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3 results on '"Imaz, Inhar"'

1. Amino acid based metal-organic nanofibers

Author

Imaz, Inhar, Rubio-Martinez, Marta, Saletra, Wojciech J., Amabilino, David B., and Maspoch, Daniel

Subjects
Amino acids -- Chemical properties, Chirality -- Analysis, Organometallic compounds -- Structure, Organometallic compounds -- Chemical properties, Chemistry
Abstract

Long chiral metal-organic nanofibers are grown by using conventional coordination chemistry and biologically derived components in a diffusion controlled growth procedure.

Published
2009

2. A new hexaferrocene complex with a [[[Me.sub.3]([mu.sub.3]-O)].sup.7+] core

Author

Mereacre, Valeriu, Nakano, Motohiro, Gomez-Segura, Jordi, Imaz, Inhar, Ruiz-Molina, Daniel, and Jaitner, Peter

Subjects
Methane -- Electric properties, Nitrogen compounds -- Electric properties, Carbon compounds -- Electric properties, X-rays -- Diffraction, X-rays -- Research, Chemistry
Abstract

The new hexaferrocene complex, [[Fe.sub.3.sup.III.III.III]O[(FeCOO).sub.6][(DMF).sub.3]].Cl[O.sub.4] (DMF = N,N-dimethylformamide), is synthesized and characterized by X-ray diffraction. The cyclic voltammogram of this complex has confirmed its redox activity associated with the presence of ferrocene units, with very small or negligible electronic interactions between them.

Published
2006

3. Evidence for increased exchange interactions with 5d compared to 4d metal ions: Experimental and theoretical insights into the ferromagnetic interactions of a series of trinuclear [[{M[(CN).sub.8]}.sup.3-]/[Ni.sup.II]] compounds (M = [Mo.sup.V] or [W.sup.V])

Author

Visinescu, Diana, Desplanches, Cedric, Imaz, Inhar, Bahers, Vincent, Pradhan, Rabindranath, Villamena, Frederick A., Guionneau, Philippe, and Sutter, Jean-Pascal

Subjects
Metal ions -- Electric properties, Ferromagnetism -- Analysis, Molybdenum compounds -- Electric properties, Chemistry
Abstract

The qualitative and quantitative insights into the exchange interaction involving 4d or 5d metal ions in cyano-bridged complexes are reported. Both the experimental and the calculated behaviors have revealed a noticeable difference between the Mo and the W derivatives that are correlated to the spin densities transferred by these metal ions onto the bridging cyano ligands.

Published
2006

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