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1. Stereoselective synthesis of photoreactive peptidomimetic gama-secretase inhibitors

Author

Jiong Chun, Ye Ingrid Yin, Guangli Yang, Leonid Tarassishin, and Yue-Ming Li

Subjects
Chemical reactions -- Research, Platinum compounds -- Chemical properties, Peptides -- Chemical properties, Biological sciences, Chemistry
Abstract

The first asymmetric synthesis of novel, potent photoreactive gama-secretase inhibitors is reported. Protected benzophenone intermediate is prepared through an aldol-elimination reaction followed by a PtO2-catalyzed asymmetric hydrogenation.

Published
2004

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