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Extracellular polymeric substances (EPS) are a critical influencing factor in sludge dewatering. Disrupting such EPS contributes to the release of bound water in sludge, enhancing the sludge dewatering performance. In This study, quaternized straw fibers that are destructive to the EPS structure and components in active sludge were prepared useing heterogeneous free radical graft polymerization. Straw fibers, dimethyl diallyl ammonium chloride (DMDAAC), ammonium persulfate (APS), and acrylamide (AM) were taken as the substrate, grafting monomer, catalyst, and cross-linking agent, respectively.The optimal processing conditions determined for the DMDAAC-based quaternization and graft modification of straw fibers were as follows: reaction temperature of 60 °C, reaction time of 5 h, 0.100 g of catalyst APS dosage per gram of straw, and 3.000 ml of DMDAAC dosage per gram of straw. The optimal processing conditions yielded 1.335 g of modified straw fibers per gram of straw, 33.67% grafting rate, and 31.70% substitution of the quaternary ammonium groups. The capillary suction time (CST) was conditioned from 243.3 ± 22.6 s in the original sludge to 134.5 ± 34.45 s. The specific resistance to filtration (SRF) was reduced from 8.82 ± 0.51 × 1012 m/kg in the original sludge to 4.59 ± 0.23 × 1012 m/kg. HIGHLIGHTS Modification of straw fiber by quaternary amination grafting can improve sludge dewatering performance.; Modified straw fiber improves sludge dewatering capacity by absorbing EPS.; Modified straw fiber can damage the stability of sludge floc.; Modified straw fiber provides a skeleton structure in the sludge for water removal from the sludge.;

In order to improve the dewatering performance of waste activated sludge，iron-based sludge biochar（Iron-SBC） activating persulfate（PDS） was used to treat sludge. The effects of PDS dosage，Iron-SBC dosage，reaction time，reaction temperature and initial pH on waste activated sludge dewatering efficiency were studied，and the mechanism was also analyzed. The results showed that when the temperature was 65 ℃，the dosage of PDS per unit TSS was 150 mg/g，the dosage of Iron-SBC per unit TSS was 350 mg/g，the initial pH was 6.68，after being conditioned by Iron-SBC/PDS for 20 minutes，the sludge capillary water absorption time，sludge specific resistance and sludge cake moisture content decreased to 8.4 s，5.4×1012 m/kg and 73.5%，respectively. The mechanism analysis indicated that oxidation reaction occurred during the process. The originally tight and flat sludge flocs and extracellular polymers were cracked and the bound water was released. The highly hydrophilic tightly bound extracellular polymeric substances（TB-EPS） in sludge were transformed into loosely bound extracellular polymeric substances（LB-EPS） and soluble extracellular polymeric substances（S-EPS），and the proteins which were unfavorable to sludge dewatering were oxidized and degraded. The decrease of TB-EPS and neutralization of positive iron ions increased the Zeta potential value. Iron-SBC with rigid structure reduced the compressibility coefficient of sludge cake. At the same time，under the flocculation of Fe3+，the fractal dimension of sludge became larger. Under the coupling action of “oxidation-skeleton construction”，the waste activated sludge deep dewatering was realized.

The reclaimed water of municipal sewage plant after advanced treatment in a power plant is used as makeup of circulating water system. Due to the problems in the advanced treatment system of reclaimed water，such as the output of the mechanical acceleration clarification tank failing to reach the designed value，poor effluent quality，the sludge dewatering system failing to operate normally，the feeding blockage of the lime system，the widespread leakage of the dosing device and no chain control，etc.，the requirements for normal use of reclaimed water in the power plant can’t be met. After the diagnosis of the problems，the optimization scheme was put forward. The internal structure of the mechanical acceleration clarification tank and the bottom sludge discharge pipeline system were modified respectively to restore the processing capacity of the mechanical acceleration clarification tank and meet the requirements of the water required of the system. The sludge dewatering system was modified to restore the sludge dewatering unit. The lime dosing system was modified to improve the problems of lime dosing and material blockage then restored the stable operation of the lime system. After optimization and transformation，the output of the clarification tank was improved，and the effluent quality of the system was optimized，effectively ensuring the normal operation of the deep treatment system for recycled water and the safety of water use in the power plant.

Activated sludge process is one of the most widely used processes for wastewater biological treatment. As the main by-product of activated sludge process，sludge with the high moisture content easily results in various problems such as the difficult transportation，high cost of resource utilization，and low calorific value. Therefore，it is necessary to conduct the sludge dewatering. Flocculation is widely used in sludge dewatering due to its unique advantages including simple operation，fast reaction rate，extensive application scope and excellent dewatering performance. The composition，advantages and disadvantages，and related flocculation mechanisms of various flocculants are introduced in detail. Subsequently，the preparation strategies of various flocculants and their application in sludge dewatering are systematically summarized. Finally，the outlooks of various flocculants on sludge dewatering are presented in order to provide a reference for future research on the application of flocculation technology on sludge dewatering.

Using electrolytic zero-valent iron-activated sodium hypochlorite (EZVI-NaClO) to pretreat sludge, the capillary suction time (CST) was utilized to evaluate sludge dewaterability. Ammonia nitrogen (NH4-N), dissolved phosphorus, and total phosphorus in the supernatant were used to analyze sludge disintegration. This approach aimed to evaluate the effectiveness of the pretreatment process and its impact on the sludge composition. The migration and transformation of extracellular polymeric substances (EPS), including dissolved EPS (S-EPS), loosely boundEPS, and tightly bound-EPS (TB-EPS), were analyzed by detecting protein and polysaccharide concentrations and three-dimensional fluorescence excitation-emission spectroscopy (3D-EEM). The sludge particle properties, including sludge viscosity and particle size, were also analyzed. The results suggested that the optimal pH value, NaClO dosage, current, and reaction time were 2, 100 mg/gDS (dry sludge), 0.2A, and 30 min, respectively, with a CST reduction of 43%. Protein and polysaccharide contents in TB-EPS were significantly reduced in the EZVI-NaClO group. Conversely, protein and polysaccharides contents in S-EPS increased, suggesting that EZVI-NaClO treatment could disrupt the EPS. Besides, the viscosity of the treated sludge decreased from 195.4 to 54.9 mPa·S, indicating that sludge fluidity became better. ZEVI-NaClO could enhance sludge dewaterability by destructing protein and polysaccharide structure and improving sludge hydrophobicity. HIGHLIGHTS Electrolytic zero-valent iron-activated sodium hypochlorite (EZVI-NaClO)-modified extracellular polymeric substance (EPS) extracted from WAS.; EZVI-NaClO can reduce O = C-NH- that affects protein strength and stiffness.; EZVI-NaClO enhances the flocculation and hydrophobicity of EPS.;

Abstract This research was carried out to evaluate the effects of different dosages (1.85–4.44 g kg−1 Ts−1) of three cationic polyelectrolytes with charge densities (CD) of 20%, 40%, and 60% on the dewatering properties of an aerobically digested sludge. The sludge was collected from the sludge processing line in a wastewater treatment plant in the city of Mashhad, Iran (MWWTP). To assess the sludge dewatering properties, parameters such as specific resistance to filtration, sludge cluster geometry, filtration rate, and filtrate turbidity and volume were measured. The experimental results were then compared with the effects of a reference polyelectrolyte that was used in the conditioning of the sludge in that treatment plant. The results indicated that the sludge samples treated with the polyelectrolyte of the highest CD matched better dewatering performance than the samples conditioned with the other two polyelectrolytes. This polyelectrolyte (60%CD) presented its best effects at the dosage of 4.07 g kg−1 Ts−1. With this dosage, its performance was similar to the performance of the reference polyelectrolyte at the dosage of 4.44 g kg−1 Ts−1.

This article presents the experience in the field of using ultrasonication as a pre-treatment method of SS. On the basis of a review of the literature, the effect of pretreatment of sewage sludge by US with different parameters on SS quality parameters and energy effects of the process was presented. The status of commercial applications of US as a sewage sludge pretreatment method was also presented, using the example of wastewater treatment plants in Poland. It was shown that the effective management of SS is an important technological and environmental problem in many wastewater treatment plants. Therefore, new strategies for dealing with this by-product are constantly being sought. In large wastewater treatment plants, the dominant method of stabilizing SS is AD. However, due to the characteristics of SS, it shows low efficiency. Among the numerous strategies, US is one of the new technologies that is finding several full-scale implementations. Its application allows for solubilization of organic matter, disruption of microbial cells, as well as SS floc description and enzyme release. A number of benefits can be obtained as a result of these developments, including increased methane production, improved reaction kinetics and removal of organic matter, as well as enhanced settability and dewatering of SS, thus contributing to savings in wastewater treatment plants.

Enhanced dewatering remains a major challenge in sludge disposal. In this paper, a thermal solidification treatment under low temperatures was first and successfully employed to improve the dewaterability of sludge from water-based ink wastewater. A total of 95.1% of dewatering ratio, 36.6% of moisture content, and 91.9% of sludge volume reduction could be acquired at 75 °C and 30 min setting time by the reported approach. The DSC results indicated that a large amount of bound water trapped in sludge could be released into the bulk solution to become free water after thermal solidification treatment. The bound water content of sludge can be reduced from 3.40 to 0.20 g g−1 dry solid. The reported thermal solidification treatment is a thermophysical process that does not involve the solubilization of solid substrates and does not cause an increase in the COD value of dehydrated water. The obtained sludge after cooling was a clot of compacted cake with a uniform coralline-like structure. The softening and shrinking of acrylic resin within the sludge during heating contributed to the formation of compacted cake and thus enhanced the dewaterability. This study offers an economical and efficient treatment of sludge for the water-based ink printing industry.

Efficient and sustainable sludge management is a significant environmental and health challenge. Sludge-treatment reed beds (STRBs) are widely recognized as a cost-effective, highly efficient, and environmentally friendly solution for sludge treatment and dewatering. This study investigated the bacterial community composition and diversity in pilot-scale STRBs operating at different sludge loading rates (75, 100, and 125 ​kg ​m2 year−1). 16S rRNA V4 DNA sequencing was used to assess the diversity of the bacterial communities within the sludge samples. The relative abundance of prokaryotic taxa was affected by all treatments. As the sludge loads increased, the Shannon entropy and evenness diversity also increased for the STRBs and unplanted beds. Interestingly, the presence of reeds resulted in significantly lower Shannon and evenness indices than unplanted beds, regardless of the sludge. Additionally, the correlation network analysis revealed distinct microbial clusters with distinct responses to reeds and sludge loads. Principal component analysis evidenced an association between cluster 5 and organic matter decomposition, primarily at higher sludge doses, while clusters 4 and 6 were related to sludge decomposition at lower doses. Additionally, cluster 4 was associated with nutrient removal. The formation of distinct microbial niches was linked to sludge stabilization and nutrient removal and was influenced by both sludge loading rates and the presence of reeds. Future research can leverage these findings to innovate pollutant removal and ecosystem services for sludge treatment, thus advancing sustainable sludge management and environmental preservation.

The decanter-centrifuge is widely used for dewatering and thickening of civil and industrial sludge. The latest generation decanters, both the bowl motors (main) and the screw (back-drive) are often driven by variable-frequency drives (VFD), with the back-drive able to recover the energy during braking. We created a decanter centrifuge energy model equipped with a braking recovery system during the sludge dewatering process, with the aim of identifying its optimal operating conditions for both energy consumption and product quality. Specific models at 15–20–25 m3 h−1 and various differentials speed (Δn) were used to derive a general model, then validated with experiments at 18–20 m3 h−1. Specific models used to identify the best operating conditions in terms of specific energy (e) and energy recovery (ERec) show that at 15–20–25 m3 h−1 the lowest energy consumptions were 1.88–1.76–1.57 kWh m−3, respectively, instead, ERec was 5.88–0.31–12.10 kW respectively, highlighting that a high recovery is not necessarily linked to an increased energy saving. The accuracy of these models was confirmed by high values of correlation coefficients R2 and very low Root Mean Square Errors (RMSE) in each case. The general model, extrapolated from the specific models, makes it possible to predict specific consumptions at different flow rates within the operating range of the decanter. This was validated with an experimental test at 18–20 m3 h−1 with R2 above 97 % and RMSE 2,59E-02 kWh m3. The dry matter content in the cake decreases when the Δn or the feed rate increases.In conclusion, the decanter centrifuge model could represent a useful tool for optimizing the sludge dehydration process.

Managing high water content sludge in wastewater treatment is crucial for sustainability. This involves a complex challenge of maximizing the removal of loosely bound extracellular polymeric substances (LB-EPS) while minimizing ultrasonic-Fenton process costs. This study introduces a novel approach to address these conflicting objectives by adopting fuzzy multi-objective optimization. This method reconciles the conflicting objectives by identifying the optimal conditions for ferrous ion (Fe2+) dosage, hydrogen peroxide (H2O2) dosage, and ultrasonication time. The optimization model incorporates empirical equations that define the effects of Fenton’s reagent and ultrasonication on LB-EPS removal, as well as considerations for material and electricity usage costs and the cumulative uncertainties associated with experimental runs. To effectively capture the trade-offs between EPS removal and process costs, the ɛ -constraint method was utilized to delineate the Pareto front. This approach significantly enhances LB-EPS removal from anaerobically digested sludge and establishes boundary limits within the Pareto front for practical application within the context of fuzzy optimization. The optimized solution derived from this innovative approach resulted in the conditions of 10 mM Fe2+dosage, 100 mM H2O2 dosage, and 10 min of ultrasonication. This configuration achieves an impressive 60.7% ± 3.7% LB-EPS removal while maintaining a cost of 26.6 USD/L and ensuring 100% overall satisfaction. This research represents a significant advancement in sludge dewatering strategies. It underscores the pivotal role of innovative decision-making approaches in advancing the field of sludge dewatering methodologies for more sustainable wastewater treatment practices.

During the dewatering process, centrate is produced, which is returned to the beginning of the technological system. The quality of the resulting centrate, and therefore the size of the returned load of pollutants, affects the demand for electricity in the process of biological wastewater treatment. The following study presents the results of centrate quality tests at five wastewater treatment plants located in Poland. The dependence between suspended solids content and ammonia and COD concentrations in the centrate was determined. It was estimated that an increase in the overall suspended solids leads to an increase in COD by about 1.15 kgCOD/kgTSS. No correlation was found between TSS concentration and ammonia. It was calculated that the complete elimination of suspended solids from the sludge would reduce the electricity consumption for all five objects by about 535 MWh/y.

This study was conducted on the feasibility of improving processes of thickening, anaerobic digestion, and sludge dewatering at wastewater treatment plants on a laboratory pilot scale, aiming to reduce polyelectrolyte consumption by 50% and replace it with chemical sludge. Parameters of Sludge Volume Index (SVI), Specific Filtration Resistance (SRF), compressibility coefficient, filtration rate, and biogas production rate were investigated. It is shown that by applying 200 mg/g of water treatment plant sludge to wastewater sludge, the compressibility coefficient was decreased by 27%, the filtration rate was increased by 70%, and SVI and SRF were decreased by 64.9% and 43.3%, respectively. Therefore, it has facilitated the sludge sedimentation and release of its free water. On the other hand, adding the sludge from a water treatment plant led to the proper access of microorganisms to micronutrients and improvement of their performance resulting in an increase of 7.77% in the total biogas production. The iron present in the digestion process caused an increase in biogas production by increasing the activity of enzymes, reducing oxidation-reduction potential, and improving the direct interspecies electrons transfer. In conclusion, adding the optimal amount of water treatment plant sludge, along with the environmental management of a meaningful portion of water and wastewater residuals, may play an important role in significantly reducing polyelectrolyte consumption and improving biogas production.

To reduce the water content and improve the incineration characteristics of sludge, rice husk and thermal hydrolysis were employed in this study. Effects of rice husk and thermal hydrolysis on the characteristics of the sludge were investigated. The results showed that synergistic thermal hydrolysis with rice husk could effectively destroy sludge particles and release more bound water. For rice husk with a particle size of 50-mesh and an additional amount of rice husk at 1:0.2, the solid content of the sludge was reduced from 17.4 to 16.2%, and the sludge particle size was reduced by 6%. Filtration time and specific resistance to filtrate (SRF) were shortened by 88.9 and 98.7%, respectively. The organic matter content of the filtration cake increased by 14%, compared with the sludge treated by thermal hydrolysis without rice husk. Furthermore, it could be shown that the most optimal conditions were rice husk of particle size 50-mesh and an additional amount of rice husk at 1:0.2, which could lead to effective thermal hydrolysis and higher organic matter content of the filtration cake. HIGHLIGHTS The optimal process of collaborative thermal hydrolysis of rice husk was selected by changing the grain size and the additional amount of rice husk.; Good drainage channels can be formed in the dehydration process of rice husk after the thermal hydrolysis of sludge to improve the efficiency of dehydration.; Rice husk combined with thermal hydrolysis can improve the organic matter content of sludge-dehydrated filter cake.;

Sludge is one of the by-products of wastewater treatment plants (WWTPs). To assist biological processes, part of the produced sludge is returned to the treatment process and the excess is removed from the treatment plant whereby it undergoes thickening and dewatering. Numerous studies have been conducted to investigate the effect of different coagulants on dewatering from sludge, but the effect of using divalent iron for this purpose has not been investigated so far. In this research, the effect of divalent and trivalent iron compounds (ferrous sulfate and ferric chloride) on the dewatering of excess sludge of the first module of the Bojnourd WWTP (Iran) has been investigated. In this regard, first, the effect of different doses of each coagulant to optimize the dewatering characteristics of sludge was investigated and then the effect of pH change by adding lime was investigated. The results showed that the addition of optimal doses of FeSO4 (0.6 and 0.4 g/l) and lime (0.664 and 1.5866 g/l) reduced the capillary suction time of sludge by 30.6 and 32.7%, respectively, while reducing the moisture content of sludge cake by 26 and 30.6%. HIGHLIGHTS A novel methodology of sludge technology.; First implementation of the new materials for sludge dewatering.;

The dewaterability of waste activated sludge (WAS) plays the key role in sludge dewatering in wastewater treatment plants. The magnetic field as a source of clean energy has been reported to be able to cause changes in sludge properties and to enhance sludge dewatering by chemical treatment. This paper focuses on the effect of pre-magnetization on the sludge dewatering performance by ozonation. The results showed that ozonation reduced the capillary suction time (CST) and water content of sludge cake (Wsc) of WAS. The CST reduced from 21.5 ​s to 12.7 ​s; and the Wsc reduced from 85.6% to 85%. However, the addition of pre-magnetization with a magnetic field did not make much improvement of the dewaterability. Further investigation on sludge properties such as EPS, TOC, particle size, and the SEM images of the treated WAS showed that the pre-magnetization prior to ozonation led to stronger oxidation and WAS particle broken, which was proofed not necessarily correlated to sludge dewaterability enhancement.

The advanced anaerobic digestion process enhances sludge resource utilization. However, thermal hydrolysis pretreatment of anaerobically digested sludge reduces dewatering efficiency due to excessive organic matter decomposition. This necessitates significant time and effort for sludge conditioning in wastewater treatment plants. Using conditioning agents can achieve high dewatering efficiency. This study investigates how the order of adding coagulants and flocculants impacts the dewatering performance of digested sludge. The results indicate that, compared to the flocculation–coagulation process with the same dosage, the coagulation–flocculation process leads to a 15–20% increase in the average particle size of digested sludge. The content of polysaccharides and proteins in S-EPS decreases by 28.8–30.8% and 10.1–11.3%, respectively. The filter cake solids content increases by 8.5%, and there is an increase in surface water channels within the flocs. This is because initially adding coagulants efficiently adsorbs small particles, forming larger aggregates that settle effectively. This promotes the breakdown of extracellular polymeric substances, releasing more bound water. Adding flocculants later bridges the aggregates, further enhancing settling and filtration performance, thereby improving sludge dewatering efficiency. These research findings contribute to a better understanding of the mechanisms of coagulant and flocculant co-conditioning for digested sludge and provide recommendations for optimizing sludge conditioning steps.

Sludge treatment and disposal processes in wastewater treatment plants account for a significant portion of the total treatment costs. One of the most expensive parts of sludge treatment is chemical conditioning. Study of the effect of process chain on the conditioning and dewaterability can effectively optimize and reduce operating costs and increase the quality of effluent sludge. This paper investigates the impact of aerobic digestion of waste sludge in Yazd wastewater treatment plant by SBR method on its dewaterability. For this purpose, the waste sludge sample of the plant was aerated in the laboratory at different residence times from 1.5 to 7 days. Then the dewaterability of the sludge was measured by two methods of Specific Resistance to Filtration (SRF) and Tests of Time of Filtration (TTF) in two cases with and without chemical conditioning with cationic polyacrylamide. The results showed that sludge aeration for up to 3 days without conditioning led to the best sludge dewaterability. The best results were obtained at 1.5 days aeration for the conditioning mode with polymer, which improved the dewaterability up to 4.5 times in the optimum polymer dosage. In this case, the polymer dosage decreased by 30% compared to the non-aerated conditioned sludge. It indicates the effect of digestion retention time on dewaterability. At the beginning of the process, the decomposition of cellular material improves the release of water from solid particles. Still, its continuation reduces the dewatering capability due to reduced particle size and conversion to colloidal materials.

The dewatering process reduces the water quantity in sludge, allowing the decrease in its volume, which facilitates its storage, transport, stabilization, and improves the post-treatment efficiency. Chemical polymers including aluminum sulphate and polyaluminum chloride were applied as flocculants in the conditioning process in order to prepare sludge for dewatering. However, these synthetic polymers may cause risks for human health, and should be substituted with ecofriendly and safe materials. These materials include plant-based flocculants, animal-based flocculants, and microbial-based flocculants. Sludge dewaterability was evaluated by considering many parameters, such as moisture content (MC), dry solids (DS), specific resistance to filtration (SRF), capillary suction time (CST), and sludge volume index (SVI). The use of microorganisms for sludge dewatering is an available option, since many strains (R. erythropolis, A. ferrooxidans, P. mirabilis, T. flavus, etc.) demonstrated their ability to produce polymers useful for dewatering sludge from various origins (chemically treated primary sludge, activated sludge, anaerobically digested sludge, etc.). For plant-based flocculants, only okra (Abelmoschus esculentus), cactus (Opuntia ficus Indica), moringa (M. oleifera), and aloe (A. vera) plants are examined for sludge dewatering. Compared to synthetic polymers, plant-based flocculants showed a viable alternative to chemicals and a step forward in green sludge treatment technology. Among the animal-based flocculants, chitosan and aminated chitosan were able to reduce the SRF (SRF reduction rate > 80%) of the anaerobically digested sludge. A new strategy using methylated hemoglobin also showed a significant enhancement in cake solid content of sludge (47%) and a decrease in sludge bound water content of 17.30%. Generally, extensive investigations are needed to explore and optimize all the related parameters (operating conditions, preparation procedure, production cost, etc.) and to choose the appropriate materials for large-scale application.

A new technology is described that enables us to completely exclude liquid discharges during production of drinking water from surface sources. The proposed described technological scheme separates the natural water into a stream of purified drinking water and dewatered sludge. The sludge moisture has a value of 80 percent. The experimental program is described to treat the natural water with nanofiltration membranes and to produce a drinking-quality water with recovery value of 0.99 and higher. Concentrate of membrane plant is mixed with the wet sludge and the reject effluent after sludge dewatering is again treated by reverse osmosis membranes and returned back to the sludge thickening tank. Results of experiments to treat reject water after sludge dewatering are presented. The use of nanofiltration membranes provides reduction in the Total Dissolved Solids content (TDS), aluminum, color and oxidation to meet drinking water standards. Experimental plots are presented that can be used to select membrane characteristics and to predict product water chemical composition at each stage of the membrane treatment scheme. Concentrate of membrane treatment plant is mixed with the wet sludge in the thickening tank. The sludge, after the thickening tank, is dewatered using either filter-press or centrifugal equipment. The reject (or fugate), after sludge dewatering, is treated by membrane facility to separate it into deionized water stream and concentrate stream. The deionized water can be mixed with the feed water or drinking water and the concentrate stream is returned back to the thickening tank. Thus, the salt balance is maintained in the thickening tank, whereby all dissolved salts and impurities that are rejected by membranes are collected in the thickening tank, and then are withdrawn together with the dewatered sludge. Based on the results of experimental data processing, balance diagrams of the sludge dehydration process with waste water purification at the membrane plant and with the addition of the membrane plant concentrate to the sludge thickener are presented, according to which all contaminants removed by the membranes are removed together with the sludge.

Mine water usually contains heavy metals and other inorganic and organic pollutants that contaminate water bodies. Reverse osmosis (RO) techniques are capable of producing purified water that meets discharge regulations. However, the problem of RO concentrate disposal and utilization is still not solved. The well-known zero liquid discharge (ZLD) process provides total concentrate utilization at the power industries but seems unreasonably expensive for the treatment of large amounts of mine water due to required chemical softening and the evaporation of concentrate. In the present article, a new approach to increase the recovery of reverse osmosis and to avoid high operational costs is demonstrated and discussed. The new technique involves radical RO concentrate flow reduction and withdrawal, together with dewatered sludge. The idea to “hide” concentrate in dewatered sludge is proposed and demonstrated during experiments. The article demonstrates results of the conducted experimental program aimed at reduction of volumes of all liquid wastes produced during mine water treatment using a new approach to concentrate it with a cascade of nanofiltration membranes and to reach a TDS value of 110–120 g per liter. The obtained concentrate is mixed with the wet sludge, which is further dewatered and withdrawn together with the dewatered sludge. Experiments are conducted that demonstrate a reduction in calcium in the concentrate due to deposition of calcium carbonate on the “seed crystals” in the circulation mode. Another distinguishing feature of the new technique is the separation of concentrate into two streams containing high concentrations of monovalent ions (sodium and ammonium chlorides) and divalent ions (calcium, magnesium and copper sulphates). Flow diagrams of the processes are presented to demonstrate the water treatment technique used to produce deionized water and two types of sludges: sludge after clarification and sludge after calcium carbonate deposition.

Municipal sludge is characterized by high organic matter content, high viscosity, and fine particles, resulting in poor dewatering performance. This article analyzes the composition and properties of municipal sludge, examines the factors affecting the dewatering performance of sludge and the mechanisms corresponding to each influencing factor, and introduces chemical conditioning in detail. Chemical conditioning includes flocculation conditioning, oxidation conditioning, acid-base conditioning, and aggregate conditioning. The principles and applications of existing sludge conditioning technologies are systematically analyzed. By comparing the advantages and disadvantages of different technologies, it is pointed out that the key to developing sludge conditioning technology lies in developing a more appropriate combination of the sludge conditioning and dewatering process according to the sludge quality of different municipal wastewater treatment plants, taking into account their local environment, input costs, subsequent sludge disposal methods, and other factors, and further optimizing the sludge dewatering process by developing new efficient and environmentally friendly sludge conditioning agents.

Introduction and Purpose: Production of large quantities of sludge is a major problem in wastewater treatment plants, which necessitates adopting proper economical and environmental approaches for its management and treatment. The aim of this study was to investigate the effect of polyacrylamide polymer, modified with aluminum oxide nanoparticles, on dewatering of sludge produced from municipal wastewater treatment. Methods: In-vitro preparation and dewatering of sludge by combination of polyacrylamide activated with aluminum oxide nanoparticles were carried out in two main steps of determination of pH and optimal dose of activated coagulant aid. For measuring sludge dewatering capability, tests of time of filtration (TTF), sludge cake moisture content, turbidity, and total suspended solids of effluent from sludge cake filtration were evaluated. Results: Modified coagulant aid with aluminum oxide nanoparticles in optimum pH and concentrations of 5 and 4 mg/l, respectively, had the best efficiency and was more suitable than a primary coagulant without any modification. The levelsof TTF, sludge cake moisture, turbidity, and total suspended solids of effluent reduced 24.4%, 11.2%, 57.2%, and 58%, respectively, in comparison with the control group. Conclusion: The results showed that polyacrylamide coagulant aid modified with aluminum oxide nanoparticles could be appropriate for sludge dewatering. Therefore, it can be employed as an alternative coagulant aid for sludge dewatering.

Sludge treatment reed beds (STRBs) are an established sludge treatment technology with multiple environmental and economic advantages in dewatering sludge generated during domestic wastewater treatment. However, little is reported regarding their appropriateness and efficiency for the treatment of sludge produced during industrial wastewater treatment and from water works. These sludge types may have significantly different quality characteristics than typical domestic sludge and may contain constituents that could affect their dewaterability. Therefore, the dewatering of these industrial sludge types is usually tested in small-scale pilot STRBs before the construction of full-scale systems. This paper presents and summarizes the state-of-the-art experience from existing pilot and full-scale STRB systems from various countries and climates treating sludge from various industrial sources, evaluates the suitability and the advantages of this sustainable treatment technology, and proposes the required dimensioning for efficient full-scale STRB operation and performance.

The design and upgrade of sludge treatment systems generally depend on the decision made regarding the appropriate system from among the options available. The selection process has become increasingly important and complex due to recent technological developments that have led to increased diversity in the available options which offer a wide variety of capabilities. The multi-criteria decision making method is one of the techniques recently developed which takes into account all the criteria involved in the decision making process. The Ghods Town WWTP in the west of Tehran located in the vicinity of residential areas has given rise to claims by citizens due to the odors emitted by the sludge sand drying bed, which justifies the replacement of the present sludge dewatering system. For this purpose, the multi-criteria decision making method based on the fuzzy synthetic evaluation method was used to identify the optimal sludge dewatering system appropriate for the WWTP under consideration. Furthermore, weighting of the subjective (social, environmental, and administrative) criteria was accomplished using the analytical hierarchy process and the objective (i.e., economic) criteria were weighted using the entropy concept. In this method, the triangular fuzzy membership function was also used to take into account the uncertainty associated with each of the decision making parameters. Based on the results obtained, the belt filter press dewatering system and the filter press were identified as the preferred solutions.

Sludge disposal is becoming an issue at the municipal solid waste incinerator (MSWI), especially for environmental and economic reasons. This paper describes a case study of the optimization of the sludge management (SM) system at the MSWI in the Czech Republic. The original concept of SM at MSWI was designed as waste-free. However, the present operation indicates that there is a need to carry out regular extraction and disposal of sludge settling at the bottom ash tank and the bottom of the retention basin. The current status of SM causes problems not only in terms of operation but it also entails significant financial costs given the necessary regular cleaning of tanks. The aim of the applied research presented in this paper is SM optimization by a mobile sludge dewatering (DW) press unit with optimal polymer combination for DW.

Cationic polyacrylamides have been employed widely to improve sludge dewatering performance, but the cationic units are randomly distributed in the molecular chain, which restricts the further enhancement of dewaterability. Common template technology to prepare block copolymers requiring a huge number of templates reduces the polymer purity and molecular weight. Here, we adopted the surface-active monomer benzyl dimethyl 2-(methacryloyloxy)ethyl ammonium chloride (BDMDAC) to synthesize cationic microblocky polyacrylamide initiated by ultrasound. The reactivity ratio of monomers suggested that novel cationic monomer BDMDAC had higher homopolymerization ability, and was thus more prone to forming a microblock structure. The statistical analysis of sequence-length distribution indicated that the number and length of cationic segments increased in the PAB molecules. In addition, the characteristic results of Fourier transform infrared (FTIR), proton nuclear magnetic resonance (1H NMR), and thermogravimetric analysis (TGA) provided evidence for the synthesis of copolymer with cationic microblocks. Finally, the results of dewatering tests demonstrated that sludge dewaterability was greatly improved by adding the synthesized novel flocculants, and the sludge-specific resistance to filtration, filter cake moisture content and residual turbidity all reached a minimum (68.7%, 5.4 × 1012 m·kg−1, and 2.6 NTU, respectively) at 40 mg·L−1. The PAB flocs were large, compact, difficult to break, and easy to regrow. Furthermore, PAB was more effective in the removal of protein from soluble extracellular polymeric substances (SEPSs). In summary, this study provides a novel solution to synthesize cationic microblock polyacrylamide for improving sludge dewatering.

Sludge Treatment Reed Beds (STRBs) are widely used in Northern Europe to dewater and mineralize surplus sludge from activated sludge systems used to treat urban domestic sewage. STRBs are low-technology, energy-efficient, and do not require addition of chemicals. They dewater and stabilize the sludge and produce a final product that can be safely used as a fertilizer for agricultural crops. Long-term sludge reduction takes place in the reed beds due to dewatering and mineralization of the organic matter in the sludge. Although, in theory, a simple technique relying largely on natural processes, experience has shown that it is very important to understand and respect the basic design and operation requirements of STRBs. This paper describes the basic design and operation requirements of STRBs, with special focus on pivotal requirements to respect in order to secure proper functioning. Also, the paper summarizes performance experience concerning final dry matter content, degree of mineralization, emission of greenhouse gases, and degradation of micro-pollutants in STRBs. There are still a number of outstanding issues that are not fully understood, particularly in relation to the importance of the sludge quality for the dewatering in an STRB. Therefore, extreme care should be taken when attempting to extrapolate the use of STRBs to applications and regions outside of their ‘normal’ and documented area of application.