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PV technology offers a sustainable solution to the increased energy demand especially based on mono- and polycrystalline silicon solar cells. The most recent years have allowed the successful development of perovskite and tandem heterojunction Si-based solar cells with energy conversion efficiency over 28%. The metal oxide heterojunction tandem solar cells have a great potential application in the future photovoltaic field. Cu2O (band gap of 2.07 eV) and ZnO (band gap of 3.3 eV) are very good materials for solar cells and their features completely justify the high interest for the research of tandem heterojunction based on them. This review article analyzes high-efficiency silicon-based tandem heterojunction solar cells (HTSCs) with metal oxides. It is structured on six chapters dedicated to four main issues: (1) fabrication techniques and device architecture; (2) characterization of Cu2O and ZnO layers; (3) numerical modelling of Cu2O/ZnO HTSC; (4) stability and reliability approach. The device architecture establishes that the HTSC is constituted from two sub-cells: ZnO/Cu2O and c-Si. The four terminal tandem solar cells contribute to the increased current density and conversion efficiency. Cu2O and ZnO materials are defined as promising candidates for high-efficiency solar devices due to the morphological, structural, and optical characterization emphasized. Based on multiscale modelling of PV technology, the electrical and optical numerical modelling of the two sub-cells of HTSC are presented. At the same time, the thermal stability and reliability approach are essential and needed for an optimum operation of HTSC, concerning the cell lifetime and degradation degree. Further progress on flexible HTSC could determine that such advanced solar devices would become commercially sustainable in the near future.

Abstract As promising candidates for solar cell and photodetection applications in the range 1.0–1.16 eV, the growth of dilute nitride GaAsSbN alloys lattice matched to GaAs is studied. With this aim, we have taken advantage of the temperature gradient in the molecular beam epitaxy reactor to analyse the impact of temperature on the incorporation of Sb and N species according to the wafer radial composition gradients. The results from the combination of X-ray diffraction (XRD) and energy-dispersive X-ray spectroscopies (EDS) show an opposite rate of incorporation between N and Sb as we move away from the centre of the wafer. A competitive behaviour between Sb and N in order to occupy the group-V position is observed that depends on the growth rate and the substrate temperature. The optical properties obtained by photoluminescence are discussed in the frame of the double-band anticrossing model. The growth conditions define two sets of different parameters for the energy level and the coupling interaction potential of N, which must be taken into account in the search for the optimum compositions 1–1.15-eV photonic applications.

The diffraction efficiencies of modified sinusoidal and blazed gratings are investigated in the high spatial frequency regime by rigorous numerical methods and are compared to experimentally manufactured gratings. The introduced modifications take actual technological induced variations of the profile geometries, such as specific corner rounding, into account. The high spatial frequency regime (resonance regime) is characterized by a local grating period, g, to wavelength, λ, ratio of 0.7 ≤ g/λ ≤ 4 and shows an important relevance for applications in spectroscopy and diffractive imaging. The investigations are carried out for both reflection on metallic surfaces and transmission of dielectric structures over a broad range of grating periods and incidence angles. It was found that near the grating resonance, the more simply producible sine gratings can compete in diffraction efficiency with sawtooth structures. Additionally, for certain application conditions, holographically modified sine structures achieve higher efficiencies than the ideal sine profile. It is also shown that holographic sinusoidal-like profiles measured by AFM can be fitted to a super-Gaussian shape, which is then used to inversely reconstruct the structure profiles from efficiency data.