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A novel fiber-optic distributed temperature sensing instrument, the Fiber-optic Laser Operated Atmospheric Temperature Sensor (FLOATS), was developed for continuous in situ profiling of the atmosphere up to 2 km below constant-altitude scientific balloons. The temperature-sensing system uses a suspended fiber-optic cable and temperature-dependent scattering of pulsed laser light in the Raman regime to retrieve continuous 3 m vertical-resolution profiles at a minimum sampling period of 20 s. FLOATS was designed for operation aboard drifting super-pressure balloons in the tropical tropopause layer at altitudes around 18 km as part of the Stratéole 2 campaign. A short test flight of the system was conducted from Laramie, Wyoming, in January 2021 to check the optical, electrical, and mechanical systems at altitude and to validate a four-reference temperature calibration procedure with a fiber-optic deployment length of 1170 m. During the 4 h flight aboard a vented balloon, FLOATS retrieved temperature profiles during ascent and while at a float altitude of about 19 km. The FLOATS retrievals provided differences of less than 1.0 ∘C compared to a commercial radiosonde aboard the flight payload during ascent. At float altitude, a comparison of optical length and GPS position at the bottom of the fiber-optic revealed little to no curvature in the fiber-optic cable, suggesting that the position of any distributed temperature measurement can be effectively modeled. Comparisons of the distributed temperature retrievals to the reference temperature sensors show strong agreement with root-mean-square-error values less than 0.4 ∘C. The instrument also demonstrated good agreement with nearby meteorological observations and COSMIC-2 satellite profiles. Observations of temperature and wind perturbations compared to the nearby radiosounding profiles provide evidence of inertial gravity wave activity during the test flight. Spectral analysis of the observed temperature perturbations shows that FLOATS is an effective and pioneering tool for the investigation of small-scale gravity waves in the upper troposphere and lower stratosphere.

The tropical tropopause layer (TTL; 14–18.5 km) is the gateway for most air entering the stratosphere, and therefore processes within this layer have an outsized influence in determining global stratospheric ozone and water vapor concentrations. Despite the importance of this layer there are few in situ measurements with the necessary detail to resolve the fine-scale processes within this region. Here, we introduce a novel platform for high-resolution in situ profiling that lowers and retracts a suspended instrument package beneath drifting long-duration balloons in the tropics. During a 100 d circumtropical flight, the instrument collected over a hundred 2 km profiles of temperature, water vapor, and aerosol at 1 m resolution, yielding unprecedented geographic sampling and vertical resolution. The instrument system integrates proven sensors for water vapor, temperature, pressure, and cloud and aerosol particles with an innovative mechanical reeling and control system. A technical evaluation of the system performance demonstrated the feasibility of this new measurement platform for future missions with minor modifications. Six instruments planned for two upcoming field campaigns are expected to provide over 4000 profiles through the TTL, quadrupling the number of high-resolution aircraft and balloon profiles collected to date. These and future measurements will provide the necessary resolution to diagnose the importance of competing mechanisms for the transport of water vapor across the TTL.

A fundamental understanding of the processes that control Antarctic aerosols is necessary in determining the aerosol impacts on climate-relevant processes from Antarctic ice cores to clouds. The first in situ observational online composition measurements by an aerosol mass spectrometer (AMS) of Antarctic aerosols were only recently performed during the Two-Season Ozone Depletion and Interaction with Aerosols Campaign (2ODIAC). 2ODIAC was deployed to sea ice on the Ross Sea near McMurdo Station over two field seasons: austral spring–summer 2014 and winter–spring 2015. The results presented here focus on the overall trends in aerosol composition primarily as functions of air masses and local meteorological conditions. The results suggest that the impact of long-range air mass back trajectories on either the absolute or relative concentrations of the aerosol constituents measured by (and inferred from) an AMS at a coastal location is small relative to the impact of local meteorology. However, when the data are parsed by wind speed, two observations become clear. First, a critical wind speed is required to loft snow from the surface, which, in turn, increases particle counts in all measured size bins. Second, elevated wind speeds showed increased aerosol chloride and sodium. Further inspection of the AMS data shows that the increased chloride concentrations have more of a fast-vaporizing nature than chloride measured at low wind speed. Also presented are the Cl : Na ratios of snow samples and aerosol filter samples, as measured by ion chromatography, as well as non-chloride aerosol constituents measured by the AMS. Additionally, submicron aerosol iodine and bromine concentrations as functions of wind speed are also presented. The results presented here suggest that aerosol composition in coastal Antarctica is a strong function of wind speed and that the mechanisms determining aerosol composition are likely linked to blowing snow.

Understanding the sources and evolution of aerosols is crucial for constraining the impacts that aerosols have on a global scale. An unanswered question in atmospheric science is the source and evolution of the Antarctic aerosol population. Previous work over the continent has primarily utilized low temporal resolution aerosol filters to answer questions about the chemical composition of Antarctic aerosols. Bulk aerosol sampling has been useful in identifying seasonal cycles in the aerosol populations, especially in populations that have been attributed to Southern Ocean phytoplankton emissions. However, real-time, high-resolution chemical composition data are necessary to identify the mechanisms and exact timing of changes in the Antarctic aerosol. The recent 2ODIAC (2-Season Ozone Depletion and Interaction with Aerosols Campaign) field campaign saw the first ever deployment of a real-time, high-resolution aerosol mass spectrometer (SP-AMS – soot particle aerosol mass spectrometer – or AMS) to the continent. Data obtained from the AMS, and a suite of other aerosol, gas-phase, and meteorological instruments, are presented here. In particular, this paper focuses on the aerosol population over coastal Antarctica and the evolution of that population in austral spring. Results indicate that there exists a sulfate mode in Antarctica that is externally mixed with a mass mode vacuum aerodynamic diameter of 250 nm. Springtime increases in sulfate aerosol are observed and attributed to biogenic sources, in agreement with previous research identifying phytoplankton activity as the source of the aerosol. Furthermore, the total Antarctic aerosol population is shown to undergo three distinct phases during the winter to summer transition. The first phase is dominated by highly aged sulfate particles comprising the majority of the aerosol mass at low wind speed. The second phase, previously unidentified, is the generation of a sub-250 nm aerosol population of unknown composition. The second phase appears as a transitional phase during the extended polar sunrise. The third phase is marked by an increased importance of biogenically derived sulfate to the total aerosol population (photolysis of dimethyl sulfate and methanesulfonic acid (DMS and MSA)). The increased importance of MSA is identified both through the direct, real-time measurement of aerosol MSA and through the use of positive matrix factorization on the sulfur-containing ions in the high-resolution mass-spectral data. Given the importance of sub-250 nm particles, the aforementioned second phase suggests that early austral spring is the season where new particle formation mechanisms are likely to have the largest contribution to the aerosol population in Antarctica.

We present ozone measurements made using state-of-the-art ultraviolet photometers onboard three long-duration stratospheric balloons launched as part of the Concordiasi campaign in austral spring 2010. Ozone loss rates calculated by matching air parcels sampled at different times and places during the polar spring are in agreement with rates previously derived from ozonesonde measurements, for the vortex average, ranging between 2 and 7 ppbv per sunlit hour or between 25 and 110 ppbv per day. However, the geographical coverage of these long-duration stratospheric balloon platforms provides new insights into the temporal and spatial patterns of ozone loss over Antarctica. Very large ozone loss rates of up to 230 ppbv per day (16 ppbv per sunlit hour) are observed for air masses that are downwind of the Antarctic Peninsula and/or over the East Antarctic region. The ozone loss rate maximum downstream of the Antarctic Peninsula region is consistent with high PSC occurrence from CALIPSO and large ClO abundances from MLS satellite observations for 12–22 September 2010, and with a chemical box model simulation using JPL 2011 kinetics with full chlorine activation.

The second-generation University of Colorado closed-path tunable-diode laser hygrometer (CLH-2) is an instrument for the airborne in situ measurement of total water content – the sum of vapor-, liquid- and ice-phase water – in clouds. This compact instrument has been flown on the NSF/NCAR Gulfstream-V aircraft in an underwing canister. It operates autonomously and uses fiber-coupled optics to eliminate the need for a supply of dry compressed gas. In operation, sample air is ingested into a forward-facing sub-isokinetic inlet; this sampling configuration results in particle concentrations that are enhanced relative to ambient and causes greater instrument sensitivity to condensed water particles. Heaters within the inlet vaporize the ingested water particles, and the resulting augmented water vapor mixing ratio is measured by absorption of near-infrared light in a single-pass optical cell. The condensed water content is then determined by subtracting the ambient water vapor content from the total and by accounting for the inertial enhancement of particles into the sampling inlet. The CLH-2 is calibrated in the laboratory over a range of pressures and water vapor mixing ratios; the uncertainty in CLH-2 condensed water retrievals is estimated to be 14.3% to 16.1% (1-σ). A vapor-only laboratory intercomparison with the first-generation University of Colorado closed-path tunable-diode laser hygrometer (CLH) shows agreement within the 2-σ uncertainty bounds of both instruments.