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1. 3D Porous metal-organic framework exhibiting selective adsorption pf water over organic solvents

Author

Jin-Zhong Gu, Wen-Guan Lu, Long Jiang, Hong-Cai Zhou, and Tong-Bu Lu

Subjects
Adsorption -- Analysis, Hydration (Chemistry) -- Analysis, Organometallic compounds -- Structure, Organometallic compounds -- Optical properties, Organometallic compounds -- Magnetic properties, X-ray crystallography -- Observations, Chemistry
Abstract

A three dimensional (3D) porous metal-organic framework (MOF) with one dimensional (1D) open channels is constructed hydrothermally by using [Zn.sup.II] and a rigid planar ligand 1D[C.sup.3-] (imidazole-4,5-dicarboxylate). The MOF has adsorbed water selectively over organic solvents and it has represented a rare example with open channels that form/collapse reversibly upon hydration/dehydration.

Published
2007

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