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Separating stars enriched in the s- and r-processes of nucleosynthesis is usually achieved by analyzing the element ratios of s-process elements (like Ba or La) to r-process elements (like Eu). The situation becomes more complex when analyzing CEMP-rs stars, which are carbon-enriched metal-poor objects enriched in a mixture of s- and r-elements. These objects, possibly resulting from the i-process of nucleosynthesis, are notoriously difficult to classify based on elemental ratios. Recent theoretical studies have outlined, however, that the s-, i-, and r-processes produce distinct isotopic mixtures. Here, we propose to analyze a sample of stars known to be enriched in s, r, or r + s elements and to determine the odd-to-even isotopic ratio measured on atomic lines of barium, in order to validate or disprove their assignation.

The foundations of stellar nucleosynthesis have been established more than 70 years ago. Since then, much progress has been made, both on the theoretical side, with stellar evolution and nucleosynthesis models of increasing complexity, using more and more accurate nuclear data, and on the observational side, with the number of analyzed stars growing tremendously. In between, the complex machinery of abundance determination has been refined, taking into account model atmospheres of non-solar chemical composition, three-dimensional, non-LTE (non-local thermodynamic equilibrium) effects, and a growing number of atomic and molecular data. Neutron-capture nucleosynthesis processes, and in particular the s-process, have been scrutinized in various types of evolved stars, among which asymptotic giant branch stars, carbon-enhanced metal-poor stars and post-AGB stars. We review here some of the successes of the comparison between models and abundance measurements of heavy elements in stars, including in binaries, and outline some remaining unexplained features.