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1. Theoretical calculations of the proton affinities of n-alkylamines, n-alkyl thiols, and n-alcohols and the ammonium of the n-alcohols

Author

Ligon, Axel Patrick

Subjects
Alcohols -- Production processes, Thiols -- Production processes, Amines -- Research, Protons -- Research, Chemicals, plastics and rubber industries
Abstract

Proton affinities of n-alkylamines, n-alkyl thiols, n-alcohols and the ammonium affinities of n-alcohols up to C-18 were calculated and they were all found to be co-relating linearly. The calculated PA's make it clear that NH3 is an appropriate reactant gas for the formation of the so-called 'quasi-molecular ions' of thiols and alcohols in CIMS.

Published
2000

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