerization of acrylamide (AM) and acrylonitrile (AN) and further utilized in assembling flexible wearable mechanosensors. Introduction of the polyacrylonitrile (PAN) component in the copolymers endows the hydrogels with excellent piezoelectric properties. Meanwhile, significant enhancement of mechanical properties has been accessed by forming dipole-dipole interactions, which results in a tensile strength of 0.51 MPa. Flexible wearable mechanosensors are fabricated by utilizing piezoelectric hydrogels as key signal converting materials. Self-powered piezoelectric pressure sensors are assembled with a sensitivity ( S ) of 0.2 V kPa -1 . Additionally, resistive strain sensors (gauge factor (GF): 0.84, strain range: 0-250%) and capacitive pressure sensors ( S : 0.23 kPa -1 , pressure range: 0-8 kPa) are fabricated by utilizing such hydrogels. These flexible wearable mechanosensors can monitor diverse body movements such as joint bending, walking, running, and stair climbing. This work is anticipated to offer promising soft materials for efficient mechanical-to-electrical signal conversion and provides new insights into the development of various wearable mechanosensors.

Good dispersion of carbon fibers is important for the carbon paper production, which is usually achieved using low carbon fiber concentrations and disposable dispersants. In this study, we developed carbomer as a recyclable and high-efficiency dispersant for carbon fibers. When the carbon fiber concentration was 0.1 wt%, carbon fiber suspension showed improved dispersion performance as increasing the carbomer dosage. It exhibited low Turbiscan Stability Index (TSI) of 0.41 and small change of delta backscattering between -0.5 to 0.8 % when using 0.5 wt% carbomer. However, the good dispersibility fade away when increasing the concentration of carbon fibers. Subsequently, the pH of the carbon fiber suspension was adjusted to 7.0 to improve the dispersibility by increasing the viscosity, but causing a worse flowability. Then the pH was further adjusted to 13.0 to ensure good flowability in the wet-forming process and good dispersibility at carbon fiber concentration of 0.5 wt%. More importantly, the dispersant was successfully recycled and still exhibited excellent dispersion effects for carbon fibers after 5 cycles. Notably, the high-efficiency dispersion of carbon fibers and the recyclability of dispersant were achieved simultaneously for the first time, which is suitable for the eco-friendly and sustainable production of carbon paper., Competing Interests: Declaration of competing interest We declare that we have no financial and personal relationships with other people or organizations that can inappropriately influences our work. There is no professional or other personal interest of any nature or kind in any product., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Lithium-sulfur (Li-S) batteries are considered as promising energy storage systems due to the high energy density of 2600 W h kg -1 . However, the practical application of Li-S batteries is hindered by the inadequate conductivity of sulfur and Li 2 S, as well as the shuttle effect caused by polysulfides during the charge-discharge process. Introducing a conductive interlayer between the cathode and the separator to physically resist polysulfides represents an effective and straightforward approach to mitigate the shuttle effect in Li-S batteries. In this paper, an ultrathin (<1 μm) 2D-2D MXene-LDH interlayer with high polysulfide adsorption ability was introduced to Li-S batteries. The synergistic effect between MXene and layered double hydroxide greatly improved the adsorption effect of the interlayers: the conductive Ti 3 C 2 T x MXene chemically adsorbs polysulfides and promotes their fast transfer, and the NiCo-LDH alleviates the restack of MXene and facilitates Li + diffusion. After inserting the MXene-LDH interlayer, the Li-S batteries exhibit an enhanced specific capacity of 1137.6 mA h g -1 at 0.1 C and retain 622.6 mA h g -1 after 100 cycles. The ultrathin 2D-2D interlayer offers a feasible way for the development of highly efficient and lightweight interlayers in Li-S batteries.

A new Candida parapsilosis ACCC 20221 ( C. parapsilosis ACCC 20221) whole-cell catalyst with a high phenolic glycoside esters synthesis activity and large biomass was obtained after culture with glucose. The possible mechanisms were revealed by using comparative proteomics. It found the expression of proteins involved in post-translational modification, protein turnover, and chaperone, and RNA processing and modification was upregulated, which ensured the metabolic balance and accurate translation, correct folding, and post-translational modification of proteins, thus enhancing the production of lipases in C. parapsilosis ACCC 20221 cultured with glucose. Moreover, the glycolysis pathway, tricarboxylic acid cycle, and fatty acids synthesis were enhanced, while the β-oxidation of fatty acids was weakened in C. parapsilosis ACCC 20221 cells cultured with glucose, which led to an increase in energy generation and cell membrane synthesis; thus, large biomass was obtained. In addition, CCE40476.1 and CAC86400.1, which were likely to exert arbutin esters synthesis activity in C. parapsilosis ACCC 20221, were screened, and it was found that vinyl propionate could easily enter the catalytic pocket of CCE40476.1 and form hydrogen bonding interactions with Leu191 and Ser266.

Due to the heterogeneity of recycled paper materials and the production conditions, pollutants in papermaking wastewater fluctuate sharply over time. Quality control of the papermaking wastewater treatment process (PWTP) is challenging and costly. As regulations are also growing about the environmental effects of the PWTP on greenhouse gas (GHG) emission, energy consumption, etc., the PWTP formulates a complex multiobjective optimization problem. This research established a multiagent deep reinforcement learning framework to simultaneously optimize process cost, energy consumption, and GHG emission in the PWTP, subjected to the effluent quality, to realize economic, energy, and environmental (3E) goals. The biological treatment process of wastewater in paper mills was simulated using benchmark simulation model no. 1 (BSM1). The data generated based on the BSM manual was utilized for model training, and real data acquired from a local papermaking factory was used to estimate the model performance. The results show that the proposed method outperforms conventional techniques in identifying the best control strategies for multiple targets.

Carbohydrate-binding modules (CBM) have emerged as useful tools for a wide range of tasks, including the use as purification tags or for cellulose fiber modification. For this purpose, the CBM needs to be attached to a target protein leading to large constructs. We investigated if short peptides from the carbohydrate binding site of CBMs can bind in a similar way as native, full-length CBMs to nanocrystalline cellulose (NCC) or cotton linter paper. We designed our cellulose-binding peptides to be less hydrophobic and shorter than those previously reported. Starting from the binding site of Cel7A-CBM1, we incorporated the essential amino acids involved in cellulose binding into our peptides. These peptides, as well as control peptides with scrambled sequences or a lack of essential amino acids, bound to cellulose with similar affinity as CBM regardless of their secondary structure, sequence, or hydrophobicity. This unspecific mode of cellulose binding displayed by the presented peptides may be exploited to functionalize cellulose-based biomaterials by means of peptide-conjugates.

Compared to traditional lithium metal batteries, anode-free lithium metal batteries use bare current collectors as an anode instead of Li metal, making them highly promising for mass production and achieving high-energy density. The current collector, as the sole component of the anode, is crucial in lithium deposition-stripping behavior and greatly impacts the rate of Li depletion from the cathode. In this study, to investigate the lithiophilicity effect of the current collector on the solid electrolyte interface (SEI) film construction and cycling performance of anode-free lithium batteries, various lightweight paper-based current collectors were prepared by electroless plating Cu and lipophilic Ag on low-dust paper (LDP). The areal densities of the as-prepared LDP@Cu, LDP@Cu-Ag, and LDP@Ag were approximately 0.33 mg cm -2 . The use of lipophilic Ag-coated collectors with varying loadings allowed for the regulation of lipophilicity. The impacts of these collectors on the distribution of SEI components and Li depletion rate in common electrolytes were investigated. The findings suggest that higher loadings of lipophilic materials, such as Ag, on the current collector increase its lipophilicity but also lead to significant Li depletion during the cycling process in full-cell anode-free Li metal batteries. Thus, moderately lithiophilic current collectors, such as LDP@Cu-Ag, show more potential for Li deposition and striping and stable SEI with a low speed of Li depletion.

In recent years, flexible sensors constructed mainly from hydrogels have received increasing attention. However, conventional hydrogels need to be prepared by high-temperature or radiation-induced polymerization reactions, which limits their practical applications due to their suboptimal electrical conductivity and weak mechanical properties. In this paper, using sodium lignosulfonate as the raw material, a dynamic catechol-quinone redox system formed by lignin‑zinc ions was constructed to initiate rapid free radical polymerization of acrylamide (AM) monomer at room temperature. In addition, Deep eutectic solvent (DES) can form a strong hydrogen bonding network within the molecules and between the molecules of the hydrogel, resulting in a hydrogel with good tensile properties (hydrogel elongation at break of 727.19 %, breaking strength of 84.09 kPa), and provides the hydrogel with high electrical conductivity, anti-dehydration, anti-freezing, and anti-bacterial properties. Meanwhile, the addition of lignin also improved the adhesion and UV resistance of the hydrogel. This hydrogel assembled into a flexible sensor can sense various small and large amplitude movements such as nodding, smiling, frowning, etc., and has a wide range of applications in flexible sensors., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier B.V.)

The rapid emergence of microfluidic paper-based devices as point-of-care testing (POCT) tools for early disease diagnosis and health monitoring, particularly in resource-limited areas, holds immense potential for enhancing healthcare accessibility. Leveraging the numerous advantages of paper, such as capillary-driven flow, porous structure, hydrophilic functional groups, biodegradability, cost-effectiveness, and flexibility, it has become a pivotal choice for microfluidic substrates. The repertoire of microfluidic paper-based devices includes one-dimensional lateral flow assays (1D LFAs), two-dimensional microfluidic paper-based analytical devices (2D μPADs), and three-dimensional (3D) μPADs. In this comprehensive review, we provide and examine crucial information related to paper substrates, design strategies, and detection methods in multi-dimensional microfluidic paper-based devices. We also investigate potential applications of microfluidic paper-based devices for detecting viruses, metabolites and hormones in non-invasive samples such as human saliva, sweat and urine. Additionally, we delve into capillary-driven flow alternative theoretical models of fluids within the paper to provide guidance. Finally, we critically examine the potential for future developments and address challenges for multi-dimensional microfluidic paper-based devices in advancing noninvasive early diagnosis and health monitoring. This article showcases their transformative impact on healthcare, paving the way for enhanced medical services worldwide., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Lignin, an abundant natural resource, has not been effectively utilized. In this study, the functionality of lignin was enhanced through amination to produce amine-crosslinked lignin, and its adsorption behavior toward cationic and anionic dyes was investigated. Chemical structure analysis confirmed the successful introduction of amine groups, thereby improving the molecular weight and thermal stability of the optimized amine-crosslinked lignin. Additionally, the amine-crosslinked lignin exhibited a larger specific surface area than kraft lignin, as well as excellent adsorption capacity for both anionic and cationic dyes. Furthermore, it selectively adsorbed anionic and cationic dyes depending on pH conditions. The adsorption kinetics were described using a pseudo-second-order model, and the adsorption isotherms for congo red and methyl green were determined using the Langmuir and Freundlich equations, respectively. Additionally, the reusability and adsorption efficiency of the optimized amine-crosslinked lignin were evaluated, confirming its stable and repeatable adsorption efficiency for congo red and methyl green even after five repeated cycles. The assumed adsorption mechanism was attributed to electrostatic interactions. Therefore, the successful synthesis and excellent adsorption properties of amine-crosslinked lignin suggest its promising potential for environmentally friendly and efficient removal of both cationic and anionic dyes, thereby offering a sustainable solution for wastewater treatment and remediation., Competing Interests: The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (© 2024 The Authors.)

This study focuses on the sustainable production of bio-jet fuel through the catalytic hydrodeoxygenation (HDO) of isoeugenol (IE). Properties of two spraying synthesis methods (in situ and ex situ metal doping) with different platinum (Pt) loading percentages. The catalyst was characterised using various techniques such as XAS, X-ray photoelectron spectroscopy, X-ray diffraction, high-resolution transmission electron microscopy (HRTEM), field-emission scanning electron microscopy (FESEM) and thermogravimetric analysis. The HRTEM and FESEM results show the successful preparation of a spherical nanoparticle doped over activated carbon, and Pt was dispersed on the outer shell of the particles. The catalytic HDO of IE showed a high yield and conversion as follows: IE conversion of 100%, liquid-phase mass balance of 95.92%, dihydroeugenol conversion of 99.32%, propylcyclohexane yield of 88.94% and HYD yield of 76.19%. Moreover, the catalyst exhibited high reusability with low metal leaching and high coke resistance for 10 cycles. The catalyst was evaluated in a continuous flow reactor for 100 h at different reaction temperatures, and interestingly, the catalyst showed low deactivation with a high half-time., (© 2024 Wiley‐VCH GmbH.)

Thermosets are well known for their advantages such as high stability and chemical resistance. However, developing sustainable thermosets with degradability and recyclability faces several principal challenges, including reconciling the desired characteristics during service with the recycling and reprocessing properties required at the end of life, establishing efficient methods for large-scale synthesis, and aligning with current manufacturing process. Here a general strategy is presented for the on-demand degradation and recycling of thermosets under mild conditions utilizing dynamic precursors with dual-factor-controlled reversibility. Specifically, dynamic triazine crosslinkers are introduced through dynamic nucleophilic aromatic substitution (S N Ar) into the precursor polyols used in polyurethane (PU) synthesis. Upon removal of the catalyst and alcohol, the reversibility of S N Ar is deactivated, allowing for the use of standard PU polymerization techniques such as injection molding, casting, and foaming. The resulting cyanurate-crosslinked PUs maintain high stability and diverse mechanical properties of traditional crosslinked PUs, yet offer the advantage of easy on-demand depolymerization for recycling by activating the reversibility of S N Ar under specific but mild conditions-a combination of base, alcohol, and mild heat. It is envisioned that this approach, involving the pre-installation of dual-factor-controlled dynamic crosslinkers, can be broadly applied to current thermosetting plastic manufacturing processes, introducing enhanced sustainability., (© 2024 Wiley‐VCH GmbH.)

Castor stalk from hemp plants is an attractive lignocellulosic feedstock for biomass refining valorization due to its similar chemical composition to hardwoods. In this study, the castor stalk fibers were pretreated with efficient dual-functional ethanolamine to achieve delignification and swelling of the cellulosic fibers, followed by cellulase enzymatic digestion for biomass conversion. Experimental results showed that ethanolamine pretreatment at 160 °C for 1 h effectively removed 69.20 % of lignin and 43.18 % of hemicellulose. In addition to efficient delignification and removal of hemicellulose, the study also revealed that supramolecular structure of cellulose was another major factor affecting enzymatic hydrolysis performance. The lowered crystallinity (60-70 %) and swelled crystal sizes (2.95-3.04 nm) promoted enzymatic hydrolysis efficiency during the heterogeneous reaction process. Under optimal conditions (160 °C, 1 h; enzyme loading: 15 FPU/g substrate), promoted yields of 100 % glucose and over 90 % xylose were achieved, which were significantly higher than those obtained from untreated castor stalk. These findings highlighted the effectiveness of the dual-functional ethanolamine pretreatment strategy for efficient bioconversion of lignocellulosic feedstocks. Overall, this study provides valuable insights into the development of new strategies for the efficient utilization of biomass resources, which is essential for the sustainable development of our society., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier B.V.)

Porphyromonas gingivalis causes various health issues through oral infections. This study investigates the antibacterial activities of food-derived dihydrochalcone flavonoids against Porphyromonas gingivalis and their mechanisms of antibacterial action through comparative transcriptome profiling. Susceptibility tests showed that two typical dihydrochalcone flavonoids (phloretin and phlorizin) had much lower minimum inhibitory concentrations (12.5 μg mL -1 and 50 μg mL -1 , respectively) than the common flavanone naringenin (100 μg mL -1 ). SEM observations and the LDH activity assay indicated obvious anomalies in cell morphology and increased cell membrane permeability, indicating the destructive effect of those compounds on the cell structure. These compounds might also induce apoptosis in P. gingivalis , as shown by the CLSM fluorescence images. Transcriptomic analysis revealed that the flavonoid treatment impacted DNA function and oxidative damage. These flavonoids may activate antioxidant-related pathways that are lethal to anaerobic bacteria like P. gingivalis . Additionally, the compounds resulted in the silencing of transposition-related genes, potentially inhibiting resistance-gene acquisition and expression. Phloretin regulated fatty acid metabolism pathways, which are related to the construction and maintenance of the cell membrane. This suggests a relationship between the structure and antibacterial activities of the tested compounds that share a flavonoid skeleton but differ in the C-ring and glucose moiety. This is the first report of the antibacterial activities and mechanisms of action of food-derived dihydrochalcone flavonoids at the transcriptome level, offering a promising approach for the development of new antibacterial agents from natural products and enhancing their applicability in treating diseases associated with oral pathogens as a substitute for antibiotics.

Concern about food safety triggers demand on rapid, accurate and on-site detection of foodborne pathogens. Among various fluorescent probes for detection, carbon dots (CDs) prepared by carbonization of carbon-rich raw materials show extraordinary performance for their excellent and tailorable photoluminescence property, as well as their facilely gained specificity by surface customization and modification. CDs-based fluorescent probes play a crucial role in many pathogenic bacteria sensing systems. In addition, microfluidic technology with characteristics of portability and functional integration is expected to combine with CDs-based fluorescent probes for point-of-care testing (POCT), which can further enhance the detection property of CDs-based fluorescent probes. Here, this paper reviews CDs-based bacterial detection methods and systems, including the structural modulation of fluorescent probes and pathogenic bacteria detection mechanisms, and describes the potential of combining CDs with microfluidic technology, providing reference for the development of novel rapid detection technology for pathogenic bacteria in food., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Food safety and authenticity analysis play a pivotal role in guaranteeing food quality, safeguarding public health, and upholding consumer trust. In recent years, significant social progress has presented fresh challenges in the realm of food analysis, underscoring the imperative requirement to devise innovative and expedient approaches for conducting on-site assessments. Consequently, cellulose paper-based devices (PADs) have come into the spotlight due to their characteristics of microchannels and inherent capillary action. This review summarizes the recent advances in cellulose PADs in various food products, comprising various fabrication strategies, detection methods such as mass spectrometry and multi-mode detection, sampling and processing considerations, as well as applications in screening food safety factors and assessing food authenticity developed in the past 3 years. According to the above studies, cellulose PADs face challenges such as limited sample processing, inadequate multiplexing capabilities, and the requirement for workflow integration, while emerging innovations, comprising the use of simplified sample pretreatment techniques, the integration of advanced nanomaterials, and advanced instruments such as portable mass spectrometer and the innovation of multimodal detection methods, offer potential solutions and are highlighted as promising directions. This review underscores the significant potential of cellulose PADs in facilitating decentralized, cost-effective, and simplified testing methodologies to maintain food safety standards. With the progression of interdisciplinary research, cellulose PADs are expected to become essential platforms for on-site food safety and authentication analysis, thereby significantly enhancing global food safety for consumers., (© 2024 Institute of Food Technologists®.)

Traditional packaging materials feed the growing global food protection. However, these packaging materials are not conducive to environment and have not the ability to kill bacteria. Herein, a green and simple strategy is reported for food packaging protection and long-term antibacterial using carboxymethylcellulose-based photothermal film (CMC@CuS NPs/PVA) that consists of carboxymethyl cellulose (CMC) immobilized copper sulfide nanoparticles (CuS NPs) and polyvinyl alcohol (PVA). With satisfied oxygen transmittance (0.03 cc/m 2 /day) and water vapor transmittance (163.3 g/m 2 /day), the tensile strength, tear strength and burst strength reached to 3401.2 N/m, 845.7 mN and 363.6 kPa, respectively, which could lift 4.5 L of water. The composite film had excellent photothermal conversion efficiency and photothermal stability. Under the irradiation of near infrared (NIR), it can rapidly heated up to 197 °C within 25 s. The antibacterial analysis showed that the inhibition rate of composite film against Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli) could all reach >99 %. Furthermore, the synthesized CuS NPs was well immobilized and the residual rate of copper kept 98.7 % after 10 days. Noticeably, the composite film can preserve freshness of strawberries for up to 6 days. Therefore, the composite film has potential application for food antibacterial protection., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

This study reports the cellulo-xylanolytic cocktail production from Hypocrea lixii GGRK4 using multi-objective genetic algorithm-artificial neural network tool, resulting in 8.32 ± 1.07 IU/mL, 51.53 ± 3.78 IU/mL activity of CMCase and xylanase, respectively with more than 85 % residual activity at 60 °C and pH 6.0. Interestingly, metal ions viz. K + and Ca 2+ stimulated the enzyme activity, whereas Fe 2+ and Cu 2+ reduced the activity. Significant amounts of hydrophobic compounds, chromophores, and phenolics were released after wastepapers deinking. The deinking efficiency of 73.60 ± 2.45 % and 38.60 ± 1.34 % was obtained for photocopier paper and newspaper, respectively, whereas brightness of 89.90 ± 2.10 % ISO and 44.90 ± 1.63 % ISO was reported for both types of waste papers. The physical strength of deinked photocopier paper and newspapers, i.e., tensile index (3.10 and 0.50 %), tearing index (7.10 and 4.83 %), and burst factor (8.61) were enhanced whereas double fold property was decreased proving wastepaper reusability. This consortium showed effective and significant enzymatic deinking efficiency for recycled wastepapers., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

To find a new way to slow down the release of glufosinate (GA) pesticide and to solve the susceptibility to decomposition by soil microorganisms, a series of novel antibacterial polysaccharide-based sustained release beads (PSRB) were prepared. The PSRB was prepared by immobilization of GA loaded polysaccharide-based chitosan quaternary ammonium salt (PS-HACC) microcapsules in the core and layers of the multilayer sodium alginate beads. The PSRB was characterized by FI-IR spectroscopy, XRD, SEM, and BET to reveal their composition and surface morphology. The optimal conditions of the slow release beads were as follows, the concentration of Ca 2+ , pH, temperature and the coating layer number was 0.1 mol/L, 7, 25 °Cand 3, respectively. The kinetic study showed that the slow release of PSRB was in accordance with the Higuchi kinetic model, and the FI-IR and XRD analyses revealed that the PS-HACC and GA were successfully cross-linked to the PSRB. BET showed that PSRB were greater than PSRB 3 at surface area, pore volume and pore size. Inhibition circles experiments demonstrated that WPSRB 3 has good antibacterial activity. The weed control in soybean with PSRB 3 application is perfect and the weed control cycle is long. Therefore, this technology can provide a potential way to control GA release, improve utilization efficiency, reduce pesticide use and environmental pollution, and at the same time, provide a potential way to achieve ecological agriculture., Competing Interests: Declaration of competing interest The authors declare no competing financial interest., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Butelase-1, the fastest known Asn/Asp-specific peptide ligase capable of catalyzing peptide ligation and cyclization, holds promising application prospects in the fields of food and biology. However, limited research exists on its recombinant expression and potential applications in peptide drugs. In this study, the activity of recombinantly-produced butelase-1 was enhanced by co-expressing it with a molecular chaperone in the SHuffle T7 strain. By introducing single or multiple synonymous rare codons at the beginning of the coding regions of beta-strand or alpha-helix, in combination with ribosomal binding site engineering, the activity of butelase-1 could be further improved. Consequently, the butelase-1 with a specific activity of 386.93 U/mg and a catalytic efficiency of 11,048 M -1  s -1 was successfully prepared in E. coli, resulting in a total activity of 8183.54 U/L and a yield of about 100 mg/L. This optimized butelase-1 was then used to efficiently cyclize the redesigned anti-cancer peptide lunasin, leading to enhanced bioavailability and anti-cancer effects. Overall, this study not only provided valuable biotechnology strategies for improving the recombinant expression of butelase-1 but also demonstrated a successful application for enhancing the biological efficacy of anti-cancer peptides., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Recently, hydrogel sensors have been widely applied in wearable and portable electronics, but the low mechanical property, intolerance of fatigue, and low sensitivity and adhesion limit their further applications. In this study, sulfonated nanocellulose (SCNF) with dual functionality was blended into polyacrylamide (PAM) hydrogel matrix to reinforce the mechanical strength and facilitate the homogeneous dispersion of carbon nanotubes (CNTs). The SCNF-CNT/PAM hydrogel was designed through free radical polymerization to achieve commendable mechanical, electrical, and multifunctional properties. The environmental-friendly SCNF serves as bio-templates to facilitate the assembling of CNT into integrated SCNF-CNT structures with good dispersity, thus enabling the establishment of an integrated conducting and reinforcing network. The fabricated SCNF-CNT/PAM hydrogel exhibited outstanding compressive strength (∼0.45 MPa at 50 % strain), tensile strength (∼169.12 kPa), and antifatigue capacity under cyclic stretching and pressing. Furthermore, the multifunctional sensors assembled using this hydrogel demonstrated high strain sensitivity (gauge factor ~ 3.7 at 100-400 % strain) and effectively detected human motions. This design principle provides promising prospects for constructing next-generation multifunctional flexible sensors, and the integration of these distinctive properties enables the prepared composite hydrogels to find potential applications in various areas, such as implantable soft electronic devices, electronic skin, and human movement monitoring., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Food waste occurs frequently worldwide, though hunger and malnutrition issues have received global attention. Short-term spoilage of perishable foods causes a significant proportion of food waste. Developing simple, green, and low-cost strategies to preserve the freshness of perishable foods is important to address this issue and improving food safety. By using strawberries as the model perishable fruit, this study reported a pectin/carboxy methyl starch sodium (PC) based coating using epigallocatechin gallate-loaded eggshell powder (ES@EGCG) as the functional fillers. In comparison to PC coating, the PC-ES@EGCG coating displayed much-enhanced performance, such as enhanced mechanical (2 folds) and barrier (water vapor & oxygen) properties. This composite coating reduced the weight loss of strawberries from over 60% to around 30% after 7-day storage. Coated strawberries exhibit better freshness retention, which achieves the purpose of preserving strawberries during storage. This study provided a cost-effective and eco-friendly coating strategy for reducing food waste., Competing Interests: Declaration of competing interest The authors report no declarations of interest., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

This study was conducted to investigate the morphological, thermal, mechanical, FTIR, physicochemical (thickness, humidity, solubility in water and water vapor permeability) and antimicrobial properties of polylactic acid film (PLA) containing hybrid graphene oxide‑zinc oxide (GO-ZnO: 1.5 % w/v) and Mentha longifolia essential oil (ML:1 % v/v) on chicken fillet kept in the refrigerator. The studied groups were microbially (total count of mesophilic aerobic bacteria, psychrotrophic bacteria, Enterobacteriaceae, Staphylococcus aureus, and lactic acid bacteria), chemically (pH, TVB-N) and sensory (color, odor, and taste) evaluated at 8-day interval (0, 2, 5 and 8). In the examination of the morphological characteristics, the PLA film had a smooth and uniform surface and the addition of ML essential oil created a discontinuous structure and the addition of GO-ZnO led to the production of a denser and more homogeneous film. The presence of GO-ZnO increased the thickness, decreased moisture content and solubility in water, and added ML essential oil increased moisture content and decreased solubility in water (p˂0.05). The results of the mechanical evaluation showed that the addition of ML essential oil and GO-ZnO reduced elongation at break and tensile strength (p˂0.05). The addition of ML essential oil increased the thermal resistance and the addition of GO-ZnO decreased the thermal resistance compared to the film containing ML essential oil. The antimicrobial effect of films containing ML essential oil was confirmed in this study (p˂0.05). The addition of GO-ZnO did not change the count of any of the microbial groups. TVB-N showed that groups containing ML essential oil had lower levels of volatile nitrogenous bases than the control group (p˂0.05). Sensory evaluation of the studied groups showed that chicken fillets packed with films containing ML essential oil had the highest score in terms of color, smell and taste. The results of the present study showed that PLA film containing GO-ZnO and ML essential oil can be used to increase the shelf life and maintain the sensory characteristics of chicken fillets, and it can be used as a suitable packaging to increase the shelf life of food products., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this article., (Copyright © 2024. Published by Elsevier B.V.)

To increase the value of waste coconut shells and further broaden their use by biorefining, a milder and greener method to prepare cellulose nanofibers (CCNFs) was developed. The CCNFs were separated from coir fibers by using peroxyformic acid and alkali treatment in combination with high-power ultrasonication. The basic properties of the CCNFs were comprehensively evaluated using scanning and transmission electron microscopy, spectroscopy, diffraction, and thermogravimetric techniques. The results revealed that the developed preparation method provided CCNFs with typical nanocellulose sizes, structures, and properties. Nanocellulose-reinforced poly(vinyl acetate) (PVA) composite films were prepared using the CCNFs, and their mechanical properties, transmittance, crystallinity, and thermal stability were investigated. The elongation at break of the film with 8% CCNFs was 612%. The tensile strength of the films with 4 and 12% CCNFs was 41.3 MPa, which was higher than that of a PVA film (36 MPa). The transmittance and thermal stability of the PVA composite films were not appreciably affected by the CCNFs. The CCNFs show promise as a nanofiller for PVA-based composite films with favorable mechanical properties, crystallinity, and high transparency., Competing Interests: The authors declare no competing financial interest., (© 2024 The Authors. Published by American Chemical Society.)

Peroxymonosulfate (PMS) activation technology has important application value in treating emerging contaminant (ECs), but it still faces challenges in achieving efficient electron transfer and metal valence cycling. In this study, the interfacial electric field characteristics of FeNC catalysts were adjusted by introducing NC defects to affect the electron transfer process, thereby enhancing the catalytic performance of PMS. It is found that in the FeNC structure, the shift of the charge generates an interfacial electric field, which can promote the directional transfer of electrons. Through quantitative structure-activity relationship (QSAR) analysis, it was confirmed that the defect played a decisive role in regulating the interfacial electric field and improving the catalytic reaction efficiency. The interfacial electric field-mediated superexchange interaction realizes the electron donor effect of organic pollutants and the effective electron transfer between the Fe site, accelerates the electron cycling of the Fe site, and realizes the rapid and stable catalysis of PMS. The increase of the occupancy state distribution of d orbitals near the Fermi level provides favorable conditions for electron transitions and catalytic activation of PMS. ECs can be converted into environmentally friendly, non-toxic and harmless substances through. This defect-controlled interface electric field strategy realizes rapid electron directional transfer, which provides a new solution for improving the catalytic efficiency of PMS and the safe treatment of ECs in water., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Inc. All rights reserved.)

This study focuses on optimizing the pulping by-product to produce effective hydrogels for controlling the release of salicylic acid (SA). In this regard, two routes are achieved: the first involves preparing black liquor (BL) composite hydrogels with various polymer macromolecules [polyacrylamide (PAM), polyvinyl alcohol (PVA), and chitosan (Cs), and the second involves carboxymethylation of BL and grafting with acrylamide. Hydrogels are evaluated using spectral analysis (ATR-FTIR), thermal analysis (TGA and DTG), and swelling measures. Encapsulation, release profile, SA release kinetics, as well as ATR-FTIR and SEM measurements, were used to evaluate the behavior of loaded hydrogels. According to the results, grafted carboxymethylated BL-gel had the maximum SA release (98.7 %), followed by PAM-BL (51.7 %) and PAM/PVA-BL (43.1 %). Over a 48-hour period, the hydrogels demonstrated a prolonged SA release pattern. The Ritger-Peppas and Higuchi models fitted to all examined hydrogels showed that SA release followed both Fickian and non-Fickian diffusion pathways., Competing Interests: Declaration of competing interest Authors declare that there is no conflict among the contributing author related to the financial or non-financial interests that are directly or indirectly related to the work submitted for publication., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Corrosion of steel in the marine environment greatly reduces their service life. Polymeric coatings are the most popular anticorrosion technology, but seawater penetration cannot be prohibited because of the distinct stacking structure of the macromolecular chains. In this context, a novel anticorrosive hyperbranched polyurethane-based coating with dopamine (DOPA) at the terminals is prepared herein. The built-in DOPA is able to capture the iron ions released from the corroded substrate and form DOPA-Fe 3+ complexation, which further cooperates with the surrounding seawater and imparts self-passivation, self-delivery and self-healing capabilities to the coating. Under the joint action of these measures, the corrosion of tinplate (serving as the steel model) is reduced to a record-low level (corrosion current = 1 × 10 -9  A cm -2 , corrosion rate = 1 × 10 -5  mm year -1 ). Conceptually, the present dynamic active anticorrosion strategy greatly outperforms the traditional static passive approach, and turns the unfavorable but unavoidable seawater into a favorable factor, which paves the way for the development of long-lasting marine coatings., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Inc. All rights reserved.)

The hybrid composite sample based on Prosopis Juliflora (PJ) bark and ramie fibre with different length, weight percentage, and curing temperature were created for the first time in this work. Totally, 120 hybrid composite samples were tested in this study. There were five different fibre lengths: 10 mm, 15 mm, 20 mm, 25 mm, and 30 mm, weight percentages 10 %, 20 %, 30 %, 40 %, and 50 %, and different curing temperatures 80 °C, 90 °C, 100 °C, 110 °C, and 120 °C used to produce the hybrid composite samples. Due to the cross-linking ability with the epoxy matrix, the hybrid composite specimen shows high resistance up to 98 Shore D hardness. The high polarity of the epoxy matrix and the hydrogen bond strengthening effect, increased the composite sample flexural strength by 12 %. The curing temperature of 100 °C, 20 mm fibre length, and 30 % of the hybrid composite sample achieved the highest tensile strength (28.76 MPa), flexural strength (46.54 MPa), impact strength (4.5 J), and hardness strength properties (98 shore D). Thermo gravimetric analysis (TGA) revealed the composite samples initial decomposition temperature (T i ) at 98 °C, maximum decomposition temperature (T max ) at 320 °C, and the final decomposition temperature (T f ) at 466 °C., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Paper relics, as carrieres of historical civilization's records and inheritance, could be severely acidic and brittle over time. In this study, the multi-functional dispersion of nanometer magnesium oxide (MgO) carried by 3-aminopropyl triethoxysilane-modified bacterial cellulose (KH550-BC) was applied in the impregnation process to repair aged paper, aiming at solving the key problems of anti-acid and strength recovery in the protection of ancient books. The KH550-BC/MgO treatment demonstrated enhanced functional efficacy in repairing aged paper, attributed to the homogeneous and stable distribution of MgO within the nanofibers of BC networks, with minimal impact on the paper's wettability and color. Furthermore, the treatment facilitated the formation of adequate alkali reserves and hydrogen bonding, resulting in superior anti-aging properties in the treated paper during prolonged preservation. Even after 30 days of hygrothermal aging tests, the paper repaired by KH550-BC/MgO was still in a gently alkaline environment (pH was about 7.56), alongside a 32.18% elevation compared to the untreated paper regarding the tear index. The results of this work indicate that KH550-BC/MgO is an effective reinforcement material for improving the long-term restoration of ancient books.

In this paper, N-vinylpyrrolidone was copolymerized with acrylic acid and itaconic acid by free radical polymerization, and a series of polyacrylic acid-co-itaconic acid-co-N-vinylpyrrolidone (PAIN) dispersants with different pyrrolidone ligand contents were synthesized and characterized. Then, the cobalt blue nano-pigment slurry (20 wt%) was prepared through a water-based grinding method, and the optimum grinding technology was explored and determined as follows: PAIN2 as a dispersant, a dispersant dosage of 10 wt%, and a grinding time of 480 min. According to this optimum grinding technology, the prepared pigment slurry had a significantly decreased agglomeration, the D 90 of which was 82 nm, and separately increased to 130 nm and 150 nm after heat storage for 3 and 7 days, exhibiting excellent heat storage stability. Additionally, its TSI value was also the lowest (1.9%), indicating good dispersion stability. The QCM and adorption capacity measuring results showed PAIN2 had a larger adsorption capacity, and the formed adsorption layer had a higher rigidity and was not easy to fall off. This was caused by both the interaction of carboxyl groups and the pyrrolidone ligand (strong coordination interaction) in PAIN2 with cobalt blue. The XPS and FT-IR measurements further proved the above-mentioned adsorption mechanism.

Background : Employing citric acid/dimethyl formamide (CA/DMF), two distinct types of carbon quantum dots (CQDs), tree-shaped/fingerprinted (TF-CQDs) and fullerene-like (F) were synthesized from both cellulose and carboxymethyl cellulose (CMC). Methods : Fluorescence microscopy revealed different emission colors: blue for TF-CQDs and green for F, highlighting the structural influence on light properties. Transmission electron microscopy (TEM) confirmed the intricate fingerprinted and tree-like morphology of TF-CQDs and the spherical nature of F derived from CMC. The adsorption behavior and kinetics of Cr(vi) removal from water by TF-CQDs and F were evaluated. Significant findings : Both samples demonstrated rapid Cr(vi) uptake; TF-CQDs reached equilibrium within 120 minutes compared to 240 minutes for F. Subsequent leaching led to decreased adsorption after these initial periods. Kinetic analysis revealed a first-order model for TF-CQDs, implying physical adsorption dominance. Conversely, F exhibited a better fit to pseudo-first and second-order models, suggesting combined chemical and physical mechanisms., Competing Interests: There are no conflicts to declare., (This journal is © The Royal Society of Chemistry.)

Cellulose microspheres (CMS) are a type of spherical regenerated cellulose particles with versatile properties which have been used as carrier materials in medical and technical applications. The integration of CMS into paper products opens up novel application scenarios for paper products in a wide range of fields. However, the incorporation of CMS carriers into paper products is challenging and hitherto no reports do exist in literature. Here, we present a feasibility study to incorporate up to 50 w.% CMS in paper hand sheets using retention aids. Our primary observations highlight the successful formation of uniform paper hand sheets retaining its tensile strengths at elevated CMS concentrations. Sheets with high CMS contents exhibit an increase in density and display enhanced surface smoothness - an outcome of a CMS layer forming atop the fiber base - which effectively bridges voids and rectifies surface irregularities as supported by Gurley testing, infinite focus microscopy and scanning electron microscopy. While our primary objective centered on the general feasibility to manufacture CMS-containing papers, the resulting composite scaffold carries significant potential as a platform for innovative, functional paper-based materials., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Ltd.. All rights reserved.)