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The Amazon Basin is the largest on the planet, and its aquatic ecosystems affect and are affected by the Earth’s processes. Specifically, Amazon aquatic ecosystems have been subjected to severe anthropogenic impacts due to deforestation, mining, dam construction, and widespread agribusiness expansion. Therefore, the monitoring of these impacts has become crucial for conservation plans and environmental legislation enforcement. However, its continental dimensions, the high variability of Amazonian water mass constituents, and cloud cover frequency impose a challenge for developing accurate satellite algorithms for water quality retrieval such as chlorophyll-a concentration (Chl-a), which is a proxy for the trophic state. This study presents the first application of the hybrid semi-analytical algorithm (HSAA) for Chl-a retrieval using a Sentinel-3 OLCI sensor over five Amazonian floodplain lakes. Inherent and apparent optical properties (IOPs and AOPs), as well as limnological data, were collected at 94 sampling stations during four field campaigns along hydrological years spanning from 2015 to 2017 and used to parameterize the hybrid SAA to retrieve Chl-a in highly turbid Amazonian waters. We implemented a re-parametrizing approach, called the generalized stacked constraints model to the Amazonian waters (GSCMLAFW), and used it to decompose the total absorption αt(λ) into the absorption coefficients of detritus, CDOM, and phytoplankton (αphy(λ)). The estimated GSCMLAFWαphy(λ) achieved errors lower than 24% at the visible bands and 70% at NIR. The performance of HSAA-based Chl-a retrieval was validated with in situ measurements of Chl-a concentration, and then it was compared to literature Chl-a algorithms. The results showed a smaller mean absolute percentage error (MAPE) for HSAA Chl-a retrieval (36.93%) than empirical Rrs models (73.39%) using a 3-band algorithm, which confirms the better performance of the semi-analytical approach. Last, the calibrated HSAA model was used to estimate the Chl-a concentration in OLCI images acquired during 2017 and 2019 field campaigns, and the results demonstrated reasonable errors (MAPE = 57%) and indicated the potential of OLCI bands for Chl-a estimation. Therefore, the outcomes of this study support the advance of semi-analytical models in highly turbid waters and highlight the importance of re-parameterization with GSCM and the applicability of HSAA in Sentinel-3 OLCI data.

The diffuse attenuation coefficient of downwelling irradiance (Kd) is an essential parameter for inland waters research by remotely sensing the water transparency. Lately, Kd semi-analytical algorithms substituted the empirical algorithms widely employed. The purpose of this research was to reparametrize a semi-analytical algorithm to estimate Kd and then apply it to a Sentinel-2 MSI time-series (2017–2019) for the Três Marias reservoir, Brazil. The results for the Kd semi-analytical reparametrization achieved good accuracies, reaching mean absolute percentage errors (MAPE) for bands B2, B3 and B4 (492, 560 and 665 nm), lower than 21% when derived from in-situ remote sensing reflectance (Rrs), while for MSI Data, a derived MAPE of 12% and 38% for B2 and B3, respectively. After the application of the algorithm to Sentinel-2 images time-series, seasonal patterns were observed in the results, showing high Kd values at 492 nm during the rainy periods, mainly in the tributary mouths, possibly due to an increase in the surface runoff and inflows and outflow rates in the reservoir watershed.

Remote sensing imagery are fundamental to increasing the knowledge about sediment dynamics in the middle-lower Amazon floodplains. Moreover, they can help to understand both how climate change and how land use and land cover changes impact the sediment exchange between the Amazon River and floodplain lakes in this important and complex ecosystem. This study investigates the suitability of Landsat-8 and Sentinel-2 spectral characteristics in retrieving total (TSS) and inorganic (TSI) suspended sediments on a set of Amazon floodplain lakes in the middle-lower Amazon basin using in situ Remote Sensing Reflectance (Rrs) measurements to simulate Landsat 8/OLI (Operational Land Imager) and Sentinel 2/MSI (Multispectral Instrument) bands and to calibrate/validate several TSS and TSI empirical algorithms. The calibration was based on the Monte Carlo Simulation carried out for the following datasets: (1) All-Dataset, consisting of all the data acquired during four field campaigns at five lakes spread over the lower Amazon floodplain (n = 94); (2) Campaign-Dataset including samples acquired in a specific hydrograph phase (season) in all lakes. As sample size varied from one season to the other, n varied from 18 to 31; (3) Lake-Dataset including samples acquired in all seasons at a given lake with n also varying from 17 to 67 for each lake. The calibrated models were, then, applied to OLI and MSI scenes acquired in August 2017. The performance of three atmospheric correction algorithms was also assessed for both OLI (6S, ACOLITE, and L8SR) and MSI (6S, ACOLITE, and Sen2Cor) images. The impact of glint correction on atmosphere-corrected image performance was assessed against in situ glint-corrected Rrs measurements. After glint correction, the L8SR and 6S atmospheric correction performed better with the OLI and MSI sensors, respectively (Mean Absolute Percentage Error (MAPE) = 16.68% and 14.38%) considering the entire set of bands. However, for a given single band, different methods have different performances. The validated TSI and TSS satellite estimates showed that both in situ TSI and TSS algorithms provided reliable estimates, having the best results for the green OLI band (561 nm) and MSI red-edge band (705 nm) (MAPE < 21%). Moreover, the findings indicate that the OLI and MSI models provided similar errors, which support the use of both sensors as a virtual constellation for the TSS and TSI estimate over an Amazon floodplain. These results demonstrate the applicability of the calibration/validation techniques developed for the empirical modeling of suspended sediments in lower Amazon floodplain lakes using medium-resolution sensors.